This paper presents an improved approach based on the equivalent-weights particle filter(EWPF)that uses the proposal density to effectively improve the traditional particle filter.The proposed approach uses historical...This paper presents an improved approach based on the equivalent-weights particle filter(EWPF)that uses the proposal density to effectively improve the traditional particle filter.The proposed approach uses historical data to calculate statistical observations instead of the future observations used in the EWPF’s proposal density and draws on the localization scheme used in the localized PF(LPF)to construct the localized EWPF.The new approach is called the statistical observation localized EWPF(LEWPF-Sobs);it uses statistical observations that are better adapted to the requirements of real-time assimilation and the localization function is used to calculate weights to reduce the effect of missing observations on the weights.This approach not only retains the advantages of the EWPF,but also improves the assimilation quality when using sparse observations.Numerical experiments performed with the Lorenz 96 model show that the statistical observation EWPF is better than the EWPF and EAKF when the model uses standard distribution observations.Comparisons of the statistical observation localized EWPF and LPF reveal the advantages of the new method,with fewer particles giving better results.In particular,the new improved filter performs better than the traditional algorithms when the observation network contains densely spaced measurements associated with model state nonlinearities.展开更多
Noise contours are used to describe the extent of airport noise pollution and to plan land use around airports. The L WECPN(weighted equivalent continuous perceive noise level) recommended by ICAO(International Civ...Noise contours are used to describe the extent of airport noise pollution and to plan land use around airports. The L WECPN(weighted equivalent continuous perceive noise level) recommended by ICAO(International Civil Aviation Organization) is adopted as airport noise rating parameter in this paper. With the help of various mathematical models in the software Surfer, noise contours can be drawn automatically by the completed program in Visual C++ Code. Corrections for thrust, velocity, atmospheric temperature, humidity and lateral ground attenuation are also considered in the new method, which can improve the efficiency of drawing contours. An example of its use for drawing noise contours of an airport in Zhejiang Province of China is proposed and the predictions and the measurements show agreements well.展开更多
To raise the room temperature ionic conductivity and improve the mechanical strength of a PEO-based polymer electrolyte, a noncrystalline two-component epoxy electrolyte system has been prepared. The diglycidyl ether ...To raise the room temperature ionic conductivity and improve the mechanical strength of a PEO-based polymer electrolyte, a noncrystalline two-component epoxy electrolyte system has been prepared. The diglycidyl ether of polyethylene glycols as precursors of the system were synthesized by a two-step process. The presumed structure of the product was characterized, by ^(13)C, ~1H NMR and IR spectroscopy. It was found that a side-reaction occurred between the secondary hydroxyl group of PEG-chlorohydrin and epichlorohydrin in some degree, resulting in a by- product containing—CH_2Cl side group. By selecting a characteristic signal, which is undistorted by the increase in the length of CH_2 CH_2—O segment, a ~1H NMR approach of determining the equivalent epoxy weight (EEW) was proposed. The method is valid to specimens even though the EEW is as high as 2,000. The examination of the specimens by DSC showed that epoxidation greatly depressed the crystallinity of the PEG's, whereas the T_g was raised.展开更多
The intention of this paper is to give direct and converse results on weighted simultaneous approximation by means of Sz(?)sz-Kantorovich operators and Baskakov-Kantorovich operators in L_p-norms using the weighted Di...The intention of this paper is to give direct and converse results on weighted simultaneous approximation by means of Sz(?)sz-Kantorovich operators and Baskakov-Kantorovich operators in L_p-norms using the weighted Ditzian-Totik modulus of smoothness.展开更多
The Gravity Recovery and Climate Experiment(GRACE) mission can significantly improve our knowledge of the temporal variability of the Earth's gravity field.We obtained monthly gravity field solutions based on varia...The Gravity Recovery and Climate Experiment(GRACE) mission can significantly improve our knowledge of the temporal variability of the Earth's gravity field.We obtained monthly gravity field solutions based on variational equations approach from GPS-derived positions of GRACE satellites and K-band range-rate measurements.The impact of different fixed data weighting ratios in temporal gravity field recovery while combining the two types of data was investigated for the purpose of deriving the best combined solution.The monthly gravity field solution obtained through above procedures was named as the Institute of Geodesy and Geophysics(IGG) temporal gravity field models.IGG temporal gravity field models were compared with GRACE Release05(RL05) products in following aspects:(i) the trend of the mass anomaly in China and its nearby regions within 2005-2010; (ii) the root mean squares of the global mass anomaly during 2005-2010; (iii) time-series changes in the mean water storage in the region of the Amazon Basin and the Sahara Desert between 2005 and 2010.The results showed that IGG solutions were almost consistent with GRACE RL05 products in above aspects(i)-(iii).Changes in the annual amplitude of mean water storage in the Amazon Basin were 14.7 ± 1.2 cm for IGG,17.1 ± 1.3 cm for the Centre for Space Research(CSR),16.4 ± 0.9 cm for the GeoForschungsZentrum(GFZ) and 16.9 ± 1.2 cm for the Jet Propulsion Laboratory(JPL) in terms of equivalent water height(EWH),respectively.The root mean squares of the mean mass anomaly in Sahara were 1.2 cm,0.9 cm,0.9 cm and 1.2 cm for temporal gravity field models of IGG,CSR,GFZ and JPL,respectively.Comparison suggested that IGG temporal gravity field solutions were at the same accuracy level with the latest temporal gravity field solutions published by CSR,GFZ and JPL.展开更多
Leveraging the interactions between ionomer and catalyst can increase the performance of proton exchangemembrane fuel cells.The impacts of the equivalent weight(EW)of perfluorosulfonic acid-based ionomers on the plati...Leveraging the interactions between ionomer and catalyst can increase the performance of proton exchangemembrane fuel cells.The impacts of the equivalent weight(EW)of perfluorosulfonic acid-based ionomers on the platinum group metal-free electrode structure and fuel cell performance have not been fully explored.Four membrane electrode assemblies(MEAs)were prepared by using a commercial Fe-N-C catalyst,two perfluorosulfonic acid ionomers with different EWs,that is,Aquivion 720(A720)and Nafion 1100(N1100),and two ionomer-tocatalyst(I/C)ratios.The four MEAswere characterized to understand the impact of the ionomer EW and content on the capacitance,proton conductivity,and mass transport on the cathode.The mass transport resistance was measured for the first time using a new oxygen reduction reaction limiting current method enabling to couple the effects of oxygen diffusion with liquid water generation.Low EW ionomer combined with a moderate I/C results in improved performance due to its enhanced proton conductivity.However,when used at high I/C,it can cause severewater flooding at high current density due to the enhanced liquid water uptake,especially at high relative humidity,resulting in lower catalyst utilization and higher mass transport resistance.展开更多
基金The National Basic Research Program of China under contract Nos 2017YFC1404100,2017YFC1404103 and 2017YFC1404104the National Natural Science Foundation of China under contract No.41676088。
文摘This paper presents an improved approach based on the equivalent-weights particle filter(EWPF)that uses the proposal density to effectively improve the traditional particle filter.The proposed approach uses historical data to calculate statistical observations instead of the future observations used in the EWPF’s proposal density and draws on the localization scheme used in the localized PF(LPF)to construct the localized EWPF.The new approach is called the statistical observation localized EWPF(LEWPF-Sobs);it uses statistical observations that are better adapted to the requirements of real-time assimilation and the localization function is used to calculate weights to reduce the effect of missing observations on the weights.This approach not only retains the advantages of the EWPF,but also improves the assimilation quality when using sparse observations.Numerical experiments performed with the Lorenz 96 model show that the statistical observation EWPF is better than the EWPF and EAKF when the model uses standard distribution observations.Comparisons of the statistical observation localized EWPF and LPF reveal the advantages of the new method,with fewer particles giving better results.In particular,the new improved filter performs better than the traditional algorithms when the observation network contains densely spaced measurements associated with model state nonlinearities.
文摘Noise contours are used to describe the extent of airport noise pollution and to plan land use around airports. The L WECPN(weighted equivalent continuous perceive noise level) recommended by ICAO(International Civil Aviation Organization) is adopted as airport noise rating parameter in this paper. With the help of various mathematical models in the software Surfer, noise contours can be drawn automatically by the completed program in Visual C++ Code. Corrections for thrust, velocity, atmospheric temperature, humidity and lateral ground attenuation are also considered in the new method, which can improve the efficiency of drawing contours. An example of its use for drawing noise contours of an airport in Zhejiang Province of China is proposed and the predictions and the measurements show agreements well.
基金The project supported by National Natural Science Foundation of China.
文摘To raise the room temperature ionic conductivity and improve the mechanical strength of a PEO-based polymer electrolyte, a noncrystalline two-component epoxy electrolyte system has been prepared. The diglycidyl ether of polyethylene glycols as precursors of the system were synthesized by a two-step process. The presumed structure of the product was characterized, by ^(13)C, ~1H NMR and IR spectroscopy. It was found that a side-reaction occurred between the secondary hydroxyl group of PEG-chlorohydrin and epichlorohydrin in some degree, resulting in a by- product containing—CH_2Cl side group. By selecting a characteristic signal, which is undistorted by the increase in the length of CH_2 CH_2—O segment, a ~1H NMR approach of determining the equivalent epoxy weight (EEW) was proposed. The method is valid to specimens even though the EEW is as high as 2,000. The examination of the specimens by DSC showed that epoxidation greatly depressed the crystallinity of the PEG's, whereas the T_g was raised.
基金Supported by the foundation of Zhejiang province
文摘The intention of this paper is to give direct and converse results on weighted simultaneous approximation by means of Sz(?)sz-Kantorovich operators and Baskakov-Kantorovich operators in L_p-norms using the weighted Ditzian-Totik modulus of smoothness.
基金funded by the Major National Scientific Research Plan(2013CB733305,2012CB957703)the National Natural Science Foundation of China(41174066,41131067,41374087,41431070)
文摘The Gravity Recovery and Climate Experiment(GRACE) mission can significantly improve our knowledge of the temporal variability of the Earth's gravity field.We obtained monthly gravity field solutions based on variational equations approach from GPS-derived positions of GRACE satellites and K-band range-rate measurements.The impact of different fixed data weighting ratios in temporal gravity field recovery while combining the two types of data was investigated for the purpose of deriving the best combined solution.The monthly gravity field solution obtained through above procedures was named as the Institute of Geodesy and Geophysics(IGG) temporal gravity field models.IGG temporal gravity field models were compared with GRACE Release05(RL05) products in following aspects:(i) the trend of the mass anomaly in China and its nearby regions within 2005-2010; (ii) the root mean squares of the global mass anomaly during 2005-2010; (iii) time-series changes in the mean water storage in the region of the Amazon Basin and the Sahara Desert between 2005 and 2010.The results showed that IGG solutions were almost consistent with GRACE RL05 products in above aspects(i)-(iii).Changes in the annual amplitude of mean water storage in the Amazon Basin were 14.7 ± 1.2 cm for IGG,17.1 ± 1.3 cm for the Centre for Space Research(CSR),16.4 ± 0.9 cm for the GeoForschungsZentrum(GFZ) and 16.9 ± 1.2 cm for the Jet Propulsion Laboratory(JPL) in terms of equivalent water height(EWH),respectively.The root mean squares of the mean mass anomaly in Sahara were 1.2 cm,0.9 cm,0.9 cm and 1.2 cm for temporal gravity field models of IGG,CSR,GFZ and JPL,respectively.Comparison suggested that IGG temporal gravity field solutions were at the same accuracy level with the latest temporal gravity field solutions published by CSR,GFZ and JPL.
基金National Renewable Energy Laboratory for the U.S.Department of Energy(DOE)under Contract No.DE-AC36-08GO28308Argonne National Laboratory is managed for the U.S.Department of Energy by the University of Chicago Argonne,LLC,also under contract DE-AC-02-06CH11357+1 种基金supported by the U.S.Department of Energy,Office of Energy Efficiency and Renewable Energy,Hydrogen and Fuel Cell Technologies Office(HFTO).This research used resources of the Advanced Photon Source(APS)a U.S.Department of Energy Office of Science User Facility operated for the DOE Office of Science by Argonne National Laboratory under Contract No.DE-AC02-06CH11357.
文摘Leveraging the interactions between ionomer and catalyst can increase the performance of proton exchangemembrane fuel cells.The impacts of the equivalent weight(EW)of perfluorosulfonic acid-based ionomers on the platinum group metal-free electrode structure and fuel cell performance have not been fully explored.Four membrane electrode assemblies(MEAs)were prepared by using a commercial Fe-N-C catalyst,two perfluorosulfonic acid ionomers with different EWs,that is,Aquivion 720(A720)and Nafion 1100(N1100),and two ionomer-tocatalyst(I/C)ratios.The four MEAswere characterized to understand the impact of the ionomer EW and content on the capacitance,proton conductivity,and mass transport on the cathode.The mass transport resistance was measured for the first time using a new oxygen reduction reaction limiting current method enabling to couple the effects of oxygen diffusion with liquid water generation.Low EW ionomer combined with a moderate I/C results in improved performance due to its enhanced proton conductivity.However,when used at high I/C,it can cause severewater flooding at high current density due to the enhanced liquid water uptake,especially at high relative humidity,resulting in lower catalyst utilization and higher mass transport resistance.