In this article, by using theory of linear evolution system and Schauder fixed point theorem, we establish a sufficient result of exact null controllability for a non-autonomous functional evolution system with nonloc...In this article, by using theory of linear evolution system and Schauder fixed point theorem, we establish a sufficient result of exact null controllability for a non-autonomous functional evolution system with nonlocal conditions. In particular, the compactness condition or Lipschitz condition for the function g in the nonlocal conditions appearing in various literatures is not required here. An example is also provided to show an application of the obtained result.展开更多
This paper first develops a Lyapunov-type theorem to study global well-posedness(existence and uniqueness of the strong variational solution)and asymptotic stability in probability of nonlinear stochastic evolution sy...This paper first develops a Lyapunov-type theorem to study global well-posedness(existence and uniqueness of the strong variational solution)and asymptotic stability in probability of nonlinear stochastic evolution systems(SESs)driven by a special class of Levy processes,which consist of Wiener and compensated Poisson processes.This theorem is then utilized to develop an approach to solve an inverse optimal stabilization problem for SESs driven by Levy processes.The inverse optimal control design achieves global well-posedness and global asymptotic stability of the closed-loop system,and minimizes a meaningful cost functional that penalizes both states and control.The approach does not require to solve a Hamilton-Jacobi-Bellman equation(HJBE).An optimal stabilization of the evolution of the frequency of a certain genetic character from the population is included to illustrate the theoretical developments.展开更多
This paper is concerned with the existence and the nonlinear asymptotic stabil- ity of traveling wave solutions to the Cauchy problem for a system of dissipative evolution equations {θt=vζx+(ζθ)x+aθxx,ζt=-θ...This paper is concerned with the existence and the nonlinear asymptotic stabil- ity of traveling wave solutions to the Cauchy problem for a system of dissipative evolution equations {θt=vζx+(ζθ)x+aθxx,ζt=-θx+βζxx;with initial data and end states (ζθ)(x,0)=(ζ0,θ0)(x)→(ζ±,θ±)as x→∞.We obtain the existence of traveling wave solutions by phase plane analysis and show the asymptotic nonlinear stability of traveling wave solutions without restrictions on the coeffi- cients a and v by the method of energy estimates.展开更多
An optimal(practical) stabilization problem is formulated in an inverse approach and solved for nonlinear evolution systems in Hilbert spaces. The optimal control design ensures global well-posedness and global practi...An optimal(practical) stabilization problem is formulated in an inverse approach and solved for nonlinear evolution systems in Hilbert spaces. The optimal control design ensures global well-posedness and global practical K∞-exponential stability of the closed-loop system, minimizes a cost functional,which appropriately penalizes both state and control in the sense that it is positive definite(and radially unbounded) in the state and control, without having to solve a Hamilton-Jacobi-Belman equation(HJBE). The Lyapunov functional used in the control design explicitly solves a family of HJBEs. The results are applied to design inverse optimal boundary stabilization control laws for extensible and shearable slender beams governed by fully nonlinear partial differential equations.展开更多
A prediction framework based on the evolution of pattern motion probability density is proposed for the output prediction and estimation problem of non-Newtonian mechanical systems,assuming that the system satisfies t...A prediction framework based on the evolution of pattern motion probability density is proposed for the output prediction and estimation problem of non-Newtonian mechanical systems,assuming that the system satisfies the generalized Lipschitz condition.As a complex nonlinear system primarily governed by statistical laws rather than Newtonian mechanics,the output of non-Newtonian mechanics systems is difficult to describe through deterministic variables such as state variables,which poses difficulties in predicting and estimating the system’s output.In this article,the temporal variation of the system is described by constructing pattern category variables,which are non-deterministic variables.Since pattern category variables have statistical attributes but not operational attributes,operational attributes are assigned to them by posterior probability density,and a method for analyzing their motion laws using probability density evolution is proposed.Furthermore,a data-driven form of pattern motion probabilistic density evolution prediction method is designed by combining pseudo partial derivative(PPD),achieving prediction of the probability density satisfying the system’s output uncertainty.Based on this,the final prediction estimation of the system’s output value is realized by minimum variance unbiased estimation.Finally,a corresponding PPD estimation algorithm is designed using an extended state observer(ESO)to estimate the parameters to be estimated in the proposed prediction method.The effectiveness of the parameter estimation algorithm and prediction method is demonstrated through theoretical analysis,and the accuracy of the algorithm is verified by two numerical simulation examples.展开更多
The optimization of the rule base of a fuzzy logic system (FLS) based on evolutionary algorithm has achievednotable results. However, due to the diversity of the deep structure in the hierarchical fuzzy system (HFS) a...The optimization of the rule base of a fuzzy logic system (FLS) based on evolutionary algorithm has achievednotable results. However, due to the diversity of the deep structure in the hierarchical fuzzy system (HFS) and thecorrelation of each sub fuzzy system, the uncertainty of the HFS’s deep structure increases. For the HFS, a largenumber of studies mainly use fixed structures, which cannot be selected automatically. To solve this problem, thispaper proposes a novel approach for constructing the incremental HFS. During system design, the deep structureand the rule base of the HFS are encoded separately. Subsequently, the deep structure is adaptively mutated basedon the fitness value, so as to realize the diversity of deep structures while ensuring reasonable competition amongthe structures. Finally, the differential evolution (DE) is used to optimize the deep structure of HFS and theparameters of antecedent and consequent simultaneously. The simulation results confirm the effectiveness of themodel. Specifically, the root mean square errors in the Laser dataset and Friedman dataset are 0.0395 and 0.0725,respectively with rule counts of rules is 8 and 12, respectively.When compared to alternative methods, the resultsindicate that the proposed method offers improvements in accuracy and rule counts.展开更多
The Da-Xiao Liangshan mountains are critical ecological function areas and essential ecological barriers in the upper reaches of the Yangtze River in China.This study selected a total of six periods of land use land c...The Da-Xiao Liangshan mountains are critical ecological function areas and essential ecological barriers in the upper reaches of the Yangtze River in China.This study selected a total of six periods of land use land cover(LULC)data from 1995 to 2020,to estimate the ecosystem service value(ESV)and analyzed its spatiotemporal evolution and topographic gradient divergence.The results showed that:(1)The ESV increased by 1.1 billion yuan,with an increase rate of 1.47%from 1995 to 2020.Two time periods,2005–2010 and 2015–2020,showed more significant increases than other periods.(2)The elevation and slope of mountainous areas determine the type of land use and further influence the spatial pattern of ESV.(3)Although woodland and grassland are the main land use types of the study area(more than 90%),the hydrological regulation function of the water area partially compensated for the impact of the encroachment of the built-up area on the ESV of grassland.(4)The spatial distribution of ESVs showed an inverted V-shaped characteristic as the topographic gradient increased,with the dominant position being the 5th topographic gradient zone.Finally,this study provided relevant recommendations for ecosystem protection and optimization.The findings of this study clarified the influence of topographical factors on the spatial differentiation of ESV and provided novel insights into ecosystem protection.展开更多
Rational design of high-performance electrocatalysts for hydrogen evolution reaction(HER)is vital for future renewable energy systems.The incorporation of foreign metal ions into catalysts can be an effective approach...Rational design of high-performance electrocatalysts for hydrogen evolution reaction(HER)is vital for future renewable energy systems.The incorporation of foreign metal ions into catalysts can be an effective approach to optimize its performance.However,there is a lack of systematic theoretical studies to reveal the quantitative relationships at the electronic level.Here,we develop a multi-level screening methodology to search for highly stable and active dopants for CoP catalysts.The density functional theory(DFT)calculations and symbolic regression(SR)were performed to investigate the relationship between the adsorption free energy(ΔG_(H^(*)))and 10 electronic parameters.The mathematic formulas derived from SR indicate that the difference of work function(ΔΦ)between doped metal and the acceptor plays the most important role in regulatingΔG_(H^(*)),followed by the d-band center(d-BC)of doped system.The descriptor of HER can be expressed asΔG_(H^(*))=1.59×√|0.188ΔΦ+d BC+0.120|1/2-0.166 with a high determination coefficient(R^(2)=0.807).Consistent with the theoretical prediction,experimental results show that the Al-CoP delivers superior electrocatalytic HER activity with a low overpotential of75 m V to drive a current density of 10 mA cm^(-2),while the overpotentials for undoped CoP,Mo-CoP,and V-CoP are 206,134,and 83 m V,respectively.The current work proves that theΔΦis the most significant regulatory parameter ofΔG_(H^(*))for ion-doped electrocatalysts.This finding can drive the discovery of high-performance ion-doped electrocatalysts,which is crucial for electrocatalytic water splitting.展开更多
Exploring carbon emission effects based on the evolution of residents’ dietary structure to achieve the carbon neutrality goal and mitigate climate change is an important task.This study took China as the research ob...Exploring carbon emission effects based on the evolution of residents’ dietary structure to achieve the carbon neutrality goal and mitigate climate change is an important task.This study took China as the research object(data excluding Hong Kong,Macao and Taiwan) and used the carbon emission coefficient method to quantitatively measure the food carbon emissions from 1987–2020,then analyzed the carbon emission effects under the evolution of dietary structure.The results showed that during the study period,the Chinese dietary structure gradually changed to a high-carbon consumption pattern.The dietary structure of urban residents developed to a balanced one,while that of rural residents developed to a high-quality one.During the study period,the per capita food carbon emissions and total food consumption of Chinese showed an increasing trend.The per capita food carbon emissions of residents in urban and rural showed an overall upward trend.The total food carbon emissions in urban increased significantly,while that in rural increased first and then decreased.The influence of beef and mutton on carbon emissions is the highest in dietary structure.Compared with the balanced dietary pattern,the food carbon emissions of Chinese residents had not yet reached the peak,but were evolving to a high-carbon consumption pattern.展开更多
The poor stability of RuO_(2)electrocatalysts has been the primary obstacles for their practical application in polymer electrolyte membrane electrolyzers.To dramatically enhance the durability of RuO_(2)to construct ...The poor stability of RuO_(2)electrocatalysts has been the primary obstacles for their practical application in polymer electrolyte membrane electrolyzers.To dramatically enhance the durability of RuO_(2)to construct activity-stability trade-off model is full of significance but challenging.Herein,a single atom Zn stabilized RuO_(2)with enriched oxygen vacancies(SA Zn-RuO_(2))is developed as a promising alternative to iridium oxide for acidic oxygen evolution reaction(OER).Compared with commercial RuO_(2),the enhanced Ru–O bond strength of SA Zn-RuO_(2)by forming Zn-O-Ru local structure motif is favorable to stabilize surface Ru,while the electrons transferred from Zn single atoms to adjacent Ru atoms protects the Ru active sites from overoxidation.Simultaneously,the optimized surrounding electronic structure of Ru sites in SA ZnRuO_(2)decreases the adsorption energies of OER intermediates to reduce the reaction barrier.As a result,the representative SA Zn-RuO_(2)exhibits a low overpotential of 210 mV to achieve 10 mA cm^(-2)and a greatly enhanced durability than commercial RuO_(2).This work provides a promising dual-engineering strategy by coupling single atom doping and vacancy for the tradeoff of high activity and catalytic stability toward acidic OER.展开更多
Rock-encased-backfill(RB)structures are common in underground mining,for example in the cut-andfill and stoping methods.To understand the effects of cyclic excavation and blasting activities on the damage of these RB ...Rock-encased-backfill(RB)structures are common in underground mining,for example in the cut-andfill and stoping methods.To understand the effects of cyclic excavation and blasting activities on the damage of these RB structures,a series of triaxial stepwise-increasing-amplitude cyclic loading experiments was conducted with cylindrical RB specimens(rock on outside,backfill on inside)with different volume fractions of rock(VF=0.48,0.61,0.73,and 0.84),confining pressures(0,6,9,and 12 MPa),and cyclic loading rates(200,300,400,and 500 N/s).The damage evolution and meso-crack formation during the cyclic tests were analyzed with results from stress-strain hysteresis loops,acoustic emission events,and post-failure X-ray 3D fracture morphology.The results showed significant differences between cyclic and monotonic loadings of RB specimens,particularly with regard to the generation of shear microcracks,the development of stress memory and strain hardening,and the contact forces and associated friction that develops along the rock-backfill interface.One important finding is that as a function of the number of cycles,the elastic strain increases linearly and the dissipated energy increases exponentially.Also,compared with monotonic loading,the cyclic strain hardening characteristics are more sensitive to rising confining pressures during the initial compaction stage.Another finding is that compared with monotonic loading,more shear microcracks are generated during every reloading stage,but these microcracks tend to be dispersed and lessen the likelihood of large shear fracture formation.The transition from elastic to plastic behavior varies depending on the parameters of each test(confinement,volume fraction,and cyclic rate),and an interesting finding was that the transformation to plastic behavior is significantly lower under the conditions of 0.73 rock volume fraction,400 N/s cyclic loading rate,and 9 MPa confinement.All the findings have important practical implications on the ability of backfill to support underground excavations.展开更多
The problem of rural development arises from the evolution of rural regional system.It is urgent to deepen the research on the evolution process and mechanism of rural regional system.However,there are relatively few ...The problem of rural development arises from the evolution of rural regional system.It is urgent to deepen the research on the evolution process and mechanism of rural regional system.However,there are relatively few studies on rural development from the perspective of the evolution process,driving mechanism and evolution mechanism of rural regional system.Therefore,this study took Huang-Huai-Hai Area for example,started with the systematicness of the rural regional system,the spatio-temporal pattern and driving mechanism of rural regional system evolution,and further summarized and refined the evolution mechanism of the rural regional system.The methods of spatial pattern analysis,gray correlation degree and geographical detection were adopted.The results showed that the problems in rural areas were often dominated by one factor and produced by the joint action of many factors.Factors such as county urbanization,county economy,county public service,agricultural mechanization,surrounding cities and convenient transportation will affect the evolution of rural regional systems.Based on the evolution of the elements in the rural regional system,the evolution types of rural regional system can be divided into decline type,equilibrium type and growth type.This study can provide a reference for understanding the process of rural rise and fall and can also guide rural revitalization and rural sustainable development.展开更多
The majority of oil and gas resources in the world are related to saline sediments, which mainly occur in sedimentary strata in the form of cap rocks or salt-associated shales. A large number of shale oil resources ha...The majority of oil and gas resources in the world are related to saline sediments, which mainly occur in sedimentary strata in the form of cap rocks or salt-associated shales. A large number of shale oil resources have been discovered in the saline shale sediments of the Cenozoic terrestrial lake basin in China. The hydrocarbon generation ability and the reservoir capacity of shale control the oil and gas generation. The reservoir capacity is mainly characterized by pore type, structure and porosity. Most of China’s shale oil and gas resources belong to salt-bearing formations. The role of gypsum-salt rocks in the formation and evolution of organic matter (OM) in such formations has received extensive attention. However, systematic understanding is lacking. Research on the pore formation and evolution in shale under the action of gypsum-salt rock sediments is especially weak. Taking the shales in the third member of the Shahejie Formation (Es_(3)) of the Bohai Bay Basin as an example, the influence of halite on the formation and evolution process of pores was studied in this paper. The results show that halite and gypsum minerals were associated with OM, which made them more likely to develop OM pores. The samples with a high halite mineral content (HC) are more developed regarding the pore volume and specific surface area than those with a low HC. The formation of thick salt rocks is influenced by factors of deep thermal brine upwelling, sea erosion and arid environments. The frequent alternation between humid and arid environments led to the outbreak and death of organisms and the precipitation of gypsum-salt rock, which formed the simultaneous deposition of OM and halite minerals. Finally, we have established a model of shale pore evolution under the participation of the gypsum-salt rock, and halite minerals contribute to pore development in both Stage II and Stage IV. This study provides strong microscopic evidence for the pore system formation and evolution in salt-bearing reservoirs.展开更多
This study aimed to investigate the mechanism of nitrogen doping,migration,and conversion during ammonia torrefaction and also explore the evolution law of the chemical structure of cellulose.The results showed that t...This study aimed to investigate the mechanism of nitrogen doping,migration,and conversion during ammonia torrefaction and also explore the evolution law of the chemical structure of cellulose.The results showed that the ammonia torrefaction pretreatment could significantly optimize the distribution of nitrogen and oxygen elements in cellulose.The carbon skeleton first captured the active nitrogenous radicals to form-NHn-N,and pyridine-N and pyrrole-N originated from the conversion of-NHn-N.The existence of C=O played a major role in the immobilization of nitrogen.The nitrogen in bio-oil exists mainly in the form of five-and six-membered heterocycles.The correlation analysis showed that the main precursors for the formation of nitrogenous heterocyclic compounds were five-membered Oheterocyclic compounds.Finally,the product distribution characteristics in the torrefaction-pyrolysis systems were summarized,and the nitrogen doping and conversion mechanisms were proposed.This study expanded the boundaries of cellulose pretreatment and the production of high-value chemicals.展开更多
Deep-water channel systems are important petroleum reservoirs,and many have been discovered worldwide.Understanding deep-water channel sedimentary elements and evolution is helpful for deep-sea petroleum exploration a...Deep-water channel systems are important petroleum reservoirs,and many have been discovered worldwide.Understanding deep-water channel sedimentary elements and evolution is helpful for deep-sea petroleum exploration and development.Based on high-resolution 3D seismic data,the Miocene channel system in the deep-water Taranaki Basin,New Zealand,was analyzed by using seismic interpretation techniques such as interlayer attribute extraction and strata slicing.The channel system was divided into five composite channels(CC-I to CC-V)according to four secondary level channel boundaries,and sedimentary elements such as channels,slump deposits,inner levees,mass transport deposits,and hemipelagic drape deposits were identified in the channel system.The morphological characteristics of several composite channels exhibited stark variances,and the overall morphology of the composite channels changed from relatively straight to highly sinuous to relatively straight.The evolution of the composite channels involved a gradual and repeated process of erosion and filling,and the composite channels could be divided into three evolutionary stages:initial erosion-filling,later erosion-filling(multistage),and channel abandonment.The middle Miocene channel system may have formed as a consequence of combined regional tectonic activity and global climatic change,and its intricate morphological alterations may have been influenced by the channel's ability to self-regulate and gravity flow properties.When studying the sedimentary evolution of a large-scale deep-water channel system in the Taranaki Basin during the Oligocene-Miocene,which transitioned from a passive margin to plate convergence,it can be understood how tectonic activity affected the channel and can also provide a theoretical reference for the evolution of the deepwater channels in areas with similar tectonic conversion environments around the world.展开更多
The interaction mechanism between coal and rock masses with supporting materials is significant in roadway control, especially in deep underground mining situations where dynamic hazards frequently happened due to hig...The interaction mechanism between coal and rock masses with supporting materials is significant in roadway control, especially in deep underground mining situations where dynamic hazards frequently happened due to high geo-stress and strong disturbed effects. This paper is to investigate the strain energy evolution in the interaction between coal and rock masses with self-designed energy-absorbing props and rock bolts by numerical modeling with the finite difference method. The interaction between rock and rock bolt/prop is accomplished by the cables element and the interface between the inner and outer props. Roadway excavation and coal extraction conditions in deep mining are numerically employed to investigate deformation, plastic zone ranges, strain energy input, accumulation, dissipation,and release. The effect on strain energy input, accumulation, dissipation, and release with rock deformation, and the plastic zone is addressed. A ratio of strain energy accumulation, dissipation, and release with energy input a, β, γ is to assess the dynamic hazards. The effects on roadway excavation and coal extraction steps of a, β, γ are discussed. The results show that:(1) In deep high geo-stress roadways, the energyabsorbing support system plays a dual role in resisting deformation and reducing the scope of plastic zones in surrounding rock, as well as absorbing energy release in the surrounding rock, especially in the coal extraction state to mitigate disturbed effects.(2) The strain energy input, accumulation is dependent on roadway deformation, the strain energy dissipation is relied on plastic zone area and disturbed effects, and strain energy release density is the difference among the three. The function of energyabsorbing rock bolts and props play a key role to mitigate strain energy release density and amount, especially in coal extraction condition, with a peak density value from 4×10^(4) to 1×10^(4)J/m^(3), and amount value from 3.57×10^(8) to 1.90×10^(6)J.(3) When mining is advanced in small steps, the strain energy accumulation is dominated. While in a large step, the released energy is dominant, thus a more dynamic hazards proneness. The energy-absorbing rock bolt and prop can reduce three times strain energy release amount, thus reducing the dynamic hazards. The results suggest that energy-absorbing props and rock bolts can effectively reduce the strain energy in the coal and rock masses, and prevent rock bursts and other hazards.The numerical model developed in this study can also be used to optimize the design of energyabsorbing props and rock bolts for specific mining conditions.展开更多
Stochastic fractional differential systems are important and useful in the mathematics,physics,and engineering fields.However,the determination of their probabilistic responses is difficult due to their non-Markovian ...Stochastic fractional differential systems are important and useful in the mathematics,physics,and engineering fields.However,the determination of their probabilistic responses is difficult due to their non-Markovian property.The recently developed globally-evolving-based generalized density evolution equation(GE-GDEE),which is a unified partial differential equation(PDE)governing the transient probability density function(PDF)of a generic path-continuous process,including non-Markovian ones,provides a feasible tool to solve this problem.In the paper,the GE-GDEE for multi-dimensional linear fractional differential systems subject to Gaussian white noise is established.In particular,it is proved that in the GE-GDEE corresponding to the state-quantities of interest,the intrinsic drift coefficient is a time-varying linear function,and can be analytically determined.In this sense,an alternative low-dimensional equivalent linear integer-order differential system with exact closed-form coefficients for the original highdimensional linear fractional differential system can be constructed such that their transient PDFs are identical.Specifically,for a multi-dimensional linear fractional differential system,if only one or two quantities are of interest,GE-GDEE is only in one or two dimensions,and the surrogate system would be a one-or two-dimensional linear integer-order system.Several examples are studied to assess the merit of the proposed method.Though presently the closed-form intrinsic drift coefficient is only available for linear stochastic fractional differential systems,the findings in the present paper provide a remarkable demonstration on the existence and eligibility of GE-GDEE for the case that the original high-dimensional system itself is non-Markovian,and provide insights for the physical-mechanism-informed determination of intrinsic drift and diffusion coefficients of GE-GDEE of more generic complex nonlinear systems.展开更多
Nyiragongo volcanic eruptions of 1977 and 2002 emitted silica-undersaturated lavas named melilite-nephelinites with microlithic to sub-porphyritic textures, and consisted of olivine, clinopyroxene (augite), phlogopite...Nyiragongo volcanic eruptions of 1977 and 2002 emitted silica-undersaturated lavas named melilite-nephelinites with microlithic to sub-porphyritic textures, and consisted of olivine, clinopyroxene (augite), phlogopite, melilite, magnetite, and rare plagioclases. This melilite-nephelinite as an evolved rock, shows low SiO<sub>2</sub> (38.40 - 39.52 wt%) and MgO (3.10 - 4.01 wt%), and relatively high FeOt (13.76 - 14.10 wt%), Al<sub>2</sub>O<sub>3</sub> (15.01 - 16.48 wt%), CaO (11.00 - 12.29 wt%) and Na<sub>2</sub>O + K<sub>2</sub>O (10.34 - 11.85 wt%). Unlike LA-ICP-MS on silicate melt inclusions (SMIs) hosted in augite show a pristine melt of picrobasaltic (low Ti-picrite) rock poor in SiO<sub>2</sub> (31.14 - 32.26 wt%), FeOt (2.19 - 2.79 wt%), Al<sub>2</sub>O<sub>3</sub> (8.01 - 9.57 wt%), and Na<sub>2</sub>O + K<sub>2</sub>O (2.34 - 3.05 wt%), while enriched in MgO (20.27 - 28.63 wt%), and CaO (24.95 - 33.17 wt%). The sums (∑REEs) for lavas and SMIs are ranging 712 - 799 and 43 - 119 ppm respectively. REE contracted multi-element patterns showed a W-feature for most lavas except for SMIs. High Rb/Sr, and low Ba/Rb, Zr/Nb, and Sm/Hf ratios of lavas suggest a phlogopite-rich source of materials. .展开更多
The far-field microdynamic disturbance caused by the excavation of deep mineral resources and underground engineering can induce surrounding rock damage in high-stress conditions and even lead to disasters.However,the...The far-field microdynamic disturbance caused by the excavation of deep mineral resources and underground engineering can induce surrounding rock damage in high-stress conditions and even lead to disasters.However,the mechanical properties and damage/fracture evolution mechanisms of deep rock induced by microdynamic disturbance under three-dimensional stress states are unclear.Therefore,a true triaxial multilevel disturbance test method is proposed,which can completely simulate natural geostress,excavation stress redistribution(such as stress unloading,concentration and rotation),and subsequently the microdynamic disturbance triggering damaged rock failure.Based on a dynamic true triaxial test platform,true triaxial microdynamic disturbance tests under different frequency and amplitudes were carried out on monzogabbro.The results show that increasing amplitude or decreasing frequency diminishes the failure strength of monzogabbro.Deformation modulus gradually decreases during disturbance failure.As frequency and amplitude increase,the degradation rate of deformation modulus decreases slightly,disturbance dissipated energy increases significantly,and disturbance deformation anisotropy strengthens obviously.A damage model has been proposed to quantitatively characterize the disturbance-induced damage evolution at different frequency and amplitude under true triaxial stress.Before disturbance failure,the micro-tensile crack mechanism is dominant,and the micro-shear crack mechanism increases significantly at failure.With the increase of amplitude and frequency,the micro-shear crack mechanism increases.When approaching disturbance failure,the acoustic emission fractal dimension changes from a stable value to local large oscillation,and finally increases sharply to a high value at failure.Finally,the disturbance-induced failure mechanism of surrounding rock in deep engineering is clearly elucidated.展开更多
A series of carbon nitride(CN)materials represented by graphitic carbon nitride(g-C3N4)have been widely used in bioimaging,biosensing,and other fields in recent years due to their nontoxicity,low cost,and high lumines...A series of carbon nitride(CN)materials represented by graphitic carbon nitride(g-C3N4)have been widely used in bioimaging,biosensing,and other fields in recent years due to their nontoxicity,low cost,and high luminescent quantum efficiency.What is more attractive is that the luminescent properties such as wavelength and intensity can be regulated by controlling the structure at the molecular level.Hence,it is time to summarize the related research on CN structural evolution and make a prospect on future developments.In this review,we first summarize the research history and multiple structural evolution of CN.Then,the progress of improving the luminescence performance of CN through structural evolution was discussed.Significantly,the relationship between CN structure evolution and energy conversion in the forms of photoluminescence,chemiluminescence,and electrochemiluminescence was reviewed.Finally,key challenges and opportunities such as nanoscale dispersion strategy,luminous efficiency improving methods,standardization evaluation,and macroscopic preparation of CN are highlighted.展开更多
基金supported by NSF of China (11171110)Shanghai Leading Academic Discipline Project (B407)
文摘In this article, by using theory of linear evolution system and Schauder fixed point theorem, we establish a sufficient result of exact null controllability for a non-autonomous functional evolution system with nonlocal conditions. In particular, the compactness condition or Lipschitz condition for the function g in the nonlocal conditions appearing in various literatures is not required here. An example is also provided to show an application of the obtained result.
文摘This paper first develops a Lyapunov-type theorem to study global well-posedness(existence and uniqueness of the strong variational solution)and asymptotic stability in probability of nonlinear stochastic evolution systems(SESs)driven by a special class of Levy processes,which consist of Wiener and compensated Poisson processes.This theorem is then utilized to develop an approach to solve an inverse optimal stabilization problem for SESs driven by Levy processes.The inverse optimal control design achieves global well-posedness and global asymptotic stability of the closed-loop system,and minimizes a meaningful cost functional that penalizes both states and control.The approach does not require to solve a Hamilton-Jacobi-Bellman equation(HJBE).An optimal stabilization of the evolution of the frequency of a certain genetic character from the population is included to illustrate the theoretical developments.
基金supported by the Natural Science Foundation of China(11001095)the Ph.D.specialized grant of the Ministry of Education of China(20100144110001)+2 种基金the Special Fund for Basic Scientific Research of Central Colleges(CCNU12C01001)supported by the Fundamental Research Funds for the Central Universities(2015IA009)the Natural Science Foundation of China(61573012)
文摘This paper is concerned with the existence and the nonlinear asymptotic stabil- ity of traveling wave solutions to the Cauchy problem for a system of dissipative evolution equations {θt=vζx+(ζθ)x+aθxx,ζt=-θx+βζxx;with initial data and end states (ζθ)(x,0)=(ζ0,θ0)(x)→(ζ±,θ±)as x→∞.We obtain the existence of traveling wave solutions by phase plane analysis and show the asymptotic nonlinear stability of traveling wave solutions without restrictions on the coeffi- cients a and v by the method of energy estimates.
文摘An optimal(practical) stabilization problem is formulated in an inverse approach and solved for nonlinear evolution systems in Hilbert spaces. The optimal control design ensures global well-posedness and global practical K∞-exponential stability of the closed-loop system, minimizes a cost functional,which appropriately penalizes both state and control in the sense that it is positive definite(and radially unbounded) in the state and control, without having to solve a Hamilton-Jacobi-Belman equation(HJBE). The Lyapunov functional used in the control design explicitly solves a family of HJBEs. The results are applied to design inverse optimal boundary stabilization control laws for extensible and shearable slender beams governed by fully nonlinear partial differential equations.
文摘A prediction framework based on the evolution of pattern motion probability density is proposed for the output prediction and estimation problem of non-Newtonian mechanical systems,assuming that the system satisfies the generalized Lipschitz condition.As a complex nonlinear system primarily governed by statistical laws rather than Newtonian mechanics,the output of non-Newtonian mechanics systems is difficult to describe through deterministic variables such as state variables,which poses difficulties in predicting and estimating the system’s output.In this article,the temporal variation of the system is described by constructing pattern category variables,which are non-deterministic variables.Since pattern category variables have statistical attributes but not operational attributes,operational attributes are assigned to them by posterior probability density,and a method for analyzing their motion laws using probability density evolution is proposed.Furthermore,a data-driven form of pattern motion probabilistic density evolution prediction method is designed by combining pseudo partial derivative(PPD),achieving prediction of the probability density satisfying the system’s output uncertainty.Based on this,the final prediction estimation of the system’s output value is realized by minimum variance unbiased estimation.Finally,a corresponding PPD estimation algorithm is designed using an extended state observer(ESO)to estimate the parameters to be estimated in the proposed prediction method.The effectiveness of the parameter estimation algorithm and prediction method is demonstrated through theoretical analysis,and the accuracy of the algorithm is verified by two numerical simulation examples.
基金the Sichuan Science and Technology Program(2021ZYD0016).
文摘The optimization of the rule base of a fuzzy logic system (FLS) based on evolutionary algorithm has achievednotable results. However, due to the diversity of the deep structure in the hierarchical fuzzy system (HFS) and thecorrelation of each sub fuzzy system, the uncertainty of the HFS’s deep structure increases. For the HFS, a largenumber of studies mainly use fixed structures, which cannot be selected automatically. To solve this problem, thispaper proposes a novel approach for constructing the incremental HFS. During system design, the deep structureand the rule base of the HFS are encoded separately. Subsequently, the deep structure is adaptively mutated basedon the fitness value, so as to realize the diversity of deep structures while ensuring reasonable competition amongthe structures. Finally, the differential evolution (DE) is used to optimize the deep structure of HFS and theparameters of antecedent and consequent simultaneously. The simulation results confirm the effectiveness of themodel. Specifically, the root mean square errors in the Laser dataset and Friedman dataset are 0.0395 and 0.0725,respectively with rule counts of rules is 8 and 12, respectively.When compared to alternative methods, the resultsindicate that the proposed method offers improvements in accuracy and rule counts.
基金supported by the National Natural Science Foundation of China(Grant No.52078423)the Sichuan Province Science and Technology Support Program(Grant No.2020YFS0309 and 2020YFS0054)+1 种基金the China Engineering Science and Technology Strategic Consulting Project(Grant No.2022JDR0356)the Key Research Institution of Philosophy and Social Sciences in Sichuan Province:Research Center of National Parks(Grant No.GJGY2023-YB001)。
文摘The Da-Xiao Liangshan mountains are critical ecological function areas and essential ecological barriers in the upper reaches of the Yangtze River in China.This study selected a total of six periods of land use land cover(LULC)data from 1995 to 2020,to estimate the ecosystem service value(ESV)and analyzed its spatiotemporal evolution and topographic gradient divergence.The results showed that:(1)The ESV increased by 1.1 billion yuan,with an increase rate of 1.47%from 1995 to 2020.Two time periods,2005–2010 and 2015–2020,showed more significant increases than other periods.(2)The elevation and slope of mountainous areas determine the type of land use and further influence the spatial pattern of ESV.(3)Although woodland and grassland are the main land use types of the study area(more than 90%),the hydrological regulation function of the water area partially compensated for the impact of the encroachment of the built-up area on the ESV of grassland.(4)The spatial distribution of ESVs showed an inverted V-shaped characteristic as the topographic gradient increased,with the dominant position being the 5th topographic gradient zone.Finally,this study provided relevant recommendations for ecosystem protection and optimization.The findings of this study clarified the influence of topographical factors on the spatial differentiation of ESV and provided novel insights into ecosystem protection.
基金Financial support from the National Natural Science Foundation of China(21676216)the Special project of Shaanxi Provincial Education Department(20JC034)+1 种基金GHfund B(202202022563)Hefei Advanced Computing Center。
文摘Rational design of high-performance electrocatalysts for hydrogen evolution reaction(HER)is vital for future renewable energy systems.The incorporation of foreign metal ions into catalysts can be an effective approach to optimize its performance.However,there is a lack of systematic theoretical studies to reveal the quantitative relationships at the electronic level.Here,we develop a multi-level screening methodology to search for highly stable and active dopants for CoP catalysts.The density functional theory(DFT)calculations and symbolic regression(SR)were performed to investigate the relationship between the adsorption free energy(ΔG_(H^(*)))and 10 electronic parameters.The mathematic formulas derived from SR indicate that the difference of work function(ΔΦ)between doped metal and the acceptor plays the most important role in regulatingΔG_(H^(*)),followed by the d-band center(d-BC)of doped system.The descriptor of HER can be expressed asΔG_(H^(*))=1.59×√|0.188ΔΦ+d BC+0.120|1/2-0.166 with a high determination coefficient(R^(2)=0.807).Consistent with the theoretical prediction,experimental results show that the Al-CoP delivers superior electrocatalytic HER activity with a low overpotential of75 m V to drive a current density of 10 mA cm^(-2),while the overpotentials for undoped CoP,Mo-CoP,and V-CoP are 206,134,and 83 m V,respectively.The current work proves that theΔΦis the most significant regulatory parameter ofΔG_(H^(*))for ion-doped electrocatalysts.This finding can drive the discovery of high-performance ion-doped electrocatalysts,which is crucial for electrocatalytic water splitting.
基金Under the auspices of National Natural Science Foundation of China(No.42171230)。
文摘Exploring carbon emission effects based on the evolution of residents’ dietary structure to achieve the carbon neutrality goal and mitigate climate change is an important task.This study took China as the research object(data excluding Hong Kong,Macao and Taiwan) and used the carbon emission coefficient method to quantitatively measure the food carbon emissions from 1987–2020,then analyzed the carbon emission effects under the evolution of dietary structure.The results showed that during the study period,the Chinese dietary structure gradually changed to a high-carbon consumption pattern.The dietary structure of urban residents developed to a balanced one,while that of rural residents developed to a high-quality one.During the study period,the per capita food carbon emissions and total food consumption of Chinese showed an increasing trend.The per capita food carbon emissions of residents in urban and rural showed an overall upward trend.The total food carbon emissions in urban increased significantly,while that in rural increased first and then decreased.The influence of beef and mutton on carbon emissions is the highest in dietary structure.Compared with the balanced dietary pattern,the food carbon emissions of Chinese residents had not yet reached the peak,but were evolving to a high-carbon consumption pattern.
基金supported by the Taishan Scholar Program of Shandong Province,China (tsqn202211162)the National Natural Science Foundation of China (22102079)the Natural Science Foundation of Shandong Province of China (ZR2021YQ10,ZR2022QB163)。
文摘The poor stability of RuO_(2)electrocatalysts has been the primary obstacles for their practical application in polymer electrolyte membrane electrolyzers.To dramatically enhance the durability of RuO_(2)to construct activity-stability trade-off model is full of significance but challenging.Herein,a single atom Zn stabilized RuO_(2)with enriched oxygen vacancies(SA Zn-RuO_(2))is developed as a promising alternative to iridium oxide for acidic oxygen evolution reaction(OER).Compared with commercial RuO_(2),the enhanced Ru–O bond strength of SA Zn-RuO_(2)by forming Zn-O-Ru local structure motif is favorable to stabilize surface Ru,while the electrons transferred from Zn single atoms to adjacent Ru atoms protects the Ru active sites from overoxidation.Simultaneously,the optimized surrounding electronic structure of Ru sites in SA ZnRuO_(2)decreases the adsorption energies of OER intermediates to reduce the reaction barrier.As a result,the representative SA Zn-RuO_(2)exhibits a low overpotential of 210 mV to achieve 10 mA cm^(-2)and a greatly enhanced durability than commercial RuO_(2).This work provides a promising dual-engineering strategy by coupling single atom doping and vacancy for the tradeoff of high activity and catalytic stability toward acidic OER.
基金We acknowledge the funding support from the National Natural Science Foundation of China Youth Fund(Grant No.52004019)the National Natural Science Foundation of China(Grant No.41825018)China Postdoctoral Science Foundation(Grant No.2023M733481).
文摘Rock-encased-backfill(RB)structures are common in underground mining,for example in the cut-andfill and stoping methods.To understand the effects of cyclic excavation and blasting activities on the damage of these RB structures,a series of triaxial stepwise-increasing-amplitude cyclic loading experiments was conducted with cylindrical RB specimens(rock on outside,backfill on inside)with different volume fractions of rock(VF=0.48,0.61,0.73,and 0.84),confining pressures(0,6,9,and 12 MPa),and cyclic loading rates(200,300,400,and 500 N/s).The damage evolution and meso-crack formation during the cyclic tests were analyzed with results from stress-strain hysteresis loops,acoustic emission events,and post-failure X-ray 3D fracture morphology.The results showed significant differences between cyclic and monotonic loadings of RB specimens,particularly with regard to the generation of shear microcracks,the development of stress memory and strain hardening,and the contact forces and associated friction that develops along the rock-backfill interface.One important finding is that as a function of the number of cycles,the elastic strain increases linearly and the dissipated energy increases exponentially.Also,compared with monotonic loading,the cyclic strain hardening characteristics are more sensitive to rising confining pressures during the initial compaction stage.Another finding is that compared with monotonic loading,more shear microcracks are generated during every reloading stage,but these microcracks tend to be dispersed and lessen the likelihood of large shear fracture formation.The transition from elastic to plastic behavior varies depending on the parameters of each test(confinement,volume fraction,and cyclic rate),and an interesting finding was that the transformation to plastic behavior is significantly lower under the conditions of 0.73 rock volume fraction,400 N/s cyclic loading rate,and 9 MPa confinement.All the findings have important practical implications on the ability of backfill to support underground excavations.
基金Under the auspices of Key projects of National Natural Science Foundation of China(No.41931293)。
文摘The problem of rural development arises from the evolution of rural regional system.It is urgent to deepen the research on the evolution process and mechanism of rural regional system.However,there are relatively few studies on rural development from the perspective of the evolution process,driving mechanism and evolution mechanism of rural regional system.Therefore,this study took Huang-Huai-Hai Area for example,started with the systematicness of the rural regional system,the spatio-temporal pattern and driving mechanism of rural regional system evolution,and further summarized and refined the evolution mechanism of the rural regional system.The methods of spatial pattern analysis,gray correlation degree and geographical detection were adopted.The results showed that the problems in rural areas were often dominated by one factor and produced by the joint action of many factors.Factors such as county urbanization,county economy,county public service,agricultural mechanization,surrounding cities and convenient transportation will affect the evolution of rural regional systems.Based on the evolution of the elements in the rural regional system,the evolution types of rural regional system can be divided into decline type,equilibrium type and growth type.This study can provide a reference for understanding the process of rural rise and fall and can also guide rural revitalization and rural sustainable development.
基金funded by the National Natural Science Foundation of China(41872128)Postdoctoral Foundation of China University of Petroleum(Beijing)(ZX20220102).
文摘The majority of oil and gas resources in the world are related to saline sediments, which mainly occur in sedimentary strata in the form of cap rocks or salt-associated shales. A large number of shale oil resources have been discovered in the saline shale sediments of the Cenozoic terrestrial lake basin in China. The hydrocarbon generation ability and the reservoir capacity of shale control the oil and gas generation. The reservoir capacity is mainly characterized by pore type, structure and porosity. Most of China’s shale oil and gas resources belong to salt-bearing formations. The role of gypsum-salt rocks in the formation and evolution of organic matter (OM) in such formations has received extensive attention. However, systematic understanding is lacking. Research on the pore formation and evolution in shale under the action of gypsum-salt rock sediments is especially weak. Taking the shales in the third member of the Shahejie Formation (Es_(3)) of the Bohai Bay Basin as an example, the influence of halite on the formation and evolution process of pores was studied in this paper. The results show that halite and gypsum minerals were associated with OM, which made them more likely to develop OM pores. The samples with a high halite mineral content (HC) are more developed regarding the pore volume and specific surface area than those with a low HC. The formation of thick salt rocks is influenced by factors of deep thermal brine upwelling, sea erosion and arid environments. The frequent alternation between humid and arid environments led to the outbreak and death of organisms and the precipitation of gypsum-salt rock, which formed the simultaneous deposition of OM and halite minerals. Finally, we have established a model of shale pore evolution under the participation of the gypsum-salt rock, and halite minerals contribute to pore development in both Stage II and Stage IV. This study provides strong microscopic evidence for the pore system formation and evolution in salt-bearing reservoirs.
基金sponsored by the National Natural Science Foundation of China(52176193)the National Key Research and Development Program of China(2019YFD1100602)+1 种基金the Shandong Provincial Natural Science Foundation,China(ZR2020ME184)the SDUT & Zhangdian City Integration Development Project(2021JSCG0013)。
文摘This study aimed to investigate the mechanism of nitrogen doping,migration,and conversion during ammonia torrefaction and also explore the evolution law of the chemical structure of cellulose.The results showed that the ammonia torrefaction pretreatment could significantly optimize the distribution of nitrogen and oxygen elements in cellulose.The carbon skeleton first captured the active nitrogenous radicals to form-NHn-N,and pyridine-N and pyrrole-N originated from the conversion of-NHn-N.The existence of C=O played a major role in the immobilization of nitrogen.The nitrogen in bio-oil exists mainly in the form of five-and six-membered heterocycles.The correlation analysis showed that the main precursors for the formation of nitrogenous heterocyclic compounds were five-membered Oheterocyclic compounds.Finally,the product distribution characteristics in the torrefaction-pyrolysis systems were summarized,and the nitrogen doping and conversion mechanisms were proposed.This study expanded the boundaries of cellulose pretreatment and the production of high-value chemicals.
基金The National Natural Science Foundation of China under contract Nos 42077410 and 41872112。
文摘Deep-water channel systems are important petroleum reservoirs,and many have been discovered worldwide.Understanding deep-water channel sedimentary elements and evolution is helpful for deep-sea petroleum exploration and development.Based on high-resolution 3D seismic data,the Miocene channel system in the deep-water Taranaki Basin,New Zealand,was analyzed by using seismic interpretation techniques such as interlayer attribute extraction and strata slicing.The channel system was divided into five composite channels(CC-I to CC-V)according to four secondary level channel boundaries,and sedimentary elements such as channels,slump deposits,inner levees,mass transport deposits,and hemipelagic drape deposits were identified in the channel system.The morphological characteristics of several composite channels exhibited stark variances,and the overall morphology of the composite channels changed from relatively straight to highly sinuous to relatively straight.The evolution of the composite channels involved a gradual and repeated process of erosion and filling,and the composite channels could be divided into three evolutionary stages:initial erosion-filling,later erosion-filling(multistage),and channel abandonment.The middle Miocene channel system may have formed as a consequence of combined regional tectonic activity and global climatic change,and its intricate morphological alterations may have been influenced by the channel's ability to self-regulate and gravity flow properties.When studying the sedimentary evolution of a large-scale deep-water channel system in the Taranaki Basin during the Oligocene-Miocene,which transitioned from a passive margin to plate convergence,it can be understood how tectonic activity affected the channel and can also provide a theoretical reference for the evolution of the deepwater channels in areas with similar tectonic conversion environments around the world.
基金the National Natural Science Foundation of China(Nos.52204114,52274145,U22A20165,and 52174089)the Natural Science Foundation of Jiangsu Province(No.BK20210522)+2 种基金the National Key Research and Development Program of China(No.2022YFE0128300)the China Postdoctoral Science Foundation(No.2023M733758)the Shandong Postdoctoral Science Foundation(No.SDCX-ZG-202302037).
文摘The interaction mechanism between coal and rock masses with supporting materials is significant in roadway control, especially in deep underground mining situations where dynamic hazards frequently happened due to high geo-stress and strong disturbed effects. This paper is to investigate the strain energy evolution in the interaction between coal and rock masses with self-designed energy-absorbing props and rock bolts by numerical modeling with the finite difference method. The interaction between rock and rock bolt/prop is accomplished by the cables element and the interface between the inner and outer props. Roadway excavation and coal extraction conditions in deep mining are numerically employed to investigate deformation, plastic zone ranges, strain energy input, accumulation, dissipation,and release. The effect on strain energy input, accumulation, dissipation, and release with rock deformation, and the plastic zone is addressed. A ratio of strain energy accumulation, dissipation, and release with energy input a, β, γ is to assess the dynamic hazards. The effects on roadway excavation and coal extraction steps of a, β, γ are discussed. The results show that:(1) In deep high geo-stress roadways, the energyabsorbing support system plays a dual role in resisting deformation and reducing the scope of plastic zones in surrounding rock, as well as absorbing energy release in the surrounding rock, especially in the coal extraction state to mitigate disturbed effects.(2) The strain energy input, accumulation is dependent on roadway deformation, the strain energy dissipation is relied on plastic zone area and disturbed effects, and strain energy release density is the difference among the three. The function of energyabsorbing rock bolts and props play a key role to mitigate strain energy release density and amount, especially in coal extraction condition, with a peak density value from 4×10^(4) to 1×10^(4)J/m^(3), and amount value from 3.57×10^(8) to 1.90×10^(6)J.(3) When mining is advanced in small steps, the strain energy accumulation is dominated. While in a large step, the released energy is dominant, thus a more dynamic hazards proneness. The energy-absorbing rock bolt and prop can reduce three times strain energy release amount, thus reducing the dynamic hazards. The results suggest that energy-absorbing props and rock bolts can effectively reduce the strain energy in the coal and rock masses, and prevent rock bursts and other hazards.The numerical model developed in this study can also be used to optimize the design of energyabsorbing props and rock bolts for specific mining conditions.
基金The supports of the National Natural Science Foundation of China(Grant Nos.51725804 and U1711264)the Research Fund for State Key Laboratories of Ministry of Science and Technology of China(SLDRCE19-B-23)the Shanghai Post-Doctoral Excellence Program(2022558)。
文摘Stochastic fractional differential systems are important and useful in the mathematics,physics,and engineering fields.However,the determination of their probabilistic responses is difficult due to their non-Markovian property.The recently developed globally-evolving-based generalized density evolution equation(GE-GDEE),which is a unified partial differential equation(PDE)governing the transient probability density function(PDF)of a generic path-continuous process,including non-Markovian ones,provides a feasible tool to solve this problem.In the paper,the GE-GDEE for multi-dimensional linear fractional differential systems subject to Gaussian white noise is established.In particular,it is proved that in the GE-GDEE corresponding to the state-quantities of interest,the intrinsic drift coefficient is a time-varying linear function,and can be analytically determined.In this sense,an alternative low-dimensional equivalent linear integer-order differential system with exact closed-form coefficients for the original highdimensional linear fractional differential system can be constructed such that their transient PDFs are identical.Specifically,for a multi-dimensional linear fractional differential system,if only one or two quantities are of interest,GE-GDEE is only in one or two dimensions,and the surrogate system would be a one-or two-dimensional linear integer-order system.Several examples are studied to assess the merit of the proposed method.Though presently the closed-form intrinsic drift coefficient is only available for linear stochastic fractional differential systems,the findings in the present paper provide a remarkable demonstration on the existence and eligibility of GE-GDEE for the case that the original high-dimensional system itself is non-Markovian,and provide insights for the physical-mechanism-informed determination of intrinsic drift and diffusion coefficients of GE-GDEE of more generic complex nonlinear systems.
文摘Nyiragongo volcanic eruptions of 1977 and 2002 emitted silica-undersaturated lavas named melilite-nephelinites with microlithic to sub-porphyritic textures, and consisted of olivine, clinopyroxene (augite), phlogopite, melilite, magnetite, and rare plagioclases. This melilite-nephelinite as an evolved rock, shows low SiO<sub>2</sub> (38.40 - 39.52 wt%) and MgO (3.10 - 4.01 wt%), and relatively high FeOt (13.76 - 14.10 wt%), Al<sub>2</sub>O<sub>3</sub> (15.01 - 16.48 wt%), CaO (11.00 - 12.29 wt%) and Na<sub>2</sub>O + K<sub>2</sub>O (10.34 - 11.85 wt%). Unlike LA-ICP-MS on silicate melt inclusions (SMIs) hosted in augite show a pristine melt of picrobasaltic (low Ti-picrite) rock poor in SiO<sub>2</sub> (31.14 - 32.26 wt%), FeOt (2.19 - 2.79 wt%), Al<sub>2</sub>O<sub>3</sub> (8.01 - 9.57 wt%), and Na<sub>2</sub>O + K<sub>2</sub>O (2.34 - 3.05 wt%), while enriched in MgO (20.27 - 28.63 wt%), and CaO (24.95 - 33.17 wt%). The sums (∑REEs) for lavas and SMIs are ranging 712 - 799 and 43 - 119 ppm respectively. REE contracted multi-element patterns showed a W-feature for most lavas except for SMIs. High Rb/Sr, and low Ba/Rb, Zr/Nb, and Sm/Hf ratios of lavas suggest a phlogopite-rich source of materials. .
基金the financial support from the National Natural Science Foundation of China(No.52109119)the Guangxi Natural Science Foundation(No.2021GXNSFBA075030)+2 种基金the Guangxi Science and Technology Project(No.Guike AD20325002)the Chinese Postdoctoral Science Fund Project(No.2022M723408)the Open Research Fund of State Key Laboratory of Simulation and Regulation of Water Cycle in River Basin(China Institute of Water Resources and Hydropower Research)(No.IWHR-SKL-202202)。
文摘The far-field microdynamic disturbance caused by the excavation of deep mineral resources and underground engineering can induce surrounding rock damage in high-stress conditions and even lead to disasters.However,the mechanical properties and damage/fracture evolution mechanisms of deep rock induced by microdynamic disturbance under three-dimensional stress states are unclear.Therefore,a true triaxial multilevel disturbance test method is proposed,which can completely simulate natural geostress,excavation stress redistribution(such as stress unloading,concentration and rotation),and subsequently the microdynamic disturbance triggering damaged rock failure.Based on a dynamic true triaxial test platform,true triaxial microdynamic disturbance tests under different frequency and amplitudes were carried out on monzogabbro.The results show that increasing amplitude or decreasing frequency diminishes the failure strength of monzogabbro.Deformation modulus gradually decreases during disturbance failure.As frequency and amplitude increase,the degradation rate of deformation modulus decreases slightly,disturbance dissipated energy increases significantly,and disturbance deformation anisotropy strengthens obviously.A damage model has been proposed to quantitatively characterize the disturbance-induced damage evolution at different frequency and amplitude under true triaxial stress.Before disturbance failure,the micro-tensile crack mechanism is dominant,and the micro-shear crack mechanism increases significantly at failure.With the increase of amplitude and frequency,the micro-shear crack mechanism increases.When approaching disturbance failure,the acoustic emission fractal dimension changes from a stable value to local large oscillation,and finally increases sharply to a high value at failure.Finally,the disturbance-induced failure mechanism of surrounding rock in deep engineering is clearly elucidated.
基金supported by the Natural Science Foundation of Hebei Province(Grant No.E2022209039)Key Research Project of North China University of Science and Technology(Grant No.ZD-YG-202301)Tangshan Talent Funding Project(Grant No.A202202007).
文摘A series of carbon nitride(CN)materials represented by graphitic carbon nitride(g-C3N4)have been widely used in bioimaging,biosensing,and other fields in recent years due to their nontoxicity,low cost,and high luminescent quantum efficiency.What is more attractive is that the luminescent properties such as wavelength and intensity can be regulated by controlling the structure at the molecular level.Hence,it is time to summarize the related research on CN structural evolution and make a prospect on future developments.In this review,we first summarize the research history and multiple structural evolution of CN.Then,the progress of improving the luminescence performance of CN through structural evolution was discussed.Significantly,the relationship between CN structure evolution and energy conversion in the forms of photoluminescence,chemiluminescence,and electrochemiluminescence was reviewed.Finally,key challenges and opportunities such as nanoscale dispersion strategy,luminous efficiency improving methods,standardization evaluation,and macroscopic preparation of CN are highlighted.