Chemical adsorption on 2D dielectric nanosheets for matrix free nanocomposites with ultrahigh electrical energy storage

Relaxor ferroelectric polymers display great potential in capacitor dielectric applications because of their excellent flexibility,light weight,and high dielectric constant.However,their electrical energy storage capacity is limited by their high conduction losses and low dielectric strength,which primarily originates from the impact-ionization-induced electron multiplication,low mechanical modulus,and low thermal conductivity of the dielectric polymers.Here a matrix free strategy is developed to effectively suppress electron multiplication effects and to enhance mechanical modulus and thermal conductivity of a dielectric polymer,which involves the chemical adsorption of an electron barrier layer on boron nitride nanosheet surfaces by chemically adsorbing an amino-containing polymer.A dramatic decrease of leakage current(from 2.4×10^(-6)to 1.1×10^(-7)A cm^(-2)at 100 MV m^(-1))and a substantial increase of breakdown strength(from 340 to 742 MV m^(-1))were achieved in the nanocompostes,which result in a remarkable increase of discharge energy density(from 5.2 to 31.8 J cm^(-3)).Moreover,the dielectric strength of the nanocomposites suffering an electrical breakdown could be restored to 88%of the original value.This study demonstrates a rational design for fabricating dielectric polymer nanocomposites with greatly enhanced electric energy storage capacity.

Value assessment of hydrogen-based electrical energy storage in view of electricity spot market

Hydrogen as an energy carrier represents one of the most promising carbon-free energy solutions.The ongoing development of power-to-gas(Pt G)technologies that supports large-scale utilization of hydrogen is therefore expected to support hydrogen economy with a final breakthrough.In this paper,the economic performance of a MW-sized hydrogen system,i.e.a composition of water electrolysis,hydrogen storage,and fuel cell combined heat and power plant(FCCHP),is assessed as an example of hydrogen-based bidirectional electrical energy storage(EES).The analysis is conducted in view of the Danish electricity spot market that has high price volatility due to its high share of wind power.An economic dispatch model is developed as a mixed-integer programming(MIP)problem to support the estimation of variable cost of such a system taking into account a good granularity of the technical details.Based on a projected technology improvement by 2020,sensitivity analysis is conducted to illustrate how much the hydrogen-based EES is sensitive to variations of the hydrogen price and the capacity of hydrogen storage.

Application and Development of Electric Energg Storage Technology in China

This paper describes the background of disseminating and applying electric energy storage technology in China. Its present application status is introduced, including governmental support and guidance, analyses on economic benefits and typical projects, etc.

Energy storage systems:a review

The world is rapidly adopting renewable energy alternatives at a remarkable rate to address the ever-increasing environmental crisis of CO_(2) emissions.Renewable energy system offers enormous potential to decarbonize the environment because they produce no greenhouse gases or other polluting emissions.However,the RES relies on natural resources for energy generation,such as sunlight,wind,water,geothermal,which are generally un-predictable and reliant on weather,season,and year.To account for these intermittencies,renewable energy can be stored using various techniques and then used in a consistent and controlled manner as needed.Several researchers from around the world have made substantial contributions over the last century to developing novel methods of energy storage that are efficient enough to meet increasing energy demand and technological break-throughs.This review attempts to provide a critical review of the advancements in the energy storage system from 1850-2022,including its evolution,classification,operating principles and comparison.

Coordination of battery energy storage and power-to-gas in distribution systems

Concerning the rapid development and deployment of Renewable Energy Systems(RES)and Energy Storage System(ESS)including Power-to-Gas(PtG)technology can significantly improve the friendliness of the integration of renewable energy.The purpose of this paper is to develop a coordination strategy between a battery energy storage and a PtG system.A simulation case is created with an electrical and a natural gas grid as well as steady-state models of RES and PtG.Charging strategies are developed accordingly for the ESS as well as production strategies for the PtG system.The size of the ESS is then observed with regards to the RES and PtG systems.As a result,it is found that surplus energy from RES can be stored and then used to support the electrical grid and the natural gas grid.It is also concluded that the capacity of the ESS can be affected,given a proper charging and production strategy,which needs to be tailored to each system.As shown in the paper,due to an improper charging strategy in the first quarter of a month,the ESSPC size has increased from its optimal size of 314 MWh to roughly 576 MWh.It can also be seen that given a proper charging strategy,this capacity can be less than 200 MWh.

Energy cost minimization through optimization of EV, home and workplace battery storage

Besides grid-to-vehicle(G2 V) and vehicle-to-grid(V2 G) functions, the battery of an electric vehicle(EV) also has the specific feature of mobility. This means that EVs not only have the potential to utilize the storage of cheap electricity for use in high energy price periods, but can also transfer energy from one place to another place. Based on these special features of an EV battery, a new EV energy scheduling method has been developed and is described in this article. The approach is aimed at optimizing the utilization EV energy for EVs that are regularly used in multiple places. The objective is to minimize electricity costs from multiple meter points. This work applies real data in order to analyze the effectiveness of the method. The results show that by applying the control strategy presented in this paper at locations where the EVs are parked, the electricity cost can be reduced without shifting the demand and lowering customer's satisfaction. The effects of PV size and number of EVs on our model are also analyzed in this paper. This model has the potential to be used by energy system designers as a new perspective to determine optimal sizes of generators or storage devices in energy systems.

Advanced inorganic/polymer hybrid electrolytes for all-solid-state lithium batteries

Solid-state batteries have become a frontrunner in humankind’s pursuit of safe and stable energy storage systems with high energy and power density.Electrolyte materials,currently,seem to be the Achilles’heel of solid-state batteries due to the slow kinetics and poor interfacial wetting.Combining the merits of solid inorganic electrolytes(SIEs)and solid polymer electrolytes(SPEs),inorganic/polymer hybrid electrolytes(IPHEs)integrate improved ionic conductivity,great interfacial compatibility,wide electrochemical stability window,and high mechanical toughness and flexibility in one material,having become a sought-after pathway to high-performance all-solid-state lithium batteries.Herein,we present a comprehensive overview of recent progress in IPHEs,including the awareness of ion migration fundamentals,advanced architectural design for better electrochemical performance,and a perspective on unconquered challenges and potential research directions.This review is expected to provide a guidance for designing IPHEs for next-generation lithium batteries,with special emphasis on developing high-voltage-tolerance polymer electrolytes to enable higher energy density and three-dimensional(3D)continuous ion transport highways to achieve faster charging and discharging.

High-performance nitrogen and sulfur co-doped nanotube-like carbon anodes for sodium ion hybrid capacitors

Sodium ion hybrid capacitors are of great concern in large-scale and cost-effective electrical energy storage owing to their high energy and power densities,as well as natural abundance and wide distribution of sodium.However,it is difficult to find a well-pleasing anode material that matches the high-performance cathode materials to achieve good energy and power output for sodium ion hybrid capacitors.In this paper,nitrogen and sulfur co-doped nanotube-like carbon prepared by a simple carbonization process of high sulfur-loaded polyaniline nanotubes is introduced as the anode.The assembled sodium ion half cell based on the optimal nanotube-like carbon delivers a high reversible capacity of ~304.8 mAh/g at 0.2 A/g and an excellent rate performance of ~124.8 mAh/g at 10 A/g in a voltage window of 0.01-2.5 V(versus sodium/sodium ion).For the hybrid capacitors assembled using the optimal nanotube-like carbon as the anode and high-capacity activated carbon as the cathode,high energy densities of ~100.2 Wh/kg at 250 W/kg and ~50.69 Wh/kg at 12,500 W/kg are achieved.