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Inter-stage performance and energy characteristics analysis of electric submersible pump based on entropy production theory
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作者 Hui Wang Yang Yang +5 位作者 Bin Xi Wei-Dong Shi Chuan Wang Lei-Lei Ji Xiang-Yu Song Zhao-Ming He 《Petroleum Science》 SCIE EI CAS CSCD 2024年第2期1354-1368,共15页
The electric submersible pump(ESP) is a crucial apparatus utilized for lifting in the oil extraction process.Its lifting capacity is enhanced by the multi-stage tandem structure, but variations in energy characteristi... The electric submersible pump(ESP) is a crucial apparatus utilized for lifting in the oil extraction process.Its lifting capacity is enhanced by the multi-stage tandem structure, but variations in energy characteristics and internal flow across stages are also introduced. In this study, the inter-stage variability of energy characteristics in ESP hydraulic systems is investigated through entropy production(EP) analysis,which incorporates numerical simulations and experimental validation. The EP theory facilitates the quantification of energy loss in each computational subdomain at all ESP stages, establishing a correlation between microscopic flow structure and energy dissipation within the system. Furthermore, the underlying causes of inter-stage variability in ESP hydraulic systems are examined, and the advantages and disadvantages of applying the EP theory in this context are evaluated. Consistent energy characteristics within the ESP, aligned with the distribution of internal flow structure, are provided by the EP theory, as demonstrated by our results. The EP theory also enables the quantitative analysis of internal flow losses and complements existing performance analysis methods to map the internal flow structure to hydraulic losses. Nonetheless, an inconsistency between the energy characterization based on EP theory and the traditional efficiency index when reflecting inter-stage differences is identified. This inconsistency arises from the exclusive focus of the EP theory on flow losses within the flow field, disregarding the quantification of external energy input to the flow field. This study provides a reference for the optimization of EP theory in rotating machinery while deeply investigating the energy dissipation characteristics of multistage hydraulic system, which has certain theoretical and practical significance. 展开更多
关键词 Electric submersible pump(ESP) entropy production theory Energy characteristics Inter-stage differences
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The Correlation between the Power Quality Indicators and Entropy Production Characteristics of Wind Power+Energy Storage Systems
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作者 Caifeng Wen Boxin Zhang +3 位作者 Yuanjun Dai Wenxin Wang Wanbing Xie Qian Du 《Energy Engineering》 EI 2024年第10期2961-2979,共19页
Power quality improvements help guide and solve the problems of inefficient energy production and unstable power output in wind power systems.The purpose of this paper is mainly to explore the influence of different e... Power quality improvements help guide and solve the problems of inefficient energy production and unstable power output in wind power systems.The purpose of this paper is mainly to explore the influence of different energy storage batteries on various power quality indicators by adding different energy storage devices to the simulated wind power system,and to explore the correlation between systementropy generation and various indicators,so as to provide a theoretical basis for directly improving power quality by reducing loss.A steady-state experiment was performed by replacing the wind wheel with an electric motor,and the output power qualities of the wind power systemwith andwithout energy storagewere compared and analyzed.Moreover,the improvement effect of different energy storage devices on various indicatorswas obtained.Then,based on the entropy theory,the loss of the internal components of the wind power system generator is simulated and explored by Ansys software.Through the analysis of power quality evaluation indicators,such as current harmonic distortion rate,frequency deviation rate,and voltage fluctuation,the correlation between entropy production and each evaluation indicator was explored to investigate effective methods to improve power quality by reducing entropy production.The results showed that the current harmonic distortion rate,voltage fluctuation,voltage deviation,and system entropy production are positively correlated in the tests and that the power factor is negatively correlated with system entropy production.In the frequency range,the frequency deviationwas not significantly correlated with the systementropy production. 展开更多
关键词 Wind power system entropy production system losses power quality indexes battery energy storage
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Economic and entropy production evaluation of extractive distillation and solvent-assisted pressure-swing distillation by multi-objective optimization
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作者 Yao Wang Qing Ye +2 位作者 Jinlong Li Qingqing Rui Azhi Yu 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第11期246-259,共14页
Extractive distillation(ED)and solvent-assisted pressure-swing distillation(SA-PSD)are both special distillation processes that perform good at separating pressure-insensitive azeotropes.However,few reported studies h... Extractive distillation(ED)and solvent-assisted pressure-swing distillation(SA-PSD)are both special distillation processes that perform good at separating pressure-insensitive azeotropes.However,few reported studies have compared the performance of the two processes.In this paper,ED processes with N-methylpyrrolidone(NMP)and dimethlac-etamide(DMCA)as entrainer,SA-PSD process with isopropyl-alcohol(IPA)as solvent and SA-PSD process with partial heat integration(PHI-PSD)are proposed to achieve high purity separation of a mixture of cyclohexane/2-butanol system.The optimal operating conditions of the processes are obtained after optimizing with NSGA-Ⅱ algorithm when total annual cost(TAC)and the entropy production of process are set as objectives.The optimal results show that the optimal PHI-PSD process has lower TAC by 28.7% and the lower entropy production by 39.5% than the optimal SA-PSD process while the ED process with NMP as entrainer has lower TAC by 50.9% and the lower entropy production by 56.1% than the optimal SA-PSD process.The optimal results show that the ED process with NMP as entrainer has the best economic and thermodynamic efficiency among the four proposed processes in this paper. 展开更多
关键词 Extractive distillation Solvent-assisted pressure-swing distillation entropy production NSGA-Ⅱalgorithm Computer simulation
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Expressions for Entropy Production Rate of Fuel Cells 被引量:2
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作者 Tong-ling Lin Ying-ru Zhao Jin-can Chen 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 北大核心 2008年第4期361-366,共6页
On the basis of a general model of fuel cells, the entropy production rates of a fuel cell system under different conditions are derived by using theories of electrochemistry and thermodynamics. In order to analyze th... On the basis of a general model of fuel cells, the entropy production rates of a fuel cell system under different conditions are derived by using theories of electrochemistry and thermodynamics. In order to analyze the influence of the irreversible losses existing in an actual fuel cell, the equivalent circuit of the fuel cell is introduced, so that the irreversible factor of the fuel cell may be determined directly as a function of the internal, leak and load resistances. Moreover, the maximum power output and efficiency of the fuel cell are calculated, the optimal operation of the fuel cell is discussed, and the matching condition of the load resistance is determined. 展开更多
关键词 Fuel cell Irreversible loss entropy production rate Optimal analysis Matching condition
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Time dependence of entropy flux and entropy production for a dynamical system driven by noises with coloured cross-correlation 被引量:2
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作者 谢文贤 徐伟 蔡力 《Chinese Physics B》 SCIE EI CAS CSCD 2007年第1期42-46,共5页
This paper shows the Fokker-Planck equation of a dynamical system driven by coloured cross-correlated white noises in the absence and presence of a small external force. Based on the Fokker-Planck equation and the def... This paper shows the Fokker-Planck equation of a dynamical system driven by coloured cross-correlated white noises in the absence and presence of a small external force. Based on the Fokker-Planck equation and the definition of Shannon's information entropy, the time dependence of entropy flux and entropy production can be calculated. The present results can be used to explain the extremal behaviour of time dependence of entropy flux and entropy production in view of the dissipative parameter γ of the system, coloured cross-correlation time τ and coloured cross-correlation strength λ. 展开更多
关键词 information entropy entropy flux entropy production coloured cross-correlation Fokker-Planck equation
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Entropy Production Analysis for Hump Characteristics of a Pump Turbine Model 被引量:4
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作者 LI Deyou GONG Ruzhi +3 位作者 WANG Hongjie XIANG Gaoming WEI Xianzhu QIN Daqing 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2016年第4期803-812,共10页
The hump characteristic is one of the main problems for the stable operation of pump turbines in pump mode.However,traditional methods cannot reflect directly the energy dissipation in the hump region.In this paper,3D... The hump characteristic is one of the main problems for the stable operation of pump turbines in pump mode.However,traditional methods cannot reflect directly the energy dissipation in the hump region.In this paper,3D simulations are carried out using the SST k-ω turbulence model in pump mode under different guide vane openings.The numerical results agree with the experimental data.The entropy production theory is introduced to determine the flow losses in the whole passage,based on the numerical simulation.The variation of entropy production under different guide vane openings is presented.The results show that entropy production appears to be a wave,with peaks under different guide vane openings,which correspond to wave troughs in the external characteristic curves.Entropy production mainly happens in the runner,guide vanes and stay vanes for a pump turbine in pump mode.Finally,entropy production rate distribution in the runner,guide vanes and stay vanes is analyzed for four points under the 18 mm guide vane opening in the hump region.The analysis indicates that the losses of the runner and guide vanes lead to hump characteristics.In addition,the losses mainly occur in the runner inlet near the band and on the suction surface of the blades.In the guide vanes and stay vanes,the losses come from pressure surface of the guide vanes and the wake effects of the vanes.A new insight-entropy production analysis is carried out in this paper in order to find the causes of hump characteristics in a pump turbine,and it could provide some basic theoretical guidance for the loss analysis of hydraulic machinery. 展开更多
关键词 fluid machinery pump turbine entropy production hump characteristics loss
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Time Dependence of Entropy Flux and Entropy Production of a Dissipative Dynamical System Driven by Non-Gaussian Noise 被引量:1
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作者 GUO Yong-Feng XU Wei LI Dong-Xi XIE Wen-Xian 《Communications in Theoretical Physics》 SCIE CAS CSCD 2008年第6期1561-1566,共6页
A stochastic dissipative dynamical system driven by non-Gaussian noise is investigated. A general approximate Fokker-Planck equation of the system is derived through a path-integral approach. Based on the definition o... A stochastic dissipative dynamical system driven by non-Gaussian noise is investigated. A general approximate Fokker-Planck equation of the system is derived through a path-integral approach. Based on the definition of Shannon's information entropy, the exact time dependence of entropy flux and entropy production of the system is calculated both in the absence and in the presence of non-equilibrium constraint. The present calculation can be used to interpret the interplay of the dissipative constant and non-Gaussian noise on the entropy flux and entropy production. 展开更多
关键词 information entropy entropy flux and entropy production non-Gaussian noise Fokker-Planck equation
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Entropy Production Rate Changes in Lysogeny/Lysis Switch Regulation of Bacteriophage Lambda
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作者 丁辉 罗辽复 林吴 《Communications in Theoretical Physics》 SCIE CAS CSCD 2011年第2期371-375,共5页
According to the chemical kinetic model of lysogeny/lysis switch in Escherichia coli (E. coil) infected by bacteriophage A, the entropy production rates of steady states are calculated. The resuits show that the lys... According to the chemical kinetic model of lysogeny/lysis switch in Escherichia coli (E. coil) infected by bacteriophage A, the entropy production rates of steady states are calculated. The resuits show that the lysogenic state has lower entropy production rate than lyric state, which provides an explanation on why the lysogenic state of A phage is so stable. We a/so notice that the entropy production rates of both lysogenic state and lyric state are lower than that of saddle-point and bifurcation state, which is consistent with the principle of minimum entropy production for living organism in nonequilibrium stationary state. Subsequently, the relations between CI and Cro degradation rates at two bifurcations and the changes of entropy production rate with CI and Cro degradation are deduced. The theory and method can be used to calculate entropy change in other molecular network. 展开更多
关键词 lysogeny/lysis switch entropy production rate stationary state BIFURCATION
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Entropy Production of Moving Bed Reactors
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作者 YAN Jian Guo CHEH Yung Ting TANG Zhong He 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 1995年第1期6-9,共5页
We present an entropy production formulationn for a gas-solid moving bed reactor,which we have not seen in any published reference. Apart from the traditional “flows” and “forces”,e. g., those for heat conduction ... We present an entropy production formulationn for a gas-solid moving bed reactor,which we have not seen in any published reference. Apart from the traditional “flows” and “forces”,e. g., those for heat conduction and mass diffusions in each phase , we introduced the heterogeneouseffects: gas-solid heat and mass transfer, which lead to some new flows and forces in the entropyproduction formulation. 展开更多
关键词 gas-solid system moving bed reactor entropy production
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ENTROPY PRODUCTION RATE OF THE MINIMAL DIFFUSION PROCESS
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作者 章复熹 钱敏 《Acta Mathematica Scientia》 SCIE CSCD 2007年第1期145-152,共8页
The entropy production rate of stationary minimal diffusion processes with smooth coefficients is calculated. As a byproduct, the continuity of paths of the minimal diffusion processes is discussed, and that the point... The entropy production rate of stationary minimal diffusion processes with smooth coefficients is calculated. As a byproduct, the continuity of paths of the minimal diffusion processes is discussed, and that the point at infinity is absorbing is proved. 展开更多
关键词 Minimal diffusion process entropy production rate continuous path
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Entropy Production along Dominant Pathway of Nonequilibrium Phase Transition in Mesoscopic Chemical System
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作者 Han-shuang Chen Gang He +1 位作者 Feng Huang Chuan-sheng Shen 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2013年第5期549-552,I0003,共5页
We consider a bistable mesoscopic chemical reaction system and calculate entropy produc- tion along the dominant pathway during nonequilibrium phase transition. Using probability generating function method and eikonal... We consider a bistable mesoscopic chemical reaction system and calculate entropy produc- tion along the dominant pathway during nonequilibrium phase transition. Using probability generating function method and eikonal approximation, we first convert the chemical master equation into the classical Hamilton-Jacobi equation, and then find the dominant pathways between two steady states in the phase space by calculating zero-energy trajectories. We find that entropy productions are related to the actions of the forward and backward dominant pathways. At the coexistence point where the stabilities of the two steady states are equiv alent, both the system entropy change and the medium entropy change are zero; whereas at non-coexistence point both of them are nonzero. 展开更多
关键词 entropy production Mesoscopic chemical reaction Nonequilibrium phasetransition
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Fluctuation theorem for entropy production at strong coupling
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作者 Y Y Xu J Liu M Feng 《Chinese Physics B》 SCIE EI CAS CSCD 2020年第1期175-180,共6页
Fluctuation theorems have been applied successfully to any system away from thermal equilibrium,which are helpful for understanding the thermodynamic state evolution.We investigate fluctuation theorems for strong coup... Fluctuation theorems have been applied successfully to any system away from thermal equilibrium,which are helpful for understanding the thermodynamic state evolution.We investigate fluctuation theorems for strong coupling between a system and its reservoir,by path-dependent definition of work and heat satisfying the first law of thermodynamics.We present the fluctuation theorems for two kinds of entropy productions.One is the informational entropy production,which is always non-negative and can be employed in either strong or weak coupling systems.The other is the thermodynamic entropy production,which differs from the informational entropy production at strong coupling by the effects regarding the reservoir.We find that,it is the negative work on the reservoir,rather than the nonequilibrium of the thermal reservoir,which invalidates the thermodynamic entropy production at strong coupling.Our results indicate that the effects from the reservoir are essential to understanding thermodynamic processes at strong coupling. 展开更多
关键词 fluctuation theorem entropy production strong coupling
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Entropy Production and Fractal Dimensions in Heavy Ion Nuclear Reaction at Intermediate Energies
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作者 Wenxia Wang Yiyan Zhao Yongzhong Xing 《Journal of Applied Mathematics and Physics》 2022年第8期2527-2537,共11页
The characteristics of the nonlinear dynamics in the Heavy Ion Collision (HIC) at intermediate energies have been studied by evaluating the productions of the Generalized Entropy (GE) and the Multifragmentation Entrop... The characteristics of the nonlinear dynamics in the Heavy Ion Collision (HIC) at intermediate energies have been studied by evaluating the productions of the Generalized Entropy (GE) and the Multifragmentation Entropy (ME) as well as the features of the information and fractal dimensions within the Isospin Quantum Molecular Dynamical Model compensated by the lattice methods. Results demonstrate from various views that the existence of deterministic chaos in the dynamical process of reaction. 展开更多
关键词 entropy production Fractal Dimensions Chaotic Behavior Heavy Ion Nuclear Collision Intermediate Energy
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Competing Cosmology Models. Can Entropy Production Help Falsify Cyclic Models of Cosmology, or Variants along the Lines Discussed by Roger Penrose at the ICG Conference in Penn State, 2007?
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作者 Andrew Walcott Beckwith 《Journal of High Energy Physics, Gravitation and Cosmology》 2016年第4期486-505,共20页
In the inaugural ICG meeting, on August 11, 2007 at Penn State, Roger Penrose [1] gave a presentation about an alternative to cyclic cosmological models, which needs experimental tests for falsifiability. As discussed... In the inaugural ICG meeting, on August 11, 2007 at Penn State, Roger Penrose [1] gave a presentation about an alternative to cyclic cosmological models, which needs experimental tests for falsifiability. As discussed by Beckwith, in EJTP [2], Penrose brought up how wave equation, as simplified in flat space could lead to a rising vacuum nucleation field which would engender the pop up behavior as sought in most emergent field models of gravity. The scalar field pop up with certain qualifications is not so startling in itself. Now for the radical extension Penrose brought to bear. Penrose asserted in his ICG lecture that there was a good chance that there was no collapse in future events, but that matter would be eventually sucked up by “millions” of black holes, creating a clean-up of most interstellar matter. The issue to be brought up is how to come up with a mapping for re-combination of the black hole collected material, for a big bang, a topic which was not solved by Penrose. 展开更多
关键词 entropy production COSMOLOGY VARIANTS
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Numerical Simulation and Entropy Production Analysis of Centrifugal Pump with Various Viscosity
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作者 Zhenjiang Zhao Lei Jiang +2 位作者 Ling Bai Bo Pan Ling Zhou 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第11期1111-1136,共26页
The fluid’s viscosity significantly affects the performance of a centrifugal pump.The entropy production method and leakage are employed to analyze the performance changes under various viscosities by numerical simul... The fluid’s viscosity significantly affects the performance of a centrifugal pump.The entropy production method and leakage are employed to analyze the performance changes under various viscosities by numerical simulation and validated by experiments.The results showed that increasing viscosity reduces both the pump head and efficiency.In addition,the optimal operating point shifts to the left.Leakage is influenced by vortex distribution in the front chamber and boundary layer thickness in wear-ring clearance,leading to an initial increase and subsequent decrease in leakage with increasing viscosity.The total entropy production Spro,Total inside the pump rises with increasing viscosity.The different mechanisms dominate under varying conditions:Turbulent dissipation dominates at low viscosity.Under high-viscosity conditions,energy loss is primarily caused by direct dissipation Spro,D and wall entropy production Spro,W.This study provides a deeper and more objective understanding of the energy characteristics of centrifugal pumps handling fluids of various viscosity,potentially aiding in optimizing pump design and improving energy conversion efficiency. 展开更多
关键词 Centrifugal pump numerical simulation viscosity leakage entropy production
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Entropy production by dissipation effects and characteristic vortex evolution in a rocket turbopump
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作者 De-you Li Jia-qi Zhu +4 位作者 Rui-yi Zhang Yi Zhang Zhi-peng Li Hong-jie Wang Zhi-peng Ren 《Journal of Hydrodynamics》 SCIE EI CSCD 2023年第5期993-1007,共15页
The relationship between entropy production and vortex evolution affects the efficiency and stability of rotating machinery.This study investigated the energy characteristics of a rocket turbopump and revealed the cor... The relationship between entropy production and vortex evolution affects the efficiency and stability of rotating machinery.This study investigated the energy characteristics of a rocket turbopump and revealed the correlated mechanisms of the entropy production rate using the dissipation effects and characteristic vortex evolution.For the first time,direct and turbulent dissipation and rigid and shear vorticity decomposition methods were utilized to analyze the correlation between flow loss and characteristic vorticities in rotating machinery.With an increase in the flow rate,the hydraulic losses of the dissipation effects and wall decreased by 60%and 38.3%,respectively,and the proportions of the input energy decreased(from 13%to 8%)and remained stable(8%),respectively.The local direct dissipative entropy production(DDEP)in the inducer-impeller is strongly related to shear entropy,and the correlated effect of total enstrophy on DDEP is weaker than that of shear vorticity,indicating that rigid enstrophy suppresses direct dissipation.The correlation between turbulent dissipation and rigid enstrophy was significantly weaker in the static flow passage of the turbopump owing to the weak rigid rotational effect.The correlation between the rigid entropy and local turbulent dissipative entropy production(TDEP)gradually increased with increasing flow rate,reaching a medium correlation(the maximal correlated degree in the turbopump)and exhibiting rigid rotation effects on the hydraulic loss.Moreover,the flow rate significantly affected the correlation(except for the diffuser),and the two characteristic vorticities reached a maximum at the designed flow rate owing to optimal efficiency and minimum hydraulic loss. 展开更多
关键词 Rocket turbopump hydraulic loss DISSIPATION entropy production vorticity decomposition Liutex
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Study on S-shaped region of pump turbine based on Omega vortex analysis method and entropy production theory
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作者 Zhenggui Li Hongji Zeng +3 位作者 Kun Wang Xiaodong Peng Shengnan Yan Qin Zhao 《International Journal of Agricultural and Biological Engineering》 SCIE 2023年第3期102-109,F0003,共9页
In order to comprehensively analyze the operation instability of the pump turbine S-shaped region,this paper uses DDES turbulence model to calculate the model pump turbine from the perspective of the evolution law of ... In order to comprehensively analyze the operation instability of the pump turbine S-shaped region,this paper uses DDES turbulence model to calculate the model pump turbine from the perspective of the evolution law of runner vortex and draft tube vortex rope and entropy production rate,combined with experiments.The results show that the numerical simulation is in good agreement with the experiment.Omega vortex analysis method is more accurate than other vortex recognition methods because it is not affected by the threshold value.The vortices at the runner region under the runaway condition and the turbine brake condition develop towards the vaneless space and the blade pressure surface respectively,which will cause the flow obstruction and blade separation.The overall vorticity of the reverse pump condition is the largest.The vortex rope of the draft tube under runaway and turbine brake conditions is columnar in shape and has very high rotational strength.The vortex rope under reverse pump conditions is prone to fracture and form scattered vortices,impeding the normal movement of the fluid.The entropy production rate of the spanwise surface near the upper ring and the lower crown is greater than the middle spanwise surface due to the boundary layer effect.And the energy dissipation in the runner under reverse pump conditions is characterized by high at both ends of the runner and low in the middle.The energy dissipation near the wall of the straight cone section of the draft tube is large due to the squeezing effect of the vortex rope on the flow. 展开更多
关键词 pump turbine S-shaped region vortex analysis method vortex evolution entropy production rate
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Local Entropy Production in Turbulent Shear Flows:A Tool for Evaluating Heat Transfer Performance 被引量:6
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作者 H. HERWIG F. KOCK 《Journal of Thermal Science》 SCIE EI CAS CSCD 2006年第2期159-167,共9页
Performance evaluation of heat transfer devices can be based on the overall entropy production in these devices. In our study we therefore provide equations for the systematic and detailed determination of local entro... Performance evaluation of heat transfer devices can be based on the overall entropy production in these devices. In our study we therefore provide equations for the systematic and detailed determination of local entropy production due to dissipation of mechanical energy and due to heat conduction, both in turbulent flows. After turbulence modeling has been incorporated for the fluctuating parts the overall entropy production can be determined by integration with respect to the whole flow domain. Since, however, entropy production rates show very steep gradients close to the wall, numerical solutions are far more effective with wall functions for the entropy production terms. These wall functions are mandatory when high Reynolds number turbulence models are used. For turbulent flow in a pipe with an inserted twisted tape as heat transfer promoter it is shown that based on the overall entropy production rate a clear statement from a thermodynamic point of view is possible. For a certain range of twist strength there is a decrease in overall entropy production compared to the case without insert. Also, the optimum twist strength can be determined. This information is unavailable when only pressure drop and heat transfer data are given. 展开更多
关键词 entropy production turbulent heat transfer wall functions
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Entropy Production and Admissibility of Shocks
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作者 Tai-Ping Liu Tommaso Ruggeri 《Acta Mathematicae Applicatae Sinica》 SCIE CSCD 2003年第1期1-12,共12页
Abstract In shock wave theory there are two considerations in selecting the physically relevant shock waves. There is the admissibility criterion for the well-posedness of hyperbolic conservation laws. Another conside... Abstract In shock wave theory there are two considerations in selecting the physically relevant shock waves. There is the admissibility criterion for the well-posedness of hyperbolic conservation laws. Another consideration concerns the entropy production across the shocks. The latter is natural from the physical point of view, but is not sufficient in its straightforward formulation, if the system is not genuinely nonlinear. In this paper we propose the principles of increasing entropy production and that of the superposition of shocks. These principles are shown to be equivalent to the admissibility criterion. 展开更多
关键词 entropy production admissibility condition conservation laws shock waves
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Fluctuation theorem for entropy production in a chemical reaction channel
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作者 XIAO TieJun HOU ZhongHuai 《Science China Chemistry》 SCIE EI CAS 2010年第2期396-401,共6页
Fluctuation theorem for entropy production in a mesoscopic chemical reaction network is discussed. When the system size is sufficiently large, it is found that, by defining a kind of coarse-grained dissipation functio... Fluctuation theorem for entropy production in a mesoscopic chemical reaction network is discussed. When the system size is sufficiently large, it is found that, by defining a kind of coarse-grained dissipation function, the entropy production in a reversible reaction channel can be approximately described by a type of detailed fluctuation theorem. Such a fluctuation relation has been successfully tested by direct simulations in a linear reaction model consisting of two reversible channels and in an oscillatory model wherein only one channel is reversible. 展开更多
关键词 nonequilibrium thermodynamics chemical reaction network entropy production fluctuation theorem
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