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Identification of time-varying system and energy-based optimization of adaptive control in seismically excited structure
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作者 Elham Aghabarari Fereidoun Amini Pedram Ghaderi 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2024年第1期227-240,共14页
The combination of structural health monitoring and vibration control is of great importance to provide components of smart structures.While synthetic algorithms have been proposed,adaptive control that is compatible ... The combination of structural health monitoring and vibration control is of great importance to provide components of smart structures.While synthetic algorithms have been proposed,adaptive control that is compatible with changing conditions still needs to be used,and time-varying systems are required to be simultaneously estimated with the application of adaptive control.In this research,the identification of structural time-varying dynamic characteristics and optimized simple adaptive control are integrated.First,reduced variations of physical parameters are estimated online using the multiple forgetting factor recursive least squares(MFRLS)method.Then,the energy from the structural vibration is simultaneously specified to optimize the control force with the identified parameters to be operational.Optimization is also performed based on the probability density function of the energy under the seismic excitation at any time.Finally,the optimal control force is obtained by the simple adaptive control(SAC)algorithm and energy coefficient.A numerical example and benchmark structure are employed to investigate the efficiency of the proposed approach.The simulation results revealed the effectiveness of the integrated online identification and optimal adaptive control in systems. 展开更多
关键词 integrated online identification time-varying systems structural energy multiple forgetting factor recursive least squares optimal simple adaptive control algorithm
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Comparative Study on Energy Consumption Structure of Ordinary Rural Households and Rural Tourism Households in Zhejiang Province, China
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作者 Bingxin Fan Wenxuan Li +2 位作者 Zilu Yin Meiyan Wang Chen Chen 《Energy and Power Engineering》 CAS 2023年第1期52-72,共21页
With the rapid development of rural tourism in China, more and more rural households operate a rural tourism business. The purpose of this study is to understand the energy consumption characteristic of ordinary rural... With the rapid development of rural tourism in China, more and more rural households operate a rural tourism business. The purpose of this study is to understand the energy consumption characteristic of ordinary rural households (ORHs) and rural tourism households (RTHs) in the mountainous area and islands area in Zhejiang province. 225 households were surveyed, including 185 ORHs and 40 RTHs, based on a field survey in Quzhou (mountainous area) and Zhoushan (islands area). Results reveal that energy consumption of ORHs is low, but energy comsumption of RTHs is high, about 3 to 5 times higher than that of ORHs. Given the results, the government and RTHs should pay more attention to take measures to reduce energy comsumption. Meanwhile, the factors affecting households’ energy consumption are also analyzed. Energy consumption of ORHs is affected by frequently used area, family income level and permanent population. Then energy consumption of RTHs is mainly related to the total building area, number of air conditioner (AC), number of guestrooms and family income level. 展开更多
关键词 Rural Tourism Ordinary Rural Households Rural Tourism Households energy Consumption energy structure
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A Footpad Structure with Reusable Energy Absorption Capability for Deep Space Exploration Lander:Design and Analysis
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作者 Weiyuan Dou Xiaohang Qiu +2 位作者 Zhiwei Xiong Yanzhao Guo Lele Zhang 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2023年第4期257-270,共14页
The footpad structure of a deep space exploration lander is a critical system that makes the initial contact with the ground,and thereby plays a crucial role in determining the stability and energy absorption characte... The footpad structure of a deep space exploration lander is a critical system that makes the initial contact with the ground,and thereby plays a crucial role in determining the stability and energy absorption characteristics during the impact process.The conventional footpad is typically designed with an aluminum honeycomb structure that dissipates energy through plastic deformation.Nevertheless,its effectiveness in providing cushioning and energy absorption becomes significantly compromised when the structure is crushed,rendering it unusable for reusable landers in the future.This study presents a methodology for designing and evaluating structural energy absorption systems incorporating recoverable strain constraints of shape memory alloys(SMA).The topological configuration of the energy absorbing structure is derived using an equivalent static load method(ESL),and three lightweight footpad designs featuring honeycomb-like Ni-Ti shape memory alloys structures and having variable stiffness skins are proposed.To verify the accuracy of the numerical modelling,a honeycomb-like structure subjected to compression load is modeled and then compared with experimental results.Moreover,the influence of the configurations and thickness distribution of the proposed structures on their energy absorption performance is comprehensively evaluated using finite element simulations.The results demonstrate that the proposed design approach effectively regulates the strain threshold to maintain the SMA within the constraint of maximum recoverable strain,resulting in a structural energy absorption capacity of 362 J/kg with a crushing force efficiency greater than 63%. 展开更多
关键词 Deep space exploration lander Footpad Shape memory alloy(SMA) Reusable energy absorption structure Design method
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Impact of energy structure adjustment on air quality:a case study in Beijing,China 被引量:4
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作者 Bin ZHAO Jiayu XU Jiming HAO 《Frontiers of Environmental Science & Engineering》 SCIE EI CSCD 2011年第3期378-390,共13页
Energy consumption is a major cause of air pollution in Beijing,and the adjustment of the energy structure is of strategic importance to the reduction of carbon intensity and the improvement of air quality.In this pap... Energy consumption is a major cause of air pollution in Beijing,and the adjustment of the energy structure is of strategic importance to the reduction of carbon intensity and the improvement of air quality.In this paper,we explored the future trend of energy structure adjustment in Beijing till 2020,designed five energy scenarios focusing on the fuel substitution in power plants and heating sectors,established emission inventories,and utilized the Mesoscale Modeling System Generation 5(MM5)and the Models-3/Community Multiscale Air Quality Model(CMAQ)to evaluate the impact of these measures on air quality.By implementing this systematic energy structure adjustment,the emissions of PM_(10),PM_(2.5),SO_(2),NO_(x),and non-methane volatile organic compounds(NMVOCs)will decrease distinctly by 34.0%,53.2%,78.3%,47.0%,and 30.6%respectively in the most coalintensive scenario of 2020 compared with 2005.Correspondingly,MM5-Models-3/CMAQ simulations indicate significant reduction in the concentrations of major pollutants,implying that energy structure adjustment can play an important role in improving Beijing’s air quality.By fuel substitution for power plants and heating boilers,PM_(10),PM_(2.5),SO_(2),NO_(x),and NMVOCs will be reduced further,but slightly by 1.7%,4.5%,11.4%,13.5%,and 8.8%respectively in the least coal-intensive scenario.The air quality impacts of different scenarios in 2020 resemble each other,indicating that the potential of air quality improvement due to structure adjustment in power plants and heating sectors is limited.However,the CO_(2) emission is 10.0%lower in the least coal-intensive scenario than in the most coal-intensive one,contributing to Beijing’s ambition to build a low carbon city.Except for energy structure adjustment,it is necessary to take further measures to ensure the attainment of air quality standards. 展开更多
关键词 BEIJING energy structure adjustment air quality Community Multiscale Air Quality Model(CMAQ) SCENARIO
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Role of Ordering Energy in Formation of Grain Structure and Special Boundaries Spectrum in Ordered Alloys with L12 Superstructure 被引量:1
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作者 O.B.Perevalova (Institute of Strength Physics and Material Science, Russian Academy of Sciences, Siberian Branch pr. Academicheskii, 2/1, 634048, Tomsk, Russia) E. V.Konovalova, N.A.Koneva and E. VKozlov (State University of Architecture and Building, Sol 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2000年第6期585-590,共6页
It was revealed that an average energy of special boundaries is proportional to APB energy in the alloys with the L12 superstructure. This fact proves the appearance of the GAPBs in the planes of location of special b... It was revealed that an average energy of special boundaries is proportional to APB energy in the alloys with the L12 superstructure. This fact proves the appearance of the GAPBs in the planes of location of special boundaries in coincidence sites of ordered alloys. It was determined that the more energy of special boundaries in ordered alloys, the more energy of complex stacking fault. There is a correlation between the distribution of special boundaries as a function its relative energy and ordering energy: the more ordering energy, the more degree of washed away of distribution. The correlation between average relative energy of special boundaries and ordering energy was detected: the more ordering energy, the more average energy of special boundaries. The reverse dependence between ordering energy and average number of special boundaries in grains limited by boundaries of general type was discovered. 展开更多
关键词 Role of Ordering energy in Formation of Grain structure and Special Boundaries Spectrum in Ordered Alloys with L12 Superstructure
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Optimization Design of an Embedded Multi-Cell Thin-Walled Energy Absorption Structures with Local Surface Nanocrystallization
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作者 Kang Xu Tong Li +3 位作者 Gaofei Guan Jianlong Qu Zhen Zhao Xinsheng Xu 《Computer Modeling in Engineering & Sciences》 SCIE EI 2022年第2期987-1002,共16页
Bymeans of the local surface nanocrystallization that enables to change the material on local positions,an innovative embedded multi-cell(EMC)thin-walled energy absorption structures with local surface nanocrystalliza... Bymeans of the local surface nanocrystallization that enables to change the material on local positions,an innovative embedded multi-cell(EMC)thin-walled energy absorption structures with local surface nanocrystallization is proposed in this paper.The local surface nanacrystallization stripes are regarded as the moving morphable components in the domain for optimal design.Results reveal that after optimizing the local surface nanocrystallization layout,the specific energy absorption(SEA)is increased by 50.78%compared with the untreated counterpart.Besides,in contrast with the optimized 4-cell structure,the SEA of the nanocrystallized embedded 9-cell structure is further enhanced by 27.68%,in contrast with the 9-cell structure,the SEA of the nanocrystallized embedded clapboard type 9-cell structure is enhanced by 3.61%.Thismethod provides a guidance for the design of newenergy absorption devices. 展开更多
关键词 Local surface nanocrystallization EMC model assembled thin-walled energy absorption structures optimization design specific energy absorption
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Optimization of energy consumption structure based on carbon emission reduction target:A case study in Shandong Province,China
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作者 Jixiang Liu Haichao Ma +7 位作者 Qingsong Wang Shu Tian Yue Xu Yujie Zhang Xueliang Yuan Qiao Ma Yuan Xu Shuo Yang 《Chinese Journal of Population,Resources and Environment》 2022年第2期125-135,共11页
It is urgent to significantly reduce greenhouse gas emissions to actively deal with global warming.This paper investigates Shandong Province,a typical province of energy consumption,as the research object,aiming to op... It is urgent to significantly reduce greenhouse gas emissions to actively deal with global warming.This paper investigates Shandong Province,a typical province of energy consumption,as the research object,aiming to optimize total energy consumption and consumption structure in the future planning year.This paper constructs a methodological system to optimize energy consumption structure in Shandong Province,using a scenario combination of system dynamics(SD)prediction and analysis based on the coupling of key scenario elements affecting different energy consumption from different perspectives.Structural equation modeling and SD sensitivity analysis indicate an overlap between key factors restricting energy consumption.Pairing the key scenario factors can better reflect the internal mechanism of energy consumption development.Based on this,21 scenarios based on different combinations of the key elements are constructed.Through SD prediction and analysis,the most suitable scenario mode for optimizing energy consumption structure in Shandong Province is selected.This paper provides a suitable development range for the average gross domestic product growth rate,the proportion of secondary industry,energy consumption intensity of secondary industry,and the urbanization rate for Shandong Province.This paper can provide a reference for similar research and the government in formulating the optimization scheme of energy consumption structure. 展开更多
关键词 energy consumption structure System dynamics Structural equation Scenario combination analysis Carbon emissions Optimization Research
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Climate change,ambient air pollution,and students'mental health
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作者 Jing-Xuan Wang Xin-Qiao Liu 《World Journal of Psychiatry》 SCIE 2024年第2期204-209,共6页
The impact of global climate change and air pollution on mental health has become a crucial public health issue.Increased public awareness of health,advancements in medical diagnosis and treatment,the way media outlet... The impact of global climate change and air pollution on mental health has become a crucial public health issue.Increased public awareness of health,advancements in medical diagnosis and treatment,the way media outlets report environmental changes and the variation in social resources affect psychological responses and adaptation methods to climate change and air pollution.In the context of climate change,extreme weather events seriously disrupt people's living environments,and unstable educational environments lead to an increase in mental health issues for students.Air pollution affects students'mental health by increasing the incidence of diseases while decreasing contact with nature,leading to problems such as anxiety,depression,and decreased cognitive function.We call for joint efforts to reduce pollutant emissions at the source,improve energy structures,strengthen environmental monitoring and governance,increase attention to the mental health issues of students,and help student groups build resilience;by establishing public policies,enhancing social support and adjusting lifestyles and habits,we can help students cope with the constantly changing environment and maintain a good level of mental health.Through these comprehensive measures,we can more effectively address the challenges of global climate change and air pollution and promote the achievement of the United Nations Sustainable Development Goals. 展开更多
关键词 Climate change Ambient air pollution Mental health energy structure Public policy Sustainable development
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Studying the variable energy band structure for energy storage materials in charge/discharge process
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作者 Xuancheng Chen Yu Huan +5 位作者 Ningqiang Sun Yuanhui Su Xuesong Shen Guoqing Li Jiaqi Zhang Tao Wei 《Chinese Chemical Letters》 SCIE CAS CSCD 2024年第2期584-589,共6页
So far,a clear understanding about the relationship of variable energy band structure with the corresponding charge-discharge process of energy storage materials is still lacking.Here,using optical spectroscopy(red-gr... So far,a clear understanding about the relationship of variable energy band structure with the corresponding charge-discharge process of energy storage materials is still lacking.Here,using optical spectroscopy(red-green-blue(RGB)value,reflectivity,transmittance,UV-vis,XPS,UPS)to studyα-Co(OH)_(2) electrode working in KOH electrolyte as the research object,we provide direct experimental evidence that:(1)The intercalation of OH-ions will reduce the valence/conduction band(VB and CB)and band gap energy(Eg)values;(2)The deintercalation of OH-ions corresponds with the reversion of VB,CB and E_(g) to the initial values;(3)The color of Co(OH)_(2) electrode also exhibit regular variations in RGB value during the charge-discharge process. 展开更多
关键词 Variable energy band structure energy storage materials Charge-discharge process Optical spectroscopy SUPERCAPACITORS
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3D printed modular Bouligand dissipative structures with adjustable mechanical properties for gradient energy absorbing
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作者 Junfeng Xiao Mengxing Zhang +6 位作者 Fei Zhai Hongrui Wei Sen Liu Peng Wang Zhiyang Liu Zhongying Ji Xiaolong Wang 《Materials Futures》 2024年第2期104-116,共13页
Three-dimensional(3D)printing allows for the creation of complex,layered structures with precise micro and macro architectures that are not achievable through traditional methods.By designing 3D structures with geomet... Three-dimensional(3D)printing allows for the creation of complex,layered structures with precise micro and macro architectures that are not achievable through traditional methods.By designing 3D structures with geometric precision,it is possible to achieve selective regulation of mechanical properties,enabling efficient dissipation of mechanical energy.In this study,a series of modular samples inspired by the Bouligand structure were designed and produced using a direct ink writing system,along with a classical printable polydimethylsiloxane ink.By altering the angles of filaments in adjacent layers(from 30◦to 90◦)and the filament spacing during printing(from 0.8 mm to 2.4 mm),the mechanical properties of these modular samples can be adjusted.Compression mechanical testing revealed that the 3D printed modular Bouligand structures exhibit stress-strain responses that enable multiple adjustments of the elastic modulus from 0.06 MPa to over 0.8 MPa.The mechanical properties were adjusted more than 10 times in printed samples prepared using uniform materials.The gradient control mechanism of mechanical properties during this process was analyzed using finite element analysis.Finally,3D printed customized modular Bouligand structures can be assembled to create an array with Bouligand structures displaying various orientations and interlayer details tailored to specific requirements.By decomposing the original Bouligand structure and then assembling the modular samples into a specialized array,this research aims to provide parameters for achieving gradient energy absorption structures through modular 3D printing. 展开更多
关键词 3D printing additive manufacturing Bouligand structure energy absorbing structures
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Summary of Steam System Optimization and Energy Saving and Carbon Reduction Practice in Yanshan Petrochemical Company
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作者 Jianxin GAO 《Asian Agricultural Research》 2022年第8期39-43,共5页
This paper analyzes the main problems of Sinopec Beijing Yanshan Petrochemical Co.,Ltd.,such as decentralized steam system layout,many types of fuels,obvious increase in fuel cost,low operation efficiency of turbine a... This paper analyzes the main problems of Sinopec Beijing Yanshan Petrochemical Co.,Ltd.,such as decentralized steam system layout,many types of fuels,obvious increase in fuel cost,low operation efficiency of turbine and boiler and high self consumption loss,and puts forward and implements optimization and improvement measures such as pressure raising transformation of natural gas system,adjustment of energy consumption structure,reduction of energy consumption cost,improvement of steam production quality and equipment efficiency.The results showed that compared with the fuel consumption in 2018,the consumption of coal coke was reduced by 550000 t,the consumption of natural gas was increased by 170000 t,and the total consumption of fuel gas and fuel oil was increased by 50000 t,equivalent to 246000 t of standard coal;the purchased electricity was increased by about 5×10^(8) kW·h.Green power trading and 14.76 MW distributed photovoltaic projects were carried out.According to the calculation of 1400-1600 h annual power generation in class II photovoltaic areas and the emission factor of North China regional power grid baseline,the annual emission reduction was about 55000 t CO_(2) in 2021.After the above transformation,the goal of zero-coking is achieved;the steam consumption of units is reduced by 21.5%,the steam production of boilers is reduced by 24.9%,and the annual emission reduction is about 760000 t CO_(2),which has achieved good results. 展开更多
关键词 Steam system Fuel structure energy structure Equipment efficiency Steam loss OPTIMIZATION energy saving Carbon reduction
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Analysis on Carbon Emissions from Energy Consumption in Agriculture and Reduction Measures in Guangdong Province 被引量:1
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作者 XIE Shu-juan1,2,3 1.Guangzhou Institute of Geochemistry,Chinese Academy of Sciences,Guangzhou 510640,China 2.Graduate University of Chinese Academy of Sciences,Beijing 100049,China 3.Guangdong Academy of Social Sciences,Guangzhou 510610,China 《Meteorological and Environmental Research》 CAS 2011年第7期66-69,73,共5页
[Objective] The aim was to study CO2 emissions from energy consumption in agricultural production in Guangdong Province and put forward feasible reduction measures.[Method] Based on the data from China Energy Statisti... [Objective] The aim was to study CO2 emissions from energy consumption in agricultural production in Guangdong Province and put forward feasible reduction measures.[Method] Based on the data from China Energy Statistical Yearbook and Guangdong Statistical Yearbook,CO2 emissions from agricultural energy use in Guangdong Province from 2000 to 2009 was estimated by using the formula of carbon emissions recommended by Intergovernmental Panel on Climate Change (IPCC),and corresponding reduction measures were put forward.[Result] With the rapid increase of agricultural output and energy consumption,CO2 emissions from energy consumption in agricultural production in Guangdong Province showed increasing trend from 2000 to 2009,that is to say,increasing from 423.63×104 t C million tons in 2000 to 605.99×104 t C in 2009,with annual growth rate of 4.1%.Meanwhile,carbon emissions intensity during energy consumption in agriculture went down in recent ten years,in other words,decreasing from 0.424 t C/×104 yuan in 2000 to 0.301 t C/×104 yuan in 2009,and its annual decreasing rate was 3.7%.The variation of CO2 emissions from energy consumption in agriculture mainly resulted from the increase of agricultural output,improvement of energy utilization efficiency,high carbonization in agricultural energy consumption structure and so forth.Therefore,in order to reduce CO2 emissions from energy consumption in agriculture,it is necessary to vigorously develop rural renewable energy,develop and popularize advanced technology for energy utilization,advance the energy conservation of agricultural machines,establish and improve the macroeconomic control mechanism for carbon emissions from the energy consumption in agricultural production in the further.[Conclusion] The study could provide references for the establishment of policy about reducing carbon emissions from agricultural energy consumption in Guangdong Province. 展开更多
关键词 energy consumption in agriculture energy consumption structure CO2 emissions Carbon emissions intensity China
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Research on Energy Consumption of Traditional Natural Villages in Transition: A Case Study in Zhejiang Province 被引量:1
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作者 Meiyan Wang Shenglan Huang +4 位作者 Xinxin Lin Didit Novianto Liyang Fan Weijun Gao Zu Wang 《Energy and Power Engineering》 2016年第1期34-50,共17页
Traditional agriculture is in the direction of increasing integration of the primary industry, secondary industry, and tertiary industry in Zhejiang province. A survey was undertaken on energy consumption of tradition... Traditional agriculture is in the direction of increasing integration of the primary industry, secondary industry, and tertiary industry in Zhejiang province. A survey was undertaken on energy consumption of traditional natural villages by taking Anji Ligeng village for an example. This paper firstly studied rural buildings, rural family structure, occupants’ activity and the usage of household appliances in the form of a questionnaire. Then, the household energy resource structure and energy consumption structure were analyzed and compared with other surveys. The results show that, the electric energy consumption was 6 kWh/(m<sup>2</sup>&bull;a), which was far less than urban residential household. In rural household energy resource structure, the proportion of non-commercial energy resource was higher than commercial energy resource. Firewood accounted for 83%, electricity for 12%, LPG for 3% and solar energy for 2%. In building energy consumption structure, cooking and hot water took up 33%, appliances 31%, lighting 20%, heating 12%, cooling 4%. In all influential factors, frequently used area, number of air conditioner per household and building function were obviously correlated with energy consumption;income, building shape factor and window to wall area ratio had no correlation with energy consumption in the low energy consumption area. 展开更多
关键词 Natural Village Rural Building energy Resource energy Consumption structure Influential Factor
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Reanalysis of energy band structure in the type-II quantum wells
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作者 李欣欣 邓震 +4 位作者 江洋 杜春花 贾海强 王文新 陈弘 《Chinese Physics B》 SCIE EI CAS 2024年第6期75-78,共4页
Band structure analysis holds significant importance for understanding the optoelectronic characteristics of semiconductor structures and exploring their potential applications in practice. For quantum well structures... Band structure analysis holds significant importance for understanding the optoelectronic characteristics of semiconductor structures and exploring their potential applications in practice. For quantum well structures, the energy of carriers in the well splits into discrete energy levels due to the confinement of barriers in the growth direction. However, the discrete energy levels obtained at a fixed wave vector cannot accurately reflect the actual energy band structure. In this work, the band structure of the type-II quantum wells is reanalyzed. When the wave vectors of the entire Brillouin region(corresponding to the growth direction) are taken into account, the quantized energy levels of the carriers in the well are replaced by subbands with certain energy distributions. This new understanding of the energy bands of low-dimensional structures not only helps us to have a deeper cognition of the structure, but also may overturn many viewpoints in traditional band theories and serve as supplementary to the band theory of low-dimensional systems. 展开更多
关键词 energy band structure type-II quantum wells low-dimensional semiconductors
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Path selection and mechanism innovation of improving railway energy efficiency–from foreign experience and Chinese practice
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作者 Xinjun Zhou 《Railway Sciences》 2022年第2期324-344,共21页
Purpose–Under the dual pressure of resources and environment,many countries have focused on the role of railways in promoting low-carbon development of integrated transportation and of even the whole society.This pap... Purpose–Under the dual pressure of resources and environment,many countries have focused on the role of railways in promoting low-carbon development of integrated transportation and of even the whole society.This paper aims to provide a comprehensive study on methods to improve railway energy efficiency in other national railways and achievements made by China’s railways in the past practice,and then to propose ways in which in the future China’s railways could rationally select the path of improving energy efficiency regarding the needs of the nation’s ever-shifting development and carry out the re-engineering for mechanism innovation in energy conservation and emission reduction process.Design/methodology/approach–This paper first studies other national railways that have tried to promote the improvement of railway energy efficiency by the ways of technology,management and structural reconstruction to reduce energy consumption and carbon emissions.Among them,the effect of structural energy conservation and emission reduction has become more prominent.It has become the main energy conservation and emission reduction measure adopted by foreign railway sectors.The practice of energy conservation and emission reduction of railways in various countries has tended to shift from a technical level to a structural one.Findings–Key aspects in improving energy efficiency include re-optimization of energy structure,reinnovation of energy-saving technologies and optimization of transportation organization.Path selection includes continuing to promote electrified railway construction,increasing the use of new and renewable energy sources,and promoting the reform of railway transportation organizations.Originality/value–This paper provides further challenges and research directions in the proposed area and has referential value for the methodologies,approaches for practice in a Chinese context.To achieve the expected goals,relevant supporting policies and measures need to be formulated,including actively guiding integrated transportation toward railway-oriented development,promoting innovation in energy-saving and emission reduction mechanisms and strengthening policy incentives,focusing on improving the energy efficiency of railways through market behavior.At the same time,it is necessary to pay attention to new phenomena in the railway industry for track and analysis. 展开更多
关键词 China’s railways energy efficiency energy consumption structure Transport organization optimization ELECTRIFICATION New energy Renewable energy
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Formation of Hybrid Ring Structure of Cyanurate/Isocyanurate in the Reaction be-tween 2,4,6-Tris(4-Phenyl-Phenoxy)-1, 3,5-Triazine and Phenyl Glycidyl Ether
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作者 Daisuke Ohno Kazuya Zenyoji +2 位作者 Youji Kurihara Kazuyoshi Ueda Hitoshi Habuka 《International Journal of Organic Chemistry》 CAS 2016年第2期117-125,共9页
Reaction products of 2,4,6-tris(4-phenyl-phenoxy)-1,3,5-triazine derived from 4-phenylphenol cyanate ester and phenyl glycidyl ether were analyzed. In addition to an isocyanurate compound and an oxazolidone compound w... Reaction products of 2,4,6-tris(4-phenyl-phenoxy)-1,3,5-triazine derived from 4-phenylphenol cyanate ester and phenyl glycidyl ether were analyzed. In addition to an isocyanurate compound and an oxazolidone compound which were well known as reaction products of cyanate esters and epoxy resins, compounds with hybrid ring structure of cyanurate/isocyanurate were determined. Gibbs free energies of the compound having hybrid ring structure of cyanurate/isocyanurate with two isocyanurate moiety were found to be lower than that of the compound with cyanurate ring structure through calculations. Calculation data supported the existence of hybrid ring structure of cy-anurate/isocyanurate. It was revealed that isomerization from cyanurate to isocyanurate occurs via hybrid ring structure of cyanurate/isocyanurate in the reaction of aryl cyanurate and epoxy. 展开更多
关键词 Reaction products of 2 4 6-tris(4-phenyl-phenoxy)-1 3 5-triazine derived from 4-phenylphenol cya-nate ester and phenyl glycidyl ether were analyzed. In addition to an isocyanurate compound and an oxazolidone compound which were well known as reaction products of cyanate esters and epoxy resins compounds with hybrid ring structure of cyanurate/isocyanurate were determined. Gibbs free energies of the compound having hybrid ring structure of cyanurate/isocyanurate with two isocyanurate moiety were found to be lower than that of the compound with cyanurate ring struc-ture through calculations. Calculation data supported the existence of hybrid ring structure of cy-anurate/isocyanurate. It was revealed that isomerization from cyanurate to isocyanurate occurs via hybrid ring structure of cyanurate/isocyanurate in the reaction of aryl cyanurate and epoxy.
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Atomistic simulations of graphene origami:Dynamics and kinetics
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作者 张盼盼 贾海洪 +1 位作者 张艳芳 杜世萱 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第8期79-85,共7页
Origami offers two-dimensional(2D)materials with great potential for applications in flexible electronics,sensors,and smart devices.However,the dynamic process,which is crucial to construct origami,is too fast to be c... Origami offers two-dimensional(2D)materials with great potential for applications in flexible electronics,sensors,and smart devices.However,the dynamic process,which is crucial to construct origami,is too fast to be characterized by using state-of-the-art experimental techniques.Here,to understand the dynamics and kinetics at the atomic level,we explore the edge effects,structural and energy evolution during the origami process of an elliptical graphene nano-island(GNI)on a highly ordered pyrolytic graphite(HOPG)substrate by employing steered molecular dynamics simulations.The results reveal that a sharper armchair edge is much easier to be lifted up and realize origami than a blunt zigzag edge.The potential energy of the GNI increases at the lifting-up stage,reaches the maximum at the beginning of the bending stage,decreases with the formation of van der Waals overlap,and finally reaches an energy minimum at a half-folded configuration.The unfolding barriers of elliptical GNIs with different lengths of major axis show that the major axis should be larger than 242 A to achieve a stable single-folded structure at room temperature.These findings pave the way for pursuing other 2D material origami and preparing origami-based nanodevices. 展开更多
关键词 origami process dynamics and kinetics structure and energy evolution stability of single-folded structure
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Structural energy storage composites based on modified carbon fiber electrode with metal-organic frame enhancing layered double hydroxide
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作者 Jinrui Ye Zhongbao Wang +2 位作者 Qin Lei Lei Sun Jinfeng Gu 《Nano Research》 SCIE EI CSCD 2024年第3期1552-1563,共12页
Structural energy storage composites present advantages in simultaneously achieving structural strength and electrochemical properties.Adoption of carbon fiber electrodes and resin structural electrolytes in energy st... Structural energy storage composites present advantages in simultaneously achieving structural strength and electrochemical properties.Adoption of carbon fiber electrodes and resin structural electrolytes in energy storage composite poses challenges in maintaining good mechanical and electrochemical properties at reasonable cost and effort.Here,we report a simple method to fabricate structural supercapacitor using carbon fiber electrodes(modified by Ni-layered double hydroxide(Ni-LDH)and in-situ growth of Co-metal-organic framework(Co-MOF)in a two-step process denoted as Co-MOF/Ni-LDH@CF)and bicontinuous-phase epoxy resin-based structural electrolyte.Co-MOF/Ni-LDH@CF as electrode material exhibits improved specific capacity(42.45 F·g^(-1))and cycle performance(93.3%capacity retention after 1000 cycles)in a three-electrode system.The bicontinuous-phase epoxy resin-based structural electrolyte exhibits an ionic conductivity of 3.27×10^(-4) S·cm^(-1).The fabricated Co-MOF/Ni-LDH@CF/SPE-50 structural supercapacitor has an energy density of 3.21 Wh·kg^(-1) at a power density of 42.25 W·kg^(-1),whilst maintaining tensile strength and modulus of 334.6 MPa and 25.2 GPa.These results show practical potential of employing modified commercial carbon fiber electrodes and epoxy resin-based structural electrolytes in structural energy storage applications. 展开更多
关键词 carbon fiber electrode structural electrolyte structural energy storage composites SUPERCAPACITOR
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Assembly mechanisms and energy transfer pathways deciphered in the cryo-EM structure of spinach photosystem Ⅱ-LHCⅡ supercomplex
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《Science Foundation in China》 CAS 2016年第4期36-,共1页
Funded by the National Natural Science Foundation of China(NSFC),Ministry of Science and Technology of China,and Chinese Academy of Sciences,ajoint team of three laboratories from the Institute of Biophysics of Chines... Funded by the National Natural Science Foundation of China(NSFC),Ministry of Science and Technology of China,and Chinese Academy of Sciences,ajoint team of three laboratories from the Institute of Biophysics of Chinese Academy of Sciences,led by Dr.Liu Zhenfeng(柳振峰),Dr.Zhang Xinzheng(章新政)and Dr.Li Mei(李梅)respectively,solved the structure of spinach photosystem II-LHCII supercom- 展开更多
关键词 PSII Assembly mechanisms and energy transfer pathways deciphered in the cryo-EM structure of spinach photosystem SUPERCOMPLEX LHC EM
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Improving performance of Cs_(2)AgBiBr_(6)solar cell through constructing gradient energy level with deep-level hole transport material
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作者 Zi-Yang Xia Wei Zhang +6 位作者 Cheng Chen Hao-Xin Wang Lin-Qin Wang Ya-Wei Miao Xing-Dong Ding Li-Cheng Sun Ming Cheng 《Rare Metals》 SCIE EI CAS CSCD 2023年第9期3004-3012,共9页
The valence band offset between Cs_(2)AgBiBr_(6)and hole transport layer(HTL)is approximately 1.00 e V,which results in high energy loss and is identified as one of the bottle necks of Cs_(2)Ag BiBr_(6)perovskite sola... The valence band offset between Cs_(2)AgBiBr_(6)and hole transport layer(HTL)is approximately 1.00 e V,which results in high energy loss and is identified as one of the bottle necks of Cs_(2)Ag BiBr_(6)perovskite solar cell(PSC)for achieving high power conversion efficiency(PCE).To tackle this problem,we propose the optimization of the energy level alignment by designing and synthesizing novel deep-level hole transport materials(HTMs).The sole introduction of deep-level HTMs successfully reduces the valence band offset between Cs_(2)Ag Bi Br_(6)and HTL,but induces the increased valence band offset at HTL/Au interface,limiting the PCE improvement.To further solve the problem and improve the PCE,the gradient energy level arrangement is constructed by combining the newly developed deep-level HTM 6,6’-(3-((9,9-dimethyl-9H-fluoren-3-yl)(4-methoxyphenyl)amino)thiophene-2,5-diyl)bis(N-(9,9-dimethyl-9H-fluoren-2-yl)-N,9-bis(4-methoxyphenyl)-9H-carbazol-3-amine)(TF)with 2,2’,7,7’-tetrakis(N,N’-dipmethoxyphenylamine)-9,9-spirobifluorene(Spiro-OMeTAD).Through optimization,an impressive PCE of 3.50%with remarkably high open-circuit voltage(V_(oc))and fill factor(FF)is achieved,qualifying it among the best pristine Cs_(2)AgBiBr_(6)PSCs. 展开更多
关键词 All-inorganic Cs_(2)AgBiBr_(6)perovskite Stepped energy level structure energy loss Moisture resistance
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