Nitrogen-14(^(14)N)overtone(OT)spectroscopy under fast magic angle spinning(MAS)conditions(>60 kHz)has emerged as a powerful technique for observing correlations and distances between ^(14)N and ^(1)H,owing to the ...Nitrogen-14(^(14)N)overtone(OT)spectroscopy under fast magic angle spinning(MAS)conditions(>60 kHz)has emerged as a powerful technique for observing correlations and distances between ^(14)N and ^(1)H,owing to the absence of the first-order quadrupolar broadenings.In addition,^(14)N^(OT) allows selective manipulation of ^(14)N nuclei for each site.Despite extensive theoretical and experimental studies,the spin dynamics of ^(14)N^(OT) remains under debate.In this study,we conducted experimental investigations to assess the spin dynamics of ^(14)N^(OT) using the rotational-echo saturation-pulse double-resonance(RESPDOR)sequence,which monitors population transfer induced by a^(14)N^(OT) pulse.The ^(14)N^(OT) spin dynamics is well represented by a model of a two-energy-level system.Unlike spin-1/2,the maximum excitation efficiency of ^(14)N^(OT) coherences of powdered solids,denoted by p,depends on the radiofrequency field(rf-field)strength due to orientation dependence of effective nutation fields even when pulse lengths are optimized.It is also found that the p factor,contributing to the ^(14)N^(OT) spin dynamics,is nearly independent of the B0 field.Consequently,the filtering efficiency of RESPDOR experiments exhibits negligible dependence on B0 when the ^(14)N^(OT) pulse length is optimized.The study also identifies the optimal experimental conditions for ^(14)N^(OT)/^(1)H RESPDOR correlation experiments.展开更多
During the period from October 2014 to March 2015, a total number of 82 seismic tremors and 66 ice-quakes were identified in both three-component short-period seismographs (HES) and broadband seismographs (STS-1) at S...During the period from October 2014 to March 2015, a total number of 82 seismic tremors and 66 ice-quakes were identified in both three-component short-period seismographs (HES) and broadband seismographs (STS-1) at Syowa Station (SYO), Antarctica. Statistics of the number of these tremors indicated that many tremors were likely to occur when large increases in temperature and/or wind speed during the period. This implied that the rapid increase in temperature enhanced a melting speed of cryosphere environment with generating seismic energy;the tremors were also excited by stormy conditions, associated with interactive resonance between sea-ices and oceanic swells. The characteristic tremors of harmonic overtones with strong amplitudes were explained by repetitive sources, suggesting inter-glacial asperities such as the collision of icebergs and fast sea-ice, calving of glaciers/ice-streams at the coastal environment of Antarctica. These high amplitude tremors occurred independently from other majority types of events, characterized by non-linear, small amplitude and weak signals at the stormy condition and rapid increase in temperature.展开更多
In the present paper are reported the OH…O out-of-plane bending band[γ(OH)] between 900—950 cm -1 of dimethylol propionic acid(DMPA), its dependence upon temperature and its overtone band investigated via FTIR s...In the present paper are reported the OH…O out-of-plane bending band[γ(OH)] between 900—950 cm -1 of dimethylol propionic acid(DMPA), its dependence upon temperature and its overtone band investigated via FTIR spectroscopy. It has been found based on the crystal structure that the band [γ(OH)] may not certainly be the characteristic band of carboxylic dimers, it can also result from another H-bond formed between carboxylic carbonyl and the primary hydroxyl. In addition, the band [γ(OH)] is very sensitive to temperature change but its overtone band can only appear at a low temperature.展开更多
A cavity ring-down spectrometer （CRDS） is constructed with a single-mode continuous-wave Ti：Sapphire laser. It allows attaining a minimum detectable absorption of 1.8× 10^-10cm^-1. The spectrometer is applied ...A cavity ring-down spectrometer （CRDS） is constructed with a single-mode continuous-wave Ti：Sapphire laser. It allows attaining a minimum detectable absorption of 1.8× 10^-10cm^-1. The spectrometer is applied to record the overtone spectrum of ^12C2H2 in the 12240- 12350 cm-1. Compared with the previous CRDS and intra-cavity laser absorption spectroscopy studies in the same region, the present measurement achieved better sensitivity and better precision as well. As a result, the ro-vibrational parameters of the high overtone bands of acetylene at 12290.12, 12311.82, and 12350.61 cm^-1 have been refined. The advantages of the present CRD spectrometer is also demonstrated by the newly observed and well characterized perturbation on the f component of the very weak band near 12289 cm^-1. The quantitative measurement capability of the spectrometer is verified with the measurement of the water lines and employed to give the absolute band intensities of those three acetylene bands.展开更多
Since 1949, modern Chinese language has, in the course o f its development in China's Mainland, twice witnessed large-scale transfers in its word emotive overtones. The first began in 1949 and went on all the way ...Since 1949, modern Chinese language has, in the course o f its development in China's Mainland, twice witnessed large-scale transfers in its word emotive overtones. The first began in 1949 and went on all the way till the end o f the Cultural Revolution in 1977. Derogation manifested itself in that period, during which the derogatory words enjoyed their greatest number, widest usages and highest frequency in the history o f the Chinese language. The second began from the Reform and Opening Up Policy in 1978 and lasted untill now. De-derogation has manifested itself in this period, during which the derogatory words have had the smallest number, least usages and lowest frequency in the history o f the Chinese language. The two large-scale transfers result from their specific social backgrounds and the development o f the Chinese language itself.展开更多
文摘Nitrogen-14(^(14)N)overtone(OT)spectroscopy under fast magic angle spinning(MAS)conditions(>60 kHz)has emerged as a powerful technique for observing correlations and distances between ^(14)N and ^(1)H,owing to the absence of the first-order quadrupolar broadenings.In addition,^(14)N^(OT) allows selective manipulation of ^(14)N nuclei for each site.Despite extensive theoretical and experimental studies,the spin dynamics of ^(14)N^(OT) remains under debate.In this study,we conducted experimental investigations to assess the spin dynamics of ^(14)N^(OT) using the rotational-echo saturation-pulse double-resonance(RESPDOR)sequence,which monitors population transfer induced by a^(14)N^(OT) pulse.The ^(14)N^(OT) spin dynamics is well represented by a model of a two-energy-level system.Unlike spin-1/2,the maximum excitation efficiency of ^(14)N^(OT) coherences of powdered solids,denoted by p,depends on the radiofrequency field(rf-field)strength due to orientation dependence of effective nutation fields even when pulse lengths are optimized.It is also found that the p factor,contributing to the ^(14)N^(OT) spin dynamics,is nearly independent of the B0 field.Consequently,the filtering efficiency of RESPDOR experiments exhibits negligible dependence on B0 when the ^(14)N^(OT) pulse length is optimized.The study also identifies the optimal experimental conditions for ^(14)N^(OT)/^(1)H RESPDOR correlation experiments.
文摘During the period from October 2014 to March 2015, a total number of 82 seismic tremors and 66 ice-quakes were identified in both three-component short-period seismographs (HES) and broadband seismographs (STS-1) at Syowa Station (SYO), Antarctica. Statistics of the number of these tremors indicated that many tremors were likely to occur when large increases in temperature and/or wind speed during the period. This implied that the rapid increase in temperature enhanced a melting speed of cryosphere environment with generating seismic energy;the tremors were also excited by stormy conditions, associated with interactive resonance between sea-ices and oceanic swells. The characteristic tremors of harmonic overtones with strong amplitudes were explained by repetitive sources, suggesting inter-glacial asperities such as the collision of icebergs and fast sea-ice, calving of glaciers/ice-streams at the coastal environment of Antarctica. These high amplitude tremors occurred independently from other majority types of events, characterized by non-linear, small amplitude and weak signals at the stormy condition and rapid increase in temperature.
文摘In the present paper are reported the OH…O out-of-plane bending band[γ(OH)] between 900—950 cm -1 of dimethylol propionic acid(DMPA), its dependence upon temperature and its overtone band investigated via FTIR spectroscopy. It has been found based on the crystal structure that the band [γ(OH)] may not certainly be the characteristic band of carboxylic dimers, it can also result from another H-bond formed between carboxylic carbonyl and the primary hydroxyl. In addition, the band [γ(OH)] is very sensitive to temperature change but its overtone band can only appear at a low temperature.
基金V. ACKNOWLEDGMENTS We are indebted to D. Romanini and S. Kassi for helpful discussion. This work was supported by the National Natural Science Foundation of China （No.20903085 and No.20533060）, Chinese Ministry of Science and Technology （No.2006CB922001 and No.2007CB815203）, and the Fok Ying Tong Education Foundation （No. 101013）.
文摘A cavity ring-down spectrometer （CRDS） is constructed with a single-mode continuous-wave Ti：Sapphire laser. It allows attaining a minimum detectable absorption of 1.8× 10^-10cm^-1. The spectrometer is applied to record the overtone spectrum of ^12C2H2 in the 12240- 12350 cm-1. Compared with the previous CRDS and intra-cavity laser absorption spectroscopy studies in the same region, the present measurement achieved better sensitivity and better precision as well. As a result, the ro-vibrational parameters of the high overtone bands of acetylene at 12290.12, 12311.82, and 12350.61 cm^-1 have been refined. The advantages of the present CRD spectrometer is also demonstrated by the newly observed and well characterized perturbation on the f component of the very weak band near 12289 cm^-1. The quantitative measurement capability of the spectrometer is verified with the measurement of the water lines and employed to give the absolute band intensities of those three acetylene bands.
文摘Since 1949, modern Chinese language has, in the course o f its development in China's Mainland, twice witnessed large-scale transfers in its word emotive overtones. The first began in 1949 and went on all the way till the end o f the Cultural Revolution in 1977. Derogation manifested itself in that period, during which the derogatory words enjoyed their greatest number, widest usages and highest frequency in the history o f the Chinese language. The second began from the Reform and Opening Up Policy in 1978 and lasted untill now. De-derogation has manifested itself in this period, during which the derogatory words have had the smallest number, least usages and lowest frequency in the history o f the Chinese language. The two large-scale transfers result from their specific social backgrounds and the development o f the Chinese language itself.
