Pressure-Induced Metallization and Electrical Phase Diagram for Polycrystalline CaB_6 under High Pressure and Low Temperature

The electrical properties of polycrystaltine CaB6 are revealed by in-situ resistance measurements under high pressure and low temperature. Due to the existence of grain boundaries, polycrystalline CaB6 behaves with semiconducting transport properties, which is different from the semimetallic CaB6 single crystals. The temperaturedependent resistance measurement results show that before the structural phase transition at 12.3 GPa the high pressure first induces the metallization at 6.5 GPa for CAB6. Moreover, the phase diagram for CaB6 is drawn based on the investigated electric conducting properties and at least three different conducting phases are found even at moderate high pressure and low temperature, indicating that the electric nature of CaB6 is very sensitive to the environment.

EFFECT OF DISPERSED PHASE PARTICLES ON ELECTRICAL CONDUCTION OF PEO-NaSCN

Fast ionic conductors are one kind of solid state material with ionic conductivity as high as that of melten salts or liquid electrolytes.Ionic conductivity is one of the important parameters for characterizing a fast ionic conductor.For a long time materialists and chemists have made great efforts in search of new fast ionic conductors with high ionic conductivity.In view of structure,they have synthesised silver and copper fast ionic conductors with so called open structures.But it is not so successful for searching more applicable alkaline fast ionic conductors.Since polymer has flexibility for making thin film,it concentrates attention on the polymer-alkaline salt complex.Fenton et al.have first reported poly(ethylene oxide) (PEO)-alkaline salt complex.Later on Armard et al.have investigated the electrical property of PEO-NaSCN.

Lunar Phases and Atmospheric Electric Field

The association between the lunar phases and the atmospheric electric field has been investigated from the superposed epoch analysis of the long series of continuous data of the vertical electric field for Colaba, Bombay (18 ° 53'N, 73 ° 48'E 11 mASL) for the period 1947-1966. Also the periodicities in the atmospheric electric field have been studied from the spectral analysis of the data. The study has indicated that when the full moon is within 4 of the ecliptic plane i.e.,Bf 4 ° , the electric field peaks on the day of the full moon followed by a steep fall in the field values up to 4 days following the full moon day and there after it showed a steep increase. Also, the electric field has exhibited 5-9 day periodicity and its multiples are nearly always present. The periodicity in the electric field corresponds with the average time interval between the successive magnetic sector boundary (MSB ) crossings i.e., 7 days. On most of the occasions, the MSB crossing day is associated with a maximum of one or more of the wavelengths derived from the spectral analysis of the atmospheric electric field.

The Influence of Deposition Temperature on the Epitaxial Growth of La_(0.7)Ca_(0.3)MnO_3 Thin Film

The growth conditions of La0.7Ca0.3MnO3(LCMO) epitaxial thin film are investigated.The results indicate that the deposition temperature plays a crucial role on the growth mode of LCMO thin film.There is an optimal deposition temperature,To,for the epitaxial growth of LCMO thin film.Just only at the To,the real epitaxial LCMO thin film can be obtained.When the deposition temperature deviates from the To,the thin film tends to be polycrystalline,although it orientes growth along a certain direction(a or c axis).Moreover,the experimental results show that just only for the epitaxial thin film the ferromagnetic-paramagnetic transition temperature(i.e.the Courier temperature Tc) equals to the metal-semiconductor transition temperature(Tp).The ferromagnetic state shows metallicity and the paramagnetic state exhibits semiconducting character.

The electric and magnetic properties of epitaxially grown A0.5-xLaxSr0.5MnO3 （A=Pr, Nd） thin film

The epitaxial （single crystal-like） Pr0.4La0.1Sr0.5MnO3 （PLSMO） and Nd0.35La0.15Sr0.5MnO3 （NLSMO） thin films are prepared and characterized, and the electric and magnetic properties are examined. We find that both PLSMO and NLSMO have their own optimum deposition temperature （To） in their growing into epitaxial thin films. When the deposition temperature is higher than To, a c-axis oriented but polycrystalline thin film grows; when the deposition temperature is lower than To, the thin film tends to be a-axis oriented and also polycrystalline. The most important point is that for the epitaxial PLSMO and NLSMO thin films the electronic phase transitions are closely consistent with the magnetic phase transitions, i.e. an antiferromagnetic phase corresponds to an insulating state, a ferromagnetic phase corresponds to a metallic state and a paramagnetic phase corresponds to a semiconducting state, while for the polycrystalline thin films the electronic phase transitions are always not consistent with the magnetic transitions.

Effect of Electric Current on Diffusion of Aluminum in Ti3AlC2 into Zirconium Alloy

The spark plasma sintering（SPS） method was used to study the mechanism of reaction interface between Zr and Ti3AlC2 with electric current going through it. It was found that electric current greatly reduced the bonding temperature of Zr and Ti3AlC2. By the micro-structure analysis of the interface through SEM/EDS, it was found that Al atoms diffused from the Ti3AlC2 substrate into the Zr side and reacted with Zr to form the Zr-Al compounds at the interface, which is the strengthening mechanism of Ti3AlC2-Zr bonding. The thickness of reaction layers（Zr-Al alloy） was from 0.879 to 13.945 mm depending on different sintering condition. Current direction, heating rate, soaking time, pulse patterns all influenced the diffusion of Al atoms which affected the joining quality of Zr and Ti3AlC2.

Evaluation of Magnetic Field from Varied Permutation Power Transmission Line at High Technology Nano-Fab

In this study, the magnetic field was lessened by mirror array power cable system, and simulation of results predicted the best permutations to decrease electromagnetic influence （EMI） value below 0.4 mG at working space without any shielding. Furthermore, this innovative method will cost down at high technology nano-Fab especially for 28 nanometer process. Through the theoretical study and numerical simulation, we predict the best permutation for mitigating EMI noise from three-phase electric power lines system without any shielding system down to 1.2 mG in 3.0 m distance from applying I = 50 A at 60 Hz with 12 series cable tray system. Followed above discussions, this study indicated different and new perspectives with before opinions of some researcher. The measured magnetic field values on the nano-Fab are in good agreement with this simulation results. These good results give more confident to apply in new building nano-Fab system. Furthermore, this innovation will cost down for EMI shielding at high technology nano-Fab especially for 40 （and below） nanometer process.

Synthesis of TiO_2 visible light catalysts with controllable crystalline phase and morphology from Ti-bearing electric arc furnace molten slag

TiO_2 visible light catalysts with different crystalline phases and morphologies were synthesized from titanium-bearing electric arc furnace molten slag（Ti-bearing EAF slag）by using a simple acidolysis process.The effects of the p H of the HCl solution,liquid to solid ratio（RL/S,HCl solution to the residue ratio,m L/g） and acidolysis time on the micro-morphology and crystalline phase of as-prepared TiO_2 photocatalysts were systematically investigated.The results indicated that with decreasing p H in the HCl solution and increasing RL/S,the crystalline phase and micro-morphology of the obtained TiO_2 nanostructures tended to transform from anatase type TiO_2 with spherical nanoparticle structures to rutile type TiO_2 with needle-like nanorod structures.The acidolysis time had little influence on the crystalline phase but great impact on the size of the obtained TiO_2.The growth mechanism of TiO_2 from Ti-bearing EAF slag during the acidolysis process was also discussed.In addition,the influence of RL/Son the photocatalytic properties of the synthesized nanostructured TiO_2 was studied.The results showed that the photodegradation efficiency for Rhodamine B solution could reach 91.00% in 120 min when the RL/Swas controlled at 50：1.