Geopolymer concrete emerges as a promising avenue for sustainable development and offers an effective solution to environmental problems.Its attributes as a non-toxic,low-carbon,and economical substitute for conventio...Geopolymer concrete emerges as a promising avenue for sustainable development and offers an effective solution to environmental problems.Its attributes as a non-toxic,low-carbon,and economical substitute for conventional cement concrete,coupled with its elevated compressive strength and reduced shrinkage properties,position it as a pivotal material for diverse applications spanning from architectural structures to transportation infrastructure.In this context,this study sets out the task of using machine learning(ML)algorithms to increase the accuracy and interpretability of predicting the compressive strength of geopolymer concrete in the civil engineering field.To achieve this goal,a new approach using convolutional neural networks(CNNs)has been adopted.This study focuses on creating a comprehensive dataset consisting of compositional and strength parameters of 162 geopolymer concrete mixes,all containing Class F fly ash.The selection of optimal input parameters is guided by two distinct criteria.The first criterion leverages insights garnered from previous research on the influence of individual features on compressive strength.The second criterion scrutinizes the impact of these features within the model’s predictive framework.Key to enhancing the CNN model’s performance is the meticulous determination of the optimal hyperparameters.Through a systematic trial-and-error process,the study ascertains the ideal number of epochs for data division and the optimal value of k for k-fold cross-validation—a technique vital to the model’s robustness.The model’s predictive prowess is rigorously assessed via a suite of performance metrics and comprehensive score analyses.Furthermore,the model’s adaptability is gauged by integrating a secondary dataset into its predictive framework,facilitating a comparative evaluation against conventional prediction methods.To unravel the intricacies of the CNN model’s learning trajectory,a loss plot is deployed to elucidate its learning rate.The study culminates in compelling findings that underscore the CNN model’s accurate prediction of geopolymer concrete compressive strength.To maximize the dataset’s potential,the application of bivariate plots unveils nuanced trends and interactions among variables,fortifying the consistency with earlier research.Evidenced by promising prediction accuracy,the study’s outcomes hold significant promise in guiding the development of innovative geopolymer concrete formulations,thereby reinforcing its role as an eco-conscious and robust construction material.The findings prove that the CNN model accurately estimated geopolymer concrete’s compressive strength.The results show that the prediction accuracy is promising and can be used for the development of new geopolymer concrete mixes.The outcomes not only underscore the significance of leveraging technology for sustainable construction practices but also pave the way for innovation and efficiency in the field of civil engineering.展开更多
The recent increase in blast/bombing incidents all over the world has pushed the development of effective strengthening approaches to enhance the blast resistance of existing civil infrastructures.Engineered geopolyme...The recent increase in blast/bombing incidents all over the world has pushed the development of effective strengthening approaches to enhance the blast resistance of existing civil infrastructures.Engineered geopolymer composite(EGC)is a promising material featured by eco-friendly,fast-setting and strain-hardening characteristics for emergent strengthening and construction.However,the fiber optimization for preparing EGC and its protective effect on structural elements under blast scenarios are uncertain.In this study,laboratory tests were firstly conducted to evaluate the effects of fiber types on the properties of EGC in terms of workability,dry shrinkage,and mechanical properties in compression,tension and flexure.The experimental results showed that EGC containing PE fiber exhibited suitable workability,acceptable dry shrinkage and superior mechanical properties compared with other types of fibers.After that,a series of field tests were carried out to evaluate the effectiveness of EGC retrofitting layer on the enhancement of blast performance of typical elements.The tests include autoclaved aerated concrete(AAC)masonry walls subjected to vented gas explosion,reinforced AAC panels subjected to TNT explosion and plain concrete slabs subjected to contact explosion.It was found that EGC could effectively enhance the blast resistance of structural elements in different scenarios.For AAC masonry walls and panels,with the existence of EGC,the integrity of specimens could be maintained,and their deflections and damage were significantly reduced.For plain concrete slabs,the EGC overlay could reduce the diameter and depth of the crater and spallation of specimens.展开更多
The effect of silica fume on the fresh and hardened properties of fly ash-based self-compacting geopolymer concrete (SCGC) was investigated in this paper. The work focused on the concrete mixes with a fixed water-to...The effect of silica fume on the fresh and hardened properties of fly ash-based self-compacting geopolymer concrete (SCGC) was investigated in this paper. The work focused on the concrete mixes with a fixed water-to-geopolymer solid (W/Gs) ratio of 0.33 by mass and a constant total binder content of 400 kg/m3. The mass fractions of silica fume that replaced fly ash in this research were 0wt%, 5wt%, 10wt%, and 15wt%. The workability-related fresh properties of SCGC were assessed through slump flow, V-funnel, and L-box test methods. Hardened concrete tests were limited to compressive, splitting tensile and flexural strengths, all of which were measured at the age of 1, 7, and 28 d after 48-h oven curing. The results indicate that the addition of silica fume as a partial replacement of fly ash results in the loss of workability; nevertheless, the mechanical properties of hardened SCGC are significantly improved by incorporating silica fume, especially up to 10wt%. Applying this percentage of silica fume results in 4.3% reduction in the slump flow; however, it increases the compressive strength by 6.9%, tensile strength by 12.8% and flexural strength by 11.5%.展开更多
Geopolymer-lightweight aggregate refractory concrete (GLARC) was prepared with geopolymer and lightweight aggregate. The mechanical property and heat-resistance (950 ℃) of GLARC were investigated. The effects of size...Geopolymer-lightweight aggregate refractory concrete (GLARC) was prepared with geopolymer and lightweight aggregate. The mechanical property and heat-resistance (950 ℃) of GLARC were investigated. The effects of size of aggregate and mass ratio of geopolymer to aggregate on mechanical and thermal properties were also studied. The results show that the highest compressive strength of the heated refractory concrete is 43.3 MPa,and the strength loss is only 42%. The mechanical property and heat-resistance are influenced by the thickness of geopolymer covered with aggregate,which can be expressed as the quantity of geopolymer on per surface area of aggregate. In order to show the relationship between the thickness of geopolymer covered with aggregate and the thermal property of concrete,equal thickness model is presented,which provides a reference for the mix design of GLARC. For the haydite sand with size of 1.18-4.75 mm,the best amount of geopolymer per surface area of aggregate should be in the range of 0.300-0.500 mg/mm2.展开更多
Reuse of concrete waste, especially in large quantity, can save not only material but also cost for its disposal. This paper presents experiment results on the use of fine and coarse aggregates from concrete waste in ...Reuse of concrete waste, especially in large quantity, can save not only material but also cost for its disposal. This paper presents experiment results on the use of fine and coarse aggregates from concrete waste in geopolymer mortars and concretes. Geopolymeric cement is an inorganic compounds of aluminosilicates synthesized from precursors with high content of silica and alumina activated by alkali silicate solutions. Geopolymer in this experiment was synthesized from fly ash as the precursor and sodium silicate solution as the activator. Hardening of geopolymers was performed by heating the casted paste in an oven at -60~Cfor 3 to 36 hours. Compressive strength of geopolymer pastes and mortars using either fresh or waste fine aggregates were in the range of 19-26 MPa. Hardening time of 3 hours at 60~C followed by leaving the test pieces at room temperature for 7 day before testing results in similar strength to that of mortars cured for 36 hours at 60~C followed by leaving the samples at room temperature for 3 days. It suggests that optimum strength can be achieved by combination of heating time and rest period before testing, i.e the specimens age. Applying mix design with a target strength of 40 MPa, conventional Portland cement concretes using fresh aggregates reached 70% of its target strength at day-7. Compressive strength of geopolymer concretes with waste aggregates was -25 MPa at day-3 while geopolymer concretes with fresh aggregates achieved -39 MPa at day-3. It can be concluded that geopolymer concretes can achieve the target strength in only 3 days. However, the expected reinforcing effect of coarse aggregates in concrete was ineffective if waste coarse aggregates were used as the strength of the concretes did not increase significantly from that of the mortars. On the other hand, waste fine aggregates can be reused for making geopolymer mortars having the same strength as the geopolymer mortars using fresh aggregates.展开更多
This research investigated the water permeability coefficient of fly ash-based geopolymer concrete. The effect of sodium hydroxide (Na(OH)) concentrations and Si/AI ratios on water permeability and compressive str...This research investigated the water permeability coefficient of fly ash-based geopolymer concrete. The effect of sodium hydroxide (Na(OH)) concentrations and Si/AI ratios on water permeability and compressive strength of geopolymer concretes were studied. The geopolymer concrete were prepared from Mae Moh fly ash with sodium silicate (Na2SiO3) and sodium hydroxide (Na(OH)) solutions. In the first group, concentration of Na(OH) was varied at 8, 10, 12, and 14 molar and the Si/AI ratio was kept constant at 1.98. In the second group, a concentration of Na(OH) was kept constant at 14 molar and the Si/AI ratio was varied at 2.2, 2.4, 2.6, and 2.8. The hardened concretes were air-cured in laboratory. The compressive strength and water permeability were tested at the age of 28 and 60 days. The results showed that compressive strengths of geopolymer concrete significantly increased with the increase of a concentration of Na(OH) and Si/AI ratio. The water permeability coefficients increase with the decrease of compressive strength. In addition, the high reduction of water permeability coefficients with time was found in geopolymer concrete with lower Na(OH) concentration than that higher Na(OH) concentration.展开更多
The physical and mechanical properties of self-compacting geopolymer concrete(SCGC) using chemically synthesized nano-geopolymer cement was investigated. Nano-geopolymer cement was synthesized using nano-silica, alkal...The physical and mechanical properties of self-compacting geopolymer concrete(SCGC) using chemically synthesized nano-geopolymer cement was investigated. Nano-geopolymer cement was synthesized using nano-silica, alkali activator, and sodium aluminate in the laboratory. Subsequently, nine nanogeopolymer cement sbased SCGC mixes with varying nano-geopolymer cement content, alkali activator content, coarse aggregate(CA) content, and curing temperature were produced. The workability-related fresh properties were assessed through slump flow diameter and slump flow rate measurements. Mechanical performances were evaluated through compressive strength, splitting tensile strength, and modulus of elasticity measurements. In addition, rapid chloride penetration test, water absorption, and porosity tests were also performed. It was assessed that all mix design parameters influenced the fresh and hardened properties of SCGC mixes. Based on test results, it was deduced that nano-geopolymer cement SCGC performed fairly well. All the SCGC mixes achieved the 28-day compressive strength in the range of 60-80 MPa. Additionally, all mixes attained 60% of their 28-day strength during the first three days of elevated temperature curing. FTIR and SEM analyses were performed to evaluate the degree of polymerization and the microstructure respectively for SCGC mixes.展开更多
This research studies the impact of different types of coarse aggregate on the behavior of geopolymer concrete based on both fly ash (FA) and ground granulated blast furnace slag (GGBFS) in different marine environmen...This research studies the impact of different types of coarse aggregate on the behavior of geopolymer concrete based on both fly ash (FA) and ground granulated blast furnace slag (GGBFS) in different marine environments. Aiming to solve the problems caused by the construction and demolition waste and the depletion of natural aggregates, in the present study coarse recycled aggregates is used to produce new green concrete with a fly ash-slag based geopolymer. By this examination, the research seeks to improve the quality and productivity of concrete used in construction and hydraulic projects. For this research, four mixtures containing different types of coarse aggregate in two different water environments were used. The utilized mixtures contained natural aggregate concrete (NAC) such as basalt and crushed marble. Also, recycled coarse aggregate concrete (RAC), which totally replaced natural aggregate, was presented in this paper such as crushed concrete and crushed ceramic. For this study, in the sieve analysis;specific and unit weights, was recorded. Furthermore, the mechanical properties were determined, using a compressive test that was conducted on the 7th, 28th, 56th and 90th days at different water environments;potable water (PW) and sea water (SW). Durability test was also performed for total absorption measurement. Results indicated that geopolymer concrete exhibits better strength in marine environments than in those of potable water. Results also showed that crushed marble (CMA) exhibits higher compressive strength and durability.展开更多
Recently,great attention has been paid to geopolymer concrete due to its advantageous mechanical and environmentally friendly properties.Much effort has been made in experimental studies to advance the understanding o...Recently,great attention has been paid to geopolymer concrete due to its advantageous mechanical and environmentally friendly properties.Much effort has been made in experimental studies to advance the understanding of geopolymer concrete,in which compressive strength is one of the most important properties.To facilitate engineering work on the material,an efficient predicting model is needed.In this study,three machine learning(ML)-based models,namely deep neural network(DNN),K-nearest neighbors(KNN),and support vector machines(SVM),are developed for forecasting the compressive strength of the geopolymer concrete.A total of 375 experimental samples are collected from the literature to build a database for the development of the predicting models.A careful procedure for data preprocessing is implemented,by which outliers are examined and removed from the database and input variables are standardized before feeding to the fitting process.The standard K-fold cross-validation approach is applied for evaluating the performance of the models so that overfitting status is well managed,thus the generalizability of the models is ensured.The effectiveness of the models is assessed via statistical metrics including root mean squared error(RMSE),mean absolute error(MAE),correlation coefficient(R),and the recently proposed performance index(PI).The basic mean square error(MSE)is used as the loss function to be minimized during the model fitting process.The three ML-based models are successfully developed for estimating the compressive strength,for which good correlations between the predicted and the true values are obtained for DNN,KNN,and SVM.The numerical results suggest that the DNN model generally outperforms the other two models.展开更多
Concretes on the basis of the alumosilicate polymer can be prepared by alkali activation (NaOH, sodium water glass) of waste brown coal fly ash. The preparation is possible: (1) by using a short-term heating of t...Concretes on the basis of the alumosilicate polymer can be prepared by alkali activation (NaOH, sodium water glass) of waste brown coal fly ash. The preparation is possible: (1) by using a short-term heating of the concrete mix (to 80 ℃); or (2) by allowing the mix to harden spontaneously at a temperature of 20 ℃. The concretes prepared by short-time heating attain high strength values after their preparation; the values are comparable to those characterizing concretes obtained on the basis of Portland cement. The strength development of concretes hardening at 20 ℃ is substantially less steep but, nevertheless, the strength attained after about 60 days is practically identical with that of the concretes exposed to a short-time heating. The shrinkage of concretes prepared by short-time heating is very small as compared with the concretes allowed to harden spontaneously; the shrinkage of latter concretes is larger than that of the concretes on the basis of Portland cement. The concretes on the basis of alumosilicate polymer exhibit much better resistance to the corrosive action of the environment as compared with those prepared on the basis of Portland cement.展开更多
Due to growing consumption of Portland cement and high levels of CO_(2) emissions in its production process,this study examined the use of Brazilian RHS(rice husk silica)obtained by FBC(fluidized bed combustion)as an ...Due to growing consumption of Portland cement and high levels of CO_(2) emissions in its production process,this study examined the use of Brazilian RHS(rice husk silica)obtained by FBC(fluidized bed combustion)as an alternative material in concrete production;the principal cause is the inappropriate disposal of carbonized or in natura rice husk in southern Brazil.To analyze its feasibility,concretes made with several types of cements were examined combined with RHS,and also concretes with different strength classes employing a slag-based binder featuring a smaller amount of clinker in its composition.Mechanical and scanning electron microscopy assays were carried out to verify formation of C-S-H and calcium hydroxide in the cement pastes.This study concludes that replacing 10%of Portland cement(CEMIII/A)by 3%of RHS can result in a cost reduction of around 5%and allows a reduction of 4%in CO_(2)eq levels.In this way,RHS from renewable sources can be a highly impactful sustainable alternative in civil engineering work,allowing the concrete industry to produce environmentally-sound concrete mixtures with lower CO_(2) emissions.展开更多
In this study,the concrete cone capacity,concrete cone angle,and load–displacement response of cast-in headed anchors in geopolymer concrete are explored using numerical analyses.The concrete damaged plasticity(CDP)m...In this study,the concrete cone capacity,concrete cone angle,and load–displacement response of cast-in headed anchors in geopolymer concrete are explored using numerical analyses.The concrete damaged plasticity(CDP)model in ABAQUS is used to simulate the behavior of concrete substrates.The tensile behavior of anchors in geopolymer concrete is compared with that in normal concrete as well as that predicted by the linear fracture mechanics(LFM)and concrete capacity design(CCD)models.The results show that the capacity of the anchors in geopolymer concrete is 30%–40%lower than that in normal concrete.The results also indicate that the CCD model overestimates the capacity of the anchors in geopolymer concrete,whereas the LFM model provides a much more conservative prediction.The extent of the difference between the predictions by the numerical analysis and those of the above prediction models depends on the effective embedment depth of the anchor and the anchor head size.The influence of concrete surface cracking on the capacity of the anchor is shown to depend on the location of the crack and the effective embedment depth.The influence of the anchor head profile on the tensile capacity of the anchors is found to be insignificant.展开更多
Geopolymer is produced through the polymerization of active aluminosilicate material with an alkaline activator,leading to the formation of a green,inorganic polymer binder.Geopolymer concrete(GPC)has become a promisi...Geopolymer is produced through the polymerization of active aluminosilicate material with an alkaline activator,leading to the formation of a green,inorganic polymer binder.Geopolymer concrete(GPC)has become a promising low-carbon alternative to traditional Portland cement-based concrete(OPC).GPC-bonded reinforcing bars offer a promising alternative for concrete structures,boasting excellent geopolymer binder/reinforcement bonding and superior corrosion and high-temperature resistance compared to Portland cement.However,due to differences in the production process of GPC,there are distinct engineering property variations,including bonding characteristics.This literature review provides an examination of the manufacturing procedures of GPC,encompassing source materials,mix design,curing regimes,and other factors directly influencing concrete properties.Additionally,it delves into the bond mechanism,bond tests,and corresponding results that represent the bond characteristics.The main conclusions are that GPC generally has superior mechanical properties and bond performance compared to ordinary Portland cement concrete(OPC).However,proper standardization is needed for its production and performance tests to limit the contradictory results in the lab and on site.展开更多
基金funded by the Researchers Supporting Program at King Saud University(RSPD2023R809).
文摘Geopolymer concrete emerges as a promising avenue for sustainable development and offers an effective solution to environmental problems.Its attributes as a non-toxic,low-carbon,and economical substitute for conventional cement concrete,coupled with its elevated compressive strength and reduced shrinkage properties,position it as a pivotal material for diverse applications spanning from architectural structures to transportation infrastructure.In this context,this study sets out the task of using machine learning(ML)algorithms to increase the accuracy and interpretability of predicting the compressive strength of geopolymer concrete in the civil engineering field.To achieve this goal,a new approach using convolutional neural networks(CNNs)has been adopted.This study focuses on creating a comprehensive dataset consisting of compositional and strength parameters of 162 geopolymer concrete mixes,all containing Class F fly ash.The selection of optimal input parameters is guided by two distinct criteria.The first criterion leverages insights garnered from previous research on the influence of individual features on compressive strength.The second criterion scrutinizes the impact of these features within the model’s predictive framework.Key to enhancing the CNN model’s performance is the meticulous determination of the optimal hyperparameters.Through a systematic trial-and-error process,the study ascertains the ideal number of epochs for data division and the optimal value of k for k-fold cross-validation—a technique vital to the model’s robustness.The model’s predictive prowess is rigorously assessed via a suite of performance metrics and comprehensive score analyses.Furthermore,the model’s adaptability is gauged by integrating a secondary dataset into its predictive framework,facilitating a comparative evaluation against conventional prediction methods.To unravel the intricacies of the CNN model’s learning trajectory,a loss plot is deployed to elucidate its learning rate.The study culminates in compelling findings that underscore the CNN model’s accurate prediction of geopolymer concrete compressive strength.To maximize the dataset’s potential,the application of bivariate plots unveils nuanced trends and interactions among variables,fortifying the consistency with earlier research.Evidenced by promising prediction accuracy,the study’s outcomes hold significant promise in guiding the development of innovative geopolymer concrete formulations,thereby reinforcing its role as an eco-conscious and robust construction material.The findings prove that the CNN model accurately estimated geopolymer concrete’s compressive strength.The results show that the prediction accuracy is promising and can be used for the development of new geopolymer concrete mixes.The outcomes not only underscore the significance of leveraging technology for sustainable construction practices but also pave the way for innovation and efficiency in the field of civil engineering.
基金National Natural Science Foundation of China(Grant Nos.51908188 and 51938011).
文摘The recent increase in blast/bombing incidents all over the world has pushed the development of effective strengthening approaches to enhance the blast resistance of existing civil infrastructures.Engineered geopolymer composite(EGC)is a promising material featured by eco-friendly,fast-setting and strain-hardening characteristics for emergent strengthening and construction.However,the fiber optimization for preparing EGC and its protective effect on structural elements under blast scenarios are uncertain.In this study,laboratory tests were firstly conducted to evaluate the effects of fiber types on the properties of EGC in terms of workability,dry shrinkage,and mechanical properties in compression,tension and flexure.The experimental results showed that EGC containing PE fiber exhibited suitable workability,acceptable dry shrinkage and superior mechanical properties compared with other types of fibers.After that,a series of field tests were carried out to evaluate the effectiveness of EGC retrofitting layer on the enhancement of blast performance of typical elements.The tests include autoclaved aerated concrete(AAC)masonry walls subjected to vented gas explosion,reinforced AAC panels subjected to TNT explosion and plain concrete slabs subjected to contact explosion.It was found that EGC could effectively enhance the blast resistance of structural elements in different scenarios.For AAC masonry walls and panels,with the existence of EGC,the integrity of specimens could be maintained,and their deflections and damage were significantly reduced.For plain concrete slabs,the EGC overlay could reduce the diameter and depth of the crater and spallation of specimens.
基金Universiti Teknologi PETRONAS and the Ministry of Science,Technology,and Innovation,Malaysia (Research grant 06-02-02-SF0052) for providing the financial support and research facilities
文摘The effect of silica fume on the fresh and hardened properties of fly ash-based self-compacting geopolymer concrete (SCGC) was investigated in this paper. The work focused on the concrete mixes with a fixed water-to-geopolymer solid (W/Gs) ratio of 0.33 by mass and a constant total binder content of 400 kg/m3. The mass fractions of silica fume that replaced fly ash in this research were 0wt%, 5wt%, 10wt%, and 15wt%. The workability-related fresh properties of SCGC were assessed through slump flow, V-funnel, and L-box test methods. Hardened concrete tests were limited to compressive, splitting tensile and flexural strengths, all of which were measured at the age of 1, 7, and 28 d after 48-h oven curing. The results indicate that the addition of silica fume as a partial replacement of fly ash results in the loss of workability; nevertheless, the mechanical properties of hardened SCGC are significantly improved by incorporating silica fume, especially up to 10wt%. Applying this percentage of silica fume results in 4.3% reduction in the slump flow; however, it increases the compressive strength by 6.9%, tensile strength by 12.8% and flexural strength by 11.5%.
基金Project(2009CB623201) supported by the National Basic Research Program of ChinaProject(G0510) supported by the Key Laboratory for Refractories and High-temperature Ceramics of Hubei Province, China
文摘Geopolymer-lightweight aggregate refractory concrete (GLARC) was prepared with geopolymer and lightweight aggregate. The mechanical property and heat-resistance (950 ℃) of GLARC were investigated. The effects of size of aggregate and mass ratio of geopolymer to aggregate on mechanical and thermal properties were also studied. The results show that the highest compressive strength of the heated refractory concrete is 43.3 MPa,and the strength loss is only 42%. The mechanical property and heat-resistance are influenced by the thickness of geopolymer covered with aggregate,which can be expressed as the quantity of geopolymer on per surface area of aggregate. In order to show the relationship between the thickness of geopolymer covered with aggregate and the thermal property of concrete,equal thickness model is presented,which provides a reference for the mix design of GLARC. For the haydite sand with size of 1.18-4.75 mm,the best amount of geopolymer per surface area of aggregate should be in the range of 0.300-0.500 mg/mm2.
文摘Reuse of concrete waste, especially in large quantity, can save not only material but also cost for its disposal. This paper presents experiment results on the use of fine and coarse aggregates from concrete waste in geopolymer mortars and concretes. Geopolymeric cement is an inorganic compounds of aluminosilicates synthesized from precursors with high content of silica and alumina activated by alkali silicate solutions. Geopolymer in this experiment was synthesized from fly ash as the precursor and sodium silicate solution as the activator. Hardening of geopolymers was performed by heating the casted paste in an oven at -60~Cfor 3 to 36 hours. Compressive strength of geopolymer pastes and mortars using either fresh or waste fine aggregates were in the range of 19-26 MPa. Hardening time of 3 hours at 60~C followed by leaving the test pieces at room temperature for 7 day before testing results in similar strength to that of mortars cured for 36 hours at 60~C followed by leaving the samples at room temperature for 3 days. It suggests that optimum strength can be achieved by combination of heating time and rest period before testing, i.e the specimens age. Applying mix design with a target strength of 40 MPa, conventional Portland cement concretes using fresh aggregates reached 70% of its target strength at day-7. Compressive strength of geopolymer concretes with waste aggregates was -25 MPa at day-3 while geopolymer concretes with fresh aggregates achieved -39 MPa at day-3. It can be concluded that geopolymer concretes can achieve the target strength in only 3 days. However, the expected reinforcing effect of coarse aggregates in concrete was ineffective if waste coarse aggregates were used as the strength of the concretes did not increase significantly from that of the mortars. On the other hand, waste fine aggregates can be reused for making geopolymer mortars having the same strength as the geopolymer mortars using fresh aggregates.
文摘This research investigated the water permeability coefficient of fly ash-based geopolymer concrete. The effect of sodium hydroxide (Na(OH)) concentrations and Si/AI ratios on water permeability and compressive strength of geopolymer concretes were studied. The geopolymer concrete were prepared from Mae Moh fly ash with sodium silicate (Na2SiO3) and sodium hydroxide (Na(OH)) solutions. In the first group, concentration of Na(OH) was varied at 8, 10, 12, and 14 molar and the Si/AI ratio was kept constant at 1.98. In the second group, a concentration of Na(OH) was kept constant at 14 molar and the Si/AI ratio was varied at 2.2, 2.4, 2.6, and 2.8. The hardened concretes were air-cured in laboratory. The compressive strength and water permeability were tested at the age of 28 and 60 days. The results showed that compressive strengths of geopolymer concrete significantly increased with the increase of a concentration of Na(OH) and Si/AI ratio. The water permeability coefficients increase with the decrease of compressive strength. In addition, the high reduction of water permeability coefficients with time was found in geopolymer concrete with lower Na(OH) concentration than that higher Na(OH) concentration.
文摘The physical and mechanical properties of self-compacting geopolymer concrete(SCGC) using chemically synthesized nano-geopolymer cement was investigated. Nano-geopolymer cement was synthesized using nano-silica, alkali activator, and sodium aluminate in the laboratory. Subsequently, nine nanogeopolymer cement sbased SCGC mixes with varying nano-geopolymer cement content, alkali activator content, coarse aggregate(CA) content, and curing temperature were produced. The workability-related fresh properties were assessed through slump flow diameter and slump flow rate measurements. Mechanical performances were evaluated through compressive strength, splitting tensile strength, and modulus of elasticity measurements. In addition, rapid chloride penetration test, water absorption, and porosity tests were also performed. It was assessed that all mix design parameters influenced the fresh and hardened properties of SCGC mixes. Based on test results, it was deduced that nano-geopolymer cement SCGC performed fairly well. All the SCGC mixes achieved the 28-day compressive strength in the range of 60-80 MPa. Additionally, all mixes attained 60% of their 28-day strength during the first three days of elevated temperature curing. FTIR and SEM analyses were performed to evaluate the degree of polymerization and the microstructure respectively for SCGC mixes.
文摘This research studies the impact of different types of coarse aggregate on the behavior of geopolymer concrete based on both fly ash (FA) and ground granulated blast furnace slag (GGBFS) in different marine environments. Aiming to solve the problems caused by the construction and demolition waste and the depletion of natural aggregates, in the present study coarse recycled aggregates is used to produce new green concrete with a fly ash-slag based geopolymer. By this examination, the research seeks to improve the quality and productivity of concrete used in construction and hydraulic projects. For this research, four mixtures containing different types of coarse aggregate in two different water environments were used. The utilized mixtures contained natural aggregate concrete (NAC) such as basalt and crushed marble. Also, recycled coarse aggregate concrete (RAC), which totally replaced natural aggregate, was presented in this paper such as crushed concrete and crushed ceramic. For this study, in the sieve analysis;specific and unit weights, was recorded. Furthermore, the mechanical properties were determined, using a compressive test that was conducted on the 7th, 28th, 56th and 90th days at different water environments;potable water (PW) and sea water (SW). Durability test was also performed for total absorption measurement. Results indicated that geopolymer concrete exhibits better strength in marine environments than in those of potable water. Results also showed that crushed marble (CMA) exhibits higher compressive strength and durability.
文摘Recently,great attention has been paid to geopolymer concrete due to its advantageous mechanical and environmentally friendly properties.Much effort has been made in experimental studies to advance the understanding of geopolymer concrete,in which compressive strength is one of the most important properties.To facilitate engineering work on the material,an efficient predicting model is needed.In this study,three machine learning(ML)-based models,namely deep neural network(DNN),K-nearest neighbors(KNN),and support vector machines(SVM),are developed for forecasting the compressive strength of the geopolymer concrete.A total of 375 experimental samples are collected from the literature to build a database for the development of the predicting models.A careful procedure for data preprocessing is implemented,by which outliers are examined and removed from the database and input variables are standardized before feeding to the fitting process.The standard K-fold cross-validation approach is applied for evaluating the performance of the models so that overfitting status is well managed,thus the generalizability of the models is ensured.The effectiveness of the models is assessed via statistical metrics including root mean squared error(RMSE),mean absolute error(MAE),correlation coefficient(R),and the recently proposed performance index(PI).The basic mean square error(MSE)is used as the loss function to be minimized during the model fitting process.The three ML-based models are successfully developed for estimating the compressive strength,for which good correlations between the predicted and the true values are obtained for DNN,KNN,and SVM.The numerical results suggest that the DNN model generally outperforms the other two models.
基金This study was part of the research project CEZ:MSM 6046137302: "Preparation and research of functional materials and material technologies using micro-and nanoscopic methods" and Czech Science Foundation Grant 103/08/1639 "Microstructure of inorganic alumosilicate polymers".
文摘Concretes on the basis of the alumosilicate polymer can be prepared by alkali activation (NaOH, sodium water glass) of waste brown coal fly ash. The preparation is possible: (1) by using a short-term heating of the concrete mix (to 80 ℃); or (2) by allowing the mix to harden spontaneously at a temperature of 20 ℃. The concretes prepared by short-time heating attain high strength values after their preparation; the values are comparable to those characterizing concretes obtained on the basis of Portland cement. The strength development of concretes hardening at 20 ℃ is substantially less steep but, nevertheless, the strength attained after about 60 days is practically identical with that of the concretes exposed to a short-time heating. The shrinkage of concretes prepared by short-time heating is very small as compared with the concretes allowed to harden spontaneously; the shrinkage of latter concretes is larger than that of the concretes on the basis of Portland cement. The concretes on the basis of alumosilicate polymer exhibit much better resistance to the corrosive action of the environment as compared with those prepared on the basis of Portland cement.
文摘Due to growing consumption of Portland cement and high levels of CO_(2) emissions in its production process,this study examined the use of Brazilian RHS(rice husk silica)obtained by FBC(fluidized bed combustion)as an alternative material in concrete production;the principal cause is the inappropriate disposal of carbonized or in natura rice husk in southern Brazil.To analyze its feasibility,concretes made with several types of cements were examined combined with RHS,and also concretes with different strength classes employing a slag-based binder featuring a smaller amount of clinker in its composition.Mechanical and scanning electron microscopy assays were carried out to verify formation of C-S-H and calcium hydroxide in the cement pastes.This study concludes that replacing 10%of Portland cement(CEMIII/A)by 3%of RHS can result in a cost reduction of around 5%and allows a reduction of 4%in CO_(2)eq levels.In this way,RHS from renewable sources can be a highly impactful sustainable alternative in civil engineering work,allowing the concrete industry to produce environmentally-sound concrete mixtures with lower CO_(2) emissions.
文摘In this study,the concrete cone capacity,concrete cone angle,and load–displacement response of cast-in headed anchors in geopolymer concrete are explored using numerical analyses.The concrete damaged plasticity(CDP)model in ABAQUS is used to simulate the behavior of concrete substrates.The tensile behavior of anchors in geopolymer concrete is compared with that in normal concrete as well as that predicted by the linear fracture mechanics(LFM)and concrete capacity design(CCD)models.The results show that the capacity of the anchors in geopolymer concrete is 30%–40%lower than that in normal concrete.The results also indicate that the CCD model overestimates the capacity of the anchors in geopolymer concrete,whereas the LFM model provides a much more conservative prediction.The extent of the difference between the predictions by the numerical analysis and those of the above prediction models depends on the effective embedment depth of the anchor and the anchor head size.The influence of concrete surface cracking on the capacity of the anchor is shown to depend on the location of the crack and the effective embedment depth.The influence of the anchor head profile on the tensile capacity of the anchors is found to be insignificant.
基金supported by the ongoing projects provided by the National Key Research and Development Program(2021YFB2600704)the National Natural Science Foundation of China(52108223,U22A20244)+3 种基金the Outstanding Youth Fund of Shandong Province(ZR2021JQ17)the Natural Science Foundation of Shandong Province(ZR2020QE249)the 111 Project(D16006)the First-Class Discipline Project funded by the Education Department of Shandong Province are gratefully acknowledged.
文摘Geopolymer is produced through the polymerization of active aluminosilicate material with an alkaline activator,leading to the formation of a green,inorganic polymer binder.Geopolymer concrete(GPC)has become a promising low-carbon alternative to traditional Portland cement-based concrete(OPC).GPC-bonded reinforcing bars offer a promising alternative for concrete structures,boasting excellent geopolymer binder/reinforcement bonding and superior corrosion and high-temperature resistance compared to Portland cement.However,due to differences in the production process of GPC,there are distinct engineering property variations,including bonding characteristics.This literature review provides an examination of the manufacturing procedures of GPC,encompassing source materials,mix design,curing regimes,and other factors directly influencing concrete properties.Additionally,it delves into the bond mechanism,bond tests,and corresponding results that represent the bond characteristics.The main conclusions are that GPC generally has superior mechanical properties and bond performance compared to ordinary Portland cement concrete(OPC).However,proper standardization is needed for its production and performance tests to limit the contradictory results in the lab and on site.