Poly(vinyl alcohol)(PVA)has been widely used in industrial and consumer products.In this study,we aimed to address this challenge by synthesizing well-defined multiarm poly(vinyl acetate)(PVAc)through the use of nonhy...Poly(vinyl alcohol)(PVA)has been widely used in industrial and consumer products.In this study,we aimed to address this challenge by synthesizing well-defined multiarm poly(vinyl acetate)(PVAc)through the use of nonhydrolyzable vinyl ethertype multifunctional RAFT agents.The control over molecular weights was achieved by the RAFT process to afford polymers with dominant head-to-head linkages at the terminal.Especially,quantitative end-functionalization of the synthesized PVAc was performed using Michael thiol−ene or disulfide exchange reactions.Consequently,saponification of the PVAc enabled the synthesis of end-functionalized multiarm PVA in an efficient manner.This straightforward approach afforded well-defined functional PVAs,which enable further chemical modification,thus widening the utility of PVA in a range of applications,such as precisely controlled network synthesis and bioconjugation.展开更多
文摘Poly(vinyl alcohol)(PVA)has been widely used in industrial and consumer products.In this study,we aimed to address this challenge by synthesizing well-defined multiarm poly(vinyl acetate)(PVAc)through the use of nonhydrolyzable vinyl ethertype multifunctional RAFT agents.The control over molecular weights was achieved by the RAFT process to afford polymers with dominant head-to-head linkages at the terminal.Especially,quantitative end-functionalization of the synthesized PVAc was performed using Michael thiol−ene or disulfide exchange reactions.Consequently,saponification of the PVAc enabled the synthesis of end-functionalized multiarm PVA in an efficient manner.This straightforward approach afforded well-defined functional PVAs,which enable further chemical modification,thus widening the utility of PVA in a range of applications,such as precisely controlled network synthesis and bioconjugation.
