Available Contents of Trace Nutrient Element and Factors Affecting Their Availability in Western Jilin

Based on the assay of the total content and available content of the trace nutrient elements and the soil pH and organic matter of the soil samples,the characteristic of the available content of the trace nutrient elements and their affecting factors are studied. The results show that the available B in western Jilin is in a middle level,the content in Nong'an is higher than that in the others; the available Mn is extremely abundant; the available Cu in Nong'an is obviously higher than other areas,and the content in Da'an differs greatly; the available Zn is in a middle level; the severe shortage of available Mo differs between different areas; and the available Fe is extremely abundant. The available Mn,Cu and Fe have significantly positive correlation with their total content; the available B has significantly positive correlation with pH,and Zn has obviously negative correlation with pH; the available Mn and Fe had significantly positive correlation with soil organic matter.

Correlation Between Chemical Element Contents in Tree Rings and Soils

The annual growth rings of ten trees and the soils near the tree roots were sampled from the mining area of lead-and zinc-dominant metals in the Xixia Mountain, Nanjing, for the determination of chemical element contents. The study results showed that the elemental contents in the tree rings were correlated with those in the soils, i. e., the elemental contents in the tree rings increased with those in the soils, even in the cases of different environments and different tree species. Therefore, a time-concentration sequence could be set up on the basis of determining the elemental contents in the successive annual growth rings of trees to qualitatively reflect the annual variations of relevant elements in the soils, and a time-concentration sequence of elemental contents in soils could also be established in terms of related model to reproduce the dynamic changes of the surroundings.

Chrono-Sequences of Elemental Contents in Tree Ringsand Soils

There exists a logarithmic linear correlation, i. e., In C'(Z, t) = a(Z) + b(Z) ln(Z, t) where Z is the atomicnumber of element and t the year when tree ring grows between the chemical element contents in tree ringsC(Z, t) and those in the soils near the tree roots C'(Z, t).By determining the elemental contents of the annual growth rings of trees, we could establish the chrono-sequences of elemental contents in the tree rings, thus calculating that of the soil, that is, reproducing thedynamic changes of contents of elements in the soil C'(Z, t). The background values of elements in the soilunder site conditions of the tree could be estimated from the minimum C(Z, t_0) in the chrono-sequences ofelemental contents in the tree rings.

Angular Distribution of Element Contents in Tree Rings and the Environmental Information

Element contents of tree rings and soils near tree roots collected from Deodar cedar (Cedrus deodara (Roxb.) G. Don) and Masson pine (Picks massoniana lamb.) were determined to study the relationship between the angular distribution of element contents in tree rings and the environmental information. The chemical composition and properties of soils are very much complicated, which leads to the non-uniform distribution of the element contents in tree rings. The statistical multi-variable regression method was used to got the information of the tree-centered distribution of element contents in the environment (soil) (C’), C’(z, θj ), from the distribution of element contents in tree rings (C), C(Z, θi), which depends on the plane azimuth angle (θi), i. e., C=C(Z,θi), where Z is the atomic number of the element, with a satisfactory result,though this study is only a primary one.

Characteristics of mineral element content of alpine vegetation in permafrost region on Qinghai-Tibetan Plateau

The content characteristics of 16 elements （Al, Ca, Cr, Cu, Fe, K, Li, Mg, Mn, Mo, Na, Ni, P, Pb, Sr, and Zn） in 23 plant species collected from the Qinghai-Tibetan Plateau permafrost region were investigated using ICP-OES. Results show that the average contents of Ca, K, Mg, Fe and P were higher than 1,000 mg/kg, those of Al, Na, Zn and Cr ranged between 10-1,000 mg/kg and those of Cu, Li, Pb and Mo were less than 10 mg/kg. The levels of Al, Ca, K, Mg and Na were within the scope of the reported terrestrial plant element content, those of Sr, Fe and Cr were higher than the average of the terrestrial plants and the maximum content of Max was higher than the upper limit of the reported Mn content. The main character of the element content was of the Ca〉K type, however, in terms of Cyperaeeae species the element content character was K〉Ca type. The contents of Ca, Li, Mg and Sr in Gramineae and Cyperaeeae species were higher than those in other species and the contents of Ca, K, Mg, Fe, E A1 and Na in all collected plants were higher than those of other elements. Zn had weak variability with the lowest coefficient （i.e., 7.81%）, while other elements had strong variability. The ratio of maximum content to minimum content indicated Ca and K had less change than other elements in the Qinghai-Tibetan Plateau permafrost region. Element content of alpine vegetation in the Qinghai-Tibetan Plateau permafrost region mainly shows a positive correlation, among which the correlation coefficient between Al and Pb, Al and Fe, Mo and Cr, Pb and Fe, Sr and Li were higher than 0.9, and negative correlation had no statistical signifi- cance. The correlation between Al and Fe, Mg, Mn in the Qinghai-Tibetan Plateau permafrost region were consistent with that reported in Kunlun Mountains.

Morphologic characters and element content during development of Pinus tabuliformis seeds

An embryo classification system for Pinus tabuliformis Carr. was established by time-tracing sam- pling and observation of zygotic embryos. The zygotic embryos were divided into nine stages. Key elements of the zygotic embryo and female gametophyte （FG） tissue of P. tabuliformis were analyzed, using inductively coupled plasma-emission spectroscopy. Several elements--includ- ing aluminum, iron, sodium, and copper--are found in both embryo and FG tissue. Boron, phosphorus, magnesium,zinc, and calcium are also required for zygotic embryo development and therefore accumulated. Manganese is selectively excluded from the embryo. The zygotic embryo development needs a low-sodium and high-potassium nutrition proportion. The results of elemental analysis from zygotic embryos and FGs can provide the mineral targets for optimizing the formulation of culture medium for somatic embryogenesis.

ELEMENTAL CONTENTS IN ORGANS AND TISSUES OF CHINESE ADULT MEN

Objective To provide basis of reference values for relevant parameters of Chinese Reference Man. Methods Eighteen kinds of major organ or tissue samples, including muscle, rib, liver, and so on, were obtained from 4 areas (Hebei, Shanxi, Jiangsu, and Sichuan provinces) with different dietary patterns in China in autopsy of 16 healthy adult men, who had just encountered sudden deaths. At the same time, whole blood samples were collected from 10 volunteers living in each of these areas. The concentrations of 56 elements in these samples were detected by using Inductively Coupled Plasma Mass Spectrometry (ICP-MS), Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES), and Graphite Furnace Atomic Absorption Spectrometry (GF-AAS) techniques. Based on obtained concentrations and reference values of these organ or tissue weights for Chinese Reference Man, the relative elemental burdens in these organs or tissues as well whole body were also estimated. Results The concentrations of 56 elements in 18 main organs or tissues were determined all together and their elemental organ or tissue and whole body burdens were estimated. Furthermore, the distributions of important elements for radiation protection in these organs or tissues were emphatically discussed. Conclusion By summing with past related results, the total results obtained from the series of research may provide more reliable and better representative basis of these reference values for Chinese Reference Man than before.

Prediction of Chemical Element Contents in Soils

Assuming that the regularity for the dynamic changes of the chrono-sequences of chemical element contents intree rings follows a k-order constant coefficient differential equation and substituting the differential with the differ-ence, we could obtain the inferred value y_(m+k+1) by the formula: Each coefficient c_i in the formula may be ascertained by use of the measured data in the chrono-sequences. Ex-tending the chrono-sequences on the assumption that the regularity of dynamic changes wouldn't change in the nearfuture, the contents of chemical elements in the soils may be predicted in termis of a logarithmic linear correlationmodel. Also, this extension method could be used for the reproduction of the contents of chemical elements in soilsduring different periods of time in the past.

Comparison of 66 chemical element contents in normal and benign hyperplastic prostate

Objective:The aim of this study was to clarify the differences between the prostatic levels of chemical elements in patients with benign prostatic hyperplasia(BPH)and healthy male.Methods:We evaluated the prostatic level of 66 chemical elements in 43 patients with BPH and 37 healthy males.Measurements were performed using five instrumental analytical methods.Results:In the hyperplastic prostates,we have observed a significant increase in the mean level of Bi,Cr,Hg,K,Sb,and Se accompanied a significant decrease in the mean level of Al,Ce,Cs,Dy,Er,Gd,Ho,La,Mo,Nd,Pb,Pr,Sm,Sn,Tb,Tm,U,and Y.No differences were found in the mean prostatic level of other chemical elements including Ag,Al,Au,B,Ba,Be,Br,Ca,Cd,Co,Cu,Fe,Li,Mg,Mn,Na,Nb,Ni,P,Rb,S,Sc,Si,Th,Ti,Tl,Yb,Zn,and Zr between BPH patients and healthy males.Conclusions:The finding of chemical element contents and correlation between pairs of chemical element mass fractions indicates that there is a great disturbance of prostatic chemical element metabolism in BPH gland.Trace elements Bi,Cr,Hg,K,Sb,and Se may be regarded as the possible tissue biomarkers of hyperplastic transformation of prostate gland.Obtained data did not confirm a critical role of Cd and Pb accumulation in the pathogenesis of BPH.A potential age-related Zn,Fe,and Se deficiency in the prostate tissue has not been found as being involved in the etiology of BPH.

Contents of Trace Metal Elements in Cow Milk Impacted by Different Feedstuffs

Feedstuff intake plays key role in impacting the yield and quality of milk. In this study, we discussed the contents of trace metal elements in cow milk impacted by different feedstuffs. We detected the contents of Pb, Cd, As, Cu, Mg, Ca, Fe and Zn in different feedstuffs and milk by atomic absorption spectrophotometry. The determinations of Pb, Cd and As contents were by graphite furnace A_AS and Cu, Mg, Ca, Fe and Zn was by flame atomic absorption spectrometry. The results showed that Pb, Cd, As and Cu presented in feedstuffs, but Pb, Cd and As were lowly detected in milk samples, and Cu was not detected in milk samples. The content of Mg in concentrates was lower than that in forages. However, the content of Mg in milk from concentrate feed was higher than that in forage feed. This suggested that the utilization of Mg in concentrate feed was higher than that in forage feed. The contents of Ca and Zn were opposite to Mg, and the utilization of Ca and Zn in forage feed was higher than that in concentrate feed. There was no obviously change law of Fe in different feedstuffs and milk samples. The relationship between the contents of trace metal elements in milk to feedstuffs would provide a theoretical basis for dairy farming. It would be useful for improving the milk yield and milk quality of dairy production.

Carbon,Nitrogen,and Sulfur Contents in Marine Phytoplankton Cells and Biomass Conversion

In this study,we isolated and cultured phytoplankton along the coast of China and measured the cellular carbon,nitrogen,and sulfur contents under four temperatures.The results showed that the contents of the cellular elements varied widely among different phytoplankton.We found that temperature is one of the important factors affecting the carbon,nitrogen,and sulfur contents in phytoplankton cells;however,the degree of influence of temperature is different for different kinds of phytoplankton.By measuring the nitrogen content in cells,we found that the C:N ratio indirectly measured in the experiment fluctuated in the range of 3.50-8.97,and the average C:N ratio was 5.52.In this experiment,we accurately measured the cell elemental contents at different temperatures and transformed the cell count results into carbon,nitrogen,and sulfur contents to express the biomass.This method ensures that the contribution of species that are small in number but with a large cell volume in biomass is considered.Moreover,this method comprehensively considers the interspecific differences of species and the uneven distribution of elements in phytoplankton cells,which is of significance in the estimation of marine carbon and nitrogen budget.The distribution of nitrogen content in marine phytoplankton can well indicate the marine eutrophication caused by human activities.Climate change can affect the community structure and element composition of marine phytoplankton,meanwhile marine carbon and nitrogen element can regulate the climate to a certain extent.

Prediction of ash content of unloaded coal based on a discrete element simulation

Based on analysis of regularity of stacking coal,discrete element simultaneous simulation is adopted to predict the process of unloading coal,which is proved to be effcient in the prediction of ash content.The results show that the altitude of new irregular coal is equal to the income coal volume divided by area of cabin.The distribution of infnitesimal flow velocity helps to induce the motion equation of infnitesimal element,which provides the mathematical model for computer simulation.Swarm,a computer programming language,is utilized in this study.Adaptive infnitesimal stacking algorithm helps settle the diffculties in attainment of infnitesimal elements.The result of simulation is similar to the actual situation,which can accurately predict the ash contents of current time and cumulative time.Coal movement in the cabin is a new project,the result of which can also be applied to other solid particles and the widespread of the result will be highly valued.

香榧种实生长早期枝叶和种实矿质元素质量分数及积累量动态分析

【目的】探究香榧Torreyagrandis‘Merrillii’种实早期生长阶段枝叶与种实矿质元素质量分数、积累量的关系,为科学施肥,提升香榧种仁品质及产量提供依据。【方法】选择浙江农林大学东湖校区(2+17)a香榧试验林(砧木为2年生,嫁接后生长了17 a),采集3月上旬至7月上旬当年生侧枝(含叶片)及2代种实,对枝叶、种实中氮、磷、钾、钙、镁、锌、锰、铜质量分数及积累量动态变化关系进行分析。【结果】香榧种实早期生长阶段,种实横纵径、单果干鲜质量及含水率在4月上旬前无明显变化,4月中旬至6月中旬均增长迅速,之后趋于平稳。4月中下旬至6月中旬,枝叶中氮、磷、钾的积累量下降,而种实中氮、磷积累量及钾质量分数持续上升,表明枝叶中的氮、磷、钾优先供应种实的生长,缓生期与花芽分化期种实对氮、磷、钾的需求量较小,速生期种实对氮、磷、钾需求增加,该现象随时间推移而增强;在时间尺度上,钙在枝叶中逐渐吸收、积累,种实中钙质量分数及积累量则呈显著、极显著降低;速生期后,种实中的镁积累量增高,枝叶中镁积累量及质量分数均随着种实的膨大而下降;香榧种实早期生长阶段枝叶中锌、铜积累量呈下降趋势,种实对锌、铜、锰需求量较小。【结论】①速生期香榧种实的体积和含水率快速增加,进入充实期后趋于稳定。②元素质量分数、积累量与香榧种实生长期密切相关。为提高香榧种实品质,应在种实缓生期末期和速生期开始时施加氮、磷、钾肥,并配合施用适量锌、铜等微量元素肥料,在种实采收后施用镁肥。图5参27.

基于Self-Attention-BiLSTM网络的西瓜种苗叶片氮磷钾含量高光谱检测方法

元素含量无损检测技术可以为植物生长发育的环境精准调控提供关键实时数据。以西瓜苗为例,提出了一种基于图谱特征融合的氮磷钾含量深度学习检测方法。首先,使用高光谱仪拍摄西瓜苗叶片的高光谱图像,使用连续流动化学分析仪测定叶片的3种元素含量。然后,采用基线偏移校正(BOC)叠加高斯平滑滤波(GF)的光谱预处理方法和随机森林算法(RF)建立预测模型,基于竞争性自适应重加权采样(CARS)和连续投影算法(SPA)2种算法初步筛选出特征波长,再综合考虑波长数和建模精度设计了一种最优波长评价方法,将波长数进一步减少到3~4个。最后,提取使用U-Net网络分割的彩色图像颜色和纹理特征,和光谱反射率特征一起作为输入,基于自注意力机制-双向长短时记忆(Self-Attention-BiLSTM)网络构建了3种元素含量的预测模型。实验结果表明,氮磷钾含量预测的R2分别为0.961、0.954、0.958,RMSE分别为0.294%、0.262%、0.196%,实现了很好的建模效果。使用该模型对另2个品种西瓜进行测试,R2超过0.899、RMSE小于0.498%,表明该模型具有很好的泛化性。该高光谱建模方法使用少量波长光谱即实现了高精度检测,在精度和效率上达成了很好的平衡,为后续便携式高光谱检测装备开发奠定了理论基础。

CONTENT AND DISTRIBUTION OF TRACE ELEMENTS IN SOILS OF THE DAM RIVER AND TUOTUO RIVER BASINS

Natural contents and distribution of trace elements in soils of the Dam River and Tuotuo River basins are demonstrated in this paper. By using contrasting methods. it is found that the content of trace elements of soil in the region is at the lower limit of the world's soil content level, that the tendency of the average trace element content in the four main types of soil is shown as: alpine mountain meadow soil>marsh soil>alpine mountain steppe soil> alpine mountain cryogenic soil. the average content of trace elements such as Cr. Co, Zn, Cu, Hg, Pb, Mo, Mn and Ni in the Dam River basin is higher than that of the Tuotuo River basin except that of the elements Ba and Sr. In addition. through correlation analysis. the relationship of intergrowth and association among soil elements are revealed.

市售348批次化妆品中锂等37种元素的含量测定及分析

采用电感耦合等离子体质谱检测法对贵州省9个市(州)线下实体经营企业的100批次祛斑美白类、62批次宣称隔离功效的彩妆类、30批次爽身粉及156批次涂抹式面膜类化妆品中锂等37种元素进行含量测定并对数据进行分析。质量浓度范围在0~100μg/L(汞为0~4μg/L)时,37种元素线性相关系数均大于0.999,回收率为88.7%~115.3%,检出限为0.004~4μg/kg,定量限为1~80μg/kg。结果发现,含元素种类较多且含量较高的产品,成分中大多含有土壤、矿物及植物提取物。

山东省胶东半岛养殖刺参中金属元素含量水平分析及健康风险评估

为探讨山东省胶东半岛养殖刺参(Apostichopus japonicus)中铅、镉、汞等11种金属及无机砷含量水平、分布特征及对人体健康的潜在风险,2018—2020年在山东省龙口、莱州、荣城随机采集低播养殖的体质量47.5~98.3 g的刺参样品130份,采用ICP-MS法测定样品中铅、镉、砷等10种元素,原子荧光法测定汞,HPLC-ICP-MS联用法测定无机砷,采用目标危险系数评估样品中金属对人体存在的潜在健康风险,为我国制订鲜海参卫生标准提供参考和数据支撑。结果表明,11种金属元素平均浓度依次递减为Al、Zn、Mn、Cu、As、Cr、Ni、Pb、Cd、Sn、Hg,无机砷含量均小于检出限。单个元素风险顺序为Cd>Cr>Pb>Cu>Al>Zn>Mn>Ni>Hg。单一元素的目标危险系数THQ与多种金属的复合目标危险系数TTHQ均小于1。结果证明:食用山东省胶东半岛养殖刺参目前对人体健康不具有危险性。其中对人体健康危害最大的元素为镉,贡献率达25.6%,应关注海参中镉元素含量对人体健康造成的潜在威胁。

基于离散元法的潮湿甘蔗复合肥参数标定

为能准确建立潮湿甘蔗复合肥的离散元模型,合理设置仿真参数,提高肥料颗粒动力学仿真结果的准确性,以休止角为响应值,对不同含水率的甘蔗复合肥进行试验研究。通过卸料仓法建立含水率与休止角的三元回归方程,决定系数为0.99;基于Hertz-Mindlin with JKR粘结模型,通过Plackett-Burman试验、爬坡试验和Box-Behnken试验从9个初始参数筛选出JKR表面能、甘蔗复合肥剪切模量、甘蔗复合肥与不锈钢静摩擦系数、甘蔗复合肥间静摩擦系数、甘蔗复合肥间恢复系数5项显著性参数,并建立休止角—离散元参数模型,模型P值小于0.01,变异系数为6.35%;最后,通过对不同含水率下的最佳参数组合进行仿真休止角试验,仿真结果与物理休止角试验的相对误差小于7.66%,验证不同含水率的甘蔗复合肥参数标定结果和研究方法是合理可靠的。研究结果可为基于离散元法的甘蔗施肥机械动力学仿真研究提供参考。

动物源营养液对卷叶霸王空气凤梨新叶生长及矿质元素含量影响

为分析动物源营养液在空气凤梨上的应用效果,以‘卷叶霸王’空气凤梨为研究对象,以清水作对照,研究动物源营养液、磷酸二氢钾、尿素喷施后对空气凤梨新叶生长、单株增重、光泽度及矿质元素含量等的影响。结果表明,动物源营养液中含有钙、镁、铁、锌、硼和锰等矿质元素,空气凤梨在各种处理后3月内都没有新根萌出,均未出现肥害与微量元素中毒现象,光泽度没有明显差异。2.50‰营养液处理的第1小叶生长率增加41.58%,增加幅度最大。0.10‰动物源营养液处理单株增重率最高,2.50‰、0.50‰营养液处理次之;不同浓度动物源营养液处理间单株增重率差异不显著。与CK相比,3.33‰营养液处理、1.00‰营养液处理显著增加空气凤梨新叶内钙、镁、铁和锰含量,3.33‰动物源营养液处理的钙含量增加27.80%,镁含量增加23.71%,铁含量增加10.75%,锰含量增加104.41%。3.33‰营养液处理新叶内钙、镁、锰和硼含量显著高于1.00‰营养液处理,但铁和锌含量显著低于1.00‰营养液处理,生产上可以将动物源营养液作为卷叶霸王空气凤梨新型叶面营养肥进行合理开发与利用。