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Energy-Saving Distributed Flexible Job Shop Scheduling Optimization with Dual Resource Constraints Based on Integrated Q-Learning Multi-Objective Grey Wolf Optimizer
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作者 Hongliang Zhang Yi Chen +1 位作者 Yuteng Zhang Gongjie Xu 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第8期1459-1483,共25页
The distributed flexible job shop scheduling problem(DFJSP)has attracted great attention with the growth of the global manufacturing industry.General DFJSP research only considers machine constraints and ignores worke... The distributed flexible job shop scheduling problem(DFJSP)has attracted great attention with the growth of the global manufacturing industry.General DFJSP research only considers machine constraints and ignores worker constraints.As one critical factor of production,effective utilization of worker resources can increase productivity.Meanwhile,energy consumption is a growing concern due to the increasingly serious environmental issues.Therefore,the distributed flexible job shop scheduling problem with dual resource constraints(DFJSP-DRC)for minimizing makespan and total energy consumption is studied in this paper.To solve the problem,we present a multi-objective mathematical model for DFJSP-DRC and propose a Q-learning-based multi-objective grey wolf optimizer(Q-MOGWO).In Q-MOGWO,high-quality initial solutions are generated by a hybrid initialization strategy,and an improved active decoding strategy is designed to obtain the scheduling schemes.To further enhance the local search capability and expand the solution space,two wolf predation strategies and three critical factory neighborhood structures based on Q-learning are proposed.These strategies and structures enable Q-MOGWO to explore the solution space more efficiently and thus find better Pareto solutions.The effectiveness of Q-MOGWO in addressing DFJSP-DRC is verified through comparison with four algorithms using 45 instances.The results reveal that Q-MOGWO outperforms comparison algorithms in terms of solution quality. 展开更多
关键词 Distributed flexible job shop scheduling problem dual resource constraints energy-saving scheduling multi-objective grey wolf optimizer Q-LEARNING
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Energy-Saving Construction Technologies for Buildings
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作者 Jingjing Sun 《Journal of World Architecture》 2024年第3期43-48,共6页
The development of the construction industry is shifting towards low-carbon construction,so it is necessary to improve and optimize related construction concepts,methods,and processes.By improving resource and energy ... The development of the construction industry is shifting towards low-carbon construction,so it is necessary to improve and optimize related construction concepts,methods,and processes.By improving resource and energy control efficiency in building projects,minimizing construction waste,and reducing environmental impact,a foundation for the sustainable development of the industry can be established.This paper mainly analyzes the significance of low-carbon energy-saving construction technology and the control factors of construction,summarizes the status quo of the development of building energy-saving construction,and puts forward strategies for applying building energy-saving construction technology.These strategies serve to achieve low-carbon and energy-saving goals to promote the healthy development of energy-saving construction. 展开更多
关键词 Low-carbon energy-saving concept CONSTRUCTION energy-saving construction Thermal insulation technology Intelligent technology
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Application of Energy-Saving Materials in Architectural Design
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作者 Yajuan Liu 《Journal of World Architecture》 2024年第3期72-77,共6页
The conventional process of building construction is associated with issues such as the waste of construction materials and environmental pollution.Sustainable development highlights the importance of energy conservat... The conventional process of building construction is associated with issues such as the waste of construction materials and environmental pollution.Sustainable development highlights the importance of energy conservation and eco-friendly practices.It is essential to use energy-efficient and green materials in building designs to ensure the healthy growth of construction companies.This article discusses the advantages and principles of incorporating energy-saving materials in architectural design.It examines the strategies and critical control points for using energy-saving materials in architectural design,offering guidance for the sustainable development of the construction industry. 展开更多
关键词 energy-saving materials Architectural design Advantages Control strategy
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Exploration of Energy-Saving Technologies in Building Electrical System Design
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作者 Yong Zhang 《Journal of Electronic Research and Application》 2024年第4期28-33,共6页
Green energy conservation is the mainstream trend in the current development of the construction industry.The application of energy-saving technology in building electrical system design can effectively reduce energy ... Green energy conservation is the mainstream trend in the current development of the construction industry.The application of energy-saving technology in building electrical system design can effectively reduce energy consumption,avoid unnecessary energy consumption,and truly achieve energy conservation and environmental protection.Based on this,the article elaborates on the principles of energy-saving design in building electrical systems,and actively explores the application of energy-saving technologies from different perspectives such as optimizing power supply and distribution system design,adopting high-efficiency energy-saving lighting equipment,applying renewable energy,promoting smart home technology,and improving the efficiency of building electrical equipment. 展开更多
关键词 Building electrical system design energy-saving technology
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Green,Sustainable Architectural Bamboo with High Light Transmission and Excellent Electromagnetic Shielding as a Candidate for Energy-Saving Buildings 被引量:4
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作者 Jing Wang Xinyu Wu +5 位作者 Yajing Wang Weiying Zhao Yue Zhao Ming Zhou Yan Wu Guangbin Ji 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第1期209-224,共16页
Currently,light-transmitting,energy-saving,and electromagnetic shielding materials are essential for reducing indoor energy consumption and improving the electromagnetic environment.Here,we developed a cellulose compo... Currently,light-transmitting,energy-saving,and electromagnetic shielding materials are essential for reducing indoor energy consumption and improving the electromagnetic environment.Here,we developed a cellulose composite with excellent optical transmittance that retained the natural shape and fiber structure of bamboo.The modified whole bamboo possessed an impressive optical transmittance of approximately 60%at 6.23 mm,illuminance of 1000 luminance(lux),water absorption stability(mass change rate less than 4%),longitudinal tensile strength(46.40 MPa),and surface properties(80.2 HD).These were attributed to not only the retention of the natural circular hollow structure of the bamboo rod on the macro,but also the complete bamboo fiber skeleton template impregnated with UV resin on the micro.Moreover,a multilayered device consisting of translucent whole bamboo,transparent bamboo sheets,and electromagnetic shielding film exhibited remarkable heat insulation and heat preservation performance as well as an electromagnetic shielding performance of 46.3 dB.The impressive optical transmittance,mechanical properties,thermal performance,and electromagnetic shielding abilities combined with the renewable and sustainable nature,as well as the fast and efficient manufacturing process,make this bamboo composite material suitable for effective application in transparent,energy-saving,and electromagnetic shielding buildings. 展开更多
关键词 Electromagnetic interference shielding Biomass material TRANSMITTANCE energy-saving BAMBOO
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Low-content Pt-triggered the optimized d-band center of Rh metallene for energy-saving hydrogen production coupled with hydrazine degradation 被引量:1
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作者 Qiqi Mao Wenxin Wang +6 位作者 Kai Deng Hongjie Yu Ziqiang Wang You Xu Xiaonian Li Liang Wang Hongjing Wang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第10期58-66,I0004,共10页
Utilizing the hydrazine-assisted water electrolysis for energy-efficient hydrogen production shows a promising application, which relies on the development and design of efficient bifunctional electrocatalysts. Herein... Utilizing the hydrazine-assisted water electrolysis for energy-efficient hydrogen production shows a promising application, which relies on the development and design of efficient bifunctional electrocatalysts. Herein, we reported a low-content Pt-doped Rh metallene(Pt-Rhene) for hydrazine-assisted water electrolysis towards energy-saving hydrogen(H_(2)) production, where the ultrathin metallene is constructed to provide enough favorable active sites for catalysis and improve atom utilization.Additionally, the synergistic effect between Rh and Pt can optimize the electronic structure of Rh for improving the intrinsic activity. Therefore, the required overpotential of Pt-Rhene is only 37 mV to reach a current density of-10 mA cm^(-2) in the hydrogen evolution reaction(HER), and the Pt-Rhene exhibits a required overpotential of only 11 mV to reach a current density of 10 mA cm^(-2) in the hydrazine oxidation reaction(HzOR). With the constructed HER-HzOR two-electrode system, the Pt-Rhene electrodes exhibit an extremely low voltage(0.06/0.19/0.28 V) to achieve current densities of 10/50/100 mA cm^(-2) for energy-saving H_(2) production, which greatly reduces the electrolysis energy consumption. Moreover,DFT calculations further demonstrate that the introduction of Pt modulates the electronic structure of Rh and optimizes the d-band center, thus enhancing the adsorption and desorption of reactant/intermediates in the electrocatalytic reaction. 展开更多
关键词 Pt-Rhene Synergistic effect Hydrogen evolution reaction Hydrazine oxidation reaction energy-saving H_(2)production
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SQL Server性能优化的技术分析
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作者 赵佳 《中国高新科技》 2024年第7期102-104,107,共4页
随着客户端/服务器技术和多层架构的进步,系统效率问题日益引发广泛讨论。由于缺乏数据库管理系统(DBMS)提供的优化方法和工具,以及基于微软技术的数据库管理员和应用程序开发人员的知识,无法对设计和服务执行系统进行优化。文章回顾了... 随着客户端/服务器技术和多层架构的进步,系统效率问题日益引发广泛讨论。由于缺乏数据库管理系统(DBMS)提供的优化方法和工具,以及基于微软技术的数据库管理员和应用程序开发人员的知识,无法对设计和服务执行系统进行优化。文章回顾了提高SQL Server实例性能时需要考虑的目标,并阐述了用于优化查询的技术。 展开更多
关键词 查询 优化 SQL server
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Design of Diversified Intelligent Control System for Energy-saving Optimization of Solar Greenhouse in North China
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作者 Yanmeng HE Baohui MA 《Asian Agricultural Research》 2023年第7期45-50,53,共7页
Intelligent greenhouse can promote the development of modern agriculture, realize the high quality and high yield of crops, and also bring greater economic benefits. In accordance with the climate conditions in northw... Intelligent greenhouse can promote the development of modern agriculture, realize the high quality and high yield of crops, and also bring greater economic benefits. In accordance with the climate conditions in northwest China, a set of intelligent control system for diversified environment of solar greenhouse was designed. The system divides the annual greenhouse control into six stages according to the optimal energy saving. It uses modern detection technology to collect the greenhouse environmental temperature, environmental humidity, soil humidity, CO_(2) concentration and illumination parameters under different working modes. It uses programmable logic control technology to realize the data processing of various parameters and the action control of rolling film, wet curtain fan and other actuators. It uses KingView monitoring software to realize the monitoring and manual control of greenhouse environment parameters. The operation results indicate that the control system runs stably and basically meets the control requirements. 展开更多
关键词 Solar greenhouse energy-saving optimization Diversified Control Intelligent control
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Behavior characteristics and market operation problems of existing building energy-saving renovation market
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作者 GUO Han-ding WANG Ming-yu +1 位作者 MA Xing-neng ZHANG Yin-xian 《Ecological Economy》 2023年第3期271-283,共13页
The long-term and effective implementation of the existing building energy efficiency renovation depends on the development of the existing building energy efficiency renovation market.The key to the development of th... The long-term and effective implementation of the existing building energy efficiency renovation depends on the development of the existing building energy efficiency renovation market.The key to the development of the existing building energy efficiency renovation market is the joint role of the market players.Starting with the analysis of the externalities and information asymmetry of the existing building energy efficiency renovation market,this paper analyzes the behavioral characteristics and influencing factors of the existing building energy efficiency renovation market entities(central government,local government,owners,energy conservation service enterprises,third-party evaluation institutions,and other market entities),and reveals the problems of the existing building energy efficiency renovation market,such as the absence of government,the lack of main power,and the lack of financing channels,Thus,it lays a platform foundation for the research on the behavior strategy and security system of the existing building energy-s aving renovation market. 展开更多
关键词 the existing buildings energy-saving transformation subjective behavior EXTERNALITY information asymmetry
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Multi-subject and multi-objective integrated optimization system and implementation strategy for energy-saving renovation of the existing residential buildings
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作者 GUO Han-ding JIN Zhen-xing +1 位作者 QIAO Wan-zhen ZHANG Yin-xian 《Ecological Economy》 2023年第2期149-162,共14页
The core of the healthy and orderly operation of the existing residential building energy-saving renovation market lies in the exploration of the implementation mechanism of multi-subject and multi-objective integrate... The core of the healthy and orderly operation of the existing residential building energy-saving renovation market lies in the exploration of the implementation mechanism of multi-subject and multi-objective integrated optimization.The multi-agent and multi-objective integrated optimization system framework is a powerful tool to guide the scientific decision-making of the market core structural entities in the future market practice. This paper analyzes the practical dilemma of energy-saving renovation of theexisting residential buildings in China, summarizes the practical experience of multi-subject and multi-objective integrated optimization of energy-saving renovation of the existing residential buildings in foreign countries, and puts forward beneficial practical enlightenment on the basis of comparison at home and abroad;The design principles of the target integrated optimization system have established a multi-subject and multi-objective integrated optimization system framework for the energy-saving renovation of the existing residential buildings, from six aspects: government guidance, trust consensus, value co-creation, risk sharing, revenue sharing, and social responsibility sharing. This paper proposes a multi-subject and multi-objective integrated practice strategy, in order to promote the efficient and orderly development of China's existing residential building energy-saving renovation market. 展开更多
关键词 the existing residential buildings energy-saving renovation win-win cooperation multi-objective integration hierarchical optimization
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Application Strategy of PLC Technology in Energy-Saving Control of Tunnel Lighting
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作者 Yuling Zhang 《Journal of Electronic Research and Application》 2023年第3期7-12,共6页
In this study,we investigated on the application of planar lightwave circuit(PLC)technology in energy-saving control of tunnel lighting.The application status of PLC in the field of energy saving followed by the neces... In this study,we investigated on the application of planar lightwave circuit(PLC)technology in energy-saving control of tunnel lighting.The application status of PLC in the field of energy saving followed by the necessity of energy saving in tunnel lighting was analyzed.Finally,the application of PLC in tunnel lighting energy-saving control around the three dimensions of system overall architecture design,control scheme,and program control process was investigated.The results showed that the system meets the requirements of control effect,robustness,and visual effect after trial operation,and is suitable for practical applications. 展开更多
关键词 energy-saving tunnel lighting PLC technology Control scheme Program control
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Python Server Page Performance Analysis and Modeling
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作者 Razafindraibe Marolahy Alix Randrianomenjanahary Lala Ferdinand +2 位作者 Rafamantanantsoa Fontaine Mahatody Thomas F. Angelo Raherinirina 《Communications and Network》 2024年第1期1-30,共30页
Today, in the field of computer networks, new services have been developed on the Internet or intranets, including the mail server, database management, sounds, videos and the web server itself Apache. The number of s... Today, in the field of computer networks, new services have been developed on the Internet or intranets, including the mail server, database management, sounds, videos and the web server itself Apache. The number of solutions for this server is therefore growing continuously, these services are becoming more and more complex and expensive, without being able to fulfill the needs of the users. The absence of benchmarks for websites with dynamic content is the major obstacle to research in this area. These users place high demands on the speed of access to information on the Internet. This is why the performance of the web server is critically important. Several factors influence performance, such as server execution speed, network saturation on the internet or intranet, increased response time, and throughputs. By measuring these factors, we propose a performance evaluation strategy for servers that allows us to determine the actual performance of different servers in terms of user satisfaction. Furthermore, we identified performance characteristics such as throughput, resource utilization, and response time of a system through measurement and modeling by simulation. Finally, we present a simple queue model of an Apache web server, which reasonably represents the behavior of a saturated web server using the Simulink model in Matlab (Matrix Laboratory) and also incorporates sporadic incoming traffic. We obtain server performance metrics such as average response time and throughput through simulations. Compared to other models, our model is conceptually straightforward. The model has been validated through measurements and simulations during the tests that we conducted. 展开更多
关键词 Performance Analysis QUEUE Performance Model Web server Internet World Wide Web Web server Performance
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A Design of an SMTP Email Server
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作者 Liheng Hu 《Journal of Electronic Research and Application》 2024年第4期41-47,共7页
This study developed a mail server program using Socket API and Python.The program uses the Hypertext Transfer Protocol(HTTP)to receive emails from browser clients and forward them to actual email service providers vi... This study developed a mail server program using Socket API and Python.The program uses the Hypertext Transfer Protocol(HTTP)to receive emails from browser clients and forward them to actual email service providers via the Simple Mail Transfer Protocol(SMTP).As a web server,it handles Transmission Control Protocol(TCP)connection requests from browsers,receives HTTP commands and email data,and temporarily stores the emails in a file.Simultaneously,as an SMTP client,the program establishes a TCP connection with the actual mail server,sends SMTP commands,and transmits the previously saved emails.In addition,we also analyzed security issues and the efficiency and availability of this server,providing insights into the design of SMTP mail servers. 展开更多
关键词 Mail server Socket API HTTP protocol SMTP protocol Security analysis Efficiency analysis
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Excel+SQL Server在实验成绩信息管理中的应用研究
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作者 舒鹏丽 高平 白心爱 《电脑编程技巧与维护》 2024年第3期107-109,共3页
深入探讨了如何利用Excel和SQL Server集成化地管理和分析大学物理实验成绩信息。通过建立数据库、导入导出数据、数据查询与分析及使用Excel的数据透视表和图表功能,可以高效地管理实验成绩数据,进而深入分析学生的学习情况和教学效果。
关键词 EXCEL表格 SQL server数据库 实验成绩 数据
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基于ArcGIS Server的网络农田地理信息系统设计 被引量:1
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作者 阮国杰 师倩 《智慧农业导刊》 2023年第15期45-48,共4页
该文为提高农田信息管理智能化水平,应用ArcGIS Server应用平台,完成对网络农田地理信息系统的设计。首先,设计和搭建系统架构和系统运行环境。其次,分别设计用户登录、信息表达、查询统计、专题图制作和空间分析等模块,保证系统功能设... 该文为提高农田信息管理智能化水平,应用ArcGIS Server应用平台,完成对网络农田地理信息系统的设计。首先,设计和搭建系统架构和系统运行环境。其次,分别设计用户登录、信息表达、查询统计、专题图制作和空间分析等模块,保证系统功能设计效果。最后,从应用层、服务层、数据层3个方面,完成对系统设计和实现。结果表明,在ArcGIS Server应用平台的应用背景下,该文所设计的网络农田地理信息系统具有操作简单、安全可靠等特点,可以实时共享和发布农田空间信息,完全符合预期设计标准和要求。希望通过这次研究,为相关人员提供有效的借鉴和参考。 展开更多
关键词 ArcGIS server 网络农田地理信息系统 农田地理信息 系统设计 农田信息化建设
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Excavator Energy-saving Efficiency Based on Diesel Engine Cylinder Deactivation Technology 被引量:15
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作者 YANG Jing QUAN Long YANG Yang 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2012年第5期897-904,共8页
The hydraulic excavator energy-saving research mainly embodies the following three measures: to improve the performance of diesel engine and hydraulic component, to improve the hydraulic system, and to improve the po... The hydraulic excavator energy-saving research mainly embodies the following three measures: to improve the performance of diesel engine and hydraulic component, to improve the hydraulic system, and to improve the power matching of diesel-hydraulic system-actuator. Although the above measures have certain energy-saving effect, but because the hydraulic excavator load changes frequently and fluctuates dramatically, so the diesel engine often works in high-speed and light load condition, and the fuel consumption is higher. Therefore, in order to improve the economy of diesel engine in light load, and reduce the fuel consumption of hydraulic excavator, energy management concept is proposed based on diesel engine cylinder deactivation technology. By comparing the universal characteristic under diesel normal and deactivated cylinder condition, the mechanism that fuel consumption can be reduced significantly by adopting cylinder deactivation technology under part of loads condition can be clarified. The simulation models for hydraulic system and diesel engine are established by using AMESim software, and fuel combustion consumption by using cylinder-deactivation-technology is studied through digital simulation approach. In this way, the zone of cylinder deactivation is specified. The testing system for the excavator with this technology is set up based on simulated results, and the results show that the diesel engine can still work at high efficiency with part of loads after adopting this technology; fuel consumption is dropped down to 11% and 13% under economic and heavy-load mode respectively under the condition of driving requirements. The research provides references to the energy-saving study of the hydraulic excavators. 展开更多
关键词 diesel engine cylinder deactivation hydraulic excavator energy-saving
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Surface free energy of copper-zinc alloy for energy-saving of boiler 被引量:6
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作者 WANG Man LIANG Jinsheng TANG Qingguo MING Xing MENG Junping DING Yan 《Rare Metals》 SCIE EI CAS CSCD 2006年第z1期324-327,共4页
Cu-Zn, Cu-Zn-Sn, Cu-Zn-Ni alloys were melted by vacuum smelter. The effect factors to the surface free energy of the alloys such as chemical composition, crystal structure and surface crystal lattice distortion etc. w... Cu-Zn, Cu-Zn-Sn, Cu-Zn-Ni alloys were melted by vacuum smelter. The effect factors to the surface free energy of the alloys such as chemical composition, crystal structure and surface crystal lattice distortion etc. were investigated by OCA30 automatic contact angle test instrument, metallography microscope and XRD instrument etc. Results suggests: adding alloy element to Cu may increase its surface free energy, and the more kinds of alloy elements are added, the more surface free energy increases; the alloy element Sn an increase the surface free energy of Cu-Zn alloy; Cu-Zn alloy with fir-tree crystal structure, great phase discrepancy and obvious composition aliquation has greater surface free energy; Cu-Zn alloy with compounds and serious surface crystal lattice distortion has greater surface free energy. 展开更多
关键词 BOILER water treatment Cu-Zn alloy crystal structure contact angle surface free energy energy-saving
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基于FreeRTOS的多连接TCP Server设计 被引量:1
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作者 范亚南 高军科 +1 位作者 韩文斌 魏亚伟 《仪表技术与传感器》 CSCD 北大核心 2023年第8期96-100,共5页
文中提出了一种支持多客户端连接的TCP Server的嵌入式软硬件设计方案。该网络服务器以Cortex-M4芯片STM32F407VET6为核心控制器,通过RMII接口与LAN8742A以太网收发器进行网络数据交互。此外,文中将LwIP协议栈移植到FreeRTOS实时操作系... 文中提出了一种支持多客户端连接的TCP Server的嵌入式软硬件设计方案。该网络服务器以Cortex-M4芯片STM32F407VET6为核心控制器,通过RMII接口与LAN8742A以太网收发器进行网络数据交互。此外,文中将LwIP协议栈移植到FreeRTOS实时操作系统中,并根据TCP客户端连接情况,动态创建或消除相应客户端的网络通信线程。研究证明,TCP Server最大可支持4个客户端同时连接,进行稳定的网络数据传输,有效解决了嵌入式网络系统仅单点连接的问题。 展开更多
关键词 FREERTOS STM32F407 多连接TCP server
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Parameters Optimization and Energy-Saving of Highway Tunnel Backlighting with LED 被引量:2
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作者 杨超 范士娟 《Journal of Donghua University(English Edition)》 EI CAS 2017年第1期9-13,共5页
In order to acquire the most energy-saving luminairedistribution-parameters(LDPs)of highway tunnel interior zone backlighting,the parameters optimization model(POM)of backlighting for tunnel interior zone was establis... In order to acquire the most energy-saving luminairedistribution-parameters(LDPs)of highway tunnel interior zone backlighting,the parameters optimization model(POM)of backlighting for tunnel interior zone was established.Yanlieshan tunnel of Jiujing highway was taken as an example for the optimization.The optimal LDPs of the backlighting system of the tunnel interior zone were obtained by the POM,a comparison between the optimization results and those of Yanlieshan tunnel’s actual lighting system was performed,which showed that the optimized backlighting system with LED lamps installed according to the optimized LDPs could save energy remarkablely even under full capacity lighting condition.Illuminance and illuminance uniformity of the tunnel road surface still met the lighting demands even the LED lamp’s luminance decreased by 30%.A backlighting simulation experiment with the optimized backlighting LDPs for Yanlieshan tunnel was accomplished in the software Dialux.The simulation results basically agreed with the optimization calculated results from the POM which proved the correctness of the backlighting POM. 展开更多
关键词 tunnel lighting parameters optimization backlighting optimization model energy-saving
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Coordination Effect-Promoted Durable Ni(OH)_(2) for Energy-Saving Hydrogen Evolution from Water/ Methanol Co-Electrocatalysis 被引量:2
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作者 Guodong Fu Xiaomin Kang +6 位作者 Yan Zhang Xiaoqiang Yang Lei Wang Xian-Zhu Fu Jiujun Zhang Jing-Li Luo Jianwen Liu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2022年第12期176-194,共19页
Electrocatalytic water splitting is a viable technique for generating hydrogen but is precluded from the sluggish kinetics of oxygen evolution reactions(OER).Small molecule oxidation reactions with lower working poten... Electrocatalytic water splitting is a viable technique for generating hydrogen but is precluded from the sluggish kinetics of oxygen evolution reactions(OER).Small molecule oxidation reactions with lower working potentials,such as methanol oxidation reactions,are good alternatives to OER with faster kinetics.However,the typically employed Ni-based electrocatalysts have poor activity and stability.Herein,a novel three-dimensional(3D)-networking Modoped Ni(OH)_(2) with ultralow Ni-Ni coordination is synthesized,which exhibits a high MOR activity of 100 mA cm^(−2) at 1.39 V,delivering 28 mV dec^(−1) for the Tafel slope.Meanwhile,hydrogen evolution with value-added formate co-generation is boosted with a current density of more than 500 mA cm^(−2) at a cell voltage of 2.00 V for 50 h,showing excellent stability in an industrial alkaline concentration(6 M KOH).Mechanistic studies based on density functional the-ory and X-ray absorption spectroscopy showed that the improved performance is mainly attributed to the ultralow Ni-Ni coordination,3D-networking structures and Mo dopants,which improve the catalytic activity,increase the active site density and strengthen the Ni(OH)_(2)3D-networking structures,respectively.This study paves a new way for designing electrocatalysts with enhanced activity and durability for industrial energy-saving hydrogen production. 展开更多
关键词 Coordination effect Methanol selective oxidation NiMoO4 FORMATE energy-saving hydrogen production
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