By partial and general dissection of large prebaked alumina electrolysis cells, the macro appearance, chemical composition and phase variations were studied employing actual observations and measurements on the cells ...By partial and general dissection of large prebaked alumina electrolysis cells, the macro appearance, chemical composition and phase variations were studied employing actual observations and measurements on the cells together with X ray diffraction phase analysis and scanning electron microscopy of samples from different locations. According to the practical production, a chemical reaction model of aluminum reduction cell failure was set up in order to reduce the incidence of cell failure and extend pot service life.展开更多
A zero-dimensional model to simulate a nano-pulse-discharged bubble in water was developed. The model consists of gas and liquid phases corresponding to the inside and outside of the bubble, respectively. The diffusio...A zero-dimensional model to simulate a nano-pulse-discharged bubble in water was developed. The model consists of gas and liquid phases corresponding to the inside and outside of the bubble, respectively. The diffusions of chemical species from the gas to the liquid phase through the bubble interface was also investigated. The initial gas is Ar, but includes a little H20 and 02 in the bubble. The time evolution of the OH concentration in the liquid phase was mainly investigated as an important species for water treatment. It was shown that OH was generated in the bubble and then diffused into the liquid. With the application of a continuous nano-pulse discharge, more OH radicals were generated as the frequency increased at a low voltage for a given power consumption.展开更多
Based on the physical chemistry principle, this paper proposes that the surface adsorption catalytic mechanism of HF is the key to dissolving the oscillation of the CaF\-2\|HCl\|H\-2O solid\|liquid reaction system. Me...Based on the physical chemistry principle, this paper proposes that the surface adsorption catalytic mechanism of HF is the key to dissolving the oscillation of the CaF\-2\|HCl\|H\-2O solid\|liquid reaction system. Meanwhile the dynamical model of this system has been established in order to study its non\|linear dynamical genesis. Although this mathematics model is based on CSTR reaction apparatus, it is applicable to the foliate flow reaction apparatus, too.展开更多
Taking the Lindemann model as a sample system in which there exist chemical reactions, diffusion and heat conduction, we found the theoretical framework of linear stability analysis for a unidimensional nonhomogeneous...Taking the Lindemann model as a sample system in which there exist chemical reactions, diffusion and heat conduction, we found the theoretical framework of linear stability analysis for a unidimensional nonhomogeneous two-variable system with one end subject to Dirichlet conditions, while the other end no-flux conditions. Furthermore, the conditions for the emergence of temperature waves are found out by the linear stability analysis and verified by a diagram for successive steps of evolution of spatial profile of temperature during a period that is plotted by numerical simulations on a computer. Without doubt, these results are in favor of the heat balance in chemical reactor designs.展开更多
The comparison of five atmospheric chemical modeling schemes was presented from accuracy,efficiency and progamming in term of Carbon bond Mechanism IV of atmospheric chemical reactions. The major results were as fo...The comparison of five atmospheric chemical modeling schemes was presented from accuracy,efficiency and progamming in term of Carbon bond Mechanism IV of atmospheric chemical reactions. The major results were as follows. The classical Gear scheme can provide an accurate solution and it is easy for programming by a computer automatically. The sparse matrix Gear type scheme can also provide an accurate solution but much faster than classical Gear scheme. QSSA,EBI and hybrid schemes can run with much longer time step without sacrificing of accuracy, therefore, much efficiently. If analytical solution is obtained by EBI scheme the accuracy and efficiency are much better.展开更多
The first necessary condition for the onset of an earthquake is the penetration of explosive gas into an explosive zone as a result of physical or chemical reaction. The second necessary condition is to ensure the sub...The first necessary condition for the onset of an earthquake is the penetration of explosive gas into an explosive zone as a result of physical or chemical reaction. The second necessary condition is to ensure the subsequent propagation of the flame after ignition. The latter condition has made it possible to explain the impact of a cyclone on the emergence of 42 strongest earthquakes in the 21st century. If violation of this condition can be achieved with the help of vibrators or explosions, this will result in a decrease in the magnitude of an earthquake or even a complete prevention of earthquakes. Thus, the second condition is essentially a “pressure lock” that opens (with a decrease in the pressure caused by a cyclone), which leads to an earthquake or closes (with an increase in the pressure caused by an anticyclone or human interference using vibrators or explosions), which leads to earthquake prevention. Kinetic equations of the 2nd type were used to describe chemical reactions and obtain formulas for the precursor time, which made it possible to describe earthquakes of the chemical channel. The set of experimental time values of the earthquake precursor described by the physical model includes about 20% of all earthquakes;80% of earthquakes can be attributed to the chemical channel for earthquakes that occurred in Dushanbe in 1983. All earthquakes in Tiberias in June 2018 passed through the chemical channel, which can be concluded from the small magnitude of these earthquakes. Several proposals have been made, including: 1) creating a new sensor for the geochemical method, which allows determining the epicenter of a future earthquake;2) creating a network of stations with a new sensor for determining the epicenter and an atmospheric pressure meter installed at each station (this will determine if the “pressure lock” is closed by an anticyclone, which can lead to a decrease in the magnitude of an earthquake or even prevent an earthquake);3) installing vibrators in epicenters (or making daily explosions with explosives delivered by trucks, drones, airplanes or helicopters, which should lower the magnitudes of future dangerous earthquakes);4) alerting the public to the expected future earthquake;5) developing specialized vibrators for reducing the magnitude of an impending catastrophic earthquake. Thus, this article is a breakthrough, describing a new mechanism in earthquakes for understanding and theory of earthquakes, which are used for the vast majority of earthquakes, including for program to reduce the magnitude of dangerous earthquakes.展开更多
A numerical study is reported for two-dimensional flow of an incompressible Powell-Eyring fluid by stretching the surface with the Cattaneo-Christov model of heat diffusion. Impacts of heat generation/absorption and d...A numerical study is reported for two-dimensional flow of an incompressible Powell-Eyring fluid by stretching the surface with the Cattaneo-Christov model of heat diffusion. Impacts of heat generation/absorption and destructive/generative chemical reactions are considered. Use of proper variables leads to a system of non-linear dimensionless expressions. Velocity, temperature and concentration profiles are achieved through a finite difference based algorithm with a successive over-relaxation(SOR) method. Emerging dimensionless quantities are described with graphs and tables. The temperature and concentration profiles decay due to enhancement in fluid parameters and Deborah numbers.展开更多
The density and viscosity of ferric chloride/trioctylmethylammonium chloride ionic liquid(rFeCl_(3)/[A336]Cl)with different molar ratios(r=0.1-0.8)of FeCl_(3) to[A336]Cl were measured at temperatures from 313.15 to 35...The density and viscosity of ferric chloride/trioctylmethylammonium chloride ionic liquid(rFeCl_(3)/[A336]Cl)with different molar ratios(r=0.1-0.8)of FeCl_(3) to[A336]Cl were measured at temperatures from 313.15 to 358.15 K and atmospheric pressure.The density and viscosity data were fitted by the relevant temperature variation equations,respectively.The variation of density and viscosity with temperature and r was obtained.The solubility of rFeCl_(3)/[A336]Cl to H_2S was measured at temperatures from 318.15 to 348.15 K and pressures from 0 to 150 kPa.The effects of temperature,pressure,and r on the solubility of H_(2)S were discussed.The reaction equilibrium thermodynamic model(RETM)was used to fit the H_(2)S solubility data,and the average relative error was less than 1.3%,indicating that the model can relate the solubility data well.And Henry's constant and chemical reaction equilibrium constant were obtained by the RETM fitting.The relationships of Henry's constant and chemical reaction equilibrium constant with temperature and r were analyzed.展开更多
A mathematical model of a class of autocatalytic chemical reaction:=a-bx-exy 2-λ x, =bx+exy 2-fy+c,is considered in this paper. There are at least sixteen different topological phase protraits for this system; and...A mathematical model of a class of autocatalytic chemical reaction:=a-bx-exy 2-λ x, =bx+exy 2-fy+c,is considered in this paper. There are at least sixteen different topological phase protraits for this system; and the corresponding conditions for each phase protrait occured are also obtained.展开更多
THE Shangmanggang gold deposit is located at the southwestern corner of Yunnan, China. The deposit occurs along the southwest-trending Shangmanggang Fault. Near the surface, the hanging wall of the fault consists of s...THE Shangmanggang gold deposit is located at the southwestern corner of Yunnan, China. The deposit occurs along the southwest-trending Shangmanggang Fault. Near the surface, the hanging wall of the fault consists of sandstone and mudstone of the Middle Jurassic Mongga Formation (J<sub>2m</sub>), and also severs asthe hanging wall of the gold orebodies. The footwall of the fault is composed of dolomitite locally intercalated with medium-bedded limestone of Lower Permian Sazipo Formation (P<sub>1s</sub>). In the depth, the faultcut into strata of the Sazipo Formation (P<sub>1s</sub>). The deposit is characterized by intense clay alteration,which is similar to the Mercur Gold Deposit, Utah of USA, and by unique hydrothermal pinnacle karsl,展开更多
文摘By partial and general dissection of large prebaked alumina electrolysis cells, the macro appearance, chemical composition and phase variations were studied employing actual observations and measurements on the cells together with X ray diffraction phase analysis and scanning electron microscopy of samples from different locations. According to the practical production, a chemical reaction model of aluminum reduction cell failure was set up in order to reduce the incidence of cell failure and extend pot service life.
基金supported partially by Japan Society for the Promotion of Science(JSPS)KAKENHI(No.26249015)
文摘A zero-dimensional model to simulate a nano-pulse-discharged bubble in water was developed. The model consists of gas and liquid phases corresponding to the inside and outside of the bubble, respectively. The diffusions of chemical species from the gas to the liquid phase through the bubble interface was also investigated. The initial gas is Ar, but includes a little H20 and 02 in the bubble. The time evolution of the OH concentration in the liquid phase was mainly investigated as an important species for water treatment. It was shown that OH was generated in the bubble and then diffused into the liquid. With the application of a continuous nano-pulse discharge, more OH radicals were generated as the frequency increased at a low voltage for a given power consumption.
文摘Based on the physical chemistry principle, this paper proposes that the surface adsorption catalytic mechanism of HF is the key to dissolving the oscillation of the CaF\-2\|HCl\|H\-2O solid\|liquid reaction system. Meanwhile the dynamical model of this system has been established in order to study its non\|linear dynamical genesis. Although this mathematics model is based on CSTR reaction apparatus, it is applicable to the foliate flow reaction apparatus, too.
文摘Taking the Lindemann model as a sample system in which there exist chemical reactions, diffusion and heat conduction, we found the theoretical framework of linear stability analysis for a unidimensional nonhomogeneous two-variable system with one end subject to Dirichlet conditions, while the other end no-flux conditions. Furthermore, the conditions for the emergence of temperature waves are found out by the linear stability analysis and verified by a diagram for successive steps of evolution of spatial profile of temperature during a period that is plotted by numerical simulations on a computer. Without doubt, these results are in favor of the heat balance in chemical reactor designs.
文摘The comparison of five atmospheric chemical modeling schemes was presented from accuracy,efficiency and progamming in term of Carbon bond Mechanism IV of atmospheric chemical reactions. The major results were as follows. The classical Gear scheme can provide an accurate solution and it is easy for programming by a computer automatically. The sparse matrix Gear type scheme can also provide an accurate solution but much faster than classical Gear scheme. QSSA,EBI and hybrid schemes can run with much longer time step without sacrificing of accuracy, therefore, much efficiently. If analytical solution is obtained by EBI scheme the accuracy and efficiency are much better.
文摘The first necessary condition for the onset of an earthquake is the penetration of explosive gas into an explosive zone as a result of physical or chemical reaction. The second necessary condition is to ensure the subsequent propagation of the flame after ignition. The latter condition has made it possible to explain the impact of a cyclone on the emergence of 42 strongest earthquakes in the 21st century. If violation of this condition can be achieved with the help of vibrators or explosions, this will result in a decrease in the magnitude of an earthquake or even a complete prevention of earthquakes. Thus, the second condition is essentially a “pressure lock” that opens (with a decrease in the pressure caused by a cyclone), which leads to an earthquake or closes (with an increase in the pressure caused by an anticyclone or human interference using vibrators or explosions), which leads to earthquake prevention. Kinetic equations of the 2nd type were used to describe chemical reactions and obtain formulas for the precursor time, which made it possible to describe earthquakes of the chemical channel. The set of experimental time values of the earthquake precursor described by the physical model includes about 20% of all earthquakes;80% of earthquakes can be attributed to the chemical channel for earthquakes that occurred in Dushanbe in 1983. All earthquakes in Tiberias in June 2018 passed through the chemical channel, which can be concluded from the small magnitude of these earthquakes. Several proposals have been made, including: 1) creating a new sensor for the geochemical method, which allows determining the epicenter of a future earthquake;2) creating a network of stations with a new sensor for determining the epicenter and an atmospheric pressure meter installed at each station (this will determine if the “pressure lock” is closed by an anticyclone, which can lead to a decrease in the magnitude of an earthquake or even prevent an earthquake);3) installing vibrators in epicenters (or making daily explosions with explosives delivered by trucks, drones, airplanes or helicopters, which should lower the magnitudes of future dangerous earthquakes);4) alerting the public to the expected future earthquake;5) developing specialized vibrators for reducing the magnitude of an impending catastrophic earthquake. Thus, this article is a breakthrough, describing a new mechanism in earthquakes for understanding and theory of earthquakes, which are used for the vast majority of earthquakes, including for program to reduce the magnitude of dangerous earthquakes.
文摘A numerical study is reported for two-dimensional flow of an incompressible Powell-Eyring fluid by stretching the surface with the Cattaneo-Christov model of heat diffusion. Impacts of heat generation/absorption and destructive/generative chemical reactions are considered. Use of proper variables leads to a system of non-linear dimensionless expressions. Velocity, temperature and concentration profiles are achieved through a finite difference based algorithm with a successive over-relaxation(SOR) method. Emerging dimensionless quantities are described with graphs and tables. The temperature and concentration profiles decay due to enhancement in fluid parameters and Deborah numbers.
基金Financial support from the National Natural Science Foundation of China(21775081)Shandong Province Natural Science Foundation(ZR2020MB145)。
文摘The density and viscosity of ferric chloride/trioctylmethylammonium chloride ionic liquid(rFeCl_(3)/[A336]Cl)with different molar ratios(r=0.1-0.8)of FeCl_(3) to[A336]Cl were measured at temperatures from 313.15 to 358.15 K and atmospheric pressure.The density and viscosity data were fitted by the relevant temperature variation equations,respectively.The variation of density and viscosity with temperature and r was obtained.The solubility of rFeCl_(3)/[A336]Cl to H_2S was measured at temperatures from 318.15 to 348.15 K and pressures from 0 to 150 kPa.The effects of temperature,pressure,and r on the solubility of H_(2)S were discussed.The reaction equilibrium thermodynamic model(RETM)was used to fit the H_(2)S solubility data,and the average relative error was less than 1.3%,indicating that the model can relate the solubility data well.And Henry's constant and chemical reaction equilibrium constant were obtained by the RETM fitting.The relationships of Henry's constant and chemical reaction equilibrium constant with temperature and r were analyzed.
文摘A mathematical model of a class of autocatalytic chemical reaction:=a-bx-exy 2-λ x, =bx+exy 2-fy+c,is considered in this paper. There are at least sixteen different topological phase protraits for this system; and the corresponding conditions for each phase protrait occured are also obtained.
文摘THE Shangmanggang gold deposit is located at the southwestern corner of Yunnan, China. The deposit occurs along the southwest-trending Shangmanggang Fault. Near the surface, the hanging wall of the fault consists of sandstone and mudstone of the Middle Jurassic Mongga Formation (J<sub>2m</sub>), and also severs asthe hanging wall of the gold orebodies. The footwall of the fault is composed of dolomitite locally intercalated with medium-bedded limestone of Lower Permian Sazipo Formation (P<sub>1s</sub>). In the depth, the faultcut into strata of the Sazipo Formation (P<sub>1s</sub>). The deposit is characterized by intense clay alteration,which is similar to the Mercur Gold Deposit, Utah of USA, and by unique hydrothermal pinnacle karsl,
