Excess molar volume(V E) data on binary liquid mixtures of methylheptenone (MHO) with methanol, ethanol, n-propanol or n-butanol have been determined from the density measurements at 298.15 K and atmospheric pressure...Excess molar volume(V E) data on binary liquid mixtures of methylheptenone (MHO) with methanol, ethanol, n-propanol or n-butanol have been determined from the density measurements at 298.15 K and atmospheric pressure. The values of V E in all the systems over the entire composition range are quantified by the Redlich-Kister equation. The effects of the chain length of alkanols on V E are discussed.展开更多
The lattice parameters a and the molar volumes Km of Pb-based a-phase solid solutions in the Pb-Sn-Cd ternary system were determined by means of X-ray diffraction. The lattice parameters a vary linearly with the molar...The lattice parameters a and the molar volumes Km of Pb-based a-phase solid solutions in the Pb-Sn-Cd ternary system were determined by means of X-ray diffraction. The lattice parameters a vary linearly with the molar fractions, the molar volumes show a positive deviation from the ideal solution behaviour, and the contribution of the solute Cd to the excess molar volumes V is much larger than that of the solute Sn. According to Vegard' s law orsub-regular solution model, the relationship between the experimental data of a or Vm andthe compositions of alloy is obtained by the mathematic regressive method, the prediction precisions of the both formulae are within the limits of experiment error.展开更多
The present work is focusing on the synthesization and physico-chemical properties of Jatropha curcas biodiesel with diesel and alcohols.The densities of binary diesel(2)+1-alkanols(C_(3) or C_(4))(3)and ternary Jatro...The present work is focusing on the synthesization and physico-chemical properties of Jatropha curcas biodiesel with diesel and alcohols.The densities of binary diesel(2)+1-alkanols(C_(3) or C_(4))(3)and ternary Jatropha curcas biodiesel(1)+diesel(2)+1-alkanols(C_(3)or C_(4))(3)blends have been reported over full range of composition at temperatures within range 288.15 to 313.15 K.Also densities of Jatropha curcas biodiesel(1)+diesel or 1-alkanols(C_(3) or C_(4))(2)blends have been measured at 313.15 K.Excess molar volumes,V^E,V^E_(123)of binary and ternary blends were calculated from the measured data and the derived properties were correlated to composition using Redlich-Kister equation.A reasonable agreement was found between the measured and estimated values.Further,densities and excess molar volumes data were reasoned to discuss molecular interactions taking into consideration effect of composition and temperature.展开更多
Excess molar volumes Vm^E and kinematic viscosities v have been measured as a function of composition for binary mixtures of propylene glycol monomethyl ether (1-methoxy-2-propanol), MeOCH2CH(OH)Me, propylene glyc...Excess molar volumes Vm^E and kinematic viscosities v have been measured as a function of composition for binary mixtures of propylene glycol monomethyl ether (1-methoxy-2-propanol), MeOCH2CH(OH)Me, propylene glycol monoethyl ether (1-ethoxy-2-propanol), EtOCH2CH(OH)Me, propylene glycol monopropyl ether (1-propoxy-2-propanol), PrOCH2CH(OH)Me, propylene glycol monobutyl ether (1-butoxy-2-propanol), BuOCH2CH(OH)Me, and propylene glycol tert-butyl ether (1-tert-butoxy-2-propanol), t-BuOCH2CH(OH)Me with 1-butanol, and 2-butanol, at 298.15 K and atmospheric pressure. The excess molar volumes are negative across the entire range of composition for all the systems with 1-butanol, and positive for the systems 2-butanol+ 1-methoxy-2-propanol, and +1-propoxy-2-propanol, negative for the systems 2-butanol+1-butoxy-2-propanol, and change sign for the systems 2-butanol+ 1-ethoxy-2-propanol, and + 1-tert-butoxy-2-propanol. From the experimental data, the deviation in dynamic viscosity η from ∑χiηi has been calculated. Both excess molar volumes and viscosity deviations have been correlated using a Redlich-Kister type polynomial equation by the method of least-squares for the estimation of the binary coefficients and the standard errors.展开更多
The thermodynamical properties of MgCl_2 in KCI-MgCl_2-LiCl molten electrolytes containing MgCl_2 below 0.5 (mole fraction, the same below) have been determined from the interchange energies of two binary systems KCI...The thermodynamical properties of MgCl_2 in KCI-MgCl_2-LiCl molten electrolytes containing MgCl_2 below 0.5 (mole fraction, the same below) have been determined from the interchange energies of two binary systems KCI-MgCl_2 and LiCI-MgCl_2, by means of a model on the assumptions that the electrolytes in the solution are treated as independent particles instead of their ion forms and the interchange energy between the component pair KCI-LiCl is ignored when compared with those of component pairs KCl-MgCl_2 and MgCl_2-LiCl. The interchange energies, wKCl-MgCl_2 and wMgcCl_2-Licl, are obtained as-70000 and -13800 J.mol-1, from the corresponding binary solutions, respectively.展开更多
Density, viscosity and sound velocity of six binary liquid mixtures of methanol, ethanol, propanol, butanol, hexanol and octanol with 1,4-dioxane have been measured over the entire range of composition at temperature ...Density, viscosity and sound velocity of six binary liquid mixtures of methanol, ethanol, propanol, butanol, hexanol and octanol with 1,4-dioxane have been measured over the entire range of composition at temperature 303.15K. From the experimental densities, viscosities and sound velocity, the excess molar volume (<i>V<sup>E</sup></i>), deviation in viscosity (Δ<i>η</i>) and deviation in isentropic compressibility (Δ<i>K<sub>S</sub></i>) have been calculated. The results have been used to discuss the nature and strength of intermolecular interactions in these mixtures.展开更多
Excess molar enthalpies,H^E,for the binary mixtures of 2-pentanol with n-alkanes(n-heptane,n-octane,and nnonane)have been determined at three different temperatures T=(293.15,298.15 and 303.15)K and normal atmospheric...Excess molar enthalpies,H^E,for the binary mixtures of 2-pentanol with n-alkanes(n-heptane,n-octane,and nnonane)have been determined at three different temperatures T=(293.15,298.15 and 303.15)K and normal atmospheric pressure over the entire composition range using a Calvet microcalorimeter.All mixtures show endothermic mixing with the maximum values of the excess enthalpies occurring in the n-alkane-rich region.The H^Edata are smoothed using Redlich–Kister equation.The applicability of the Treszczanowicz–Benson,ERAS,Renon–Prausnitz and Chen–Bagley models to correlate H^Eof studied mixtures is tested,and the agreement between experimental and theoretical results is satisfactory.Each model includes a self-association equilibrium constant that represents hydrogen bonding and an adjustable parameter that reflects physical interactions.展开更多
Densities of methanol+trimethyl phosphate binary mixtures were measured over a temperature range of (293.15 to 333.15)K at atmospheric pressure. From these data, excess molar volume(VE) was calculated. Viscositie...Densities of methanol+trimethyl phosphate binary mixtures were measured over a temperature range of (293.15 to 333.15)K at atmospheric pressure. From these data, excess molar volume(VE) was calculated. Viscosities of trimethyl phosphate were also measured over a temperature range of (283.15 to 373.15)K and the data were fitted to the Andrade equation. The density data were fitted to a second-order polynomial. The excess molar volumes were fitted to the Redlich-Kister equation using a nonlinear regression method. Results show that the density and viscosity gradually decreases with the increase of temperature.展开更多
New experimental data of densities and surface tensions are presented for the binary mixtures of the ionic liquid 1-ethyl-3- methyl imidazolium nitrate ([EMIM]NO3) with methanol and ethanol. Measurements were perfor...New experimental data of densities and surface tensions are presented for the binary mixtures of the ionic liquid 1-ethyl-3- methyl imidazolium nitrate ([EMIM]NO3) with methanol and ethanol. Measurements were performed at 298.15 K and atmospheric pressure, covering the whole composition range. Excess molar volumes VE and the surface tension deviations 8y have been determined. For the excess molar volumes of binary mixture, there is a region of negative VE at low IL mole fraction, passing through a minimum and then VE increases and becomes positive, showing maximum at higher IL mole fraction. It is shown that the surface tension deviations ~y of [EMIM]NO3 + methanol system are positive but those of [EMIM]NO3 + ethanol system are negative over the entire mole fraction range.展开更多
基金Supported by the National Natural Science Foundation of China( No.2 99760 3 5 ) and the Zhejiang Provincial NatioralScience Foundation of China( No.2 990 3 5 )
文摘Excess molar volume(V E) data on binary liquid mixtures of methylheptenone (MHO) with methanol, ethanol, n-propanol or n-butanol have been determined from the density measurements at 298.15 K and atmospheric pressure. The values of V E in all the systems over the entire composition range are quantified by the Redlich-Kister equation. The effects of the chain length of alkanols on V E are discussed.
文摘The lattice parameters a and the molar volumes Km of Pb-based a-phase solid solutions in the Pb-Sn-Cd ternary system were determined by means of X-ray diffraction. The lattice parameters a vary linearly with the molar fractions, the molar volumes show a positive deviation from the ideal solution behaviour, and the contribution of the solute Cd to the excess molar volumes V is much larger than that of the solute Sn. According to Vegard' s law orsub-regular solution model, the relationship between the experimental data of a or Vm andthe compositions of alloy is obtained by the mathematic regressive method, the prediction precisions of the both formulae are within the limits of experiment error.
文摘The present work is focusing on the synthesization and physico-chemical properties of Jatropha curcas biodiesel with diesel and alcohols.The densities of binary diesel(2)+1-alkanols(C_(3) or C_(4))(3)and ternary Jatropha curcas biodiesel(1)+diesel(2)+1-alkanols(C_(3)or C_(4))(3)blends have been reported over full range of composition at temperatures within range 288.15 to 313.15 K.Also densities of Jatropha curcas biodiesel(1)+diesel or 1-alkanols(C_(3) or C_(4))(2)blends have been measured at 313.15 K.Excess molar volumes,V^E,V^E_(123)of binary and ternary blends were calculated from the measured data and the derived properties were correlated to composition using Redlich-Kister equation.A reasonable agreement was found between the measured and estimated values.Further,densities and excess molar volumes data were reasoned to discuss molecular interactions taking into consideration effect of composition and temperature.
文摘Excess molar volumes Vm^E and kinematic viscosities v have been measured as a function of composition for binary mixtures of propylene glycol monomethyl ether (1-methoxy-2-propanol), MeOCH2CH(OH)Me, propylene glycol monoethyl ether (1-ethoxy-2-propanol), EtOCH2CH(OH)Me, propylene glycol monopropyl ether (1-propoxy-2-propanol), PrOCH2CH(OH)Me, propylene glycol monobutyl ether (1-butoxy-2-propanol), BuOCH2CH(OH)Me, and propylene glycol tert-butyl ether (1-tert-butoxy-2-propanol), t-BuOCH2CH(OH)Me with 1-butanol, and 2-butanol, at 298.15 K and atmospheric pressure. The excess molar volumes are negative across the entire range of composition for all the systems with 1-butanol, and positive for the systems 2-butanol+ 1-methoxy-2-propanol, and +1-propoxy-2-propanol, negative for the systems 2-butanol+1-butoxy-2-propanol, and change sign for the systems 2-butanol+ 1-ethoxy-2-propanol, and + 1-tert-butoxy-2-propanol. From the experimental data, the deviation in dynamic viscosity η from ∑χiηi has been calculated. Both excess molar volumes and viscosity deviations have been correlated using a Redlich-Kister type polynomial equation by the method of least-squares for the estimation of the binary coefficients and the standard errors.
基金National Natural Science Foundation of China!No.59774028
文摘The thermodynamical properties of MgCl_2 in KCI-MgCl_2-LiCl molten electrolytes containing MgCl_2 below 0.5 (mole fraction, the same below) have been determined from the interchange energies of two binary systems KCI-MgCl_2 and LiCI-MgCl_2, by means of a model on the assumptions that the electrolytes in the solution are treated as independent particles instead of their ion forms and the interchange energy between the component pair KCI-LiCl is ignored when compared with those of component pairs KCl-MgCl_2 and MgCl_2-LiCl. The interchange energies, wKCl-MgCl_2 and wMgcCl_2-Licl, are obtained as-70000 and -13800 J.mol-1, from the corresponding binary solutions, respectively.
文摘Density, viscosity and sound velocity of six binary liquid mixtures of methanol, ethanol, propanol, butanol, hexanol and octanol with 1,4-dioxane have been measured over the entire range of composition at temperature 303.15K. From the experimental densities, viscosities and sound velocity, the excess molar volume (<i>V<sup>E</sup></i>), deviation in viscosity (Δ<i>η</i>) and deviation in isentropic compressibility (Δ<i>K<sub>S</sub></i>) have been calculated. The results have been used to discuss the nature and strength of intermolecular interactions in these mixtures.
文摘Excess molar enthalpies,H^E,for the binary mixtures of 2-pentanol with n-alkanes(n-heptane,n-octane,and nnonane)have been determined at three different temperatures T=(293.15,298.15 and 303.15)K and normal atmospheric pressure over the entire composition range using a Calvet microcalorimeter.All mixtures show endothermic mixing with the maximum values of the excess enthalpies occurring in the n-alkane-rich region.The H^Edata are smoothed using Redlich–Kister equation.The applicability of the Treszczanowicz–Benson,ERAS,Renon–Prausnitz and Chen–Bagley models to correlate H^Eof studied mixtures is tested,and the agreement between experimental and theoretical results is satisfactory.Each model includes a self-association equilibrium constant that represents hydrogen bonding and an adjustable parameter that reflects physical interactions.
文摘Densities of methanol+trimethyl phosphate binary mixtures were measured over a temperature range of (293.15 to 333.15)K at atmospheric pressure. From these data, excess molar volume(VE) was calculated. Viscosities of trimethyl phosphate were also measured over a temperature range of (283.15 to 373.15)K and the data were fitted to the Andrade equation. The density data were fitted to a second-order polynomial. The excess molar volumes were fitted to the Redlich-Kister equation using a nonlinear regression method. Results show that the density and viscosity gradually decreases with the increase of temperature.
基金supported by the National Natural Science Foundation of China(No.20776037)the Natural Science Foundation of Hebei Province(No.B2012208084)
文摘New experimental data of densities and surface tensions are presented for the binary mixtures of the ionic liquid 1-ethyl-3- methyl imidazolium nitrate ([EMIM]NO3) with methanol and ethanol. Measurements were performed at 298.15 K and atmospheric pressure, covering the whole composition range. Excess molar volumes VE and the surface tension deviations 8y have been determined. For the excess molar volumes of binary mixture, there is a region of negative VE at low IL mole fraction, passing through a minimum and then VE increases and becomes positive, showing maximum at higher IL mole fraction. It is shown that the surface tension deviations ~y of [EMIM]NO3 + methanol system are positive but those of [EMIM]NO3 + ethanol system are negative over the entire mole fraction range.