A kind of novel experiment was disclosed as it possessed two bands of fluorescence emission at 1.4 and 1.6 μm, which were perfectly complimentary to the current C band of optic communication. The fluorescence was bas...A kind of novel experiment was disclosed as it possessed two bands of fluorescence emission at 1.4 and 1.6 μm, which were perfectly complimentary to the current C band of optic communication. The fluorescence was based on energy transfer and up-conversion processes between Tm^3+ and Yb^3+ under direct pumping of 975 nm LD. The spectra and lifetimes of Tm^3+ fluorescence in the tellurite glass were described. The corresponding fluorescence characteristics and energy migration process were analyzed by the method of lifetime and intensity comparison. The mechanism of the up-conversion based IR fluorescence was presented upon analyzing the multi-photon pumping process. The potential advantages of Tm^3+/Yb^3+ co-doped tellurite glass as amplifier material were concluded.展开更多
The Nd^3+-doped pared. The absorption and tellurite glasses were preemission spectra of Nd^3 +- doped tellurite glasses at room temperature were measured. The Judd-Ofelt parameters (Ω2, Ω4, Ω6) of the glasses w...The Nd^3+-doped pared. The absorption and tellurite glasses were preemission spectra of Nd^3 +- doped tellurite glasses at room temperature were measured. The Judd-Ofelt parameters (Ω2, Ω4, Ω6) of the glasses were calculated from measured absorption spectra. The calculation results of luminescence properties (A, β, τrad, σ) of Nd^3+ ions in the tellurite were glasses were given. Spectroscopic properties, concentration quenching in these kinds of the glasses were investigated. The results indicate that the tellurite glasses with composition of 70% TeO2, 20% ZnO, ( 10 - x ) % La2O3, x % Nd2O3 ( mol% ) show high emission cross section and low phonon energy. The fluorescent intensity and the emission cross section have a maxi- mum value at x = 0.5, namely, the optimum Nd^3 + ion concentration in the tellurite glass is 0.5% (1.93 × 10^20 ions·cm^-3). The fluorescence properties of Nd^3+ measured are basically in accord with the calculated results.展开更多
The Er^3+/Yb^3+ co-doped TeO2-Nb2O5-Li2O glass is prepared by conventional melting method, and its upconversion spectra are measured. The intense green upconversion luminescence upon excitation with a 976 nm laser d...The Er^3+/Yb^3+ co-doped TeO2-Nb2O5-Li2O glass is prepared by conventional melting method, and its upconversion spectra are measured. The intense green upconversion luminescence upon excitation with a 976 nm laser diode is observed with the naked eyes. The dependence of luminescence intensity on the ratio of Yb^3+/Er^3+ is discussed in detail, and the relationship between the ratio of green luminescence intensity to red luminescence intensity and the ratio of Yb^3+/Er^3+ is also studied, The luminescence intensity increases with the ratio of Yb^3+/Er^3+ increasing. The ratio of Yb^3+/Er^3+ plays a more important role than the concentration of Er^3+ in determining the upconversion luminescence intensity. The ratio of green luminescence intensity to red luminescence intensity reaches a maximum when ratio of Yb^3+/Er^3+ is 3. Thus the glass could be one of the potential candidates for LD pumping solid-state lasers.展开更多
A transparent tellufite glass-ceramic containing nanocrystals based on the composition of 15Li2O-15Nb2O5-7OTeO2-0. 1ErEr2O3-0. 4Yb2O3 (mol%)was prepared by using a two-step heat-treatment. The XRD patterns show that...A transparent tellufite glass-ceramic containing nanocrystals based on the composition of 15Li2O-15Nb2O5-7OTeO2-0. 1ErEr2O3-0. 4Yb2O3 (mol%)was prepared by using a two-step heat-treatment. The XRD patterns show that the composition of crystals in glass-ceramics is possibly Yb6Te5O19.2 or Er6Te5O19.2, and the dimension of crystals is about 55 nm. The Judd-Ofeh parameters, Ωt, (t = 2, 4, 6), and the spontaneous emission probability of Er^3+ in glass and glass-ceramics were calculated from optical absorption spectra. The absorption cross section of Er^3 :^4I15/2→I13/2 and the emission cross section of Er^3 + :^4I15/2→I13/2 in two samples were also calculated. Raman scattering spectra of glass and glass-ceramic were measured, the fluorescence spectra and the upconversion spectra of Er^3 + ion in glass and glass-ceramic were compared.展开更多
The Er^(3+)-doped TeO_2-WO_3-ZnO-ZnF_2(TWZOF) glasses were prepared. The absorption spectra, 1.5 μm emission spectra and fluorescence lifetimes of Er^(3+), excited at 970 nm, were measured. The J-O parameters Ω_ t (...The Er^(3+)-doped TeO_2-WO_3-ZnO-ZnF_2(TWZOF) glasses were prepared. The absorption spectra, 1.5 μm emission spectra and fluorescence lifetimes of Er^(3+), excited at 970 nm, were measured. The J-O parameters Ω_ t (t =2, 4, 6), absorption and emission cross-sections were calculated. The dependence of the 1.5 μm emission intensity, fluorescence lifetime and bandwidth of the Er^(3+) emission upon the contents of ZnF_2 in glass were investigated. In TWZOF glass, Er^(3+) ions had a broad emission profile around 1.5 μm with the maximum FWHM of 83 nm. With the increasing of the content of ZnF_2, the emission intensity at peak wavelength and the fluorescence lifetime of Er^(3+) at 1.5 μm increase.展开更多
The energy transfer and upconversion of Er 3+ /Yb 3+ co-doped TeO2-TiO2-K2O glasses upon excitation with 976nm lasers diode were studied. The tellurite glasses were prepared by conventional melting methods. Their op...The energy transfer and upconversion of Er 3+ /Yb 3+ co-doped TeO2-TiO2-K2O glasses upon excitation with 976nm lasers diode were studied. The tellurite glasses were prepared by conventional melting methods. Their optical properties and sensitization upconversion spectra were performed. The dependence of green upconversion luminescence intensity on the mole ratio of Yb 3+ to Er 3+ and Er 3+ concentration were discussed in detail. When the mole ratio of Yb 3+ to Er 3+ is 25/1 and Er 3+ concentration is 0.1% (mole fraction), or when the mole ratio of Yb 3+ to Er 3+ is 10/1 and Er 3+ concentration is 0.15%, the optimal upconversion luminescence intensity is obtained. The obtained glasses can be one of the potential candidates for lasers-diode pumping microchip solid-state lasers.展开更多
Er3+-doped 25BaO-(25-x)SiO2-xAl2O3-25B2O3 transparent glasses are prepared with x = 0,12.5 and 25 by a solid-state reaction.The Er-related NIR luminescence intensity,which corresponds to the transition of 4I15/2-4I13/...Er3+-doped 25BaO-(25-x)SiO2-xAl2O3-25B2O3 transparent glasses are prepared with x = 0,12.5 and 25 by a solid-state reaction.The Er-related NIR luminescence intensity,which corresponds to the transition of 4I15/2-4I13/2,is obviously altered with different silicon/aluminum ratios.The Judd-Ofelt parameters of the Er3+ ions are adopted to explain the intensity change in the NIR fluorescence,and the Raman scattering intensity versus the amount of Al and/or Si components are discussed.The spectra of the three samples are quite similar in the peak positions,but different in intensity.The maximal phonon density of state for the samples is calculated from the Raman spectra and is correlated to the NIR luminescence efficiency.展开更多
Based on the host of tellurite glasses, the glass formation, preform manufacture, and fiber fabrication are described. The characterization of amplified spontaneous emission (ASE) from this newly fabricated single-mod...Based on the host of tellurite glasses, the glass formation, preform manufacture, and fiber fabrication are described. The characterization of amplified spontaneous emission (ASE) from this newly fabricated single-mode Er3+-doped tellurite fibers is also presented. When pumped at 980 nm, a very broad erbium ASE around 1.53 μm was observed. The variations of ASE with fiber length and pumping power are measured and discussed. The output of 2 mW from Er3+-doped tellurite fiber ASE source was obtained under the pump power of 660 mW.展开更多
Fluorescence of Tm^3+/Er^3+ codoped bismuth-silica (BS) glasses and the sensitization of Ce^3+ are investigated, It shows that Ce^3+ codoping with Tm^3+/Er^3+ in BS glasses results in a quenching of Tm^3+ ion...Fluorescence of Tm^3+/Er^3+ codoped bismuth-silica (BS) glasses and the sensitization of Ce^3+ are investigated, It shows that Ce^3+ codoping with Tm^3+/Er^3+ in BS glasses results in a quenching of Tm^3+ ion emission from ^3F4 to the ^3H6 level. Consequently, the 1.47μm emission occurs after the population inversion between the ^3H4 and ^3F4 levels. Furthermore, the codoped glasses show the broad emission spectra over the whole S and C bands with full-width at half-maximum (FWHM) up to about 119nm, as it combines 1.55μm emission band of Er^3+ with 1.47μm emission band of Tm^3+ under 800hm excitation.展开更多
For the Er^3+ /Yb^3+ codoped fluorophosphate glasses, Judd-Ofelt theory is used to analyse the influence of YbF3 as not a sensitizer but an average component on the spectroscopic properties around 1530nm emission. T...For the Er^3+ /Yb^3+ codoped fluorophosphate glasses, Judd-Ofelt theory is used to analyse the influence of YbF3 as not a sensitizer but an average component on the spectroscopic properties around 1530nm emission. The double roles of Yb^3+, as a sensitizer and as an average component, are discussed. It is found that Yb^3+ as an average component contributes to the increase of fluorescence lifetime, and Yb^3+ as a sensitizer has the best sensitization when its concentration is 2.4 mol%.展开更多
基金supported by the Natural Science Foundation of Zhejiang Provience, China (2006C21082)National Natural Science Foundation of China (60677015)+1 种基金Foundation of Ningbo University (XR0710018)sponsored by KC Wong Magna Fund in NingBo University
文摘A kind of novel experiment was disclosed as it possessed two bands of fluorescence emission at 1.4 and 1.6 μm, which were perfectly complimentary to the current C band of optic communication. The fluorescence was based on energy transfer and up-conversion processes between Tm^3+ and Yb^3+ under direct pumping of 975 nm LD. The spectra and lifetimes of Tm^3+ fluorescence in the tellurite glass were described. The corresponding fluorescence characteristics and energy migration process were analyzed by the method of lifetime and intensity comparison. The mechanism of the up-conversion based IR fluorescence was presented upon analyzing the multi-photon pumping process. The potential advantages of Tm^3+/Yb^3+ co-doped tellurite glass as amplifier material were concluded.
文摘The Nd^3+-doped pared. The absorption and tellurite glasses were preemission spectra of Nd^3 +- doped tellurite glasses at room temperature were measured. The Judd-Ofelt parameters (Ω2, Ω4, Ω6) of the glasses were calculated from measured absorption spectra. The calculation results of luminescence properties (A, β, τrad, σ) of Nd^3+ ions in the tellurite were glasses were given. Spectroscopic properties, concentration quenching in these kinds of the glasses were investigated. The results indicate that the tellurite glasses with composition of 70% TeO2, 20% ZnO, ( 10 - x ) % La2O3, x % Nd2O3 ( mol% ) show high emission cross section and low phonon energy. The fluorescent intensity and the emission cross section have a maxi- mum value at x = 0.5, namely, the optimum Nd^3 + ion concentration in the tellurite glass is 0.5% (1.93 × 10^20 ions·cm^-3). The fluorescence properties of Nd^3+ measured are basically in accord with the calculated results.
基金Project supported by the National Natural Science Foundation of China (Grant No 60307004) and the Science and Technology Program of Guangzhou, Guangdong province, China (Grant No 2004Z2-D0131).
文摘The Er^3+/Yb^3+ co-doped TeO2-Nb2O5-Li2O glass is prepared by conventional melting method, and its upconversion spectra are measured. The intense green upconversion luminescence upon excitation with a 976 nm laser diode is observed with the naked eyes. The dependence of luminescence intensity on the ratio of Yb^3+/Er^3+ is discussed in detail, and the relationship between the ratio of green luminescence intensity to red luminescence intensity and the ratio of Yb^3+/Er^3+ is also studied, The luminescence intensity increases with the ratio of Yb^3+/Er^3+ increasing. The ratio of Yb^3+/Er^3+ plays a more important role than the concentration of Er^3+ in determining the upconversion luminescence intensity. The ratio of green luminescence intensity to red luminescence intensity reaches a maximum when ratio of Yb^3+/Er^3+ is 3. Thus the glass could be one of the potential candidates for LD pumping solid-state lasers.
文摘A transparent tellufite glass-ceramic containing nanocrystals based on the composition of 15Li2O-15Nb2O5-7OTeO2-0. 1ErEr2O3-0. 4Yb2O3 (mol%)was prepared by using a two-step heat-treatment. The XRD patterns show that the composition of crystals in glass-ceramics is possibly Yb6Te5O19.2 or Er6Te5O19.2, and the dimension of crystals is about 55 nm. The Judd-Ofeh parameters, Ωt, (t = 2, 4, 6), and the spontaneous emission probability of Er^3+ in glass and glass-ceramics were calculated from optical absorption spectra. The absorption cross section of Er^3 :^4I15/2→I13/2 and the emission cross section of Er^3 + :^4I15/2→I13/2 in two samples were also calculated. Raman scattering spectra of glass and glass-ceramic were measured, the fluorescence spectra and the upconversion spectra of Er^3 + ion in glass and glass-ceramic were compared.
文摘The Er^(3+)-doped TeO_2-WO_3-ZnO-ZnF_2(TWZOF) glasses were prepared. The absorption spectra, 1.5 μm emission spectra and fluorescence lifetimes of Er^(3+), excited at 970 nm, were measured. The J-O parameters Ω_ t (t =2, 4, 6), absorption and emission cross-sections were calculated. The dependence of the 1.5 μm emission intensity, fluorescence lifetime and bandwidth of the Er^(3+) emission upon the contents of ZnF_2 in glass were investigated. In TWZOF glass, Er^(3+) ions had a broad emission profile around 1.5 μm with the maximum FWHM of 83 nm. With the increasing of the content of ZnF_2, the emission intensity at peak wavelength and the fluorescence lifetime of Er^(3+) at 1.5 μm increase.
基金Projects(2004Z2-D0131 and 2004A10602002) supported by the Science and Technology Programof Guangzhou , Guang-dong Province project(60307004 and 50472053) supported by the National Natural Science Foundation of China project(04200036) sup-ported by the Natural Foundation of Guangdong Province
文摘The energy transfer and upconversion of Er 3+ /Yb 3+ co-doped TeO2-TiO2-K2O glasses upon excitation with 976nm lasers diode were studied. The tellurite glasses were prepared by conventional melting methods. Their optical properties and sensitization upconversion spectra were performed. The dependence of green upconversion luminescence intensity on the mole ratio of Yb 3+ to Er 3+ and Er 3+ concentration were discussed in detail. When the mole ratio of Yb 3+ to Er 3+ is 25/1 and Er 3+ concentration is 0.1% (mole fraction), or when the mole ratio of Yb 3+ to Er 3+ is 10/1 and Er 3+ concentration is 0.15%, the optimal upconversion luminescence intensity is obtained. The obtained glasses can be one of the potential candidates for lasers-diode pumping microchip solid-state lasers.
基金Project supported by the Natural Science Foundation of Tianjin (Grant Nos. 09JCYBJC01400 and 11JCYBJC00300)the Natural Science Foundation of the Tianjin Education Committee (Grant No. 20071207)Tianjin Key Subject for Materials Physics and Chemistry
文摘Er3+-doped 25BaO-(25-x)SiO2-xAl2O3-25B2O3 transparent glasses are prepared with x = 0,12.5 and 25 by a solid-state reaction.The Er-related NIR luminescence intensity,which corresponds to the transition of 4I15/2-4I13/2,is obviously altered with different silicon/aluminum ratios.The Judd-Ofelt parameters of the Er3+ ions are adopted to explain the intensity change in the NIR fluorescence,and the Raman scattering intensity versus the amount of Al and/or Si components are discussed.The spectra of the three samples are quite similar in the peak positions,but different in intensity.The maximal phonon density of state for the samples is calculated from the Raman spectra and is correlated to the NIR luminescence efficiency.
基金The authors are grateful to the Rising-star Project of Shanghai Municipal Science and Technology Commission(No.04QMX1448)the Project of Optical Science and Technology of Shanghai(No.022261046)the National Natural Science Foundation of China(No.60207006)for the support of this project.
文摘Based on the host of tellurite glasses, the glass formation, preform manufacture, and fiber fabrication are described. The characterization of amplified spontaneous emission (ASE) from this newly fabricated single-mode Er3+-doped tellurite fibers is also presented. When pumped at 980 nm, a very broad erbium ASE around 1.53 μm was observed. The variations of ASE with fiber length and pumping power are measured and discussed. The output of 2 mW from Er3+-doped tellurite fiber ASE source was obtained under the pump power of 660 mW.
基金Supported by the Natural Science Foundation of Zhejiang Province under Grant No Y104498, the Science and Technology Department of Zhejiang Province under Grant Nos 2005C31014 and 2006C21082.
文摘Fluorescence of Tm^3+/Er^3+ codoped bismuth-silica (BS) glasses and the sensitization of Ce^3+ are investigated, It shows that Ce^3+ codoping with Tm^3+/Er^3+ in BS glasses results in a quenching of Tm^3+ ion emission from ^3F4 to the ^3H6 level. Consequently, the 1.47μm emission occurs after the population inversion between the ^3H4 and ^3F4 levels. Furthermore, the codoped glasses show the broad emission spectra over the whole S and C bands with full-width at half-maximum (FWHM) up to about 119nm, as it combines 1.55μm emission band of Er^3+ with 1.47μm emission band of Tm^3+ under 800hm excitation.
基金Supported by the National Natural Science Foundation of China under Grant Nos 50502030 and 60508014.
文摘For the Er^3+ /Yb^3+ codoped fluorophosphate glasses, Judd-Ofelt theory is used to analyse the influence of YbF3 as not a sensitizer but an average component on the spectroscopic properties around 1530nm emission. The double roles of Yb^3+, as a sensitizer and as an average component, are discussed. It is found that Yb^3+ as an average component contributes to the increase of fluorescence lifetime, and Yb^3+ as a sensitizer has the best sensitization when its concentration is 2.4 mol%.