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SUPERPLASTICALLY FREE BULGING OFDURA LUMINLY12CZ UNDER AN EXTERNAL STRONG ELECTRIC FIELD
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作者 Li Miaoquan Wu Shichun(Departnient of Materiais Science and Engineering, Northtt,esternPolytechnical Universily, Xi’an, China, 710072) 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 1995年第4期277-281,共5页
Superplastically free bulging of duralumin LY 12CZ (approximately corre-sponding to ASTM 2024) without any pretreatment has been investigated under an ex-ternal strong electnc field. The experimental results show that... Superplastically free bulging of duralumin LY 12CZ (approximately corre-sponding to ASTM 2024) without any pretreatment has been investigated under an ex-ternal strong electnc field. The experimental results show that the electric field makesthe relative maximum height of the superplastically formed parts increase by 15%.Moreover, the determination of grain size and aspect ratio of grains and themetallographic observation of cavities have also been done. These results have verifiedthat the electric field improves the superplasticity during superplastically free bulging ofduralumin LY12CZ and that it is possible to utilize superplastic defonnation with elec-tric field in industrial practice. 展开更多
关键词 aluminum alloys electric field SUPERPLASTICITY BULGING
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Analysis of impulse electric field effect on organic exhaust gas decomposition
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作者 Zhang Yu Jin Xin-yu +1 位作者 Jiang Xuan-zhen Wang Rui 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 1999年第1期61-66,共6页
The technique of organic exhaust gas decomposition with impulse corono dischrge plasma has been investigated in this study. It has been discovered that the impulse electric field affected the decomposition efficiency ... The technique of organic exhaust gas decomposition with impulse corono dischrge plasma has been investigated in this study. It has been discovered that the impulse electric field affected the decomposition efficiency with the secondary electron emission coefficient (δ) of the corona electrode as an intermediary: when the impulse voltage power ( W ) was fixed the corona electrode material with higher δ could induce higher decomposition efficiency. In these experiments, wolfram electrode which has the highest δ has really induced the highest decomposition efficiency. 展开更多
关键词 impulse electric field power impulse corona discharge secondary electron emission coefficient organic exhaust gas decomposition.
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A kind of informationon short-term and imminent earthquake precursors-research on atmospheric electric field anomalies before earthquakes
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作者 郝建国 唐天明 李德瑞 《Acta Seismologica Sinica(English Edition)》 CSCD 1998年第1期116-126,共11页
The long time practice of observational research on earthquake prediction has shown that the information on shortterm and imminent earthquake precursors can hardly be detected, but it is very important for practical ... The long time practice of observational research on earthquake prediction has shown that the information on shortterm and imminent earthquake precursors can hardly be detected, but it is very important for practical and effective earthquake prediction. The result of analysis and study in this paper has shown that the anomaly of quasi static atmospheric electric field may be a kind of reliable information on short term and imminent earthquake precursors.On such a basis, the 20 years′ continuous and reliable data of atmospheric electric field observed at the Baijiatuan seismic station are used to study the correlation between the anomalies in seismic activity and relative quiet periods bear on the occurrence of near earthquakes within 200 km range around Beijing after the Tangshan earthquake. The observational results recently reported before hand in written form and earthquakes that actually occurred in near field in corresponding time periods are compared and analyzed. The efficacy of these written prediction opinions about near earthquakes in the recent 10 years is tested. From the test results, the brilliant prospect that the anomaly of quasi static atmospheric electric field may really become a reliable mark for making short term and imminent earthquake predictions is discussed. Besides, as a preliminary step, some judgment indexes for predicting earthquakes by use of the observational data of atmospheric electric field before earthquakes are put forward. In the last part, it is pointed out that it would be possible to obtain more believable judgment indexes for determining the three elements of near earthquakes before greater earthquakes ( M S5) only if a relatively reasonable station network (2~4 stations every 10 000 km 2) is deployed and further investigation is made. 展开更多
关键词 atmospheric electric field judgment index monthly report form
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On the Spontaneous Electric Field in a Ferroelectric Body
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作者 张颖 《Journal of Modern Transportation》 1998年第2期39-49,共11页
The incompatibility of the spontaneous polarization across the interface between two grains may induce internal stress and electric fields in a ferroelectric body. The built up of stresses and electric fields may ser... The incompatibility of the spontaneous polarization across the interface between two grains may induce internal stress and electric fields in a ferroelectric body. The built up of stresses and electric fields may seriously affect the functioning of ferroelectric materials. In this article, the effects of the incompatibility of the spontaneous polarization for various types of interfaces on the electric fields are discussed. Numerical results indicate that the incompatibility of the spontaneous polarization may result in the electric field being unbounded when the interface does not have a continuous normal. 展开更多
关键词 FERROelectricS spontaneous polarization electric field
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External Electric Field Dependence of Optical Absorbance in SnO_2 Nanoclusters
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作者 WANG Dehuang (Dept. of Physics, Peking University, National Laboratory for Superlattice and Microstructures, Beijing 100871, CHN) CHENG Humin, MA Jiming (Dept. of Chemistry, Peking University, Beijing 100871, CHN) 《Semiconductor Photonics and Technology》 CAS 1998年第4期256-258,共3页
The optical absorbance in near UV wavelength region in SnO 2 nanoclusters in an external electric field is determined at room temperature. The absorbance spectra as applied field and the absorbance variations with th... The optical absorbance in near UV wavelength region in SnO 2 nanoclusters in an external electric field is determined at room temperature. The absorbance spectra as applied field and the absorbance variations with the applied field are obtained.The relation between absorbance change and applied field is non-linear, and is saturated at high field region. 展开更多
关键词 ABSORBANCE External electric field SnO 2 Nanoclusters
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Influence of filler characteristics on particle removal in fluid catalytic cracking slurry under an alternating electric field
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作者 Qiang Li Hui-Zhen Yang +3 位作者 Can Yang Qing-Zhu Qiu Wei-Wei Xu Zhao-Zeng Liu 《Petroleum Science》 SCIE EI CAS CSCD 2024年第3期2102-2111,共10页
The characteristics of the packing material under an alternating electric field are an important factor in the removal of FCCS particles.In this study,the electric field distribution of a separation unit consisting of... The characteristics of the packing material under an alternating electric field are an important factor in the removal of FCCS particles.In this study,the electric field distribution of a separation unit consisting of packed spheres under an alternating electric field is simulated,and the movement mechanism of catalyst particles is analysed.An"effective contact point"model is derived to predict the adsorption of filler contact points on catalyst particles under the alternating electric field,and the model is validated by simulations and experiments.The numerical calculation and experimental results indicate that the electrical properties of the filler spheres,the filler angleθ,and the frequency f of the alternating electric field affect the adsorption of catalyst particles.As the frequency of the electric field increases,the particle removal efficiency of the high-conductivity filler(silicon carbide)increases and then settles,and the separation efficiency of the low-conductivity filler(glass,zirconia)is not sensitive to the change in electric field frequency. 展开更多
关键词 Fluid catalyticcracking slurry(FCCS) PARTICLE AC electric field FILLERS REMOVAL
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Coexisting fast–slow dendritic traveling waves in a 3D-array electric field coupled neuronal network
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作者 魏熙乐 任泽宇 +2 位作者 卢梅丽 樊亚琴 常思远 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第6期614-626,共13页
Coexistence of fast and slow traveling waves without synaptic transmission has been found in hhhippocampal tissues,which is closely related to both normal brain activity and abnormal neural activity such as epileptic ... Coexistence of fast and slow traveling waves without synaptic transmission has been found in hhhippocampal tissues,which is closely related to both normal brain activity and abnormal neural activity such as epileptic discharge. However, the propagation mechanism behind this coexistence phenomenon remains unclear. In this paper, a three-dimensional electric field coupled hippocampal neural network is established to investigate generation of coexisting spontaneous fast and slow traveling waves. This model captures two types of dendritic traveling waves propagating in both transverse and longitude directions: the N-methyl-D-aspartate(NMDA)-dependent wave with a speed of about 0.1 m/s and the Ca-dependent wave with a speed of about 0.009 m/s. These traveling waves are synaptic-independent and could be conducted only by the electric fields generated by neighboring neurons, which are basically consistent with the in vitro data measured experiments. It is also found that the slow Ca wave could trigger generation of fast NMDA waves in the propagation path of slow waves whereas fast NMDA waves cannot affect the propagation of slow Ca waves. These results suggest that dendritic Ca waves could acted as the source of the coexistence fast and slow waves. Furthermore, we also confirm the impact of cellular spacing heterogeneity on the onset of coexisting fast and slow waves. The local region with decreasing distances among neighbor neurons is more liable to promote the onset of spontaneous slow waves which, as sources, excite propagation of fast waves. These modeling studies provide possible biophysical mechanisms underlying the neural dynamics of spontaneous traveling waves in brain tissues. 展开更多
关键词 hippocampal network EPILEPTIFORM dendritic oscillation traveling wave electric field coupling
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Constructing Built-In Electric Fields with Semiconductor Junctions and Schottky Junctions Based on Mo-MXene/Mo-Metal Sulfides for Electromagnetic Response
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作者 Xiaojun Zeng Xiao Jiang +2 位作者 Ya Ning Yanfeng Gao Renchao Che 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第10期453-473,共21页
The exploration of novel multivariate heterostructures has emerged as a pivotal strategy for developing high-performance electromagnetic wave(EMW)absorption materials.However,the loss mechanism in traditional heterost... The exploration of novel multivariate heterostructures has emerged as a pivotal strategy for developing high-performance electromagnetic wave(EMW)absorption materials.However,the loss mechanism in traditional heterostructures is relatively simple,guided by empirical observations,and is not monotonous.In this work,we presented a novel semiconductor-semiconductor-metal heterostructure sys-tem,Mo-MXene/Mo-metal sulfides(metal=Sn,Fe,Mn,Co,Ni,Zn,and Cu),including semiconductor junctions and Mott-Schottky junctions.By skillfully combining these distinct functional components(Mo-MXene,MoS_(2),metal sulfides),we can engineer a multiple heterogeneous interface with superior absorption capabilities,broad effective absorption bandwidths,and ultrathin matching thickness.The successful establishment of semiconductor-semiconductor-metal heterostructures gives rise to a built-in electric field that intensifies electron transfer,as confirmed by density functional theory,which collaborates with multiple dielectric polarization mechanisms to substantially amplify EMW absorption.We detailed a successful synthesis of a series of Mo-MXene/Mo-metal sulfides featuring both semiconductor-semiconductor and semiconductor-metal interfaces.The achievements were most pronounced in Mo-MXene/Mo-Sn sulfide,which achieved remarkable reflection loss values of-70.6 dB at a matching thickness of only 1.885 mm.Radar cross-section calculations indicate that these MXene/Mo-metal sulfides have tremendous potential in practical military stealth technology.This work marks a departure from conventional component design limitations and presents a novel pathway for the creation of advanced MXene-based composites with potent EMW absorption capabilities. 展开更多
关键词 Semiconductor-semiconductor-metal heterostructure Semiconductor junctions Mott-Schottky junctions Built-in electric field Electromagnetic wave absorption
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Enabling built-in electric fields on rhenium-vacancy-rich heterojunction interfaces of transition-metal dichalcogenides for pH-universal efficient hydrogen and electric energy generation
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作者 Benzhi Wang Lixia Wang +3 位作者 Ji Hoon Lee Tayirjan Taylor Isimjan Hyung Mo Jeong Xiulin Yang 《Carbon Energy》 SCIE EI CAS CSCD 2024年第9期195-209,共15页
Most advanced hydrogen evolution reaction(HER)catalysts show high activity under alkaline conditions.However,the performance deteriorates at a natural and acidic pH,which is often problematic in practical applications... Most advanced hydrogen evolution reaction(HER)catalysts show high activity under alkaline conditions.However,the performance deteriorates at a natural and acidic pH,which is often problematic in practical applications.Herein,a rhenium(Re)sulfide–transition-metal dichalcogenide heterojunc-tion catalyst with Re-rich vacancies(NiS_(2)-ReS_(2)-V)has been constructed.The optimized catalyst shows extraordinary electrocatalytic HER performance over a wide range of pH,with ultralow overpotentials of 42,85,and 122 mV under alkaline,acidic,and neutral conditions,respectively.Moreover,the two-electrode system with NiS_(2)-ReS_(2)-V1 as the cathode provides a voltage of 1.73 V at 500 mA cm^(-2),superior to industrial systems.Besides,the open-circuit voltage of a single Zn–H_(2)O cell with NiS_(2)-ReS_(2)-V1 as the cathode can reach an impressive 90.9% of the theoretical value,with a maximum power density of up to 31.6 mW cm^(-2).Moreover,it shows remarkable stability,with sustained discharge for approximately 120 h at 10 mA cm^(-2),significantly outperforming commercial Pt/C catalysts under the same conditions in all aspects.A series of systematic characterizations and theoretical calculations demonstrate that Re vacancies on the heterojunction interface would generate a stronger built-in electric field,which profoundly affects surface charge distribution and subsequently enhances HER performance. 展开更多
关键词 built-in electric field ELECTROCATALYSTS hydrogen evolution reaction self-powered system water splitting Zn-H_(2)O cell
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The action mechanism of the work done by the electric field force on moving charges to stimulate the emergence of carrier generation/recombination in a PN junction
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作者 Lingyun GUO Yizhan YANG +1 位作者 Wanli YANG Yuantai HU 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2024年第6期1001-1014,共14页
It is discovered that the product of the current and the electric field in a PN junction should be regarded as the rate of work(power)done by the electric field force on moving charges(hole current and electron curren... It is discovered that the product of the current and the electric field in a PN junction should be regarded as the rate of work(power)done by the electric field force on moving charges(hole current and electron current),which was previously misinterpreted as solely a Joule heating effect.We clarify that it is exactly the work done by the electric field force on the moving charges to stimulate the emergence of non-equilibrium carriers,which triggers the novel physical phenomena.As regards to Joule heat,we point out that it should be calculated from Ohm’s law,rather than simply from the product of the current and the electric field.Based on this understanding,we conduct thorough discussion on the role of the electric field force in the process of carrier recombination and carrier generation.The thermal effects of carrier recombination and carrier generation followed are incorporated into the thermal equation of energy.The present study shows that the exothermic effect of carrier recombination leads to a temperature rise at the PN interface,while the endothermic effect of carrier generation causes a temperature reduction at the interface.These two opposite effects cause opposite heat flow directions in the PN junction under forward and backward bias voltages,highlighting the significance of managing device heating phenomena in design considerations.Therefore,this study possesses referential significance for the design and tuning on the performance of piezotronic devices. 展开更多
关键词 piezoelectric semiconductor(PS) work done by electric field force thermal effect piezotronic device resistivity conductivity
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Electric field and force characteristic of dust aerosol particles on the surface of high-voltage transmission line
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作者 刘滢格 李兴财 +2 位作者 王娟 马鑫 孙文海 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第1期368-378,共11页
High-voltage transmission lines play a crucial role in facilitating the utilization of renewable energy in regions prone to desertification. The accumulation of atmospheric particles on the surface of these lines can ... High-voltage transmission lines play a crucial role in facilitating the utilization of renewable energy in regions prone to desertification. The accumulation of atmospheric particles on the surface of these lines can significantly impact corona discharge and wind-induced conductor displacement. Accurately quantifying the force exerted by particles adhering to conductor surfaces is essential for evaluating fouling conditions and making informed decisions. Therefore, this study investigates the changes in electric field intensity along branched conductors caused by various fouling layers and their resulting influence on the adhesion of dust particles. The findings indicate that as individual particle size increases, the field strength at the top of the particle gradually decreases and eventually stabilizes at approximately 49.22 k V/cm, which corresponds to a field strength approximately 1.96 times higher than that of an unpolluted transmission line. Furthermore,when particle spacing exceeds 15 times the particle size, the field strength around the transmission line gradually decreases and approaches the level observed on non-adhering surface. The electric field remains relatively stable. In a triangular arrangement of three particles, the maximum field strength at the tip of the fouling layer is approximately 1.44 times higher than that of double particles and 1.5 times higher compared to single particles. These results suggest that particles adhering to the transmission line have a greater affinity for adsorbing charged particles. Additionally, relevant numerical calculations demonstrate that in dry environments, the primary adhesion forces between particles and transmission lines follow an order of electrostatic force and van der Waals force. Specifically, at the minimum field strength, these forces are approximately74.73 times and 19.43 times stronger than the gravitational force acting on the particles. 展开更多
关键词 high-voltage current electric field aerosol particles force characteristic
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A new electric field mill array with each of the mill’s rotor controlled precisely by a GPS module:Equipment and initial results
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作者 Kozo Yamashita Hironobu Fujisaka +4 位作者 DaoHong Wang Hiroyuki Iwasaki Kazuo Yamamoto Koichiro Michimoto Masashi Hayakawa 《Earth and Planetary Physics》 EI CAS CSCD 2024年第2期423-435,共13页
We have newly designed an electrostatic sensor,called an electric field mill(EFM),to simplify the estimation of the charge position and charge amount transferred by lightning discharges.It is necessary for this remote... We have newly designed an electrostatic sensor,called an electric field mill(EFM),to simplify the estimation of the charge position and charge amount transferred by lightning discharges.It is necessary for this remote estimation of the transferred charge to measure electric field changes caused by charge loss at the time of a lightning strike at multiple locations.For multiple-station measurement of electric field changes,not only speed but also phase for exposure and shielding of the sensing plates inside each EFM of the array should be synchronized to maintain the sensitivities of the deployed instruments.Currently,there is no such EFM with specified speed and phase control performance of the rotary part.Thus,we developed a new EFM in which the rotary mechanism was controlled consistently to within 3%error by a GPS module.Five EFMs had been distributed in the Hokuriku area of Japan during the winter season of 2022-2023 for a test observation.Here we describe the design and a simple calibration method for our new EFM array.Data analysis method based on the assumption of a simple monopole charge structure is also summarized.For validation,locations of assumed point charges were compared with three-dimensional lightning mapping data estimated by radio observations in the MF-HF bands.Initial results indicated the validity to estimate transferred charge amounts and positions of winter cloud-to-ground lightning discharges with our new EFM array. 展开更多
关键词 LIGHTNING electrostatic field electric field mill electric field change
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Effect of applied electric fields on supralinear dendritic integration of interneuron
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作者 樊亚琴 魏熙乐 +1 位作者 卢梅丽 伊国胜 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第2期84-95,共12页
Evidences show that electric fields(EFs)induced by the magnetic stimulation could modulates brain activities by regulating the excitability of GABAergic interneuron.However,it is still unclear how and why the EF-induc... Evidences show that electric fields(EFs)induced by the magnetic stimulation could modulates brain activities by regulating the excitability of GABAergic interneuron.However,it is still unclear how and why the EF-induced polarization affects the interneuron response as the interneuron receives NMDA synaptic inputs.Considering the key role of NMDA receptor-mediated supralinear dendritic integration in neuronal computations,we suppose that the applied EFs could functionally modulate interneurons’response via regulating dendritic integration.At first,we build a simplified multi-dendritic circuit model with inhomogeneous extracellular potentials,which characterizes the relationship among EF-induced spatial polarizations,dendritic integration,and somatic output.By performing model-based singular perturbation analysis,it is found that the equilibrium point of fast subsystem can be used to asymptotically depict the subthreshold input–output(sI/O)relationship of dendritic integration.It predicted that EF-induced strong depolarizations on the distal dendrites reduce the dendritic saturation output by reducing driving force of synaptic input,and it shifts the steep change of sI/O curve left by reducing stimulation threshold of triggering NMDA spike.Also,the EF modulation prefers the global dendritic integration with asymmetric scatter distribution of NMDA synapses.Furthermore,we identify the respective contribution of EF-regulated dendritic integration and EF-induced somatic polarization to an action potential generation and find that they have an antagonistic effect on AP generation due to the varied NMDA spike threshold under EF stimulation. 展开更多
关键词 GABAergic interneuron electrical field supralinear dendritic integration action potential generation
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Internal electric field modulation by copper vacancy concentration of cuprous sulfide nanosheets for enhanced selective CO_(2) photoreduction
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作者 Xian Shi Weidong Dai +4 位作者 Xiaoqian Li Yang Bai Qin Ren Yao Lei Xing'an Dong 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第4期324-330,共7页
Although the internal electric field(IEF)of photocatalysts is acknowledged as a potent driving force for photocharge separation,modulating the IEF intensity to achieve enhanced photocatalytic performances remains a ch... Although the internal electric field(IEF)of photocatalysts is acknowledged as a potent driving force for photocharge separation,modulating the IEF intensity to achieve enhanced photocatalytic performances remains a challenge.Herein,cuprous sulfide nanosheets with different Cu vacancy concentration were employed to study IEF modulation and corresponding direct charge transfer.Among the samples,Cu_(1.8)S nanosheets possessed intensified IEF intensity compared with those of Cu_(2)S and Cu_(1.95)S nanosheets,suggesting that an enhanced IEF intensity could be achieved by introducing more Cu vacancies.This intensified IEF of Cu_(1.8)S nanosheets induced numerous photogenerated electrons to migrate to its surface,and the dissociative electrons were then captured by Cu vacancies,resulting in efficient charge separation spatially.In addition,the Cu vacancies on Cu_(1.8)S nanosheets accumulated electrons as active sites to lower the energy barrier of rate-determining step of CO_(2)photoreduction,leading to the selective conversion of CO_(2)to CO.Herein,the manipulation of IEF intensity through Cu vacancy concentration regulation of cuprous sulfide photocatalysts for efficient charge separation has been discussed,providing a scientific strategy to rationally improve photocata lytic performances for solar energy conversion. 展开更多
关键词 Internal electric field intensity Cuprous sulfide photocatalysts Cu vacancies Charge separation Selective CO_(2) photoreduction
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Extending microwave-frequency electric-field detection through single transmission peak method
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作者 刘青 陈进湛 +6 位作者 王赫 张杰 阮伟民 伍国柱 郑顺元 罗景庭 宋振飞 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第5期417-423,共7页
The strength of microwave(MW)electric field can be observed with high precision by using the standard electromagnetically induced transparency and Aulter–Towns(EIT-AT)technique,when its frequency is resonant or nearl... The strength of microwave(MW)electric field can be observed with high precision by using the standard electromagnetically induced transparency and Aulter–Towns(EIT-AT)technique,when its frequency is resonant or nearly-resonant with the Rydberg transition frequency.As the detuning of MW field increases,one of the transmission peaks(single peak)is easier to measure due to its increased amplitude.It can be found that the central symmetry point of the two transmission peaks f_(1/2)is only related to the detuning of MW field△_(MW)and central symmetry point f_(0)of resonant MW field,satisfying the relation f_(1/2)=△_(MW)/2+f_(0).Thus,we demonstrate a single transmission peak method that the MW E-field can be determined by interval between the position of single peak and f_(1/2).We use this method to measure continuous frequencies in a band from-200 MHz to 200 MHz of the MW field.The experimental results and theoretical analysis are presented to describe the effectiveness of this method.For 50 MHz<△_(MW)<200 MHz,this method solves the problem that the AT splitting cannot be measured by using the standard EIT-AT techniques or multiple atomic-level Rydberg atom schemes. 展开更多
关键词 microwave electric field Rydberg atom electromagnetically induced transparency(EIT) Aulter-Towns splitting
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Oscillation of Dzyaloshinskii–Moriya interaction driven by weak electric fields
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作者 陈润泽 曹安妮 +3 位作者 王馨苒 柳洋 杨洪新 赵巍胜 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第2期487-491,共5页
Dzyaloshinskii–Moriya interaction(DMI) is under extensive investigation considering its crucial status in chiral magnetic orders, such as Néel-type domain wall(DW) and skyrmions. It has been reported that the in... Dzyaloshinskii–Moriya interaction(DMI) is under extensive investigation considering its crucial status in chiral magnetic orders, such as Néel-type domain wall(DW) and skyrmions. It has been reported that the interfacial DMI originating from Rashba spin–orbit coupling(SOC) can be linearly tuned with strong external electric fields. In this work, we experimentally demonstrate that the strength of DMI exhibits rapid fluctuations, ranging from 10% to 30% of its original value, as a function of applied electric fields in Pt/Co/MgO heterostructures within the small field regime(< 10-2V/nm). Brillouin light scattering(BLS) experiments have been performed to measure DMI, and first-principles calculations show agreement with this observation, which can be explained by the variation in orbital hybridization at the Co/MgO interface in response to the weak electric fields. Our results on voltage control of DMI(VCDMI) suggest that research related to the voltage control of magnetic anisotropy for spin–orbit torque or the motion control of skyrmions might also have to consider the role of the external electric field on DMI as small voltages are generally used for the magnetoresistance detection. 展开更多
关键词 Dzyaloshinskii-Moriya interaction weak electric field control effect Rashba spin-orbit coupling interfacial orbital hybridization
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VSe_(2)/V_(2)C heterocatalyst with built-in electric field for efficient lithium-sulfur batteries:Remedies polysulfide shuttle and conversion kinetics
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作者 Yanwei Lv Lina Bai +7 位作者 Qi Jin Siyu Deng Xinzhi Ma Fengfeng Han Juan Wang Lirong Zhang Lili Wu Xitian Zhang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第2期397-409,I0010,共14页
Lithium sulfur(Li-S)battery is a kind of burgeoning energy storage system with high energy density.However,the electrolyte-soluble intermediate lithium polysulfides(Li PSs)undergo notorious shuttle effect,which seriou... Lithium sulfur(Li-S)battery is a kind of burgeoning energy storage system with high energy density.However,the electrolyte-soluble intermediate lithium polysulfides(Li PSs)undergo notorious shuttle effect,which seriously hinders the commercialization of Li-S batteries.Herein,a unique VSe_(2)/V_(2)C heterostructure with local built-in electric field was rationally engineered from V_(2)C parent via a facile thermal selenization process.It exquisitely synergizes the strong affinity of V_(2)C with the effective electrocatalytic activity of VSe_(2).More importantly,the local built-in electric field at the heterointerface can sufficiently promote the electron/ion transport ability and eventually boost the conversion kinetics of sulfur species.The Li-S battery equipped with VSe_(2)/V_(2)C-CNTs-PP separator achieved an outstanding initial specific capacity of 1439.1 m A h g^(-1)with a high capacity retention of 73%after 100 cycles at0.1 C.More impressively,a wonderful capacity of 571.6 mA h g^(-1)was effectively maintained after 600cycles at 2 C with a capacity decay rate of 0.07%.Even under a sulfur loading of 4.8 mg cm^(-2),areal capacity still can be up to 5.6 m A h cm^(-2).In-situ Raman tests explicitly illustrate the effectiveness of VSe_(2)/V_(2)C-CNTs modifier in restricting Li PSs shuttle.Combined with density functional theory calculations,the underlying mechanism of VSe_(2)/V_(2)C heterostructure for remedying Li PSs shuttling and conversion kinetics was deciphered.The strategy of constructing VSe_(2)/V_(2)C heterocatalyst in this work proposes a universal protocol to design metal selenide-based separator modifier for Li-S battery.Besides,it opens an efficient avenue for the separator engineering of Li-S batteries. 展开更多
关键词 Li-S battery Shuttle effect Separator modifier VSe_(2)/V_(2)C heterostructure Built-in electric field
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Effects of vacancy and external electric field on the electronic properties of the MoSi_(2)N_(4)/graphene heterostructure
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作者 梁前 罗祥燕 +3 位作者 钱国林 王远帆 梁永超 谢泉 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第3期542-550,共9页
Recently,the newly synthesized septuple-atomic layer two-dimensional(2D)material MoSi_(2)N_(4)(MSN)has attracted attention worldwide.Our work delves into the effect of vacancies and external electric fields on the ele... Recently,the newly synthesized septuple-atomic layer two-dimensional(2D)material MoSi_(2)N_(4)(MSN)has attracted attention worldwide.Our work delves into the effect of vacancies and external electric fields on the electronic properties of the MSN/graphene(Gr)heterostructure using first-principles calculation.We find that four types of defective structures,N-in,N-out,Si and Mo vacancy defects of monolayer MSN and MSN/Gr heterostructure are stable in air.Moreover,vacancy defects can effectively modulate the charge transfer at the interface of the MSN/Gr heterostructure as well as the work function of the pristine monolayer MSN and MSN/Gr heterostructure.Finally,the application of an external electric field enables the dynamic switching between n-type and p-type Schottky contacts.Our work may offer the possibility of exceeding the capabilities of conventional Schottky diodes based on MSN/Gr heterostructures. 展开更多
关键词 MoSi_(2)N_(4) vacancy defects external electric field Schottky contacts
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Modulating charge separation and transfer for high-performance photoelectrodes via built-in electric field
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作者 Houyan Cheng Peng Liu +3 位作者 Yuntao Cui Ru Ya Yuxiang Hu Jinshu Wang 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第5期1126-1146,共21页
Constructing a built-in electric field has emerged as a key strategy for enhancing charge separation and transfer,thereby improving photoelectrochemical performance.Recently,considerable efforts have been devoted to t... Constructing a built-in electric field has emerged as a key strategy for enhancing charge separation and transfer,thereby improving photoelectrochemical performance.Recently,considerable efforts have been devoted to this endeavor.This review systematically summarizes the impact of built-in electric fields on enhancing charge separation and transfer mechanisms,focusing on the modulation of built-in electric fields in terms of depth and orderliness.First,mechanisms and tuning strategies for built-in electric fields are explored.Then,the state-of-the-art works regarding built-in electric fields for modulating charge separation and transfer are summarized and categorized according to surface and interface depth.Finally,current strategies for constructing bulk built-in electric fields in photoelectrodes are explored,and insights into future developments for enhancing charge separation and transfer in high-performance photoelectrochemical applications are provided. 展开更多
关键词 photoelectrochemical water splitting bulk built-in electric field cation intercalation charge separation and transfer
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Self-Adaptive and Electric Field-Driven Protective Layer with Anchored Lithium Deposition Enable Stable Lithium Metal Anode
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作者 Ting Chen Luchao Yue +8 位作者 Guoqiang Shu Qing Yang Dong Wang Ruoyang Wang Xianyan Qiao Yan Sun Benhe Zhong Zhenguo Wu Xiaodong Guo 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第3期32-40,共9页
Lithium metal battery has great development potential because of its lowest electrochemical potential and highest theoretical capacity.However,the uneven deposition of Li^(+)flux in the process of deposition and strip... Lithium metal battery has great development potential because of its lowest electrochemical potential and highest theoretical capacity.However,the uneven deposition of Li^(+)flux in the process of deposition and stripping induces the vigorous growth of lithium dendrites,which results in severely battery performance degradation and serious safety hazards.Here,the tetragonal BaTiO3 polarized by high voltage corona was used to build an artificial protective layer with uniform positive polarization direction,which enables uniform Li^(+)flux.In contrast to traditional strategies of using protective layer,which can guide the uniform deposition of lithium metal.The ferroelectric protective layer can accurately anchor the Li^(+)and achieve bottom deposition of lithium due to the automatic adjustment of the electric field.Simultaneously,the huge volume changes caused by Li^(+)migration change of the lithium metal anode during charging and discharging is functioned to excite the piezoelectric effect of the protective layer,and achieve seamless dynamic tuning of lithium deposition/stripping.This dynamic effect can accurately anchor and capture Li^(+).Finally,the layer-modified Li anode enables reversible Li plating/stripping over 1500 h at 1 mA cm^(-2)and 50℃in symmetric cells.In addition,the assembled Li-S full cell exhibits over 300 cycles with N/P≈1.35.This work provides a new perspective on the uniform Li^(+)flux at the Li-anode interface of the artificial protective layer. 展开更多
关键词 dense plating/stripping process electric field ferroelectric materials lithium metal batteries solid electrolyte interphase
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