Tuning of the magnetic interaction plays the vital role in reducing the clustering of magnetic dopant in diluted magnetic semiconductors(DMS).Due to the not well understood magnetic mechanism and the interplay between...Tuning of the magnetic interaction plays the vital role in reducing the clustering of magnetic dopant in diluted magnetic semiconductors(DMS).Due to the not well understood magnetic mechanism and the interplay between different magnetic mechanisms,no efficient and universal tuning strategy is proposed at present.Here,the magnetic interactions and formation energies of isovalent-doped(Mn) and aliovalent(Cr)-doped LiZnAs are studied based on density functional theory(DFT).It is found that the dopant–dopant distance-dependent magnetic interaction is highly sensitive to the carrier concentration and carrier type and can only be explained by the interplay between two magnetic mechanisms,i.e.,superexchange and Zener’s p–d exchange model.Thus,the magnetic behavior and clustering of magnetic dopant can be tuned by the interplay between two magnetic mechanisms.The insensitivity of the tuning effect to U parameter suggests that our strategy could be universal to other DMS.展开更多
We have successfully developed cryogen-free dilution refrigerators with medium cooling power that can be applied to quantum experiments. Breakthroughs have been made in some key technologies and components of heat swi...We have successfully developed cryogen-free dilution refrigerators with medium cooling power that can be applied to quantum experiments. Breakthroughs have been made in some key technologies and components of heat switches and dilution units. Our prototype has been running continuously and stably for more than 100 hours below 10 m K, with a minimum temperature of 7.6 m K and a cooling power of 450 μW at 100 m K. At the same time, we have also made progress in the application of dilution refrigerators, such as quantum computing, low-temperature detector, and magnet integration. These indicators and test results indicate good prospects for application in physics, astronomy, and quantum information.展开更多
Electronic interactions of the Group 2A elements with magnesium have been studied through the dilute solid solutions in binary Mg-Ca,Mg-Sr and Mg-Ba systems.This investigation incorporated the difference in the‘Work ...Electronic interactions of the Group 2A elements with magnesium have been studied through the dilute solid solutions in binary Mg-Ca,Mg-Sr and Mg-Ba systems.This investigation incorporated the difference in the‘Work Function'(ΔWF)measured via Kelvin Probe Force Microscopy(KPFM),as a property directly affected by interatomic bond types,i.e.the electronic structure,nanoindentation measurements,and Stacking Fault Energy values reported in the literature.It was shown that the nano-hardness of the solid-solutionα-Mg phase changed in the order of Mg-Ca>Mg-Sr>Mg-Ba.Thus,it was shown,by also considering the nano-hardness levels,that SFE of a solid-solution is closely correlated with its‘Work Function'level.Nano-hardness measurements on the eutectics andΔWF difference between eutectic phases enabled an assessment of the relative bond strength and the pertinent electronic structures of the eutectics in the three alloys.Correlation withΔWF and at least qualitative verification of those computed SFE values with some experimental measurement techniques were considered important as those computational methods are based on zero Kelvin degree,relatively simple atomic models and a number of assumptions.As asserted by this investigation,if the results of measurement techniques can be qualitatively correlated with those of the computational methods,it can be possible to evaluate the electronic structures in alloys,starting from binary systems,going to ternary and then multi-elemental systems.Our investigation has shown that such a qualitative correlation is possible.After all,the SFE values are not treated as absolute values but rather become essential in comparative investigations when assessing the influences of alloying elements at a fundamental level,that is,free electron density distributions.Our study indicated that the principles of‘electronic metallurgy'in developing multi-elemental alloy systems can be followed via practical experimental methods,i.e.ΔWF measurements using KPFM and nanoindentation.展开更多
The band structure,DOSs,and optical properties of(Y_(0.75)Ca_(0.25))(Cu_(0.75)Mn_(0.25))SO,including dielectric function,absorption function,reflection function,and energy loss spectrum were studied by using the first...The band structure,DOSs,and optical properties of(Y_(0.75)Ca_(0.25))(Cu_(0.75)Mn_(0.25))SO,including dielectric function,absorption function,reflection function,and energy loss spectrum were studied by using the first-principles calculation.The calculation results indicate that(Y_(0.75)Ca_(0.25))(Cu_(0.75)Mn_(0.25))SO is a direct bandgap semiconductor with a bandgap of 1.1 eV.The Fermi surface is asymmetric and exhibits spin splitting phenomenon.The new type of dilute magnetic semiconductor(Y_(0.75)Ca_(0.25))(Cu_(0.75)Mn_(0.25))SO exhibits significant light loss around 70 eV,with light reflection gradually increasing after 30 eV,and light absorption mainly occurring around 8-30 eV.These results also provide a basis for the discovery of more types of 1111 phase new dilute magnetic semiconductors in the future.展开更多
The laminar combustion characteristics of CH_(4)/air premixed flames with CO_(2) addition are systemically studied.Experimental measurements and numerical simulations of the laminar burning velocity(LBV)are performed ...The laminar combustion characteristics of CH_(4)/air premixed flames with CO_(2) addition are systemically studied.Experimental measurements and numerical simulations of the laminar burning velocity(LBV)are performed in CH_(4)/CO_(2)/Air flames with various CO_(2) doping ratio under equivalence ratios of 1.0–1.4.GRI 3.0 mech and Aramco mech are employed for predicting LBV,adiabatic flame temperature(AFT),important intermediate radicals(CH_(3),H,OH,O)and NO_(x) emissions(NO,NO_(2),N2O),as well as the sensitivity analysis is also conducted.The detail analysis of experiment and simulation reveals that as the CO_(2) addition increases from 0%to 40%,the LBVs and AFTs decrease monotonously.Under the same CO_(2) doping ratio,the LBVs and AFTs increase first and then decrease with the increase of equivalence ratio,and the maximum of LBV is reached at equivalence ratio of 1.05.The mole fraction tendency of important intermediates and NO_(x) with equivalence ratio and CO_(2) doping ratio are similar to the LBVs and AFTs.Reaction H+O_(2)⇔O+OH is found to be responsible for the promotion of the generation of important intermediates and NO_(x) under the equivalence ratios and CO_(2) addition through sensitivity analysis.The sensitivity coefficients of elementary reactions that the increasing of CO_(2) doping ratio promotes or inhibits formation of intermediate radicals and NO_(x) decreases.展开更多
Due to the difference in density between the discharge effluent and coastal water,partially treated wastewater is often discharged into the marine environment as a buoyant jet via submarine outfalls with multiport dif...Due to the difference in density between the discharge effluent and coastal water,partially treated wastewater is often discharged into the marine environment as a buoyant jet via submarine outfalls with multiport diffusers.The dilution characteristics of effluent discharge(dual buoyant jets)in a wavy cross-flow environment were studied in a laboratory.The planar laser-induced fluorescence technique was used to obtain the concentration data of the jets.The effects of different environmental variables on the diffusion and dilution characteristics of the jets were examined through physical experiments,dimensional analysis,and empirical formulations.It was found that the dilution process of the dual jets could be divided into two components:the original jet component and the effluent cloud component.The jet-to-current velocity ratio was the main parameter affecting the concentration levels of the effluent cloud.The merging of the two jets increased the jet concentration in the flow field.When the jets traveled further downstream,the axial dilution increased gradually and then increased significantly along the axis.Under the effects of strong waves,the concentration contours branched into two peaks,and the mean dilution became more significant than under the effects of weak waves.Therefore,the dilution of the effluent discharge was expected to be significant under strong wave effects because the hydrodynamic force increased.A dilution equation was derived to improve our understanding of the dilution process of buoyant jets in a wavy cross-flow environment.This equation was used to determine the influences of the jet-to-current velocity ratio,wave-to-current velocity ratio,and Strouhal number on the minimum jet dilution.It revealed that the wave and buoyancy effects in effluent discharges were significant.展开更多
Considering the importance of the tomato crop and the high costs for controlling Meloidogyne incognita with resistant cultivar or nematicides, it is necessary for the search of new alternatives to manage the root-knot...Considering the importance of the tomato crop and the high costs for controlling Meloidogyne incognita with resistant cultivar or nematicides, it is necessary for the search of new alternatives to manage the root-knot disease. The homeopathy may be an alternative way of control, by inducing plant resistance. This study aimed to evaluate the influence of the homeopathic product Cina at dynamizations 12, 24, 50, 100, 200, and 400 CH (centesimal hahnemanian dilutions) on the number of root galls, eggs and second-stage juveniles (J2) present in the roots of tomato and soil, as well on the growth of tomato plants. The Cina demonstrated effectiveness in stimulating root development, once the results of root volume were higher in homeopathic treatments than those in the control. Cina 100 CH also favored the growth of the stalk diameter of the plants. However, the homeopathic product showed no nematostatic nor nematicide effects. The potentized Cina is capable to induce tomato growth besides the presence of M. incognita infecting the roots, with no nematotoxic effects.展开更多
Introduction: β<sub>2</sub>-microglobulin and prolactin are medium-molecular-weight toxins. We believe that the rate of removal of these molecules, using filters with two different surfaces, in post- and ...Introduction: β<sub>2</sub>-microglobulin and prolactin are medium-molecular-weight toxins. We believe that the rate of removal of these molecules, using filters with two different surfaces, in post- and pre-dilution haemodiafiltration, will be of interest to the literature. Methods: We studied, in 12 haemodialyzed patients, the removal of those, with filter with surface of 2.5 m<sup>2</sup> (Group A) or 2.1 m<sup>2</sup> (Group B) with post-dilution haemodiafiltration, and with a filter with surface 2.5 m<sup>2</sup> with pre-dilution (Group C). Results: Satisfactory removal of β<sub>2</sub>-microglobulin (best with post-dilution) was found, and a good rate of removal of prolactin without the filter surface played a role in both cases. Conclusion: The elimination of β<sub>2</sub>-microglobulin in post-dilution is not affected by the filter surface area. Pre-dilution achieves removal of β<sub>2</sub>-microglobulin, less than that of post-dilution. Prolactin was removed satisfactorily regardless of the filter surface in post-dilution, and its removal appears to be less than that of β<sub>2</sub>-microglobulin.展开更多
基金Project supported by the Natural Science Foundation of Shaanxi Province of China(Grant No.2013JQ1018)the Natural Science Foundation of Department of Education of Shaanxi Province of China(Grant No.15JK1759)+3 种基金the Double First-class University Construction Project of Northwest Universitythe financial support of Chinese University of Hong Kong(CUHK)(Grant No.4053084)University Grants Committee of Hong Kong,China(Grant No.24300814)start-up funding of CUHK。
文摘Tuning of the magnetic interaction plays the vital role in reducing the clustering of magnetic dopant in diluted magnetic semiconductors(DMS).Due to the not well understood magnetic mechanism and the interplay between different magnetic mechanisms,no efficient and universal tuning strategy is proposed at present.Here,the magnetic interactions and formation energies of isovalent-doped(Mn) and aliovalent(Cr)-doped LiZnAs are studied based on density functional theory(DFT).It is found that the dopant–dopant distance-dependent magnetic interaction is highly sensitive to the carrier concentration and carrier type and can only be explained by the interplay between two magnetic mechanisms,i.e.,superexchange and Zener’s p–d exchange model.Thus,the magnetic behavior and clustering of magnetic dopant can be tuned by the interplay between two magnetic mechanisms.The insensitivity of the tuning effect to U parameter suggests that our strategy could be universal to other DMS.
基金supported by the Beijing Commission of Science and Technology(Grant No.Z211100004021012)Special Research Assistant Program of the Chinese Academy of Sciences(Grant No.E3VP021RX4)。
文摘We have successfully developed cryogen-free dilution refrigerators with medium cooling power that can be applied to quantum experiments. Breakthroughs have been made in some key technologies and components of heat switches and dilution units. Our prototype has been running continuously and stably for more than 100 hours below 10 m K, with a minimum temperature of 7.6 m K and a cooling power of 450 μW at 100 m K. At the same time, we have also made progress in the application of dilution refrigerators, such as quantum computing, low-temperature detector, and magnet integration. These indicators and test results indicate good prospects for application in physics, astronomy, and quantum information.
基金financial support for this work provided by Eski sehir Technical University Scientific Research Projects Unit with Grant Number 20DRP059support provided by the Turkish Ministry of Science,Industry and Technology under the SANTEZ Project 0286.STZ.2013±2。
文摘Electronic interactions of the Group 2A elements with magnesium have been studied through the dilute solid solutions in binary Mg-Ca,Mg-Sr and Mg-Ba systems.This investigation incorporated the difference in the‘Work Function'(ΔWF)measured via Kelvin Probe Force Microscopy(KPFM),as a property directly affected by interatomic bond types,i.e.the electronic structure,nanoindentation measurements,and Stacking Fault Energy values reported in the literature.It was shown that the nano-hardness of the solid-solutionα-Mg phase changed in the order of Mg-Ca>Mg-Sr>Mg-Ba.Thus,it was shown,by also considering the nano-hardness levels,that SFE of a solid-solution is closely correlated with its‘Work Function'level.Nano-hardness measurements on the eutectics andΔWF difference between eutectic phases enabled an assessment of the relative bond strength and the pertinent electronic structures of the eutectics in the three alloys.Correlation withΔWF and at least qualitative verification of those computed SFE values with some experimental measurement techniques were considered important as those computational methods are based on zero Kelvin degree,relatively simple atomic models and a number of assumptions.As asserted by this investigation,if the results of measurement techniques can be qualitatively correlated with those of the computational methods,it can be possible to evaluate the electronic structures in alloys,starting from binary systems,going to ternary and then multi-elemental systems.Our investigation has shown that such a qualitative correlation is possible.After all,the SFE values are not treated as absolute values but rather become essential in comparative investigations when assessing the influences of alloying elements at a fundamental level,that is,free electron density distributions.Our study indicated that the principles of‘electronic metallurgy'in developing multi-elemental alloy systems can be followed via practical experimental methods,i.e.ΔWF measurements using KPFM and nanoindentation.
文摘The band structure,DOSs,and optical properties of(Y_(0.75)Ca_(0.25))(Cu_(0.75)Mn_(0.25))SO,including dielectric function,absorption function,reflection function,and energy loss spectrum were studied by using the first-principles calculation.The calculation results indicate that(Y_(0.75)Ca_(0.25))(Cu_(0.75)Mn_(0.25))SO is a direct bandgap semiconductor with a bandgap of 1.1 eV.The Fermi surface is asymmetric and exhibits spin splitting phenomenon.The new type of dilute magnetic semiconductor(Y_(0.75)Ca_(0.25))(Cu_(0.75)Mn_(0.25))SO exhibits significant light loss around 70 eV,with light reflection gradually increasing after 30 eV,and light absorption mainly occurring around 8-30 eV.These results also provide a basis for the discovery of more types of 1111 phase new dilute magnetic semiconductors in the future.
基金The authors would like to thank the National Natural Science Foundation of China(52176095)Anhui Provincial Natural Science Foundation(2008085J25)the Project of support program for outstanding young people in Colleges and Universities(gxyqZD201830)for their financial support of this study.
文摘The laminar combustion characteristics of CH_(4)/air premixed flames with CO_(2) addition are systemically studied.Experimental measurements and numerical simulations of the laminar burning velocity(LBV)are performed in CH_(4)/CO_(2)/Air flames with various CO_(2) doping ratio under equivalence ratios of 1.0–1.4.GRI 3.0 mech and Aramco mech are employed for predicting LBV,adiabatic flame temperature(AFT),important intermediate radicals(CH_(3),H,OH,O)and NO_(x) emissions(NO,NO_(2),N2O),as well as the sensitivity analysis is also conducted.The detail analysis of experiment and simulation reveals that as the CO_(2) addition increases from 0%to 40%,the LBVs and AFTs decrease monotonously.Under the same CO_(2) doping ratio,the LBVs and AFTs increase first and then decrease with the increase of equivalence ratio,and the maximum of LBV is reached at equivalence ratio of 1.05.The mole fraction tendency of important intermediates and NO_(x) with equivalence ratio and CO_(2) doping ratio are similar to the LBVs and AFTs.Reaction H+O_(2)⇔O+OH is found to be responsible for the promotion of the generation of important intermediates and NO_(x) under the equivalence ratios and CO_(2) addition through sensitivity analysis.The sensitivity coefficients of elementary reactions that the increasing of CO_(2) doping ratio promotes or inhibits formation of intermediate radicals and NO_(x) decreases.
基金supported by the Fundamental Research Funds for the Central Universities of China(Grant No.B200202057)and the National Natural Science Foundation of China(Grant No.51979076)。
文摘Due to the difference in density between the discharge effluent and coastal water,partially treated wastewater is often discharged into the marine environment as a buoyant jet via submarine outfalls with multiport diffusers.The dilution characteristics of effluent discharge(dual buoyant jets)in a wavy cross-flow environment were studied in a laboratory.The planar laser-induced fluorescence technique was used to obtain the concentration data of the jets.The effects of different environmental variables on the diffusion and dilution characteristics of the jets were examined through physical experiments,dimensional analysis,and empirical formulations.It was found that the dilution process of the dual jets could be divided into two components:the original jet component and the effluent cloud component.The jet-to-current velocity ratio was the main parameter affecting the concentration levels of the effluent cloud.The merging of the two jets increased the jet concentration in the flow field.When the jets traveled further downstream,the axial dilution increased gradually and then increased significantly along the axis.Under the effects of strong waves,the concentration contours branched into two peaks,and the mean dilution became more significant than under the effects of weak waves.Therefore,the dilution of the effluent discharge was expected to be significant under strong wave effects because the hydrodynamic force increased.A dilution equation was derived to improve our understanding of the dilution process of buoyant jets in a wavy cross-flow environment.This equation was used to determine the influences of the jet-to-current velocity ratio,wave-to-current velocity ratio,and Strouhal number on the minimum jet dilution.It revealed that the wave and buoyancy effects in effluent discharges were significant.
基金Conselho Nacional de Desenvolvimento Científico e Tacnologico(CNPq)for the productivity scholarship provided to Jose R.Stangarlin
文摘Considering the importance of the tomato crop and the high costs for controlling Meloidogyne incognita with resistant cultivar or nematicides, it is necessary for the search of new alternatives to manage the root-knot disease. The homeopathy may be an alternative way of control, by inducing plant resistance. This study aimed to evaluate the influence of the homeopathic product Cina at dynamizations 12, 24, 50, 100, 200, and 400 CH (centesimal hahnemanian dilutions) on the number of root galls, eggs and second-stage juveniles (J2) present in the roots of tomato and soil, as well on the growth of tomato plants. The Cina demonstrated effectiveness in stimulating root development, once the results of root volume were higher in homeopathic treatments than those in the control. Cina 100 CH also favored the growth of the stalk diameter of the plants. However, the homeopathic product showed no nematostatic nor nematicide effects. The potentized Cina is capable to induce tomato growth besides the presence of M. incognita infecting the roots, with no nematotoxic effects.
文摘Introduction: β<sub>2</sub>-microglobulin and prolactin are medium-molecular-weight toxins. We believe that the rate of removal of these molecules, using filters with two different surfaces, in post- and pre-dilution haemodiafiltration, will be of interest to the literature. Methods: We studied, in 12 haemodialyzed patients, the removal of those, with filter with surface of 2.5 m<sup>2</sup> (Group A) or 2.1 m<sup>2</sup> (Group B) with post-dilution haemodiafiltration, and with a filter with surface 2.5 m<sup>2</sup> with pre-dilution (Group C). Results: Satisfactory removal of β<sub>2</sub>-microglobulin (best with post-dilution) was found, and a good rate of removal of prolactin without the filter surface played a role in both cases. Conclusion: The elimination of β<sub>2</sub>-microglobulin in post-dilution is not affected by the filter surface area. Pre-dilution achieves removal of β<sub>2</sub>-microglobulin, less than that of post-dilution. Prolactin was removed satisfactorily regardless of the filter surface in post-dilution, and its removal appears to be less than that of β<sub>2</sub>-microglobulin.