Effects of freeze-thaw cycles on sandstone in sunny and shady slopes

A growing rock engineering activity in cold regions is facing the threat of freeze-thaw(FT)weathering,especially in high mountains where the sunny-shady slope effects strongly control the difference in weathering behavior of rocks.In this paper,an investigation of the degradation of petrophysical characteristics of sandstone specimens subjected to FT cycle tests to simulate the sunny-shady slope effects is presented.To this aim,non-destructive and repeatable testing techniques including weight,ultrasonic waves,and nuclear magnetic resonance methods on standard specimens were performed.For the sunny slope specimens,accompanied by the enlargement of small pores,100 FT cycles caused a significant decrease in P-wave velocity with an average of 23%,but a consistent rise of 0.18%in mass loss,34%in porosity,67%in pore geometrical mean radius,and a remarkable 14.5-fold increase in permeability.However,slight changes with some abnormal trends in physical parameters of the shady slope specimens were observed during FT cycling,which can be attributed to superficial granular disaggregation and pore throat obstruction.Thermal shocks enhance rock weathering on sunny slopes during FT cycles,while FT weathering on shady slopes is restricted to the small pores and the superficial cover.These two factors are primarily responsible for the differences in FT weathering intensity between sunny and shady slopes.The conclusions derived from the interpretation of the experimental results may provide theoretical guidance for the design of slope-failure prevention measures and the selection of transportation routes in cold mountainous regions.

Quantification of the concrete freeze–thaw environment across the Qinghai–Tibet Plateau based on machine learning algorithms

The reasonable quantification of the concrete freezing environment on the Qinghai–Tibet Plateau(QTP) is the primary issue in frost resistant concrete design, which is one of the challenges that the QTP engineering managers should take into account. In this paper, we propose a more realistic method to calculate the number of concrete freeze–thaw cycles(NFTCs) on the QTP. The calculated results show that the NFTCs increase as the altitude of the meteorological station increases with the average NFTCs being 208.7. Four machine learning methods, i.e., the random forest(RF) model, generalized boosting method(GBM), generalized linear model(GLM), and generalized additive model(GAM), are used to fit the NFTCs. The root mean square error(RMSE) values of the RF, GBM, GLM, and GAM are 32.3, 4.3, 247.9, and 161.3, respectively. The R^(2) values of the RF, GBM, GLM, and GAM are 0.93, 0.99, 0.48, and 0.66, respectively. The GBM method performs the best compared to the other three methods, which was shown by the results of RMSE and R^(2) values. The quantitative results from the GBM method indicate that the lowest, medium, and highest NFTC values are distributed in the northern, central, and southern parts of the QTP, respectively. The annual NFTCs in the QTP region are mainly concentrated at 160 and above, and the average NFTCs is 200 across the QTP. Our results can provide scientific guidance and a theoretical basis for the freezing resistance design of concrete in various projects on the QTP.

Thinning intensity aff ects carbon sequestration and release in seasonal freeze–thaw areas

To explore how to respond to seasonal freeze–thaw cycles on forest ecosystems in the context of climate change through thinning,we assessed the potential impact of thinning intensity on carbon cycle dynamics.By varying the number of temperature cycles,the eff ects of various thinning intensities in four seasons.The rate of mass,litter organic carbon,and soil organic carbon(SOC)loss in response to temperature variations was examined in two degrees of decomposition.The unfrozen season had the highest decomposition rate of litter,followed by the frozen season.Semi-decomposed litter had a higher decomposition rate than undecomposed litter.The decomposition rate of litter was the highest when the thinning intensity was 10%,while the litter and SOC were low.Forest litter had a good carbon sequestration impact in the unfrozen and freeze–thaw seasons,while the converse was confi rmed in the frozen and thaw seasons.The best carbon sequestration impact was identifi ed in litter,and soil layers under a 20–25%thinning intensity,and the infl uence of undecomposed litter on SOC was more noticeable than that of semi-decomposed litter.Both litter and soil can store carbon:however,carbon is transported from undecomposed litter to semi-decomposed litter and to the soil over time.In summary,the best thinning intensity being 20–25%.

Change in Grain-Size Composition of Lignite under Cyclic Freezing-Thawing and Wetting-Drying

The paper presents the change in grain-size composition of lignite under cyclic freezing-thawing (FTC) and wetting-drying (WDC). The article shows that in the spring and autumn periods the lignites can be subjected to repeated freezing-thawing and wetting-drying, which determines the possibility of changing their grain-size composition and structure. Experimental studies in laboratory conditions on the influence of cyclic freezing-thawing (FTC) and wetting-drying (WDC) on the quality indicators of lignites have been carried out, their granulometric (fractional) composition has been studied. Freezing-thawing cycle conditions are as follows (FTC): minimum exposure temperature: -20°C;maximum: +5°C;relative humidity: 30%;number of processing cycles: 3. Wetting-drying cycles are as follows (WDC): drying temperatures are +20, +40, +60, +80°C, drying time 90 minutes, the coals are further subjected to rain (soaking) for a period of water saturation to humidity of 30% - 40% and dry again. The number of wetting-drying cycles is 3 times. The tests have revealed the destructive effects of FTC and WDC on the samples of lower metamorphic grade coal, and the cycles of wet-dry lead to the much higher yield of fine sizes (-6+0;-13+0 mm) than the cycles of freeze-thaw. Furthermore, it is found that the increase in the yield of fines depends on the heating temperature: coal disintegration proceeds more intensively at a higher temperature of drying.

Coupling of the Calculated Freezing and Thawing Front Parameterization in the Earth System Model CAS-ESM

The soil freezing and thawing process affects soil physical properties,such as heat conductivity,heat capacity,and hydraulic conductivity in frozen ground regions,and further affects the processes of soil energy,hydrology,and carbon and nitrogen cycles.In this study,the calculation of freezing and thawing front parameterization was implemented into the earth system model of the Chinese Academy of Sciences(CAS-ESM)and its land component,the Common Land Model(CoLM),to investigate the dynamic change of freezing and thawing fronts and their effects.Our results showed that the developed models could reproduce the soil freezing and thawing process and the dynamic change of freezing and thawing fronts.The regionally averaged value of active layer thickness in the permafrost regions was 1.92 m,and the regionally averaged trend value was 0.35 cm yr–1.The regionally averaged value of maximum freezing depth in the seasonally frozen ground regions was 2.15 m,and the regionally averaged trend value was–0.48 cm yr–1.The active layer thickness increased while the maximum freezing depth decreased year by year.These results contribute to a better understanding of the freezing and thawing cycle process.

Response of Freezing/Thawing Indexes to the Wetting Trend under Warming Climate Conditions over the Qinghai–Tibetan Plateau during 1961–2010:A Numerical Simulation

Since the 1990s,the Qinghai–Tibetan Plateau(QTP)has experienced a strikingly warming and wetter climate that alters the thermal and hydrological properties of frozen ground.A positive correlation between the warming and thermal degradation in permafrost or seasonally frozen ground(SFG)has long been recognized.Still,a predictive relationship between historical wetting under warming climate conditions and frozen ground has not yet been well demonstrated,despite the expectation that it will become even more important because precipitation over the QTP has been projected to increase continuously in the near future.This study investigates the response of the thermal regime to historical wetting in both permafrost and SFG areas and examines their relationships separately using the Community Land Surface Model version 4.5.Results show that wetting before the 1990s across the QTP mainly cooled the permafrost body in the arid and semiarid zones,with significant correlation coefficients of 0.60 and 0.48,respectively.Precipitation increased continually at the rate of 6.16 mm decade–1 in the arid zone after the 1990s but had a contrasting warming effect on permafrost through a significant shortening of the thawing duration within the active layer.However,diminished rainfall in the humid zone after the 1990s also significantly extended the thawing duration of SFG.The relationship between the ground thawing index and precipitation was significantly negatively correlated(−0.75).The dual effects of wetting on the thermal dynamics of the QTP are becoming critical because of the projected increases in future precipitation.

The mechanism underlying overwintering death in poplar:the cumulative effect of effective freeze-thaw damage

We analyzed the relationships linking overwintering death and frost cracking to temperature and sunlight as well as the effects of low temperatures and freeze–thaw cycles on bud-burst rates,relative electrical conductivity,and phloem and cambial ultrastructures of poplar.Overwintering death rates of poplar were not correlated with negative accumulated temperature or winter minimum temperature.Freeze–thaw cycles caused more bud damage than constant exposure to low temperatures.Resistance to freeze–thaw cycles differed among clones,and the budburst rate decreased with increasing exposure to freeze–thaw cycles.Cold-resistant clones had the lowest relative electrical conductivity.Chloroplasts exhibited the fastest and the most obvious reaction to freeze–thaw damage,whereas a single freeze–thaw cycle caused little damage to cambium ultrastructure.Several such cycles resulted in damage to plasma membranes,severe damage to organelles,dehydration of cells and cell death.We conclude that overwintering death of poplar is mainly attributed to the accumulation of effective freeze–thaw damage beyond the limits of freeze–thaw resistance.

Effects of Freeze–thaw Cycles on Soil Mechanical and Physical Properties in the Qinghai–Tibet Plateau

Extreme freeze-thaw action occurs on the Qinghai-Tibet Plateau due to its unique climate resulting from high elevation and cold temperature.This action causes damage to the surface soil structure, as soil erosion in the Qinghai-Tibet Plateau is dominated by freeze-thaw erosion.In this research,freezing–thawing process of the soil samples collected from the Qinghai–Tibet Plateau was carried out by laboratory experiments to determinate the volume variation of soil as well as physical and mechanical properties, such as porosity, granularity and uniaxial compressive strength, after the soil experiences various freeze–thaw cycles.Results show that cohesion and uniaxial compressive strength decreased as the volume and porosity of the soil increased after experiencing various freeze–thaw cycles, especially in the first six freeze–thaw cycles.Consequently, the physical and mechanical properties of the soil were altered.However, granularity and internal friction angle did not vary significantly with an increase in the freeze–thaw cycle.The structural damage among soil particles due to frozen water expansion was the major cause of changes in soil mechanical behavior in the Qinghai–Tibet Plateau.

Classification and Assessment of Freeze-Thaw Erosion in Tibet, China

Based on the analysis of existing relevant research result, a theoretical basis for the defining freeze- thaw erosion zones of Qinghai-Tibet Plateau was been put forward, and a equation for calculating the altitude of the lower bound of the freeze-thaw erosion zones of Qinghai-Tibet Plateau was been established in this paper. Moreover, the freeze-thaw erosion zones in Tibet was been identified by using Geographical Information System (GIS) software. Next, based on the comprehensive analysis of impact factors of freeze-thaw erosion, this paper chooses annul temperature range, slop and vegetation as three indexes, works out the criteria for relative classification of freeze-thaw erosion, and realizes the relative classification of the freeze-thaw erosion in Tibet under the support of GIS software. Then, a synthetic assessment of freeze-thaw erosion in Tibet was been done according to the relative classification result.

Effect of freeze-thaw cycles on uniaxial mechanical properties of cohesive coarse-grained soils

Freeze-thaw cycles are closely related to the slope instability in high-altitude mountain regions. In this study, cohesive coarse-grained soils were collected from a high-altitude slope in the Qinghai–Tibet Plateau to study the effect of cyclic freeze-thaw on their uniaxial mechanical properties. The soil specimens were remolded with three dry densities and three moisture contents. Then, after performing a series of freeze-thaw tests in a closed system without water supply, the soil specimens were subjected to a uniaxial compression test. The results showed that the stress-strain curves of the tested soils mainly performed as strain-softening. The softening feature intensified with the increasing dry density but weakened with an increase in freeze-thaw cycles and moisture content. The uniaxial compressive strength, resilient modulus, residual strength and softening modulus decreased considerably with the increase of freeze-thaw cycles. After more than nine freeze-thaw cycles, these four parameters tended to be stable. These parameters increased with the increase of dry density and decreased with the increasing moisture content, except for the residual strength which did not exhibit any clear variation with an increase in moisture content. The residual strength, however, generally increased with an increase in dry density. The soil structural damage caused by frozen water expansion during the freeze-thaw is the major cause for the changes in mechanical behaviors of cohesive coarse-grained soils. With results in this study, the deterioration effect of freeze-thaw cycles on the mechanical properties of soils should be considered during the slope stability analysis in high-altitude mountain regions.

Experimental study of dynamic resilient modulus of subgrade soils under coupling of freeze–thaw cycles and dynamic load

Although the dynamic properties of subgrade soils in seasonally frozen areas have already been studied, few researchers have considered the influence of shallow groundwater during the freeze–thaw(F–T) cycles. So a multifunctional F–T cycle system was developed to imitate the groundwater recharge in the subgrade during the freezing process and a large number of dynamic triaxial experiments were conducted after the F–T cycles. Some significant factors including the F–T cycle number, compaction degree, confining pressure, cyclic deviator stress, loading frequency, and water content were investigated for the resilient modulus of soils. The experimental results indicated that the dynamic resilient modulus of the subgrade was negatively correlated with the cyclic deviator stress, F–T cycle number, and initial water content, whereas the degree of compaction, confining pressure, and loading frequency could enhance the resilient modulus. Furthermore, a modified model considering the F–T cycle number and stress state was established to predict the dynamic resilient modulus. The calculated results of this modified model were very close to the experimental results. Consequently, calculation of the resilient modulus for F–T cycles considering the dynamic load was appropriate. This study provides reference for research focusing on F–T cycles with groundwater supply and the dynamic resilient moduli of subgrade soils in seasonally frozen areas.

Numerical simulation based on two-directional freeze and thaw algorithm for thermal diffusion model

Freeze-thaw processes significantly modulate hydraulic and thermal char- acteristics of soil. The changes in the frost and thaw fronts （FTFs） affect the water and energy cycles between the land surface and the atmosphere. Thus, the frozen soil com- prising permafrost and seasonally frozen soil has important effects on the land surface hydrology in cold regions. In this study, a two-directional freeze and thaw algorithm is incorporated into a thermal diffusion equation for simulating FTFs. A local adaptive variable-grid method is used to discretize the model. Sensitivity tests demonstrate that the method is stable and FTFs can be tracked continuously. The FTFs and soil tempera- ture at the Qinghai-Tibet Plateau D66 site are simulated hourly from September 1, 1997 to September 22, 1998. The results show that the incorporated model performs much better in the soil temperature simulation than the original thermal diffusion equation, showing potential applications of the method in land-surface process modeling.

Effects of Freeze/Thaw Cycles and Gas Purging Method on Polymer Electrolyte Membrane Fuel Cells

At subzero temperature, the startup capability and performance of polymer electrolyte membrane fuel cell (PEMFC) deteriorates markedly. The object of this work is to study the degradation mechanism of key components of PEMFC-membrane-electrode assembly (MEA) and seek feasible measures to avoid degradation. The effect of freeze/thaw cycles on the structure of MEA is investigated based on porosity and SEM measurement. The performance of a single cell was also tested before and after repetitious freeze/thaw cycles. The experimental results indicated that the performance of a PEMFC decreased along with the total operating time as well as the pore size distribution shifting and micro configuration changing. However, when the redundant water had been removed by gas purging, the performance of the PEMFC stack was almost resumed when it experienced again the same subzero temperature test. These results show that it is necessary to remove the water in PEMFCs to maintain stable performance under subzero temperature and gas purging is proved to be the effective operation.

Cracking in an expansive soil under freeze–thaw cycles

Expansive soils located in cold regions can easily endure the action of frost heaving and cyclic freezing–thawing. Cracking can also occur in expansive clayey soils under freeze–thaw cycles, of which little attention has been paid on this issue.In this study, laboratory experiment and cracking analysis were performed on an expansive soil. Crack patterns were quantitatively analyzed using the fractal concept. The relationships among crack pattern, water loss, number of freeze–thaw cycles, and fractal dimension were discussed. It was found that crack patterns on the surface exhibit a hierarchical network structure that is fractal at a statistical level. Cracks induced by freeze–thaw cycles are shorter, more irregularly oriented,and slowly evolves from an irregularly rectilinear pattern towards a polygonal or quasi–hexagonal one; water loss, closely related to specimen thickness, plays a significant role in the process of soil cracking; crack development under freeze-thaw cycles are not only attributed to capillary effect, but also to expansion and absorption effects.

Typical Soft–Sediment Deformation Structures Induced by Freeze/Thaw Cycles: A Case Study of Quaternary Alluvial Deposits in the Northern Qiangtang Basin, Tibetan Plateau

With the objective of establishing a distinction between deformation structures caused by freeze/thaw cycles and those resulting from seismic activity, we studied three well–exposed alluvial deposits in a section at Dogai Coring, northern Qiangtang Basin, Tibetan Plateau. Deformation is present in the form of plastic structures(diapirs, folds and clastic dykes), brittle structures(micro–faults) and cryogenic wedges. These soft–sediment deformation features(except the micro–faults) are mainly characterized by meter–scale, non–interlayered, low–speed and low–pressure displacements within soft sediments, most commonly in the form of plastic deformation. Taking into account the geographic setting, lithology and deformation features, we interpret these soft–sediment deformation features as the products of freeze/thaw cycles, rather than of earthquake–induced shock waves, thus reflecting regional temperature changes and fluctuations of hydrothermal conditions in the uppermost sediments. The micro–faults(close to linear hot springs) are ascribed to regional fault activity;however, we were unable to identify the nature of the micro–faults, perhaps due to disturbance by subsequent freeze/thaw cycles. This study may serve as a guide to recognizing the differences between deformation structures attributed to freeze/thaw cycles and seismic processes.

Deformation monitoring and analysis at two frost mounds during freeze–thaw cycles along the Qinghai–Tibet Engineering Corridor

This paper presents various deformation-monitoring technologies employed to monitor the frost heave and thaw settlement of two mounds along the Qinghai–Tibet Engineering Corridor(QTEC), China. The QTEC is known as a critical infrastructure and passage connecting inland China and the Qinghai–Tibet Plateau(QTP). Three technologies—global navigation satellite system(GNSS), terrestrial laser scanning(TLS), and unmanned aerial vehicle(UAV)—were used to estimate the freeze/thaw–induced 3D surface deformation of two frost mounds. Our results showed that (1) the two frost mounds exhibited mainly thaw settlement in thawing periods and frost heave in the freezing period, but frost heave dominated after repeated freeze–thaw cycles;(2) different zones of the mounds showed different deformation characteristics;(3) active-layer thickness(ALT) and elevation changes were highly correlated during thaw periods;(4) integrated 3D-measurement technologies can achieve a better understanding and assessment of hazards in the permafrost area.

The classification and assessment of freeze-thaw erosion in Tibet

Freeze-thaw erosion is the third largest soil erosion type after water erosion and wind erosion. Restricted by many factors, few researches on freeze-thaw erosion have so far been done at home and abroad, especially those on the assessment method of freeze-thaw erosion. Based on the comprehensive analysis of impact factors of free-thaw erosion, this paper chooses six indexes, including the annual temperature range, annual precipitation, slope, aspect, vegetation and soil, to build the model for relative classification of freeze-thaw erosion using weighted and additive methods, and realizes the relative classification of the freeze-thaw erosion in Tibet with the support of GIS software. Then a synthetic assessment of freeze-thaw erosion in Tibet has been carried out according to the relative classification result. The result shows that the distribution of freeze-thaw eroded area is very extensive in Tibet, accounting for 55.3% of the total local land area; the spatial differentiation of freeze-thaw erosion with different intensities is obvious; and the difference in distribution among different regions is also obvious.

Effect of Freeze-thaw Cycles on Bond Strength between Steel Bars and Concrete

The effect of freezing and thawing cycles on mechanical properties of concrete （compressive, splitting tensile strength） was experimentally investigated. According to the pullout test data of three kinds of deformed steel bars, the bond stress-slip curves after freezing and thawing were obtained. The empirical equations of peak bond strength were proposed that the damage accounted for effects of freezing and thawing cycle. Meanwhile, the mechanism of bond deterioration between steel bars and concrete after freezing and thawing cycles was discussed. All these conclusions will be useful to the durability design and reliability calculation of RC structures in cold region.

Deterioration Mechanism of Sulfate Attack on Concrete under Freeze-thaw Cycles

The experiments of concrete attacked by sulfate solution under freeze-thaw cycles were investigated. The sulfate solution includes two types of 5% Na2SO4 and 5% MgSO4. Through the experiment, microstructural analyses such as SEM, XRD and TGA measurements were performed on the selected samples after freeze-thaw cycles. The corrosion products of the concrete were distinguished and quantitatively compared by the thermal analysis. Besides, the damage mechanism considering the dynamic modulus of elastically of concrete under the coupling effect was also investigated. The experimental results show that, under the action of freeze-thaw cycles and sulfate attack, the main attack products in concrete are ettringite and gypsum. The corrosion products exposed to MgSO4 solution are more than those to Na2SO4 solution. Furthermore, the content of gypsum in concrete is less than that of ettringite in test, and some of gypsum can be observed only after a certain corrosion extent. It is also shown that MgSO4 solution has a promoting effect to the damage of concrete under freeze-thaw cycles. Whereas for Na：SO4 solution, the damage of concrete has restrained before 300 freeze-thaw cycles, but the sulfate attack accelerates the deterioration process in its further test period.

The influence of freeze-thaw cycles on the granulometric composition of Moscow morainic clay

The freeze-thaw cycling process considerably changes the composition, structure, and properties of soils. Since the grain size is the most important factor in determining soil characteristics, our current research primarily aims to investigate dynamic changes of the soil fraction when exposed to freeze-thaw conditions. We observed two series of Moscow morainic clayey specimens （gQⅡm）： （Ⅰ） the original series, and （Ⅱ） the remolded series. We subjected each series of soil specimens to different frequencies of freeze-thaw cycles （3, 6, 20, and 40 cycles）, and we used granulometric tests to analyze both series before and after exposure to freeze-thaw conditions. As a result of our experiments, the granulometric compositions tended to be distributed evenly after 40 freeze-thaw processes （i.e., content of fraction for 0.1-0.05 mm was increased after 40 freeze-thaw cycles） because the division of coarse grains and the aggregation of fine grains were synchronized during the freeze-thaw process. The soil grains in both series changed bi-directionally. In the original series, changes of the sand grains were conjugated with the clay grains, and in the remolded series, changes of the sand grains were conjugated with the silt grains, because potential energy difference caused the division and aggregation processes to relate to the counteraction process. The even distribution of soil grain size indicated the state of equilibrium or balance. The granulometric compositions were altered the most during the sixth freeze-thaw cycle, because the coefficient of the intensity variation of the grain fineness （Kvar） had its maximum value at that time.