The wave equation of the electron, recently improved, allows physics to obtain all the quantum numbers and other results explaining the hydrogen spectrum. The Pauli exclusion principle then gives the description of el...The wave equation of the electron, recently improved, allows physics to obtain all the quantum numbers and other results explaining the hydrogen spectrum. The Pauli exclusion principle then gives the description of electron clouds used in chemistry. The relativistic wave equation is associated with a Lagrangian density, thus also with an energy-momentum tensorial density. The wave of an electron cloud adds these energy-momentum densities, while photons in light are precisely those differences between such energy-momentum densities.展开更多
Since the position of the electron in a hydrogen atom cannot be determined, the region in which it resides is said to be determined stochastically and forms an electron cloud. The probability density function of the s...Since the position of the electron in a hydrogen atom cannot be determined, the region in which it resides is said to be determined stochastically and forms an electron cloud. The probability density function of the single electron in 1s orbit is expressed as φ2, a function of distance from the nucleus. However, the probability of existence of the electron is expressed as a radial distribution function at an arbitrary distance from the nucleus, so it is estimated as the probability of the entire spherical shape of that radius. In this study, it has been found that the electron existence probability approximates the radial distribution function by assuming that the probability of existence of the electron being in the vicinity of the nucleus follows a normal distribution for arbitrary x-, y-, and z-axis directions. This implies that the probability of existence of the electron, which has been known only from the distance information, would follow a normal distribution independently in the three directions. When the electrons’ motion is extremely restricted in a certain direction by the magnetic field of both tokamak and helical fusion reactors, the probability of existence of the electron increases with proximity to the nucleus, and as a result, it is less likely to be liberated from the nucleus. Therefore, more and more energy is required to free the nucleus from the electron in order to generate plasma.展开更多
The study of the characteristic graph of an atom in all its aspects, allows to describe the concepts of atomistic. From this graph, some concepts of the recomposition of the electronic cloud have been described by spe...The study of the characteristic graph of an atom in all its aspects, allows to describe the concepts of atomistic. From this graph, some concepts of the recomposition of the electronic cloud have been described by specific graphs derived from it. The results are very conclusive. This graph illustrates each of the concepts of atomistics such as blocks, orders, periods and electronic layers. These concepts have been represented by lines, segments and even points. This has made it possible to draw up tables with orders, periods and even their correlations. Thus, this work promotes a better understanding of theoretical concepts by transposing the “abstract” aspect to a more “concrete” aspect of these concepts. This eventually facilitates the learning of this essential part of chemistry at its core. These results indicate that the research hypothesis has been verified.展开更多
The perovskite transition metal oxide(TMO) has been considered in electrocatalysis for the modern clean energy technologies as its high electrochemical activity and low cost. The atomic scale engineering to the local ...The perovskite transition metal oxide(TMO) has been considered in electrocatalysis for the modern clean energy technologies as its high electrochemical activity and low cost. The atomic scale engineering to the local stoichiometry of single crystal TMO provides a clue of the relation between electronic structure and catalytic performance. Here we report a hydrogen evolution reaction(HER) activity enhancement ~ 1761% of Bi_(0.85)Sr_(0.15)FeO_3 compared to the pure BiFeO_3. By the systemic investigation of the Sr doping level of Bi_(1-x)Sr_xFeO_3(BSFO), it is found that the HER enhancement originates from the improvement of ferromagnetism of BSFO without obvious scarification of the ferroelectricity at the room temperature. The multiple ferroic orderings in BSFO are beneficial for HER activity, which offers the strengthen of hybridization of Fe 3d and O2 p orbitals from the view of ferromagnetism, and the assistance of electron drift by spontaneous electric polarization. Our study not only affords the strategy of developing multiple ferroic orderings in TMO, but also facilitates the atomic scale understanding of the improved HER activity.展开更多
Electron cloud interaction with high energy positive beams are believed responsible for various undesirable effects such as vacuum degradation, collective beam instability and even beam loss in high power proton circu...Electron cloud interaction with high energy positive beams are believed responsible for various undesirable effects such as vacuum degradation, collective beam instability and even beam loss in high power proton circular accelerators. An important uncertainty in predicting electron cloud instability lies in the detailed processes of the generation and accumulation of the electron cloud. The simulation on the build-up of electron cloud is necessary to further studies on beam instability caused by electron clouds. The China Spallation Neutron Source (CSNS) is an intense proton accelerator facility now being built, whose accelerator complex includes two main parts: an H-linac and a rapid cycling synchrotron (RCS). The RCS accumulates the 80 MeV proton beam and accelerates it to 1.6 GeV with a repetition rate of 25 Hz. During beam injection with lower energy, the emerging electron cloud may cause serious instability and beam loss on the vacuum pipe. A simulation code has been developed to simulate the build-up, distribution and density of electron cloud in CSNS/RCS.展开更多
Electron Cloud Instability has been studied in the operation of BEPC. The BEPCⅡ began the commissioning in November 2006 and the positron beam current has reached 500 mA. Because of such a high beam current, some ins...Electron Cloud Instability has been studied in the operation of BEPC. The BEPCⅡ began the commissioning in November 2006 and the positron beam current has reached 500 mA. Because of such a high beam current, some instabilities such as ECI, bunch lengthening et al, have appeared during the operation. The experimental investigation on ECI during the commissioning of BEPCⅡ will be reported in this paper.展开更多
In this paper we treat first some nonlinear beam dynamics problems in storage rings, such as beam dynamic apertures due to magnetic multipoles, wiggles, beam-beam effects, nonlinear space charge effect, and then nonli...In this paper we treat first some nonlinear beam dynamics problems in storage rings, such as beam dynamic apertures due to magnetic multipoles, wiggles, beam-beam effects, nonlinear space charge effect, and then nonlinear electron cloud effect combined with beam-beam and space charge effects, analytically. This analytical treatment is applied to BEPC II. The corresponding analytical expressions developed in this paper are useful both in understanding the physics behind these problems and also in making practical quick hand estimations.展开更多
A secondary electron yield test device for vacuum material study is set up,and its detailed design described in this paper.The test results for a few common vacuum materials with and without TiN film coating are prese...A secondary electron yield test device for vacuum material study is set up,and its detailed design described in this paper.The test results for a few common vacuum materials with and without TiN film coating are presented,and the influential factors on secondary electron yield are analyzed.All the work will be helpful to the surface pretreatment of vacuum materials.展开更多
The electron proton (e-p) instability has been observed in many proton accelerators. It will induce transverse beam size blow-up, cause beam loss and restrict the machine performance. Much research work has been done ...The electron proton (e-p) instability has been observed in many proton accelerators. It will induce transverse beam size blow-up, cause beam loss and restrict the machine performance. Much research work has been done on the causes, dynamics and cures of this instability. A simulation code is developed to study the e-p instability in the ring of the China Spallation Neutron Source (CSNS).展开更多
文摘The wave equation of the electron, recently improved, allows physics to obtain all the quantum numbers and other results explaining the hydrogen spectrum. The Pauli exclusion principle then gives the description of electron clouds used in chemistry. The relativistic wave equation is associated with a Lagrangian density, thus also with an energy-momentum tensorial density. The wave of an electron cloud adds these energy-momentum densities, while photons in light are precisely those differences between such energy-momentum densities.
文摘Since the position of the electron in a hydrogen atom cannot be determined, the region in which it resides is said to be determined stochastically and forms an electron cloud. The probability density function of the single electron in 1s orbit is expressed as φ2, a function of distance from the nucleus. However, the probability of existence of the electron is expressed as a radial distribution function at an arbitrary distance from the nucleus, so it is estimated as the probability of the entire spherical shape of that radius. In this study, it has been found that the electron existence probability approximates the radial distribution function by assuming that the probability of existence of the electron being in the vicinity of the nucleus follows a normal distribution for arbitrary x-, y-, and z-axis directions. This implies that the probability of existence of the electron, which has been known only from the distance information, would follow a normal distribution independently in the three directions. When the electrons’ motion is extremely restricted in a certain direction by the magnetic field of both tokamak and helical fusion reactors, the probability of existence of the electron increases with proximity to the nucleus, and as a result, it is less likely to be liberated from the nucleus. Therefore, more and more energy is required to free the nucleus from the electron in order to generate plasma.
文摘The study of the characteristic graph of an atom in all its aspects, allows to describe the concepts of atomistic. From this graph, some concepts of the recomposition of the electronic cloud have been described by specific graphs derived from it. The results are very conclusive. This graph illustrates each of the concepts of atomistics such as blocks, orders, periods and electronic layers. These concepts have been represented by lines, segments and even points. This has made it possible to draw up tables with orders, periods and even their correlations. Thus, this work promotes a better understanding of theoretical concepts by transposing the “abstract” aspect to a more “concrete” aspect of these concepts. This eventually facilitates the learning of this essential part of chemistry at its core. These results indicate that the research hypothesis has been verified.
基金supported by the National Natural Science Foundation of China (Nos. 51772126 and 21978110)the Jilin Province Science and Technology Department Program (Nos. 20200201277JC, 20200201279JC, 20190201309JC and 20190101009JH)+4 种基金the National Science Foundation of Heilongjiang Province (E2017031)the Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education (Nos. 2017002, 2016010, 2015003 and 2015011)the Jilin Province Development and Reform Commission Program (Nos. 2019C042-1 and 2020C026-3)the ‘‘13th five-year” science and technology project of Jilin provincial education department (No. JJKH20200407KJ)the Jilin Province Fund for Talent Development Program (No. [2019] 874)。
文摘The perovskite transition metal oxide(TMO) has been considered in electrocatalysis for the modern clean energy technologies as its high electrochemical activity and low cost. The atomic scale engineering to the local stoichiometry of single crystal TMO provides a clue of the relation between electronic structure and catalytic performance. Here we report a hydrogen evolution reaction(HER) activity enhancement ~ 1761% of Bi_(0.85)Sr_(0.15)FeO_3 compared to the pure BiFeO_3. By the systemic investigation of the Sr doping level of Bi_(1-x)Sr_xFeO_3(BSFO), it is found that the HER enhancement originates from the improvement of ferromagnetism of BSFO without obvious scarification of the ferroelectricity at the room temperature. The multiple ferroic orderings in BSFO are beneficial for HER activity, which offers the strengthen of hybridization of Fe 3d and O2 p orbitals from the view of ferromagnetism, and the assistance of electron drift by spontaneous electric polarization. Our study not only affords the strategy of developing multiple ferroic orderings in TMO, but also facilitates the atomic scale understanding of the improved HER activity.
基金Supported by National Natural Science Foundation of China(11275221,11175193)
文摘Electron cloud interaction with high energy positive beams are believed responsible for various undesirable effects such as vacuum degradation, collective beam instability and even beam loss in high power proton circular accelerators. An important uncertainty in predicting electron cloud instability lies in the detailed processes of the generation and accumulation of the electron cloud. The simulation on the build-up of electron cloud is necessary to further studies on beam instability caused by electron clouds. The China Spallation Neutron Source (CSNS) is an intense proton accelerator facility now being built, whose accelerator complex includes two main parts: an H-linac and a rapid cycling synchrotron (RCS). The RCS accumulates the 80 MeV proton beam and accelerates it to 1.6 GeV with a repetition rate of 25 Hz. During beam injection with lower energy, the emerging electron cloud may cause serious instability and beam loss on the vacuum pipe. A simulation code has been developed to simulate the build-up, distribution and density of electron cloud in CSNS/RCS.
基金Supported by National Natural Science Foundation of China (10605032)
文摘Electron Cloud Instability has been studied in the operation of BEPC. The BEPCⅡ began the commissioning in November 2006 and the positron beam current has reached 500 mA. Because of such a high beam current, some instabilities such as ECI, bunch lengthening et al, have appeared during the operation. The experimental investigation on ECI during the commissioning of BEPCⅡ will be reported in this paper.
文摘In this paper we treat first some nonlinear beam dynamics problems in storage rings, such as beam dynamic apertures due to magnetic multipoles, wiggles, beam-beam effects, nonlinear space charge effect, and then nonlinear electron cloud effect combined with beam-beam and space charge effects, analytically. This analytical treatment is applied to BEPC II. The corresponding analytical expressions developed in this paper are useful both in understanding the physics behind these problems and also in making practical quick hand estimations.
文摘A secondary electron yield test device for vacuum material study is set up,and its detailed design described in this paper.The test results for a few common vacuum materials with and without TiN film coating are presented,and the influential factors on secondary electron yield are analyzed.All the work will be helpful to the surface pretreatment of vacuum materials.
文摘The electron proton (e-p) instability has been observed in many proton accelerators. It will induce transverse beam size blow-up, cause beam loss and restrict the machine performance. Much research work has been done on the causes, dynamics and cures of this instability. A simulation code is developed to study the e-p instability in the ring of the China Spallation Neutron Source (CSNS).