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Determination of Element Levels of Lagoon from Townships near Cocody City Abidjan Côte D’Ivoire Using Energy Dispersive X-Ray Fluorescence 被引量:1
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作者 Alfred Djoman Djama Agbo Koudou Djagouri +1 位作者 Jean-Claude Olkalé Brigui Konin Pierre-Claver Kakou 《World Journal of Nuclear Science and Technology》 2021年第2期109-118,共10页
Eight water bottles from Ebrie lagoon with pollution potency were studied using nuclear chemistry technique and Energy dispersive X-ray fluorescence. This pollution is characterized by pH and conductivity parameters, ... Eight water bottles from Ebrie lagoon with pollution potency were studied using nuclear chemistry technique and Energy dispersive X-ray fluorescence. This pollution is characterized by pH and conductivity parameters, concentrations average in mg/L of metals such Fe (0.731), Mn (0.345), Cr (0.070), Cu (0.014) and concentrations of nutrients known to be pollutants and toxic for living or-ganisms. These heavy metals are dangerous to the lives, the local inhabitants and also a threat to aquatic life since this water is essential for the economical town, Abidjan. According to the Manganese concentration average (0.345 mg) values that higher than WHO (0.05 mg) value, the main likely source of pollu-tants is anthropogenic, industrial and agricultural. This study also shows the use of materials and lubricants near the lagoon that pollute this water. 展开更多
关键词 Ebrie Lagoon POLLUTION Heavy Metals energy dispersive x-ray fluorescence
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Minipal4便携式能量色散X射线荧光光谱仪在勘查地球化学中的应用 被引量:20
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作者 张勤 樊守忠 +2 位作者 潘宴山 李国会 李小莉 《岩矿测试》 CAS CSCD 2007年第5期377-380,共4页
使用粉末样品压片制样,用Minipal 4便携式能量色散X射线荧光光谱仪测定化探样品中的Na2O、MgO、Al2O3、SiO2、CaO、Fe2O3、K2O、As、Ba、Br、Ce、Co、Cr、Cu、Ga、La、Mn、Nb、Ni、P、Pb、Rb、Sr、Th、V、Y、Zn、Zr、Ti、Mo等30种组分... 使用粉末样品压片制样,用Minipal 4便携式能量色散X射线荧光光谱仪测定化探样品中的Na2O、MgO、Al2O3、SiO2、CaO、Fe2O3、K2O、As、Ba、Br、Ce、Co、Cr、Cu、Ga、La、Mn、Nb、Ni、P、Pb、Rb、Sr、Th、V、Y、Zn、Zr、Ti、Mo等30种组分。方法简便、快速,分析结果的精度和准确度能满足野外现场分析的要求。 展开更多
关键词 便携式能量色散X射线荧光光谱仪 粉末样品压片 多元素同时分析
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基于PCA-BP神经网络的EDXRF分析测定地质样品中铁、钛元素含量的应用研究 被引量:14
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作者 徐立鹏 葛良全 +4 位作者 谷懿 刘敏 张庆贤 李飞 罗斌 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2013年第5期1392-1396,共5页
为实现地质样品中元素含量的准确预测,提出了基于主成分分析(PCA)的改进型BP神经网络模型。采用X荧光光谱法,对新疆西天山地质样品中Fe,Ti,V,Pb和Zn等元素进行测量,将得到的X荧光计数作为输入变量,应用该模型对未知地质样品中Fe和Ti元... 为实现地质样品中元素含量的准确预测,提出了基于主成分分析(PCA)的改进型BP神经网络模型。采用X荧光光谱法,对新疆西天山地质样品中Fe,Ti,V,Pb和Zn等元素进行测量,将得到的X荧光计数作为输入变量,应用该模型对未知地质样品中Fe和Ti元素进行定量预测。结果表明:主成分分析与改进型BP神经网络模型取得了较好的预测效果,预测结果与化学分析值的相对误差小于3%,为地质样品元素含量预测提供了一种新型有效的方法。 展开更多
关键词 能量色散X荧光(EDXRF) 主成分分析(PCA) 主成分-误差反向传播网络(PCA-BP) 地质样品
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改进型M-P神经网络在能量色散X荧光分析测定铅锌矿元素含量的应用研究 被引量:3
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作者 李飞 葛良全 +3 位作者 张庆贤 谷懿 万志雄 李王燕 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2012年第5期1410-1412,共3页
以新疆西天山铅锌矿样品的Cu,Fe,Pb等元素X荧光测量数据做训练样本,McCulloch-Pitts神经网络(M-P神经网络)为基础,基体效应为依据,建立新的神经网络模型对Zn进行定量预测。结果预测值与测量值的相对误差在<5%。此方法可较准确,快速... 以新疆西天山铅锌矿样品的Cu,Fe,Pb等元素X荧光测量数据做训练样本,McCulloch-Pitts神经网络(M-P神经网络)为基础,基体效应为依据,建立新的神经网络模型对Zn进行定量预测。结果预测值与测量值的相对误差在<5%。此方法可较准确,快速的应用于现场X荧光测定,为X荧光光谱信息修正提供一种新方法。 展开更多
关键词 能量色散X荧光分析 改进型M-P神经网络 基体效应 定量预测
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能量色散X射线荧光光谱法测定大米中镉元素的不确定度评定 被引量:1
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作者 李强 欧飞 +1 位作者 吴敏 黄万燕 《中国稻米》 2018年第2期64-66,69,共4页
分析了能量色散X荧光光谱法测定大米中镉含量不确定度的各分量,分析了测量不确定度的来源。测量不确定度主要来源于标准物质和工作曲线拟合。对不确定度分量进行评定,经计算得出合成标准不确定度和扩展不确定度。当大米中镉元素的含量为... 分析了能量色散X荧光光谱法测定大米中镉含量不确定度的各分量,分析了测量不确定度的来源。测量不确定度主要来源于标准物质和工作曲线拟合。对不确定度分量进行评定,经计算得出合成标准不确定度和扩展不确定度。当大米中镉元素的含量为0.268 mg/kg时,扩展不确定度为0.029 mg/kg(k=2)。 展开更多
关键词 能量色散X荧光光谱法 大米 不确定度
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Si-PIN与CdTe探测器应用于X射线荧光能谱测量的研究 被引量:2
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作者 胡传皓 曾国强 +5 位作者 葛良全 喻明福 魏世龙 张开琪 杨剑 陈川 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2017年第1期262-266,共5页
半导体探测器具有优异的性能因而被广泛应用于能量色散X射线荧光测量,以传统型Si-PIN半导体探测器与复合型CdTe半导体探测器为研究对象,分别从材料属性、探测效率、能量分辨率等方面对两种探测器进行对比,重点分析探测器灵敏区厚度、入... 半导体探测器具有优异的性能因而被广泛应用于能量色散X射线荧光测量,以传统型Si-PIN半导体探测器与复合型CdTe半导体探测器为研究对象,分别从材料属性、探测效率、能量分辨率等方面对两种探测器进行对比,重点分析探测器灵敏区厚度、入射X射线能量、后级电路成型时间等因素对其性能的影响,并对由逃逸峰、空穴拖尾效应所导致的X射线荧光能谱的差异进行分析;同时,针对探测器空穴收集不完全的问题,基于FPGA设计了带有上升时间甄别功能的数字多道脉冲幅度分析器,能够有效消除空穴拖尾的影响,提高能量分辨率。从实验结果可知:对能量低于15keV的射线,Si-PIN与CdTe探测器的探测效率基本相当;对能量大于15keV的射线,CdTe探测器的的探测效率明显占优;Si-PIN探测器的最佳成形时间约为10μs,CdTe探测器的最佳成形时间约为2.6μs,因而CdTe探测器更适用于高计数率条件;对于不同能量的X射线,Si-PIN探测器的能量分辨率优于CdTe探测器;CdTe探测器具有明显的空穴拖尾效应,将CdTe探测器与带上升时间甄别功能的数字多道脉冲幅度分析器配合使用,其能量分辨率显著提高。 展开更多
关键词 Si-PIN CDTE 能量色散X射线荧光 能谱测量
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基于能量色散型X射线荧光光谱法煤中全硫含量的测定 被引量:5
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作者 陈旭鑫 李子琪 +3 位作者 骆丁玲 张润元 姚志湘 张锴 《煤炭学报》 EI CAS CSCD 北大核心 2020年第8期2933-2939,共7页
针对艾士卡法、库仑滴定法、高温燃烧中和法和红外光谱法等现有国家标准煤中全硫含量测量方法所需化学试剂多、操作复杂和耗时较长的问题,提出了一种采用能量色散型X射线荧光光谱仪快速、无损和可靠测定煤中全硫含量的方法。该方法是一... 针对艾士卡法、库仑滴定法、高温燃烧中和法和红外光谱法等现有国家标准煤中全硫含量测量方法所需化学试剂多、操作复杂和耗时较长的问题,提出了一种采用能量色散型X射线荧光光谱仪快速、无损和可靠测定煤中全硫含量的方法。该方法是一种相对分析方法,通过将未知样品与已知硫含量的样品谱图对比以进行定量分析。通过实验确定了应用该方法分析煤中硫元素的适宜制样方式、制样条件和测量条件;经过样品数据采集、谱图预处理和基体校正后,建立了相应的校准曲线。结果表明:硼酸镶边垫底压片法的制样效果良好,在12 MPa、保压40 s条件下可获得表面光滑平整、不易破裂的样片;实验所确定的硫元素测量管电压和管电流分别为13 kV和800μA;采用真空装置可以有效控制轻基体背景散射严重及硫元素特征谱线易被空气吸收的问题;通过减小样品粒径和采用经验系数法校正相结合的办法可以降低基体效应的影响;对谱图进行平滑预处理后,有效地增强了谱图分辨率,提高了测量准确性。能量色散型X射线荧光光谱法可将煤中全硫含量的测量时间压缩至60 s;所建立的校准曲线R2为0.9963,随机选取10个待测样品,除个别样品的测量结果略有差异外,其余均在库仑法的范围内;特低硫样品的再现性和重复性试验RSD分别为3.21%和1.57%,低中硫样品对应的RSD分别为0.56%和0.47%,中高硫样品的RSD分别为0.26%和0.22%。 展开更多
关键词 硫含量 能量色散型X射线荧光光谱 粉末压片法 测量条件优化
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能量色散X射线荧光光谱仪快速测定土壤中Cu、Pb、Zn、Rb、Nb和Th6种元素 被引量:15
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作者 李玉莲 敖迎春 +2 位作者 孙宁 李小莉 李国会 《现代仪器》 2012年第6期81-84,共4页
直接使用粉末样品,用便携式能量色散X射线荧光光谱仪测定土壤样品中的Cu、、Zn、Pb、Rb、Nb和Th等6种元素。使用土壤、水系沉积物标准样品建立校准曲线,用铑靶Kα线的康普顿散射线作为内标校正基体效应。方法简便、快速、准确。除Th精... 直接使用粉末样品,用便携式能量色散X射线荧光光谱仪测定土壤样品中的Cu、、Zn、Pb、Rb、Nb和Th等6种元素。使用土壤、水系沉积物标准样品建立校准曲线,用铑靶Kα线的康普顿散射线作为内标校正基体效应。方法简便、快速、准确。除Th精密度为13%外,各组分分析的精密度(RSD,n=12)均小于6%,完全能满足化探样品测定的要求。 展开更多
关键词 便携式能量色散X射线荧光光谱仪 粉末样品 土壤 多元素同时分析
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Minipal4便携X射线荧光光谱仪现场快速测定水系沉积物中多种元素 被引量:3
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作者 王戈 武斌 +2 位作者 苏文 李小莉 张华 《现代仪器》 2012年第1期48-52,共5页
直接使用粉末样品,用Minipal 4便携式能量色散X射线荧光光谱仪现场测定水系成积物样品中的Cu、Zn、AS、Ba、Ni、Co、Mo、Mn等元素,方法简便、快速,把采到的样品再送到实验室内进行测量,两者的分析结果基本符合;精密度试验结果,除Mo以外... 直接使用粉末样品,用Minipal 4便携式能量色散X射线荧光光谱仪现场测定水系成积物样品中的Cu、Zn、AS、Ba、Ni、Co、Mo、Mn等元素,方法简便、快速,把采到的样品再送到实验室内进行测量,两者的分析结果基本符合;精密度试验结果,除Mo以外,各组分的RSD(n=12)均小于5%,能满足矿山和野外现场快速测定的要求。 展开更多
关键词 便携式能量色散X射线荧光光谱仪粉末样品 多元素同时分析
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Palaeodiet of Miocene Producers and Depositional Environments:Inferences from the First Evidence of Microcoprolites from India
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作者 Vivesh VKAPUR Kamlesh KUMAR +1 位作者 P.MORTHEKAI Amritpal Singh CHADDHA 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2020年第5期1574-1590,共17页
This paper reviews research on coprolites from India,providing the first evidence of microcoprolites from the early Miocene(Aquitanian)Khari Nadi Formation sedimentary succession,exposed about 1.5 km northeast of the ... This paper reviews research on coprolites from India,providing the first evidence of microcoprolites from the early Miocene(Aquitanian)Khari Nadi Formation sedimentary succession,exposed about 1.5 km northeast of the village of Kotada,Kachchh(Kutch)District,Gujarat State,western India.Morphometric and size comparisons(in a statistical framework)with known coprolites from the Mesozoic-Cenozoic successions of India(including those recorded herein)and globally suggest that fishes were the likely producers of the Kotada coprolites.Scanning electron microscopy confirms the presence of fish dental remains within the coprolites,while both Scanning Electron Microscopy(SEM)and Energy Dispersive X-ray Spectroscopy(EDS)reveal the phosphatic nature of the microscopic coprolite specimens(recorded herein)hinting that the producer(s)were predominantly carnivorous(ichthyophagous)in their diet.Furthermore,X-Ray Fluorescence(XRF)analysis of the host and associated lithologies allows us to deduce that the Kotada coprolites were deposited in a shallow marine environment,with possible aerial exposure of the host lithology occurring at some point after deposition.To the best of our knowledge,the present report is the first record of microscopic fish coprolites from India,as well as being the first from the Aquitanian of India and the oldest Neogene record from India. 展开更多
关键词 COPROLITES palaeodiet PALAEOENVIRONMENT energy dispersive Spectroscopy(EDS) x-ray fluorescence(XRF)analysis Miocene(Aquitanian)
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Scientific studies on pottery and pro-porcelain from group of graves in Henglingshan, Guangdong Province 被引量:2
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作者 WU Juan WU JunMing +3 位作者 LI QiJiang LI JiaZhi LUO HongJie DENG ZeQun 《Science China(Technological Sciences)》 SCIE EI CAS 2009年第10期3085-3091,共7页
The findings of the Henglingshan group of graves, Guangdong Province, were appraised as one of the ten major archaeological excavations in 2000. The pottery and proto-porcelain samples excavated from the group of grav... The findings of the Henglingshan group of graves, Guangdong Province, were appraised as one of the ten major archaeological excavations in 2000. The pottery and proto-porcelain samples excavated from the group of graves in Henglingshan are very important for studying the development history of Guang-dong ceramics. In this paper, the chemical compositions, micro-structure and physical properties of the samples were systematically analyzed. The results were subjected to multivariate statistical analysis. Different compositional patterns were found for specimens from different periods. The reasons for these variations were discussed. In addition, compared with the pottery and proto-porcelain samples from different production sites in other provinces of China, the obvious regional characters and unique law of the development for ancient ceramics of Guangdong were also discussed. 展开更多
关键词 energy dispersIVE x-ray fluorescence ANALYSIS POTTERY proto-porcelain CORRESPONDENCE ANALYSIS
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Use of geochemical fingerprints to trace sediment sources in an agricultural catchment of Argentina 被引量:2
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作者 Romina Torres Astorga Yanina Garcias +4 位作者 Gisela Borgatello Hugo Velasco Román Padilla Gerd Dercon Lionel Mabit 《International Soil and Water Conservation Research》 SCIE CSCD 2020年第4期410-417,共8页
Soil erosion and associated sediment redistribution are key environmental problems in Central Argentina.Specific land uses and management practices,such as intensive grazing and crop cultivation,are considered to be s... Soil erosion and associated sediment redistribution are key environmental problems in Central Argentina.Specific land uses and management practices,such as intensive grazing and crop cultivation,are considered to be significantly driving and accelerating these processes.This research focuses on the identification of suitable soil tracers from hot spots of land degradation and sediment fate in an agricultural catchment of central Argentina with erodible loess soils.Using Energy Dispersive X-Ray Fluorescence(EDXRF),elemental concentrations were determined and later used as soil tracers for geochemical characterization.The best set of tracers were identified using two artificial mixtures composed of known proportions of soil sources collected from different lands having contrasting soil uses.Barium,calcium,iron,phosphorus,and titanium were identified for obtaining the best suitable reconstruction of source proportions in the laboratory-prepared artificial mixtures.Then,these elements,as well as the total organic carbon,were applied for pinpointing critical hot spots of erosion within the studied catchment.Feedlots were identified to be the main source of sediments,river banks and dirt roads together are the second most important source.This investigation provides key information for optimizing soil conservation strategies and selecting land management practices and land uses which do not generate great contribution of sediment,preventing pollution of the waterways of the region. 展开更多
关键词 Fingerprinting Geochemical elements energy dispersive x-ray fluorescence Soil erosion Mixing models
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Chinese Jingdezhen blue and white imperial porcelain 被引量:1
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作者 WU Juan1, LI Jiazhi1, DENG Zequn1 & WANG Changsui2 1. Laboratory of Ancient Ceramics, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China 2. Department of History of Science and Archaeometry, University of Science and Technology of China, Hefei 230026, China 《Science China(Technological Sciences)》 SCIE EI CAS 2004年第3期366-375,共10页
Jingdezhen blue and white imperial porcelain specimens from the Yuan, Ming and Qing dynasties have been systematically analyzed using a nondestructive test method—— energy dispersive X-ray fluorescence analysis (EDX... Jingdezhen blue and white imperial porcelain specimens from the Yuan, Ming and Qing dynasties have been systematically analyzed using a nondestructive test method—— energy dispersive X-ray fluorescence analysis (EDXRF). The derived data of major and trace element compositions have been treated by correspondence analysis. The variation laws of the composition patterns for Jingdezhen blue and white imperial porcelain in different historical periods owing to the change in raw materials, recipe and technology have been discussed, and a time model related to variation of element composition has been preliminarily established, It would be helpful for scientific dating of Jingdezhen blue and white imperial porcelain, and even for the studies on the whole field of identification of ancient ceramics. 展开更多
关键词 energy dispersIVE x-ray fluorescence analysis BLUE and WHITE imperial porcelain CORRESPONDENCE analysis.
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