Novel Method for Evaluating the Aging of Aviation Turbine Engine Oils via High-Temperature Bearing Deposit Tests

Aviation turbine engine oils require excellent thermal-oxidative stability because of their high-temperature environments.High-temperature bearing deposit testing is a mandatory method for measuring the thermal-oxidative performance of aviation lubricant oils,and the relevant apparatus was improved in the present study.Two different commercial aviation turbine engine oils were tested,one with standard performance(known as the SL oil)and the other with high thermal stability,and their thermal-oxidative stability characteristics were evaluated.After 100 h of high-temperature bearing testing,the SL oil was analyzed by using various analytical techniques to investigate its thermal-oxidative process in the bearing test,with its thermal-oxidative degradation mechanism also being discussed.The results indicate that the developed high-temperature bearing apparatus easily meets the test requirements of method 3410.1 in standard FED-STD-791D.The viscosity and total acid number(TAN)of the SL oil increased with the bearing test time,and various deposits were produced in the bearing test,with the micro-particles of the carbon deposits being sphere-like,rod-like,and sheet-like in appearance.The antioxidant additives in the oil were consumed very rapidly in the first 30 h of the bearing test,with N-phenyl-1-naphthylamine being consumed faster than dioctyldiphenylamine.Overall,the oil thermal-oxidative process involves very complex physical and chemical mechanisms.

A Study of Lead Corrosion of Diesel Engine Oil

The effect of base oils,sulfur-containing multi-functional additives and dispersants in formulated diesel lubricants on lead corrosion was evaluated by a self-established high temperature corrosion bench test.Test lead coupons were analyzed by XPS to determine the resulting surface chemistry.The results showed a close correlation between the oxidation stability of base oil blend and the lead corrosion of formulated diesel lubricants.The zinc dialkyldithiophosphate(ZDDP)and zinc dialkyldithiocarbamate(ZDDC)have formed different protective films on lead coupon surfaces.A more or less amount of the protective film formed is the main factor affecting the degree of lead corrosion.The glassy zinc phosphates protective film formed by ZDDP is more effective than the zinc sulfides film formed by ZDDC.The interaction between dispersants and ZDDP had a significant impact on lead corrosion.

Using the TEOST^(■) MHT-4 to Identify Robust Antioxidant Systems for Modern Engine Oils

A research tool has been developed that utilizes the Thermo-Oxidation Engine Oil Simulation Test (TEOST) MHT-4 to collect information on engine oil oxidation and deposit formation. The technique capitalizes on the traditional TEOST features as a deposit formation test, but also generates additional oxidation information by monitoring peak increase in the carbonyl region of the Fourier Transform Infrared Spectrum (FT-IR) of TEOST used oils and volatiles. The data on overall oxidation and deposit formation is used to generate a "robustness" model for modern engine oil degradation. The tool is used to study low phosphorus Group Ⅱ passenger car engine oils formulated with different types of antioxidants and a molybdenum dithiocarbamate (MoDTC). The model shows that improved oxidation and deposit control can be achieved by formulating with the molybdenum compound, and that the most effective stabilization system is composed of the organo-molybdenum compound,an alkylated diphenylamine (NDPA), and the hindered phenolic antioxidant 4,4′-methylenebis(2,6-di-tert-butylphenol) (MBDTBP).

A Multifunctional Borate Ester/Amide for Engine Oils

Global economic and pollution concerns are having a major impact on how modern engine oils are being formulated.Modern engine oil specifications mandate reduced levels of phosphorus and sulfur to protect the efficacy of pollution control devices.In addition,modern engine oil must also be more fuel efficient than earlier generations to reduce greenhouse gas emissions and the impact of high priced gasoline and diesel fuel to the consumer.At the same time,oxidation,wear,and corrosion performance of the oil must not be compromised.Multifunctional additives are useful formulation tools that help formulators meet these tough new challenges.One such additive is the organo-borate ester/amide.Originally conceived as an organic friction modifier,this patented technology is really a multifunctional additive that addresses the global economic and pollution concerns.With the addition of boron,this unique commercial organic friction modifier also imparts antioxidancy,antiwear and anticorrosion properties to engine oil.In addition,the organo-borate ester/amide is compatible with pollution control devices because it does not contain sulfur or phosphorus.Work is on going to uncover additional beneficial properties of this chemistry.

Study on Improving Storage Stability of Marine Engine Oil

According to the conductivity test results,it is found that oil conductivity increases with an increasing additive content,and the turbidity of engine oil is also augmented with an increasing additive content.After testing the turbidity and stability of oils containing the typical conventional calcium sulfonate,the overbased calcium sulfonate and the mixture of the above two calcium sulfonates,the results show that at the same amount of additives used,the oil with a higher turbidity demonstrated a worse stability.A nonionic dispersant that was added into lube oils at a definite concentration could improve the detergent compatibility.For this reason,the sediment volume in three kinds of oils all decreased obviously,resulting in successful improvement of storage stability of marine engine oils.

Analysis of Silver Nanoparticles in Engine Oil: Atangana–Baleanu Fractional Model

The present article aims to examine the heat and mass distribution in a free convection flow of electrically conducted,generalized Jeffrey nanofluid in a heated rotatory system.The flow analysis is considered in the presence of thermal radiation and the transverse magnetic field of strength B0.The medium is porous accepting generalized Darcy’s law.The motion of the fluid is due to the cosine oscillations of the plate.Nanofluid has been formed by the uniform dispersing of the Silver nanoparticles in regular engine oil.The problem has been modeled in the form of classical partial differential equations and then generalized by replacing time derivative with Atangana–Baleanu(AB)time-fractional derivative.Upon taking the Laplace transform technique(LTT)and using physical boundary conditions,exact expressions have been obtained for momentum,energy,and concentration distributions.The impact of a number of parameters on fluid flow is shown graphically.The numerical tables have been computed for variation in the rate of heat and mass transfer with respect to rooted parameters.Finally,the classical solution is recovered by taking the fractional parameter approaching unity.It is worth noting that by adding silver nanoparticles in regular engine oil,its heat transfer rate increased by 14.59%,which will improve the life and workability of the engine.

Kinematic Viscosity and Shear Stress of Used Engine Oil

The goal of this paper describes kinematic viscosity and shear stress of two used engine oils, which have been taken from two different passenger cars. Kinematic viscosity and shear stress are two of the most important physical behaviours of fluids, especially lubricating fluids. In this paper the authors have focused on engine oil. Knowledge of these properties of engine oil is very important due to its lifetime. The experiments have been done using digital rotary rheometer Anton Paar DV-3 P with use of TR8 spindle and special adapter for a small amount of sample （20 mL）. Two different engine oils have been observed--first from passenger car Renault Scenic with petrol engine （engine capacity 1.6 dm3） and the second from passenger car Skoda Roomster with diesel engine （engine capacity 1.4 dm3）. Castrol Magnatec 10W-40 engine oil has been taken from Renault car and Shell Helix Ultra Extra 5W-30 engine oil has been taken from ~koda car. Service interval of change oil has been set to 15,000 km and samples of used engine oils have been taken after 1,500 km. Only first samples of used engine oils have been taken after raid of 20 km. All samples of used engine oils have been compared with new （unused） engine oils same specification. The measured values of kinematic viscosity and shear stress have been modeled using linear function. The coefficients of correlation R have been achieved high values （0.88-0.96）. The obtained models can be used to prediction of engine oil flow behaviour.

Physical and Thermo-Oxidative Characterization of Asphalt Modified with High Density Polyethylene and Recycled Engine Oil

Modification of asphalt using polymers, oils and other additives has been an option to improve asphalt pavement performance and extend its lifespan. The present work aims to evaluate the influence of the addition of engine oil on the consistency and thermal properties of HDPE-modified asphalt. For this study, compositions containing asphalt, engine oil and high-density polyethylene (HDPE) were prepared, varying the concentration of engine oil by 2.5 wt%, 5 wt%, 7.5 wt% and 10 wt% and keeping the concentration of HDPE at 5 wt%. The samples were characterized by conventional tests of penetration, softening point and viscosity, aging in a Rotational Thin Film Oven (RTFO), Thermogravimetric Analysis (TGA). According to the results, the addition of HDPE to virgin asphalt causes an increase in the consistency of the virgin asphalt, which then decreases linearly as the engine oil is added into the matrix. Conventional tests showed improvements in the applicability of the asphalt in terms of resistance to cracks and permanent deformation. TGA showed a slight increase in stability for the modified asphalt samples at elevated temperatures. The RTFO showed mass gain and loss for samples with and without engine oil, respectively.

Geological characteristics of unconventional tight oil reservoir (10^(9) t): A case study of Upper Cretaceous Qingshankou Formation, northern Songliao Basin, NE China

The Daqing exploration area in the northern Songliao Basin has great potential for unconventional oil and gas resources,among which the total resources of tight oil alone exceed 109 t and is regarded as an important resource base of Daqing oilfield.After years of exploration in the Qijia area,Songliao Basin,NE China,tight oil has been found in the Upper Cretaceous Qingshankou Formation.To work out tight oil’s geological characteristics,taking tight oil in Gaotaizi oil layers of the Upper Cretaceous Qingshankou Formation in northern Songliao Basin as an example,this paper systematically analyzed the geological characteristics of unconventional tight oil in Gao3 and Gao4 layers of the Qijia area,based on the data of the geological survey,well drilling journey,well logging,and test.It is that three sets of hydrocarbon source rocks(K2qn1,K2qn2+3,and K2n1)develop in the examined area,and exhibit excellent type I and II kerogens,high organic matter abundance,and moderate maturity.The reservoir is generally composed of thin-bedded mudstone,siltstone,and sandstone,and presents poor porosity(average 8.5 vol.%)and air permeability(average 4 mD).The main reservoir space primarily includes intergranular pores,secondary soluble pores,and intergranular soluble pores.Three types of orifice throats were identified,namely fine throat,extra-fine throat,and micro-fine throat.The siltstone is generally oil-bearing,the reservoirs with slime and calcium become worse oil-bearing,and the mudstone has no obvious oil-bearing characteristics.The brittleness indices of the sandstone in the tight oil reservoir range from 40%to 60%,and those of the mudstone range from 40%to 45%,indicating a better brittleness of the tight oil reservoir.Based on the study of typical core hole data,this paper gives a comprehensive evaluation of the properties of the tight oil and establishes a tight oil single well composite bar chart as well as the initial evaluation system with the core of properties in the tight oil reservoir.This study has theoretical guiding significance and practical application value for tight oil exploration and evaluation in the Qijia area.

Formation,evolution,reconstruction of black shales and their influence on shale oil and gas resource

Black shales are important products of material cycling and energy exchange among the lithosphere,atmosphere,hydrosphere,and biosphere.They are widely distributed throughout geological history and provide essential energy and mineral resources for the development of human society.They also record the evolution process of the earth and improve the understanding of the earth.This review focuses on the diagenesis and formation mechanisms of black shales sedimentation,composition,evolution,and reconstruction,which have had a significant impact on the formation and enrichment of shale oil and gas.In terms of sedimentary environment,black shales can be classified into three types:Marine,terrestrial,and marine-terrestrial transitional facies.The formation processes include mechanisms such as eolian input,hypopycnal flow,gravity-driven and offshore bottom currents.From a geological perspective,the formation of black shales is often closely related to global or regional major geological events.The enrichment of organic matter is generally the result of the interaction and coupling of several factors such as primary productivity,water redox condition,and sedimentation rate.In terms of evolution,black shales have undergone diagenetic evolution of inorganic minerals,thermal evolution of organic matter and hydrocarbon generation,interactions between organic matter and inorganic minerals,and pore evolution.In terms of reconstruction,the effects of fold deformation,uplift and erosion,and fracturing have changed the stress state of black shale reservoirs,thereby having a significant impact on the pore structure.Fluid activity promotes the formation of veins,and have changed the material composition,stress structure,and reservoir properties of black shales.Regarding resource effects,the deposition of black shales is fundamental for shale oil and gas resources,the evolution of black shales promotes the shale oil and gas formation and storage,and the reconstruction of black shales would have caused the heterogeneous distribution of oil and gas in shales.Exploring the formation mechanisms and interactions of black shales at different scales is a key to in-depth research on shale formation and evolution,as well as the key to revealing the mechanism controlling shale oil and gas accumulation.The present records can reveal how these processes worked in geological history,and improve our understanding of the coupling mechanisms among regional geological events,black shales evolution,and shale oil and gas formation and enrichment.

Study of engine performance, emission and combustion characteristics fueled with diesel-like fuel produced from waste engine oil and waste plastics

Utilizing oil extracted from waste engine oil and waste plastics, by pyrolysis, as a filel for internal combustion engines has been demonstrated to be one of the best available waste management methods. Separate blends of fuel from waste engine oil and waste plastic oil was prepared by mixing with diesel and experimental investigation is conducted to study engine performance, combustion and exhaust emissions. It is observed that carbon monoxide （CO） emission increases by 50% for 50% waste plastic oil （50WPO：50D） and by 58% for 50% waste engine oil （50WEO：50D） at full load as compared to diesel. Unburnt hydrocarbon （HC） emission increases by 16% for 50WPO：50D and by 32% for 50WEO：50D as compared to diesel at maximum load. Smoke is fotmd to decrease at all loading conditions for 50WPO：50D operation, but it is comparatively higher for 50WEO：50D operation. 50WPO：50D operation shows higher brake thermal efficiency for all loads as compared to 50WEO：50D and diesel fuel operation. Exhaust gas temperature is higher at all loads tbr 50WPO：50D and 50WEO：50D as compared to diesel fuel operation.

Treatment of engine-oil polluted wastewater with a mixed bacterial flora and kinetics of biodegradation

A mixed bacterial flora was isolated from the soil of two petroleum-contaminated sites, then cultivated and domesticated in an open environment. The bacteria were used to degrade engine oil in wastewater. The optimum biodegradation conditions for all engine oil concentrations of respectively 489 mg L^-1, 1. 075 mg L^-1 and 2 088 mg L^-1 are bacterial inoculum concentration of 0.1%, temperature at 30 ℃ to 35 ℃, pH 7.0 to 7.5, and rotation at 190 r mia^-1 to 240 r rain^-1. The second-order kinetic model proposed by Quiroga and Sales describes the characteristics of the biodegradation of the engine oil very well. Engine oil concentration barely changes the growth rate of the bacterial consortium. The mixed bacterial flora has a high biodegrading capability for engine oil.

Progress and prospects of oil and gas production engineering technology in China

This paper summarizes the important progress in the field of oil and gas production engineering during the"Thirteenth Five-Year Plan"period of China,analyzes the challenges faced by the current oil and gas production engineering in terms of technological adaptability,digital construction,energy-saving and emission reduction,and points out the future development direction.During the"Thirteenth Five-Year Plan"period,series of important progresses have been made in five major technologies,including separated-layer injection,artificial lift,reservoir stimulation,gas well de-watering,and workover,which provide key technical support for continuous potential tapping of mature oilfields and profitable production of new oilfields.Under the current complex international political and economic situation,oil and gas production engineering is facing severe challenges in three aspects:technical difficulty increases in oil and gas production,insignificant improvements in digital transformation,and lack of core technical support for energy-saving and emission reduction.This paper establishes three major strategic directions and implementation paths,including oil stabilization and gas enhancement,digital transformation,and green and low-carbon development.Five key research areas are listed including fine separated-layer injection technology,high efficiency artificial lift technology,fine reservoir stimulation technology,long term gas well de-watering technology and intelligent workover technology,so as to provide engineering technical support for the transformation,upgrading and high-quality development of China’s oil and gas industry.

Development and Application of WebGIS Middleware in Oil Production Engineering

WebGIS is the result of combining the technology of Internet with that of Geographic Information Systems (GIS). This paper aims at some problems in the development of GIS, such as the system of development is instable, and presents the method of adopting component technology to accomplish WebGIS middleware which has been successfully applied to the Oil Production Engineering information visible system. It showed in practice that the WebGIS middleware can be casily embedded in the web pages to accomplish GIS application system in a network environment. On the one hand, its application can reduce complexity of system and speed up the pace of development. On the other hand, it is certain to reduce the development costs and improve the maintainability. Key words WebGIS - middleware - oil production engineering CLC number TP 31 Biography: LIU Quan (1969-), male, Ph. D. candidate, research direction: include automated resoning, WebGIS.

Evaluation of the oil and gas preservation conditions, source rocks, and hydrocarbongenerating potential of the Qiangtang Basin: New evidence from the scientific drilling project

The Qiangtang Basin of the Tibetan Plateau,located in the eastern Tethys tectonic domain,is the largest new marine petroliferous region for exploration in China.The scientific drilling project consisting primarily of well QK-1 and its supporting shallow boreholes for geological surveys(also referred to as the Project)completed in recent years contributes to a series of new discoveries and insights into the oil and gas preservation conditions and source rock evaluation of the Qiangtang Basin.These findings differ from previous views that the Qiangtang Basin has poor oil and gas preservation conditions and lacks high-quality source rocks.As revealed by well QK-1 and its supporting shallow boreholes in the Project,the Qiangtang Basin hosts two sets of high-quality regional seals,namely an anhydrite layer in the Quemo Co Formation and the gypsum-bearing mudstones in the Xiali Formation.Moreover,the Qiangtang Basin has favorable oil and gas preservation conditions,as verified by the comprehensive study of the sealing capacity of seals,basin structure,tectonic uplift,magmatic activity,and groundwater motion.Furthermore,the shallow boreholes have also revealed that the Qiangtang Basin has high-quality hydrocarbon source rocks in the Upper Triassic Bagong Formation,which are thick and widely distributed according to the geological and geophysical data.In addition,the petroleum geological conditions,such as the type,abundance,and thermal evolution of organic matter,indicate that the Qiangtang Basin has great hydrocarbon-generating potential.

Strategies of Chinese Offshore Oil Engineering Companies to Go Global

Alang with big drop of oil prices, offshore oil engineering market demand is witnessing profound changes. This brings rare opportunities while huge challenges for Chinese offshore oil engineering enterprises. Chinese offshore oil engineering enterprises have made rapid development in recent years, but they still have a certain gap with European and American competitors. Only by answering the time＇s call for developmentof international market and having the courage to participate in international competition could Chinese offshore oil engineering enterprises gnaw strong unceasingly.

Pure Jatropha Oil for Power Generation on Floreana IslandlGalapagos： Four Years Experience on Engine Operation and Fuel Quality

In the small country of Ecuador, all environmental risks of the production and consumption of fossil fuels can be observed by damages through oil exploration in the amazonite rainforest and two tank ship accidents close by Galapagos Islands causing death of 10,000 marine iguanas and other species. Now Ecuador plans to replace all environmentally dangerous diesel generators from all four inhabited Galapagos Islands by a hybrid system using 100% renewable energy for electricity production. Since 2010 a hybrid system of two Jatropha oil generators with an electrical power of 69 kW （kWel） and a photovoltaic plant with an electrical peak power of 21 kW （kWpeak） is successfully providing electricity from renewable energy for inhabitants and tourists of Floreana Island. After more than 15.000 engine operation hours of each engine there is no engine defect. For fuel supply, the so-called ＂Living Fence＂ concept collecting Jatropha seeds by farmers and families from already existing 6,000 km hedges on Ecuadorian mainland was chosen to comply with highest biofuel sustainability standards. The Jatropha oil is produced in a decentralized so-called CompacTropha oil mill container following the ambitious German fuel quality standard DIN51605. Since 2010 Floreana project successfully demonstrates that it is possible to replace diesel gen sets by generators fueled with pure Jatropha oil from decentralized sustainable production.

Series 190 Diesel Engines Used in China's Oil Drilling

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Diffusion and Regeneration Mechanism of Waste Composite Oils Rejuvenator in Aged Asphalt

The physical performance of recycled asphalt was used as the main evaluation index to study the optimal range of a self-made rejuvenator.Through the penetration,viscosity and gel permeation chromatography(GPC)tests,the diffusion degree of the rejuvenator under different temperatures and time process was analyzed,and the diffusion efficiency of the rejuvenator was evaluated from the macro and micro perspective.The regeneration mechanism of the rejuvenator in the aged asphalt was also analyzed using the Fourier transform infrared spectroscopy(FTIR),scanning electron microscope(SEM)and chemical composition tests.The research results showed that the optimum rejuvenator content was about 3%.Higher temperature and longer time were beneficial to improving the permeability and diffusion of the rejuvenator.During the aging process,the light components were reduced,and more macromolecular asphaltenes were generated as well as a large number of carbonyl and sulfoxide.After diffusion and regeneration,the light components in the asphalt were supplemented,the wrinkles and gullies of the aged asphalt were almost improved to the surface state of the matrix asphalt.

Depositional process of hyperpycnal flow deposits:A case study on Lower Cretaceous Sangyuan outcrop in the Luanping Basin,Northeast China

Sedimentary process research is of great significance for understanding the distribution and characteristics of sediments.Through the detailed observation and measurement of the Sangyuan outcrop in Luanping Basin,this paper studies the depositional process of the hyperpycnal flow deposits,and divides their depositional process into three phases,namely,acceleration,erosion and deceleration.In the acceleration phase,hyperpycnal flow begins to enter the basin nearby,and then speeds up gradually.Deposits developed in the acceleration phase are reverse.In addition,the original deposits become unstable and are taken away by hyperpycnal flows under the eroding force.As a result,there are a lot of mixture of red mud pebbles outside the basin and gray mud pebbles within the basin.In the erosion phase,the reverse deposits are eroded and become thinner or even disappear.Therefore,no reverse grading characteristic is found in the proximal major channel that is closer to the source,but it is still preserved in the middle branch channel that is far from the source.After entering the deceleration phase,normally grading deposits appear and cover previous deposits.The final deposits in the basin are special.Some are reverse,and others are normal.They are superimposed with each other under the action of hyperpycnal flow.The analysis of the Sangyuan outcrop demonstrates the sedimentary process and distribution of hyperpycnites,and reasonably explain the sedimentary characteristics of hyperpycnites.It is helpful to the prediction of oil and gas exploration targets in gravity flow deposits.