Hydroisomerization catalysts Pt/ZSM-22, Pt/ZSM-23, and Pt/ZSM-22/ZSM-23 were prepared by supporting Pt on ZSM-22, ZSM-23, and intergrowth zeolite ZSM-22/ZSM-23, respectively. The typical physicochemical properties of ...Hydroisomerization catalysts Pt/ZSM-22, Pt/ZSM-23, and Pt/ZSM-22/ZSM-23 were prepared by supporting Pt on ZSM-22, ZSM-23, and intergrowth zeolite ZSM-22/ZSM-23, respectively. The typical physicochemical properties of these catalysts were characterized by X-Ray Diffraction (XRD), N2 absorption-desorption, Pyridine-Fourier Transform Infrared (Py-FTIR), Transmission Electron Microscopy (TEM), X-Ray Fluorescence (XRF), Scanning Electron Microscopy (SEM) and NH3- Temperature Programmed Desorption (NH3-TPD), and the performance of these catalysts in n-dodecane hydroisomerization was evaluated in a continuous down-flow fixed bed with a stainless steel tubular reactor. The characterization results indicated that the intergrowth zeolite ZSM-22/ZSM-23 possessed the dual structure of ZSM-22 and ZSM-23, and the catalyst Pt/ZSM-22/ZSM-23 had similar pores and weak acidity to Pt/ZSM-22 and Pt/ZSM-23 catalysts. Moreover, Pt/ZSM-22/ZSM-23 catalyst showed a high selectivity in hydroisomerization of long chain n-alkanes to mono-branched isomers. The evaluation results for n-dodecane hydroisomerization indicated that the activity of Pt/ZSM-22/ZSM-23 was the lowest, while the hydroisomerization selectivity was the highest among the three catalysts. The maximum yield of i-dodecane product was 68.3% over Pt/ZSM-22/ZSM-23 at 320 ℃.展开更多
By calculation of thermodynamics,analysis of crystal structure and study of TEM and eletron probe,it is first discovered that SiO2 can be acted as one of the heterogeneous nu- clei for lamellar intergorowth eutectic(a...By calculation of thermodynamics,analysis of crystal structure and study of TEM and eletron probe,it is first discovered that SiO2 can be acted as one of the heterogeneous nu- clei for lamellar intergorowth eutectic(austenite and cementite)crystallizing in modified as-cast medium manganese steel.展开更多
Ore textures and electron microprobe analyses show that in addition to highly scattered blebs in sphalerite grains, intergrown chalcopyrite also occurs as reds, myrrmekites andlamellae aligned along cleavages and twin...Ore textures and electron microprobe analyses show that in addition to highly scattered blebs in sphalerite grains, intergrown chalcopyrite also occurs as reds, myrrmekites andlamellae aligned along cleavages and twin boundaries of the host sphalerite. The majority of theintergrowths could have been formed by replacement of sphalerite by chalcopyrite, albeit part ofthem may have resulted from exsolution. Not only copper, but also iron were introduced intothe sphalerite by replacive fluids.While the front of the replacing fluid was moving forward through a sulphide orebody, Znand Pb were dissolved and Cu was precipitated, resulting in zonal refining of the sulphide ores.The remobilized zinc and lead were precipitated at favourable sites with changed physiccrchemical conditions. This is a Possible mechanism for the formation of copper-poor zinc and lead oresabove or lateral to the copper orebodies in some of the massive sulphide deceits reworked andoverprinted by late-stage granites and their hydrothermal fluids.展开更多
Jiangjia Ravine is a world-famous debris flow valley in Dongchuan,Yunnan Province,China.Every year large numbers of landslides and collapses happened and caused enormous damages to people's properties and lives.Wi...Jiangjia Ravine is a world-famous debris flow valley in Dongchuan,Yunnan Province,China.Every year large numbers of landslides and collapses happened and caused enormous damages to people's properties and lives.With longtime observation and testing in Jiangjia Ravine we had found out one kind of special landslide which had the characteristics of landslide and collapse.Landslide and collapse supplied sufficient materials for debris flow.When a debris flow broke out,some kind of intergrowth existed among rainfall,landslide and debris flow.In order to study the intergrowth and some key parameters,we carried out artificial rainfall landslide tests and model experiments to observe the phenomena such as collapse,surface slide and surface flow.By observing the experimental phenomena and monitoring water contents,the transformation process among landslide deposits and debris flow under the condition of rainfall had been analyzed.Research results revealed the relationship of this kind of intergrowth among rainfall,landslide and debris flow in Jiangjia Ravine.Meanwhile,it was found that this kind of intergrowth relationship existed only when the moisture content was in a certain range.That is,the critical state seemed to be existed in the transformation process.展开更多
The microstructural characteristics of syntactic polycrystal in the calcium rare earth fluorocarbonate minerals from Southwest China have been studied by means of selected area electron diffraction and high resolutio...The microstructural characteristics of syntactic polycrystal in the calcium rare earth fluorocarbonate minerals from Southwest China have been studied by means of selected area electron diffraction and high resolution electron microscopy(HREM). The complication of the heterogeneous fabric of the minerals have been revealed by HREM. The results show that the crystal structure of the minerals was formed by a disorder stacking of the unit layers of bast naesite and synchisite in the calcium rare earth fluorocarbonate minerals along c direction. The stacking fault and other crystal defects in the syntactic polycrystal have been discussed.展开更多
The integrated planting and breeding of paddy fields is a kind of eco-planting and breeding mode which makes rice and aquatic animals benefit from each other,greatly reducing the harm of rice pests and diseases,using ...The integrated planting and breeding of paddy fields is a kind of eco-planting and breeding mode which makes rice and aquatic animals benefit from each other,greatly reducing the harm of rice pests and diseases,using less or even no fertilizers or pesticides,greatly reducing the agricultural non-point source pollution,thus achieving the " multiple use of water,multiple harvests in one field,grain and fishing winwin,ecological and high efficient use. " In this paper,the high yield and efficient cultivation techniques of rice under the rice-fish intergrowth model in Chengdu was introduced from the aspects of selecting good paddy fields for fishing,using appropriate rice varieties,soaking disinfection,timely sowing and nurturing strong seedlings,reasonable close planting,reasonable fertilization,scientific water management,scientific pest control and rice harvests.展开更多
Dong Zhongshu reordered the Five Elements,that is,wood,fire,soil,gold,and water,and believed that this was the order given by heaven and could not be changed.The Five Elements are related to each other.The relationshi...Dong Zhongshu reordered the Five Elements,that is,wood,fire,soil,gold,and water,and believed that this was the order given by heaven and could not be changed.The Five Elements are related to each other.The relationship between the two adjacent to each other is the relationship of generation and father-son;the relationship between the two separated is reciprocal.The soil is in the middle,and the soil has the noblest morality.Therefore,Dong Zhongshu’s view of“Filial piety is natural”originates from the father-son relationship between the Five Elements and the nobility of soil virtue.According to the Five Elements,the state management should set up five kinds of official posts in order to achieve the purpose of interdependence,mutual restriction,balance,and promotion.Dong Zhongshu matched the Five Elements with the four seasons,and believed that each of the Five Elements had its own virtues,and thus extended it to the virtues of the monarch.Dong Zhongshu linked the Five Elements with the five things,thinking that the five things of the king will affect the Five Elements;the five things are appearance,speech,sight,listening,thinking,which is given by heaven.To govern the country and the people the king must have five important cultivations.展开更多
基金the financial supports form Petrochina(050508-04-02)the National Natural Science Foundation of China(No.21073235,and 20833011)
文摘Hydroisomerization catalysts Pt/ZSM-22, Pt/ZSM-23, and Pt/ZSM-22/ZSM-23 were prepared by supporting Pt on ZSM-22, ZSM-23, and intergrowth zeolite ZSM-22/ZSM-23, respectively. The typical physicochemical properties of these catalysts were characterized by X-Ray Diffraction (XRD), N2 absorption-desorption, Pyridine-Fourier Transform Infrared (Py-FTIR), Transmission Electron Microscopy (TEM), X-Ray Fluorescence (XRF), Scanning Electron Microscopy (SEM) and NH3- Temperature Programmed Desorption (NH3-TPD), and the performance of these catalysts in n-dodecane hydroisomerization was evaluated in a continuous down-flow fixed bed with a stainless steel tubular reactor. The characterization results indicated that the intergrowth zeolite ZSM-22/ZSM-23 possessed the dual structure of ZSM-22 and ZSM-23, and the catalyst Pt/ZSM-22/ZSM-23 had similar pores and weak acidity to Pt/ZSM-22 and Pt/ZSM-23 catalysts. Moreover, Pt/ZSM-22/ZSM-23 catalyst showed a high selectivity in hydroisomerization of long chain n-alkanes to mono-branched isomers. The evaluation results for n-dodecane hydroisomerization indicated that the activity of Pt/ZSM-22/ZSM-23 was the lowest, while the hydroisomerization selectivity was the highest among the three catalysts. The maximum yield of i-dodecane product was 68.3% over Pt/ZSM-22/ZSM-23 at 320 ℃.
基金The projected was supported by National Natural Science Foundation of China
文摘By calculation of thermodynamics,analysis of crystal structure and study of TEM and eletron probe,it is first discovered that SiO2 can be acted as one of the heterogeneous nu- clei for lamellar intergorowth eutectic(austenite and cementite)crystallizing in modified as-cast medium manganese steel.
文摘Ore textures and electron microprobe analyses show that in addition to highly scattered blebs in sphalerite grains, intergrown chalcopyrite also occurs as reds, myrrmekites andlamellae aligned along cleavages and twin boundaries of the host sphalerite. The majority of theintergrowths could have been formed by replacement of sphalerite by chalcopyrite, albeit part ofthem may have resulted from exsolution. Not only copper, but also iron were introduced intothe sphalerite by replacive fluids.While the front of the replacing fluid was moving forward through a sulphide orebody, Znand Pb were dissolved and Cu was precipitated, resulting in zonal refining of the sulphide ores.The remobilized zinc and lead were precipitated at favourable sites with changed physiccrchemical conditions. This is a Possible mechanism for the formation of copper-poor zinc and lead oresabove or lateral to the copper orebodies in some of the massive sulphide deceits reworked andoverprinted by late-stage granites and their hydrothermal fluids.
基金financially supported by the National Natural Science Foundation of China(Grant No.50709035,40672193)the Youth Science and Technology Dawn Plan of Wuhan,China(Grant No.20065004116-42)
文摘Jiangjia Ravine is a world-famous debris flow valley in Dongchuan,Yunnan Province,China.Every year large numbers of landslides and collapses happened and caused enormous damages to people's properties and lives.With longtime observation and testing in Jiangjia Ravine we had found out one kind of special landslide which had the characteristics of landslide and collapse.Landslide and collapse supplied sufficient materials for debris flow.When a debris flow broke out,some kind of intergrowth existed among rainfall,landslide and debris flow.In order to study the intergrowth and some key parameters,we carried out artificial rainfall landslide tests and model experiments to observe the phenomena such as collapse,surface slide and surface flow.By observing the experimental phenomena and monitoring water contents,the transformation process among landslide deposits and debris flow under the condition of rainfall had been analyzed.Research results revealed the relationship of this kind of intergrowth among rainfall,landslide and debris flow in Jiangjia Ravine.Meanwhile,it was found that this kind of intergrowth relationship existed only when the moisture content was in a certain range.That is,the critical state seemed to be existed in the transformation process.
文摘The microstructural characteristics of syntactic polycrystal in the calcium rare earth fluorocarbonate minerals from Southwest China have been studied by means of selected area electron diffraction and high resolution electron microscopy(HREM). The complication of the heterogeneous fabric of the minerals have been revealed by HREM. The results show that the crystal structure of the minerals was formed by a disorder stacking of the unit layers of bast naesite and synchisite in the calcium rare earth fluorocarbonate minerals along c direction. The stacking fault and other crystal defects in the syntactic polycrystal have been discussed.
文摘The integrated planting and breeding of paddy fields is a kind of eco-planting and breeding mode which makes rice and aquatic animals benefit from each other,greatly reducing the harm of rice pests and diseases,using less or even no fertilizers or pesticides,greatly reducing the agricultural non-point source pollution,thus achieving the " multiple use of water,multiple harvests in one field,grain and fishing winwin,ecological and high efficient use. " In this paper,the high yield and efficient cultivation techniques of rice under the rice-fish intergrowth model in Chengdu was introduced from the aspects of selecting good paddy fields for fishing,using appropriate rice varieties,soaking disinfection,timely sowing and nurturing strong seedlings,reasonable close planting,reasonable fertilization,scientific water management,scientific pest control and rice harvests.
基金STS Regional key projects of CAS(KFJ-STS-QYZD-2-21-06-002)Qinghai province science and technology department Key R&D and transformation plan(2021-GX-C04).
基金Great Research Project of Humanities and Social Sciences of Hebei Provincial Department of Education(ZD202125)Project commissioned by Dong Zhongshu and Traditional Culture Research Center in Hebei Province(JDA2302).
文摘Dong Zhongshu reordered the Five Elements,that is,wood,fire,soil,gold,and water,and believed that this was the order given by heaven and could not be changed.The Five Elements are related to each other.The relationship between the two adjacent to each other is the relationship of generation and father-son;the relationship between the two separated is reciprocal.The soil is in the middle,and the soil has the noblest morality.Therefore,Dong Zhongshu’s view of“Filial piety is natural”originates from the father-son relationship between the Five Elements and the nobility of soil virtue.According to the Five Elements,the state management should set up five kinds of official posts in order to achieve the purpose of interdependence,mutual restriction,balance,and promotion.Dong Zhongshu matched the Five Elements with the four seasons,and believed that each of the Five Elements had its own virtues,and thus extended it to the virtues of the monarch.Dong Zhongshu linked the Five Elements with the five things,thinking that the five things of the king will affect the Five Elements;the five things are appearance,speech,sight,listening,thinking,which is given by heaven.To govern the country and the people the king must have five important cultivations.