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Electrostatic Structure of the Electron Phase-space Holes Generated by the Electron Two-stream Instability with a Finite Width 被引量:1
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作者 SANG Longlong WU Mingyu LU Quanming 《空间科学学报》 CSCD 北大核心 2017年第5期517-523,共7页
Space satellite observations in an electron phase-space hole(electron hole) have shown that bipolar structures are discovered at the parallel cut of parallel electric field, while unipolar structures spring from the p... Space satellite observations in an electron phase-space hole(electron hole) have shown that bipolar structures are discovered at the parallel cut of parallel electric field, while unipolar structures spring from the parallel cut of perpendicular electric field. Particle-in-cell(PIC) simulations have demonstrated that the electron bi-stream instability induces several electron holes during its nonlinear evolution. However, how the unipolar structure of the parallel cut of the perpendicular electric field formed in these electron holes is still an unsolved problem,especially in a strongly magnetized plasma(Ω_e >ω_(pe), where Ω_e is defined as electron gyrofrequency and ω_(pe) is defined as plasma frequency, respectively). In this paper, with two-dimensional(2D) electrostatic PIC simulations, the evolution of the electron two-stream instability with a finite width in strongly magnetized plasma is investigated. Initially, those conditions lead to monochromatic electrostatic waves, and these waves coalesce with each other during their nonlinear evolution. At last, a solitary electrostatic structure is formed. In such an electron hole, a bipolar structure is formed in the parallel cut. of parallel electric field, while a unipolar structure presents in the parallel cut of perpendicular electric field. 展开更多
关键词 electron phase-space hole Two-stream instability PIC simulation
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Effect of Ion Dynamics on the Evolution of Electron Phase-space Holes
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作者 WANG Peiran LU Quanming +1 位作者 WU Mingyu WANG Shui 《空间科学学报》 CAS CSCD 北大核心 2013年第4期413-417,共5页
The evolution of two-dimensional(2D) electron phase-space holes(electron holes) has been previously investigated with electrostatic Particle-in-Cell(PIC) simulations,which neglect ion dynamics.The electron holes... The evolution of two-dimensional(2D) electron phase-space holes(electron holes) has been previously investigated with electrostatic Particle-in-Cell(PIC) simulations,which neglect ion dynamics.The electron holes are found to be unstable to the transverse instability,and their evolution is determined by the combined action between the transverse instability and the stabilization by the background magnetic field.In this paper,the effect of ion dynamics on the evolution of an electron hole is studied.In weakly magnetized plasma(Ωe<ωpe,whereΩe andωpe are electron gyrofrequency and plasma frequency,respectively),the electron hole is still unstable to the transverse instability. However,it evolves a little faster and is destroyed in a shorter time when ion dynamics is considered. In strongly magnetized plasma(Ωe>ωpe),the electron hole is broken due to the lower hybrid waves, and its evolution is much faster. 展开更多
关键词 Ion dynamics electron holes Transverse instability Magnetized plasma
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Effect of normalized plasma frequency on electron phase-space orbits in a free-electron laser 被引量:2
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作者 吉驭嫔 王时建 +5 位作者 徐竟跃 徐勇根 刘晓旭 卢宏 黄小莉 张世昌 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第2期242-246,共5页
Irregular phase-space orbits of the electrons are harmful to the electron-beam transport quality and hence deteriorate the performance of a free-electron laser (FEL). In previous literature, it was demonstrated that... Irregular phase-space orbits of the electrons are harmful to the electron-beam transport quality and hence deteriorate the performance of a free-electron laser (FEL). In previous literature, it was demonstrated that the irregularity of the electron phase-space orbits could be caused in several ways, such as varying the wiggler amplitude and inducing sidebands. Based on a Hamiltonian model with a set of self-consistent differential equations, it is shown in this paper that the electron- beam normalized plasma frequency functions not only couple the electron motion with the FEL wave, which results in the evolution of the FEL wave field and a possible power saturation at a large beam current, but also cause the irregularity of the electron phase-space orbits when the normalized plasma frequency has a sufficiently large value, even if the initial energy of the electron is equal to the synchronous energy or the FEL wave does not reach power saturation. 展开更多
关键词 free-electron laser electron phase-space orbit normalized plasma frequency IRREGULARITY
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Quanta of the Phase-Space Areas Given by Intervals of Energy and Time Associated with Electron Transitions
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作者 Stanislaw Olszewski 《Journal of Modern Physics》 2017年第8期1158-1174,共17页
The paper examines the energy of electron transitions in an emission process and the time intervals necessary for that process. For simple quantum systems, the both parameters—that of energy and time—depend on the d... The paper examines the energy of electron transitions in an emission process and the time intervals necessary for that process. For simple quantum systems, the both parameters—that of energy and time—depend on the difference &Delta;n of the quantum numbers n labelling the beginning and end state of emission. It is shown that the phase-space areas formed by products of energy and time involved in the emission can be represented as a quadratic function of &Delta;n multiplied by the Planck constant h. 展开更多
关键词 electron Transitions Their Energies and Transition Times Quanta of the phase-space Areas of Energy and Time
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Effects of electron correlation and the Breit interaction on one- and two-electron one-photon transitions in double K hole states of He-like ions(10 ≤ Z ≤ 47) 被引量:1
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作者 丁晓彬 吴存强 +5 位作者 曹铭欣 张登红 张明武 薛迎利 于得洋 董晨钟 《Chinese Physics B》 SCIE EI CAS CSCD 2020年第3期148-155,共8页
The x-ray energies and transition rates associated with single and double electron radiative transitions from the double K hole state 2s2p to the 1s2s and 1s^2 configurations of 11 selected He-like ions(10 ≤ Z ≤ 47)... The x-ray energies and transition rates associated with single and double electron radiative transitions from the double K hole state 2s2p to the 1s2s and 1s^2 configurations of 11 selected He-like ions(10 ≤ Z ≤ 47) are calculated using the fully relativistic multi-configuration Dirac–Fock method(MCDF). An appropriate electron correlation model is constructed with the aid of the active space method, which allows the electron correlation effects to be studied efficiently. The contributions of the electron correlation and the Breit interaction to the transition properties are analyzed in detail. It is found that the two-electron one-photon(TEOP) transition is correlation sensitive. The Breit interaction and electron correlation both contribute significantly to the radiative transition properties of the double K hole state of the He-like ions. Good agreement between the present calculation and previous work is achieved. The calculated data will be helpful to future investigations on double K hole decay processes of He-like ions. 展开更多
关键词 electron correlation multi-configuration Dirac–Fock method(MCDF) DOUBLE K hole state two-electron one-photon(TEOP)transition
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Suppression of electron and hole overflow in GaN-based near-ultraviolet laser diodes 被引量:3
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作者 邢瑶 赵德刚 +13 位作者 江德生 李翔 刘宗顺 朱建军 陈平 杨静 刘炜 梁锋 刘双韬 张立群 王文杰 李沫 张源涛 杜国同 《Chinese Physics B》 SCIE EI CAS CSCD 2018年第2期588-593,共6页
In order to suppress the electron leakage to p-type region of near-ultraviolet GaN/In_xGa_(1-x )N/GaN multiple-quantumwell(MQW) laser diode(LD), the Al composition of inserted p-type AlxGa_(1-x)N electron bloc... In order to suppress the electron leakage to p-type region of near-ultraviolet GaN/In_xGa_(1-x )N/GaN multiple-quantumwell(MQW) laser diode(LD), the Al composition of inserted p-type AlxGa_(1-x)N electron blocking layer(EBL) is optimized in an effective way, but which could only partially enhance the performance of LD. Here, due to the relatively shallow GaN/In_(0.04)Ga_(0.96)N/GaN quantum well, the hole leakage to n-type region is considered in the ultraviolet LD. To reduce the hole leakage, a 10-nm n-type Al_xGa_(1-x)N hole blocking layer(HBL) is inserted between n-type waveguide and the first quantum barrier, and the effect of Al composition of Al_xGa_(1-x)N HBL on LD performance is studied. Numerical simulations by the LASTIP reveal that when an appropriate Al composition of Al_xGa_(1-x)N HBL is chosen, both electron leakage and hole leakage can be reduced dramatically, leading to a lower threshold current and higher output power of LD. 展开更多
关键词 GaN-based ultraviolet LD electron and hole leakage
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Different charging behaviors between electrons and holes in Si nanocrystals embedded in SiN_x matrix by the influence of near-interface oxide traps
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作者 方忠慧 江小帆 +3 位作者 陈坤基 王越飞 李伟 徐骏 《Chinese Physics B》 SCIE EI CAS CSCD 2015年第1期457-461,共5页
Si-rich silicon nitride films are prepared by plasma-enhanced chemical vapor deposition method, followed by thermal annealing to form the Si nanocrystals(Si-NCs) embedded in Si Nx floating gate MOS structures. The c... Si-rich silicon nitride films are prepared by plasma-enhanced chemical vapor deposition method, followed by thermal annealing to form the Si nanocrystals(Si-NCs) embedded in Si Nx floating gate MOS structures. The capacitance–voltage(C–V), current–voltage(I–V), and admittance–voltage(G–V) measurements are used to investigate the charging characteristics. It is found that the maximum flat band voltage shift(△VFB) due to full charged holes(~ 6.2 V) is much larger than that due to full charged electrons(~ 1 V). The charging displacement current peaks of electrons and holes can be also observed by the I–V measurements, respectively. From the G–V measurements we find that the hole injection is influenced by the oxide hole traps which are located near the Si O2/Si-substrate interface. Combining the results of C–V and G–V measurements, we find that the hole charging of the Si-NCs occurs via a two-step tunneling mechanism. The evolution of G–V peak originated from oxide traps exhibits the process of hole injection into these defects and transferring to the Si-NCs. 展开更多
关键词 silicon nanocrystals memory different charging of electrons and holes oxide traps admittancevoltage characteristics
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A Novel Micro-hole Electrode Used to Investigate Electron Transfer Reactions at ITIES
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作者 Dong Ping ZHAN Bing Liang WU 《Chinese Chemical Letters》 SCIE CAS CSCD 2002年第3期273-276,共4页
A novel micro-hole electrode was fabricated to investigate the electron transfer reaction at the interface between two immiscible electrolyte solutions (ITIES). The electron transfer reaction between ferro/ferricyani... A novel micro-hole electrode was fabricated to investigate the electron transfer reaction at the interface between two immiscible electrolyte solutions (ITIES). The electron transfer reaction between ferro/ferricyanide in aqueous phase (W) and ferrocene in 1, 2-dichloroethane (O) phase was studied as a test experiment. The results showed that the diffusion coefficient obtained from the micro-hole electrode was consistent with that obtained at macro-interface. Due to its simplicity and the very small IR drop it will be a useful tool for the study of ITIES systems. 展开更多
关键词 Micro-hole electrode electron transfer ITIES.
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NeoMinkowskian Cosmological Black Hole, Poincaré’s Gravific Electron and Density of CBR
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作者 Yves Pierseaux 《Journal of Modern Physics》 2020年第2期237-280,共44页
In the previous paper (JMP 2014) we showed that there exists a NeoMinkowskian Gravitational Expanding Solution of GR (General Relativity) with CC (Cosmological Constant). We prove now that NeoMinkowskian Vacuum (non-b... In the previous paper (JMP 2014) we showed that there exists a NeoMinkowskian Gravitational Expanding Solution of GR (General Relativity) with CC (Cosmological Constant). We prove now that NeoMinkowskian Vacuum (non-baryonic Fluid), with gravitational (first) density (dark energy) and gravitational waves (at light speed), corresponds to the Gravitation Field of a Cosmological Black Hole (CBH). The latter predicts furthermore a basic emission of Radiation (CBR) from Hubble spherical singular Horizon to the inside of CBH (unlike Hawking’s emission) at an initial singular time. Our solution is then compatible with a well-tempered Big Bang and Expanding Universe (Escher’s Figure, see Penrose, 3) but incompatible with inflation. The latter is based on Hypothesis of a so-called Planck’s particle (Lemaitre’s primitive atom) characterized by a so-called Planck length. We prove that we can short-circuit this unstable particle with a stable cosmological Poincaré’s electron with gravific pressure. It is well known that electron is a stranger in usual Minkowskian vacuum (dixit Einstein). The stranger electron can be perfectly integrated in NeoMinkowskian Radiation fluid and then also (with its mass, charge and wavelength) in (second density of) CBR. Everything happens as if the leptonic mass of the electron were induced by our cosmological field. The unexpected cosmological model proposed here is the only one that predicts numerical values of (second) density and temperature of CBR very close to the observed (COBE) values. 展开更多
关键词 COSMOLOGICAL Constant General Relativity Minkowskian Metric Cosmolog-ical Black hole Tachyons Hyperbolic Horizon DENSITY of Vacuum DENSITY of CBR Poincaré’s Gravitational Waves Poincaré’s electron DE Broglie’s Wave Electrodynamics DE Broglie’s Subquantum Substratum
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Theoretical and numerical simulation investigation of deep hole dispersed charge cut blasting
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作者 Chengxiao Li Renshu Yang +3 位作者 Yanbing Wang Yiqiang Kang Yuantong Zhang Pin Xie 《International Journal of Coal Science & Technology》 EI CAS CSCD 2023年第1期87-107,共21页
Drilling and blasting methods have been used as a common driving technique for shallow-hole driving and blasting in rock roadways.With the advent of digital electronic detonators and the need for increased production ... Drilling and blasting methods have been used as a common driving technique for shallow-hole driving and blasting in rock roadways.With the advent of digital electronic detonators and the need for increased production efciency,the traditional blasting design is no longer suitable for deep hole blasting.In this paper,a disperse charge cut blasting method was proposed to address the issues of low excavation depth and high block rate in deep hole undercut blasting.First,a blasting model was used to illustrate the mechanism of the deep hole dispersive charge cut blasting process.Then,continuous charge and dispersed charge blasting models were developed using the smooth particle hydrodynamics-fnite element method(SPHFEM).The cutting parameters were determined theoretically,and the cutting efciency was introduced to evaluate the cutting efect.The blasting efects of the two charging models were analyzed utilizing the evolution law of rock damage,the number of rock particles thrown,and the cutting efciency.The results show that using a dispersed charge improves the cutting efciency by about 20%and the rock breakage for the deep hole cut blasting compared to the traditional continuous charge.In addition,important parameters such as cutting hole spacing,cutting hole depth and upper charge proportion also have a signifcant impact on the cutting efect.Finally,the deep hole dispersed charge cut blasting technology is combined with the digital electronic detonator through the feld engineering practice.It provides a reference for the subsequent deep hole cutting blasting and the use of electronic detonators in rock roadways. 展开更多
关键词 Deep hole blasting Cut blasting Dispersed charge SPH-FEM Digital electronic detonator
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氧化物中存在O2p空穴的典型实验结果和磁性氧化物的O2p巡游电子模型
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作者 唐贵德 齐伟华 《河北师范大学学报(自然科学版)》 CAS 2024年第1期1-8,共8页
负二价氧离子具有满壳层价电子结构(2s^(2)2p^(6)).负一价氧离子的价电子结构为2s^(2)2p^(5),相当于存在1个O2p空穴.传统的凝聚态物理和材料化学研究中都假设氧化物中的氧离子全部为负二价离子,在迄今为止的绝大多数研究氧化物磁性和电... 负二价氧离子具有满壳层价电子结构(2s^(2)2p^(6)).负一价氧离子的价电子结构为2s^(2)2p^(5),相当于存在1个O2p空穴.传统的凝聚态物理和材料化学研究中都假设氧化物中的氧离子全部为负二价离子,在迄今为止的绝大多数研究氧化物磁性和电输运性质的报道中,采用关于磁有序的超交换和双交换作用模型,都没有考虑O2p空穴的影响.然而,许多价电子状态实验证明,在氧化物中存在不可忽略的O2p空穴,即存在不可忽略的负一价氧离子,其占比可达30%或更多.基于这些实验结果,对传统磁有序模型进行改进,英美学者首先进行了探讨,笔者所在课题组与中国科学院物理研究所磁学国家重点实验室合作进行了系统的研究.介绍了相关的典型实验结果和理论模型. 展开更多
关键词 磁性材料 磁有序模型 O2p空穴 电子能量损失谱 X-射线光电子谱
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Ge/Sn合金化对CsPbBr_(3)钙钛矿热载流子弛豫影响的非绝热分子动力学研究
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作者 王斐 杨振清 +2 位作者 夏雨虹 刘畅 林春丹 《物理学报》 SCIE EI CSCD 北大核心 2024年第2期310-316,共7页
铯基全无机钙钛矿CsPbBr_(3)具有良好的热稳定性,在应用中表现出优越的发光特性,是近年来光电领域的明星材料.CsPbBr_(3)界面的光生载流子过程与其光电性能密切相关.本文采用非绝热分子动力学方法结合含时密度泛函理论,对CsPbBr_(3)及... 铯基全无机钙钛矿CsPbBr_(3)具有良好的热稳定性,在应用中表现出优越的发光特性,是近年来光电领域的明星材料.CsPbBr_(3)界面的光生载流子过程与其光电性能密切相关.本文采用非绝热分子动力学方法结合含时密度泛函理论,对CsPbBr_(3)及其合金化结构的激发态动力学过程进行了系统研究.研究结果表明,Sn/Ge合金化能够有效缩短退相干时间,减缓电子-空穴复合.CsPb_(0.75)Ge_(0.25)Br_(3)体系的载流子寿命延长至1.6倍,而CsPb_(0.5)Ge_(0.25)Sn_(0.25)Br_(3)体系的载流子寿命延长为原始体系的4.2倍.证明了B位(钙钛矿结构ABX_(3)中的B位)金属阳离子的双原子合金化对CsPbBr_(3)的非辐射电子-空穴复合具有很强的影响.本研究提供了一种能够有效延长钙钛矿载流子寿命,合理优化太阳能电池性能的合金化方案,为未来钙钛矿太阳能电池材料的设计提供了思路. 展开更多
关键词 CsPbBr_(3) 非绝热分子动力学 合金化 非辐射电子-空穴复合
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三种同分异构的双苯并吩噻嗪材料的合成、理论计算及光物理性质
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作者 王鹤然 陈凯 +5 位作者 伏硕 王晧暄 袁加轩 胡星奕 许文娟 密保秀 《物理化学学报》 SCIE CAS CSCD 北大核心 2024年第1期48-56,共9页
吩噻嗪及其衍生物材料是一类重要的多环芳烃材料,在光电子领域有着广泛的应用。其中,基于苯并噻嗪材料的研究相对较少。在本文中,我们分别在吩噻嗪的1,2-、2,3-和3,4-位引入苯基,制备了三种同分异构的双苯并吩噻嗪化合物D-PTZa、D-PTZb... 吩噻嗪及其衍生物材料是一类重要的多环芳烃材料,在光电子领域有着广泛的应用。其中,基于苯并噻嗪材料的研究相对较少。在本文中,我们分别在吩噻嗪的1,2-、2,3-和3,4-位引入苯基,制备了三种同分异构的双苯并吩噻嗪化合物D-PTZa、D-PTZb和D-PTZc,研究了它们的构效关系,并与双吩噻嗪化合物(D-PTZ)进行了对比。研究发现,D-PTZb和D-PTZc的HOMO和LUMO分布与D-PTZ的类似;对于D-PTZa,其1,2-位引入的苯基与中间的苯环空间张力较大,造成空间结构极度扭曲,性质比较特殊。并苯的引入可以有效增加分子的共轭长度,使得最大吸收波长发生红移;在2,3-位引入苯基可以有效地稳定HOMO能级,使基于π→π*跃迁的能隙稍有增大,呈现蓝光发射,溶液的荧光量子产率为1.7%;而在3,4-位引入苯基使LUMO分布更加趋向于线型,从而使LUMO更加稳定,使基于π→π*跃迁的能隙降低,其最大发射峰位于520 nm处,呈现黄绿光发射,溶液荧光量子产率为13%。此外并入苯环之后,空间张力增大,化合物的分解温度降低。我们的分子设计和结构–性质关系的研究可以为设计新的吩噻嗪材料提供基础指导。 展开更多
关键词 苯并吩噻嗪 有机光电材料 密度泛函理论 空穴-电子分析 前线轨道分布 光物理性质
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铁酸铋基异质结光催化剂降解有机污染物的研究进展
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作者 杨雪 黄瑞 +2 位作者 饶泽平 王振华 蔡苇 《化工新型材料》 CAS CSCD 北大核心 2024年第2期70-76,共7页
铁酸铋(BiFeO_(3))作为一种典型的窄带隙铁电半导体,其自身的退极化场可以抑制光生电子空穴对的复合,已被广泛应用于光催化领域。通过构建异质结,借助界面电场对电子-空穴对进行有效分离是一种提升光催化剂降解性能的重要策略。综述了Bi... 铁酸铋(BiFeO_(3))作为一种典型的窄带隙铁电半导体,其自身的退极化场可以抑制光生电子空穴对的复合,已被广泛应用于光催化领域。通过构建异质结,借助界面电场对电子-空穴对进行有效分离是一种提升光催化剂降解性能的重要策略。综述了BiFeO_(3)基Ⅱ型异质结、Z型异质结、肖特基结和S型异质结光催化剂的构建原理,重点介绍了在BiFeO_(3)基异质结光催化剂在降解有机污染物方面的应用及其光催化反应机制,最后对BiFeO_(3)基异质结光催化剂研究的不足和未来的发展方向进行了展望。 展开更多
关键词 铁酸铋 异质结 光催化 电子-空穴复合率 铁电材料
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石墨烯在钙钛矿太阳能电池电荷传输层中应用进展
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作者 张发荣 曹雅静 +1 位作者 刘怡琳 刘炳光 《盐科学与化工》 CAS 2024年第2期4-9,共6页
结合对石墨烯和钙钛矿太阳能电池材料薄膜制备方面的研究,归纳总结了钙钛矿太阳能电池电荷传输层的作用;介绍了常用电荷传输层材料品种及其不足;综述了石墨烯在太阳能电池电子传输层和空穴传输层中应用进展,以促进石墨烯在钙钛矿太阳能... 结合对石墨烯和钙钛矿太阳能电池材料薄膜制备方面的研究,归纳总结了钙钛矿太阳能电池电荷传输层的作用;介绍了常用电荷传输层材料品种及其不足;综述了石墨烯在太阳能电池电子传输层和空穴传输层中应用进展,以促进石墨烯在钙钛矿太阳能电池中的研究开发。目前,钙钛矿太阳能电池的性能稳定性较差,商业化开发难以启动。文章认为从设计和优化钙钛矿太阳电池电荷传输层复合材料着手,稳定和提高钙钛矿太阳能电池性能,可望取得事半功倍的效果。 展开更多
关键词 石墨烯 钙钛矿 太阳能 电荷传输 空穴传输
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钙钛矿太阳能电池界面缺陷及其抑制方法
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作者 李宏 廖鑫 +1 位作者 侯静 徐众 《人工晶体学报》 北大核心 2024年第1期38-50,共13页
目前,绝大多数高效有机-无机卤化物钙钛矿(OIHP)太阳能电池都是由多晶钙钛矿薄膜构成,这些多晶薄膜表面或晶界往往含有大量的缺陷,将导致光生载流子发生非辐射复合,并诱导OIHP材料分解,从而使器件的光电转换效率(PCE)和稳定性降低。本... 目前,绝大多数高效有机-无机卤化物钙钛矿(OIHP)太阳能电池都是由多晶钙钛矿薄膜构成,这些多晶薄膜表面或晶界往往含有大量的缺陷,将导致光生载流子发生非辐射复合,并诱导OIHP材料分解,从而使器件的光电转换效率(PCE)和稳定性降低。本综述分析了钙钛矿太阳能电池的缺陷类型及缺陷对钙钛矿太阳能电池(PSCs)性能的影响,详细介绍了通过钝化电极与传输层,或传输层与钙钛矿层间的界面缺陷以获得更高效率和高稳定性的钙钛矿太阳能电池方面的研究进展,展望了钝化分子的设计思路及钙钛矿光伏商业化应用所面临的挑战。 展开更多
关键词 钙钛矿太阳能电池 有机-无机卤化物钙钛矿 界面缺陷 缺陷钝化 电子传输层 空穴传输层 光电转换效率
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PO2X…PX3/PH2X(X=F,Cl,Br,CH3,NH2)复合物中π-hole磷键作用的电子密度拓扑分析 被引量:4
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作者 王月红 李晓艳 +2 位作者 曾艳丽 孟令鹏 张雪英 《物理化学学报》 SCIE CAS CSCD 北大核心 2016年第3期671-682,共12页
磷键作为一种新型的分子键合力,因在晶体工程和超分子合成等方面的重要作用而越来越多地引起科研工作者的广泛关注。本文采用量子化学从头算和电子密度拓扑分析等方法,在MP2/aug-cc-pVTZ理论水平上,对PO_2X…PX_3和PO_2X…PH_2X(X=F,Cl,... 磷键作为一种新型的分子键合力,因在晶体工程和超分子合成等方面的重要作用而越来越多地引起科研工作者的广泛关注。本文采用量子化学从头算和电子密度拓扑分析等方法,在MP2/aug-cc-pVTZ理论水平上,对PO_2X…PX_3和PO_2X…PH_2X(X=F,Cl,Br,CH_3,NH_2)π型复合物的结构和磷键性质进行了理论研究。研究表明:π-hole磷键复合物存在A和B两种稳定构型,分别以P…P和P…X磷键作用为主。分子中原子(AIM)、非共价作用(NCI)、电子定域函数(ELF)及适应性自然密度划分(AdNDP)分析表明,不同取代基对该类磷键作用的性质产生很大影响:当取代基为给电子基(CH_3,NH_2)时,磷键具有明显的共价作用特征;当取代基为吸电子基(F,Cl,Br)时,构型和取代基不同的磷键分别表现为非共价、部分共价或共价作用特征。自然键轨道(NBO)分析指出,分子间磷键的Wiberg键级的数值越大,磷键的共价性越强,磷键的作用强度越大。构型B的电荷转移主要是PX_3/PH_2X中X原子上的孤对电子转移到PO_2X中π*(P=O)反键空轨道。 展开更多
关键词 分子间相互作用 磷键 π-hole作用 NCl分析 电子密度拓扑分析 ELF分析
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The influence of trapping centres on the photoelectron decay in silver halide 被引量:7
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作者 李晓苇 张荣香 +3 位作者 刘荣鹃 杨少鹏 韩理 傅广生 《Chinese Physics B》 SCIE EI CAS CSCD 2006年第3期624-630,共7页
Photoelectron is the foundation of latent image formation, the decay process of photoelectrons is influenced by all kinds of trapping centres in silver halide. By analysing the mechanism of latent image formation it i... Photoelectron is the foundation of latent image formation, the decay process of photoelectrons is influenced by all kinds of trapping centres in silver halide. By analysing the mechanism of latent image formation it is found that electron trap, hole trap, and one kind of recombination centre where free electron and trapped hole recombine are the main trapping centres in silver halide. Different trapping centres have different influences on the photoelectron behaviour. The effects of all kinds of typical trapping centres on the decay of photoelectrons are systematically investigated by solving the photoelectron decay kinetic equations. The results are in agreement with those obtained in the microwave absorption dielectric spectrum experiment. 展开更多
关键词 silver halide electron trap recombination centre hole trap
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Study on Electronic Conductivity of CaO-SiO2-Al2O3-FeOx Slag System 被引量:1
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作者 LU Xiong-gang LI Fu-shen +1 位作者 LI Li-fen CHOU Kou-chih 《Journal of Iron and Steel Research(International)》 SCIE EI CAS CSCD 2000年第1期9-13,共5页
A study on electronic conductivity of CaO-SiO2-Al2O3-FeOxslag system with Wagner polarization technique was carried out.The experimental data show that electronic conductivity is consisted of free electron conductivit... A study on electronic conductivity of CaO-SiO2-Al2O3-FeOxslag system with Wagner polarization technique was carried out.The experimental data show that electronic conductivity is consisted of free electron conductivity and electron hole conductivity and both are related to the content of Fe3+and Fe2+.Free electron conductivity is decreasing and electron hole conductivity is increasing while Fe3+changes to Fe2+.There is a maximum electronic conductivity at some ratio of ferric ions Fe3+to total ion content.Under the experimental conditions,the electronic conductivity is in the range of 10-4—10-2S/cm. 展开更多
关键词 smelt slag electron hole electronic conductivity
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Statistical properties of kinetic-scale magnetic holes in terrestrial space 被引量:2
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作者 ShuTao Yao ZongShun Yue +15 位作者 QuanQi Shi Alexander William Degeling HuiShan Fu AnMin Tian Hui Zhang Andrew Vu RuiLong Guo ZhongHua Yao Ji Liu Qiu-Gang Zong XuZhi Zhou JingHuan Li WenYa Li HongQiao Hu YangYang Liu WeiJie Sun 《Earth and Planetary Physics》 CSCD 2021年第1期63-72,共10页
Kinetic-scale magnetic holes(KSMHs)are structures characterized by a significant magnetic depression with a length scale on the order of the proton gyroradius.These structures have been investigated in recent studies ... Kinetic-scale magnetic holes(KSMHs)are structures characterized by a significant magnetic depression with a length scale on the order of the proton gyroradius.These structures have been investigated in recent studies in near-Earth space,and found to be closely related to energy conversion and particle acceleration,wave-particle interactions,magnetic reconnection,and turbulence at the kineticscale.However,there are still several major issues of the KSMHs that need further study—including(a)the source of these structures(locally generated in near-Earth space,or carried by the solar wind),(b)the environmental conditions leading to their generation,and(c)their spatio-temporal characteristics.In this study,KSMHs in near-Earth space are investigated statistically using data from the Magnetospheric Multiscale mission.Approximately 200,000 events were observed from September 2015 to March 2020.Occurrence rates of such structures in the solar wind,magnetosheath,and magnetotail were obtained.We find that KSMHs occur in the magnetosheath at rates far above their occurrence in the solar wind.This indicates that most of the structures are generated locally in the magnetosheath,rather than advected with the solar wind.Moreover,KSMHs occur in the downstream region of the quasi-parallel shock at rates significantly higher than in the downstream region of the quasi-perpendicular shock,indicating a relationship with the turbulent plasma environment.Close to the magnetopause,we find that the depths of KSMHs decrease as their temporal-scale increases.We also find that the spatial-scales of the KSMHs near the subsolar magnetosheath are smaller than those in the flanks.Furthermore,their global distribution shows a significant dawn-dusk asymmetry(duskside dominating)in the magnetotail. 展开更多
关键词 kinetic scale magnetic hole magnetic dip electron vortex turbulence
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