yb^3+:Er^3+ co-doped oxy-fluoride ceramics glass has been prepared. The mechanism of up-conversion emissions about Er^3+ was discussed, and the temperature properties of green up-conversion fluorescence between 30...yb^3+:Er^3+ co-doped oxy-fluoride ceramics glass has been prepared. The mechanism of up-conversion emissions about Er^3+ was discussed, and the temperature properties of green up-conversion fluorescence between 303 and 823 K were investigated. The results show that the sensitivity of this sample reaches its maximum value, about 0.0047 K^-1, when the temperature is 383 K, indicating that this kind of sample can be used as high temperature and high sensitivity optical temperature sensor.展开更多
Er^3 +/Yb^3 + phosphate glasses were fabricated. According to McCumber theory, the stimulated emission cross-section of Er^3+ ions at 1533 nm was calculated on the basis of absorption spectrum, and 0.84 × 10^-...Er^3 +/Yb^3 + phosphate glasses were fabricated. According to McCumber theory, the stimulated emission cross-section of Er^3+ ions at 1533 nm was calculated on the basis of absorption spectrum, and 0.84 × 10^-20 cm^2 is derived, the fluorescence lifetime of ^4I13/2 level is 8.5 ms. An Er^3+/Yb^3+ co-doped phosphate glass CW laser pumped by LD was demonstrated at room temperature. The maximum output power is 80 mW and slope efficiency is 16.5%.展开更多
The Er^3+/yb^3+ co-doped transparent oxyfluoride glass-ceramics containing CaF2 nano-crystals were successfully prepared. After heat treatments, transmission electron microscopy (TEM) images showed that CaF2 nano-...The Er^3+/yb^3+ co-doped transparent oxyfluoride glass-ceramics containing CaF2 nano-crystals were successfully prepared. After heat treatments, transmission electron microscopy (TEM) images showed that CaF2 nano-crystals of 20-30 nm in diameter precipitated uniformly in the glass matrix. luminescence of Er^3+ at 540 nm and 658 nm was observed in Comparing with the host glass, high efficiency upconversion the glass ceramics under the excitation of 980 nm. Moreover, the size of the precipitated nano-crystals can be controlled by heat-treatment temperature and time. With the increase of the nano-crystal size, the intensity of the red emission increased more rapidly than that of the green emission. The energy transfer process of Er^3+ and Yb^3+ was convinced and the possible mechanism of Er^3+ up-conversion was discussed.展开更多
Yb^3+:Er^3+:Tm^3+co-doped borosilicate glasses are prepared. Their strong up-conversion photoluminescence spectra in a range from ultra-violet to near-infrared, which are excited by a 978-nm laser diode, are meas...Yb^3+:Er^3+:Tm^3+co-doped borosilicate glasses are prepared. Their strong up-conversion photoluminescence spectra in a range from ultra-violet to near-infrared, which are excited by a 978-nm laser diode, are measured, and the mechanisms of energy transfer among Yb^3+ Er^3+ and Tm^3+ ions are discussed. The results show that there is an unexpected wavelength at 900-nm emission from Yb^3+ Stark splitting levels to pump Tm^3+ ions and there exists an optimum pump power. The concentration of the Tm^3+ dopant gives rise to a prominent effect on the intensity of visible and near-infrared emissions for the yb^3+:Er^3+:Tm^3+ co-doped borosilicate glasses.展开更多
The Er3+/yb3+ co-doped phosphate (EYDP) glass waveguides operated at 1539 nm have been manufactured by using the implantation technique of carbon ions under the condition of 6.0 MeV energy and 5.0 × 10^13 ion...The Er3+/yb3+ co-doped phosphate (EYDP) glass waveguides operated at 1539 nm have been manufactured by using the implantation technique of carbon ions under the condition of 6.0 MeV energy and 5.0 × 10^13 ions/cm2 fluence in this work. The ion implantation process was computed by means of the stopping and range of ions in matter. The dark-mode spectrum at 1539 nm of the waveguide was recorded by the method of the prism coupling measurement. The microscopic image of the fabricated structure was photographed by an optical microscope. It is the first step for the application of the waveguides on the base of EYDP glasses in optical- integrated photonic devices at near-infrared band.展开更多
基金Project supported by the National Natural Science Foundation of China (Grant No. 10804015 )the Science Foundation of the Education Department of Liaoning Province of China (Grant No. 2009A417)
文摘yb^3+:Er^3+ co-doped oxy-fluoride ceramics glass has been prepared. The mechanism of up-conversion emissions about Er^3+ was discussed, and the temperature properties of green up-conversion fluorescence between 303 and 823 K were investigated. The results show that the sensitivity of this sample reaches its maximum value, about 0.0047 K^-1, when the temperature is 383 K, indicating that this kind of sample can be used as high temperature and high sensitivity optical temperature sensor.
文摘Er^3 +/Yb^3 + phosphate glasses were fabricated. According to McCumber theory, the stimulated emission cross-section of Er^3+ ions at 1533 nm was calculated on the basis of absorption spectrum, and 0.84 × 10^-20 cm^2 is derived, the fluorescence lifetime of ^4I13/2 level is 8.5 ms. An Er^3+/Yb^3+ co-doped phosphate glass CW laser pumped by LD was demonstrated at room temperature. The maximum output power is 80 mW and slope efficiency is 16.5%.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.61265004,51272097,and 11204113)the Nature and Science Fund from Yunnan Province Ministry of Education,China(Grant No.2011C13211708)
文摘The Er^3+/yb^3+ co-doped transparent oxyfluoride glass-ceramics containing CaF2 nano-crystals were successfully prepared. After heat treatments, transmission electron microscopy (TEM) images showed that CaF2 nano-crystals of 20-30 nm in diameter precipitated uniformly in the glass matrix. luminescence of Er^3+ at 540 nm and 658 nm was observed in Comparing with the host glass, high efficiency upconversion the glass ceramics under the excitation of 980 nm. Moreover, the size of the precipitated nano-crystals can be controlled by heat-treatment temperature and time. With the increase of the nano-crystal size, the intensity of the red emission increased more rapidly than that of the green emission. The energy transfer process of Er^3+ and Yb^3+ was convinced and the possible mechanism of Er^3+ up-conversion was discussed.
基金Project supported by the National Natural Science Foundation of China (Grant No. 10804015)the Science Foundation of the Education Department of Liaoning Province of China (Grant No. 2009A417)
文摘Yb^3+:Er^3+:Tm^3+co-doped borosilicate glasses are prepared. Their strong up-conversion photoluminescence spectra in a range from ultra-violet to near-infrared, which are excited by a 978-nm laser diode, are measured, and the mechanisms of energy transfer among Yb^3+ Er^3+ and Tm^3+ ions are discussed. The results show that there is an unexpected wavelength at 900-nm emission from Yb^3+ Stark splitting levels to pump Tm^3+ ions and there exists an optimum pump power. The concentration of the Tm^3+ dopant gives rise to a prominent effect on the intensity of visible and near-infrared emissions for the yb^3+:Er^3+:Tm^3+ co-doped borosilicate glasses.
文摘The Er3+/yb3+ co-doped phosphate (EYDP) glass waveguides operated at 1539 nm have been manufactured by using the implantation technique of carbon ions under the condition of 6.0 MeV energy and 5.0 × 10^13 ions/cm2 fluence in this work. The ion implantation process was computed by means of the stopping and range of ions in matter. The dark-mode spectrum at 1539 nm of the waveguide was recorded by the method of the prism coupling measurement. The microscopic image of the fabricated structure was photographed by an optical microscope. It is the first step for the application of the waveguides on the base of EYDP glasses in optical- integrated photonic devices at near-infrared band.