Statistical Downscaling Retrieval of Land Surface Temperature in an Area with Complex Landforms in the Eastern Qinling Mountains of China Based on Sentinel-2/3 Satellite Data

The study of land surface temperature(LST)is of great significance for ecosystem monitoring and ecological environmental protection in the Qinling Mountains of China.In view of the contradicting spatial and temporal resolutions in extracting LST from satellite remote sensing(RS)data,the areas with complex landforms of the Eastern Qinling Mountains were selected as the research targets to establish the correlation between the normalized difference vegetation index(NDVI)and LST.Detailed information on the surface features and temporal changes in the land surface was provided by Sentinel-2 and Sentinel-3,respectively.Based on the statistically downscaling method,the spatial scale could be decreased from 1000 m to 10 m,and LST with a Sentinel-3 temporal resolution and a 10 m spatial resolution could be retrieved.Comparing the 1 km resolution Sentinel-3 LST with the downscaling results,the 10 m LST downscaling data could accurately reflect the spatial distribution of the thermal characteristics of the original LST image.Moreover,the surface temperature data with a 10 m high spatial resolution had clear texture and obvious geomorphic features that could depict the detailed information of the ground features.The results showed that the average error was 5 K on April 16,2019 and 2.6 K on July 15,2019.The smaller error values indicated the higher vegetation coverage of summer downscaling result with the highest level on July 15.

Determination of the Neoproterozoic Shicaogou Syn-collisional Granite in the Eastern Qinling Mountains and Its Geological Implications

The Shicaogou granite has been identified as a magnesian (Fe-number=0.71-0.76), calcic to calc-alkalic (MALI=3.84-5.76) and peraluminous (ASI=1.06-1.13) granite of the syn-collisional S-type, with high SiO2(>71%), A12O3 (>13%) and Na2O+K2O (6.28%-7.33%, equal for NaO2 and K2O). Trace element and REE analyses show that the granite is rich in LILE such as of Rb, Sr, Ba and Th, and poor in HFSE like Yb, Y, Zr and Hf. Its Rb/Sr ratio is greater than 1; the contents of Nb and Ta, and the ratio of Nb/Ta as well as the REE geochemical features (e.g. REE abundance, visible fractionation of LREE and HREE and medium to pronounced negative Eu anomalies) are all similar to those of crust-origin, continent-continent syn-collisional granite. Moreover, the granite exhibits almost the same pattern as that of the typical continent-continent syn-collisional granite on the spider diagram and all samples fall within the syn-collisional granite field.The cathodoluminescence (CL) investigations have revealed that the zircon from the Shicaogou granite represents a typical magmatic product characterized by its colorless, transparent and euhedral crystals, and distinct zoning of oscillatory bands. Residual cores of irregular zircon can be found in a few enhedral grains. Trace element studies of the zircon grains, with high contents of P, Y, Hf, Th, U and REE and high ratios of Th/U, obviously positive Ce anomalies and HREE enrichment compared to LREE, also result in the same conclusion.The LA-ICP-MS U-Pb isotopic data from 24 spots of 21 zircon grains demonstrate that 20 spots in the oscillatory zone yield an average weighted 206Pb/238U age of 925±11 Ma, indicating that the Shicaogou granite was formed in the Neoproterozoic. Combined with other Neoproterozoic syn-collisional granites found in the study area, the present geochronological determination can further reveal that collision-amalgamation events could have occurred among some continental blocks in the Qinling orogenic belt during the Neoproterozoic. This in turn provides an accurate chronological constraint on the Neoproterozoic break-up and convergence in the belt.

Geochemical Characteristics and LA-ICP-MS Zircon U-Pb Dating of Amphibolites in the Songshugou Ophiolite in the Eastern Qinling

Geochemical studies on the arnphibolites in the Songshugou ophiolite from Shangnan County, Shaanxi Province demonstrate that the protolith of the amphibolites is tholeiitic. The arnphibolites can be classified into two groups according to their REE patterns and trace element features. Rocks of the first group are depleted in LREE while rocks of the second group are slightly depleted in LREE or flat from LREE to HREE without significant Eu anomaly. The first group of rocks have (La/Yb)N=0.33-0.55, (La/Sm)N= 0.45-0.65, and their La/Nb, Ce/Zr, Zr/Nb, Zr/Y and Ti/Y ratios are averaged at 1.20, 0.12, 31.02, 2.92 and 198, respectively, close to those of typical N-MORB. The second group of rocks have (La/Yb)N=0.63-0.95, (La/ Sm)N = 0.69--0.90, and their average La/Nb, Ce/Zr, Zr/Nb, Zr/Y and Ti/Y ratios are 0.82, 0.83, 1.15, 0.16, 19.00, 2.58 and 225, respectively, which lie between those of typical N-MORB and E-MORB but closer to the former. The two groups of rocks both exhibit flat patterns from Th to Yb in the highly incompatible elements spider diagram, but the first group of rocks have lower element abundances than the modern N-MORB, indicating a derivation of their mantle source from more depleted mantle source than the present N-MORB. The abundances of Th, Ta, Nb, La and Ce in the second group of rocks are slightly higher than those of the present N-MORB, and other elements, such as Hf, Zr, Sm, Ti, Y and Yb, are close to those of the N-MORB, indicating that the original magma was derived from depleted mantle but mixed with the enriched mantle. These characteristics, combined with the regional geology and previous studies, provide further evidence that the mafic-ultramafic rocks have the features of a typical ophiolite.Zircon grains from the amphibolite are generally rounded, and in most of them a distinguishable core-mantle texture is preserved as shown in the cathodoluminescence (CL) images. The core or core-mantle parts of the zircon grains are also rounded, same as those in basalts from other regions of the world. The LA-ICP-MS trace element and U-Pb isotopic analyses show that the zircon grains from the amphibolites are similar to the typical magmatic zircon in terms of their very low U and Th contents (62.36-0.10 μg/g and 78.47-0.003 μg/g, respectively). Seven pits from the core and core-mantle parts of the zircon grains yielded an average weighted 206Pb/ 238U age of 973±35 (2σ) Ma with the Th/U ratios range from 0.01 to 8.38 and mostly greater than 0.23. This age is consistent within the error range with the whole-rock Sm-Nd isochron age of 1030±46 Ma for the same kind of rocks reported by Dong et al. (1997a). In a combined analysis with the zircon positions on the CL images and the corresponding Th/U ratios, the age of 973±35 Ma is probably the formation age of tholeiite, the protolith of the Songshugou amphibolite. The geochronological determination gives further evidence that the Songshugou ophiolite was formed during the Neoproterozoic. In addition, there is one pit from the rim of a zircon grain giving a 206Pb/ 238U age of 5721199 (1σ) Ma with a Th/U ratio of 0.08. It may represent the age of the accretionary zircon in the amphibolite-facies metamorphism.

U-Pb Zircon Geochronology and Geochemistry of Granitoids in the Douling Group in the Eastern Qinling

LA-ICPMS U-Pb zircon dating of the Sanpinggou, Gangou and Fengzishan granitoids in the Douling Group of the Eastern Qinling yields ages of 760-685 Ma, which represents a strong tectono-magmatic event in the southern Qinling during the late Neoproterozoic. Geochemical data show that these intrusions have wide compositions ranging from minor gabbros through diorites to granodiorites. They are relatively enriched in LILE, poor in HFSE and strongly depleted in Nb and Ta, displaying affinities of Ⅰ-type granites formed in an active continental margin with oceanic subduction. In contrast to granitoids, gabbros and enclaves in the granitoids have higher REE abundances, relatively flat REE patterns, lower LILE, slightly higher HFSE and more depletion in Nb and Ta. All these suggest that the gabbros were formed by partial melting of the upper mantle above the subduction zone and the granitoids by the partial melting of the lower crust. Combined with regional geological data, the subduction-related granitoids in the Douling Group, together with the Tuwushan A-type granite with an age of 725 Ma and contemporaneous basic dikes in the Wudang Block, provide evidence for local subduction of oceanic basins between different blocks during the rifting in the Southern Qinling in the Neoproterozoic. Thus, the coexistences of various magmatic rocks formed in different tectonic environments indicate a complicated tectonic evolution and variety of tectonic frameworks in the Qinling area in the Neoproterozoic.

Timing of granite pegmatite-type high-purity quartz deposit in the Eastern Qinling,China:constraints from in-situ LA-ICP-MS trace analyses of quartz and monazite U–Pb dating

Eastern Qinling,China is one of the important rare metal metallogenic provinces with extensively distributed granite pegmatite dikes.The No.5 granite pegmatite intruded into the granitic gneiss of the Qinling Group,and the major minerals are quartz(39.8%),K-feldspar(18.8%),albite(36.3%),muscovite(3.4%),and garnet(1.1%).Monazite U–Pb isotopic dating indicates that the No.5 pegmatite from the Eastern Qinling was emplaced at ca.420.2±2.2 Ma,which confirms that highpurity quartz mineralization probably formed during the Early Devonian.In-situ laser ablation inductively coupled plasma mass spectrometry analysis of quartz show that quartz samples from Eastern Qinling have total trace element concentrations(Al,Ti,Sc,Li,B,Cr,Mn,and Fe)ranging from 23.2 to 52.8 ppm,slightly higher than the quartz(impurity element content from 13.4 to 25.9 ppm)of the Spruce Pine high-purity quartz deposit in western North Carolina.The No.5 pegmatite of Eastern Qinling could be defined as one high-purity quartz deposit of China.

Feldspar Lead Isotopic Composition of Granitoids from the Eastern Qinling Orogenic Belt and Their Tectonic Significance

This paper reports 48 feldspar lead isotope analyses from 27 granitic intrusions,which formed from the Late Proterozic to Mesozoic within the Eastern Qinling oregenic belt. Itis found that the granitic rocks of South Qinling are characterized by a strong block-effect anddepletion in U-Pb and Th-Pb, showing that these rocks came from the same lead isotopetectono-geochemical province, while those of North Qinling are characterized by higher U-Pband Th-Pb for Late Proterozoic to Early Paleozoic ones and lower U-Pb and Th-Pb forLate-Palaeozoic and younger ones in their feldspar lead isotopic composition. In the NorthQinling block, lead isotopic signatures reflect that the source of granitic magma had changedsince the Late Palaeozoic. Comparison of feldspar lead isotopic composition between SouthQinling and North Qinling shows that there is marked difference in lead isotopic compositionfor pre-Palaeozoic granitoids, indicating that the South Qinling and the North Qinling blocksbelong to different tectonic units, but the similarities in lead isotopic composition are quiteclear, which indicates that the South Qinling block had been welded with the North Qinlingblock and that the magma sources of both blocks were identical. The analysis provides directevidence for underplating of the continental crust of South Qinling beneath the North Qinlingblock in the continent-continent interaction stage of the Eastern Qinling oregenic belt.

Petrological Study on the Ductile Shear Zones in the Core of the Eastern Qinling Orogenic Belt in Western Henan

A series of ductile shear zones of the overthrust and strike-slip-types and related ductile shear metamorphicrocks, including tectonic melange and mylonites. were formed in the core of the Qinling orogenic belt in thecourse of the Caledonian-Indosinian ductilc and brittle-ductile reworking. The study on their petrography. va-riations in composition and conditions of formation is conducive to revealing the metamorphism-deformationhistory of the core of the Qinling orogenic belt and further to understanding the dynamic mechanism of its evo-lution.

A Comparison about Metamorphism among the Oldest-Rock Units from Orogenic Belts of Dabie,Eastern Qinling and Eastern Kunlun of Central Mountain Ranges,China

The Dabie orogen, Eastern Qinling orogen and Eastern Kunlun orogen are the major components of the Central Mountain Ranges of China and each has distinctively metamorphic processes in their oldest rock units. The Dabie orogen oldest rock units had experienced an intermediate-higher pressure, upper amphibolite to lower granulite facies metamorphism in the Indosinian intracontinental subduction collision event. The clockwise pt path, synchronous attainment of t max and p max and a segment of high slope retrograde path suggest a tectono driven rapid exhumation of the oldest rock units to upper middle crustal level following the end of the subduction collision process. The oldest rock units, also called Qinling Group, of Eastern Qinling Mountains suffered intensively collisional metamorphism at an immature plate tectonic framework during Jinningian movement about 1 000 Ma ago. The clockwise pt path with reach of t max following several hundreds of MPa decreasing from p max suggests that the denudation of the deeply burial rock units was due essentially to isostatic relaxation. During the Caledonian stage, the highly metamorphosed oldest rock units suffered from a high t thermal event in arc environment and superimposed by contact metamorphism. After thermal peaks, the rock units were exhumed in a short distance and cooled down isobarically. No regional metamorphism higher than upper greenschist facies condition since 300 Ma has been traced within exposed rocks in the eastern portion of Northern Qinling orogen. The oldest rock units in the Eastern Kunlun orogen were metamorphosed to upper amphibolite facies to lower granulite facies rocks early or during the Luliang movement (some 1 800 Ma ago). The high grade metamorphic rock units had a long resident time at the deep crustal level, and were exhumed to middle upper crustal level during the Caledonian to Hercynian tectonometamorphic events. Shallow erosion of the orogenic belt led to good preservation of the low pressure metamorphic belt.

Early Palaeozoic Evolution of the Zhen' an- Xichuan Block and the Small Qinling Multi-Island Ocean Basin

Based on studies of palaeogeography, palaeobiogeography, palaeomagnetism, geochemistry and volcanism, this paper proposes that the Zhen'an-Xichuan area was a small Early Palaeozoic block rifted away from South Qinling and suturing onto North Qinling earlier than the other parts of South Qinling. In the Early Palaeozoic Qinling was a small archipelagic ocean basin with 5 rows of islands including the Zhen'an-Xichuan block. The drifting of the Yangtze and North China plates and the islands between them in the same direction at different speeds caused their suturing process to be different from the classic plate collision, which is the major feature of the suturing of the multi-island Tethys ocean basin. This also explains the problem that the Caledonian collision did not result in orogeny in eastern Qinling.