The microstructures and mechanical properties of C-Mn-Cr-Nb and C-Mn-Si-Nb ultra-high strength dual-phase steels were studied by scanning electron microscopy (SEM), transmission electron microscopy (TEM), and tens...The microstructures and mechanical properties of C-Mn-Cr-Nb and C-Mn-Si-Nb ultra-high strength dual-phase steels were studied by scanning electron microscopy (SEM), transmission electron microscopy (TEM), and tensile test. The results show that Si can promote the transformation of austenite (γ) to ferrite (α), enlarge the (α+γ) region, and increase the aging stability of martensite by inhibiting carbide precipitation. Adding Cr leads to the formation of retained austenite and martensite/austenite (M/A) constituents, as well as the decomposi- tion of martensite during the overaging stage. Both of the steels show higher initial strain-hardening rates and two-stage strain-hardening characteristics. The C-Mn-Si-Nb steel shows the higher strain-hardening rate than the C-Mn-Cr-Nb steel in the first stage; however, there is no significant difference in the second stage. Although the tensile strength and elongation of the two steels both exceed 1000 MPa and 15%, respectively, the comprehensive mechanical properties of the C-Mn-Si-Nb steel are superior.展开更多
The hydrogen trapping phenomena in two bainite/martensite dual-phase high strength steels(U20Si and U20DSi)were investigated by electrochemical permeation technique.The hydrogen diffusivity was calculated from data of...The hydrogen trapping phenomena in two bainite/martensite dual-phase high strength steels(U20Si and U20DSi)were investigated by electrochemical permeation technique.The hydrogen diffusivity was calculated from data of permeation delay time,and the diffusion coefficient in U20 Si is far less than that in U20 DSi.Moreover,the hydrogen diffusivity decreases as the volume percent of retained austenite increases.The experiment results show that there are different hydrogen trappings and different volume percents of retained austenite in U20 Si and U20 DSi.The retained austenite is precipitated as films.The trap binding energy for the retained austenite and hydrogen is calculated to be 40.4kJ·mol-1.展开更多
Influence of microstructure of the experimental steels on the corrosion fatigue behavior in 3.5% of NaCl aqueous solution was studied.Experimental results show that compared with the full martensite(FM)steel,the car...Influence of microstructure of the experimental steels on the corrosion fatigue behavior in 3.5% of NaCl aqueous solution was studied.Experimental results show that compared with the full martensite(FM)steel,the carbide-free bainite/martensite(CFB/M)steel has higher corrosion fatigue strength and corrosion fatigue crack threshold(ΔKthcf),and lower corrosion crack propagation rate [(da/dN)cf].展开更多
Car manufacturing is always regarded as the key industry behind sheet metal forming, and thus, the requirements of and developments in car manufacturing play a decisive role in the development of sheet metal forming. ...Car manufacturing is always regarded as the key industry behind sheet metal forming, and thus, the requirements of and developments in car manufacturing play a decisive role in the development of sheet metal forming. The automotive industry is faced with contradictory demands and requirements: better performance with lower consumption and less harmful emissions, more safety and comfort; these are extremely difficult to supply simultaneously with conventional materials and conventional manufacturing processes. The fulfillment of these often contradictory requirements is one of the main driving forces in the automotive industry and thus in the material and process developments in sheet metal forming, as well. In recent years, significant developments can be observed in the application of high-strength steels. In this respect, the application of various dual-phase steels is one of the best examples. However, the application of these highstrength steels often leads to formability and manufacturing problems. One formability problem is the springback occurring after sheet metal forming. In the current research, we have dealt mainly with advanced high-strength steels, primarily with dual-phase steels. When applying them, the springback phenomenon is one of the most critical issues. To reduce the tremendous amount of experimental work needed, we also applied numerical simulation using isotropic–kinematic hardening rules. The isotropic–kinematic hardening behavior of a given material in the applied Auto Form numerical package may be characterized with three independent material parameters c, v and K(a detailed explanation of their meaning will be given in the main part of this paper). However, we found that the material data included in simulation packages for these new high-strength steels are not fully adequate. For the determination of more reliable material parameters and to achieve better simulation results, a new testing device was developed. Numerical simulations were performed using the material parameters determined by the new device to show the sensitivity of springback behavior to these material parameters.展开更多
The expanding curves of two kinds of 1000 MPa ultra-high strength cold rolled dual phase steels,which were C-Si-Mn-Cr and C-Si-Mn-Cr-Mo steel respectively,were detected on Gleeble-1500 thermal-mechanical simulator at ...The expanding curves of two kinds of 1000 MPa ultra-high strength cold rolled dual phase steels,which were C-Si-Mn-Cr and C-Si-Mn-Cr-Mo steel respectively,were detected on Gleeble-1500 thermal-mechanical simulator at different cooling rates.Combined with metallographic and hardness methods,the continuous cooling transformation curves (CCT) of the two steels were obtained.The results showed that Mo could raise the A r3 temperature,and strongly restrain the pearlite and bainite transformation.The reason for this was the interaction that the addition of Mo could increase the chemical driving force of ferrite transformation and the activation energy for the diffusion of carbon in austenite,which could decelerate the ferrite transformation.The hardness of the two steels was similar in the cooling rates range of this experiment and got higher with the increase of the cooling rates.When the cooling rates were above 7 ℃/s,the hardness almost kept constant because the most part of the microstructure was martensite.展开更多
Two kinds of 980MPa grade cold rolled dual phase steels have been developed by designing C-Si-Mn and C-Si-Mn-Nb alloy systems.The microstructure of martensite in Nb-free steel is consisted of lath martensite and twine...Two kinds of 980MPa grade cold rolled dual phase steels have been developed by designing C-Si-Mn and C-Si-Mn-Nb alloy systems.The microstructure of martensite in Nb-free steel is consisted of lath martensite and twined martensite with the volume fraction of 67%.However,the main hard phase in Nb-containing one is twined martensit with the volume percent of 59%.The size of martensite islands in Nb-containing steel is from 1μm to 3μm,and the size of NbC precipitates is from 15nm to 40nm.As to Nb-containing steel,the yield strength,tensile strength,yield ratio and elongation are 501MPa,1035MPa,0.48 and 17.5% respectively.Futhermore,Nb-containing steel has higher working hardening rate value above the critical strain 6.5%.And it decreases slowly with increasing the strain.This is mainly because of ultrafine grain size and nano-precipitates in ferrite,which improves the compatibility of phases and reduces the stress concentration at the phase interface.展开更多
基金financially supported by the National Natural Science Foundation of China(No.50904006)the Fundamental Research Funds for the Central Universities of China(No.FRT-TP-10-001A)
文摘The microstructures and mechanical properties of C-Mn-Cr-Nb and C-Mn-Si-Nb ultra-high strength dual-phase steels were studied by scanning electron microscopy (SEM), transmission electron microscopy (TEM), and tensile test. The results show that Si can promote the transformation of austenite (γ) to ferrite (α), enlarge the (α+γ) region, and increase the aging stability of martensite by inhibiting carbide precipitation. Adding Cr leads to the formation of retained austenite and martensite/austenite (M/A) constituents, as well as the decomposi- tion of martensite during the overaging stage. Both of the steels show higher initial strain-hardening rates and two-stage strain-hardening characteristics. The C-Mn-Si-Nb steel shows the higher strain-hardening rate than the C-Mn-Cr-Nb steel in the first stage; however, there is no significant difference in the second stage. Although the tensile strength and elongation of the two steels both exceed 1000 MPa and 15%, respectively, the comprehensive mechanical properties of the C-Mn-Si-Nb steel are superior.
基金Item Sponsored by Ministry of Science and Technology of China(G1998061513)
文摘The hydrogen trapping phenomena in two bainite/martensite dual-phase high strength steels(U20Si and U20DSi)were investigated by electrochemical permeation technique.The hydrogen diffusivity was calculated from data of permeation delay time,and the diffusion coefficient in U20 Si is far less than that in U20 DSi.Moreover,the hydrogen diffusivity decreases as the volume percent of retained austenite increases.The experiment results show that there are different hydrogen trappings and different volume percents of retained austenite in U20 Si and U20 DSi.The retained austenite is precipitated as films.The trap binding energy for the retained austenite and hydrogen is calculated to be 40.4kJ·mol-1.
基金Item Sponsored by State Key Development Programfor Basic Research of China(2004CB619105)
文摘Influence of microstructure of the experimental steels on the corrosion fatigue behavior in 3.5% of NaCl aqueous solution was studied.Experimental results show that compared with the full martensite(FM)steel,the carbide-free bainite/martensite(CFB/M)steel has higher corrosion fatigue strength and corrosion fatigue crack threshold(ΔKthcf),and lower corrosion crack propagation rate [(da/dN)cf].
基金the New Hungarian Development Plan and jointly financed by the European Union and European Social Fund
文摘Car manufacturing is always regarded as the key industry behind sheet metal forming, and thus, the requirements of and developments in car manufacturing play a decisive role in the development of sheet metal forming. The automotive industry is faced with contradictory demands and requirements: better performance with lower consumption and less harmful emissions, more safety and comfort; these are extremely difficult to supply simultaneously with conventional materials and conventional manufacturing processes. The fulfillment of these often contradictory requirements is one of the main driving forces in the automotive industry and thus in the material and process developments in sheet metal forming, as well. In recent years, significant developments can be observed in the application of high-strength steels. In this respect, the application of various dual-phase steels is one of the best examples. However, the application of these highstrength steels often leads to formability and manufacturing problems. One formability problem is the springback occurring after sheet metal forming. In the current research, we have dealt mainly with advanced high-strength steels, primarily with dual-phase steels. When applying them, the springback phenomenon is one of the most critical issues. To reduce the tremendous amount of experimental work needed, we also applied numerical simulation using isotropic–kinematic hardening rules. The isotropic–kinematic hardening behavior of a given material in the applied Auto Form numerical package may be characterized with three independent material parameters c, v and K(a detailed explanation of their meaning will be given in the main part of this paper). However, we found that the material data included in simulation packages for these new high-strength steels are not fully adequate. For the determination of more reliable material parameters and to achieve better simulation results, a new testing device was developed. Numerical simulations were performed using the material parameters determined by the new device to show the sensitivity of springback behavior to these material parameters.
基金financially supported by the National High-tech Research and Development Program 863 (No.2009AA03Z518)
文摘The expanding curves of two kinds of 1000 MPa ultra-high strength cold rolled dual phase steels,which were C-Si-Mn-Cr and C-Si-Mn-Cr-Mo steel respectively,were detected on Gleeble-1500 thermal-mechanical simulator at different cooling rates.Combined with metallographic and hardness methods,the continuous cooling transformation curves (CCT) of the two steels were obtained.The results showed that Mo could raise the A r3 temperature,and strongly restrain the pearlite and bainite transformation.The reason for this was the interaction that the addition of Mo could increase the chemical driving force of ferrite transformation and the activation energy for the diffusion of carbon in austenite,which could decelerate the ferrite transformation.The hardness of the two steels was similar in the cooling rates range of this experiment and got higher with the increase of the cooling rates.When the cooling rates were above 7 ℃/s,the hardness almost kept constant because the most part of the microstructure was martensite.
文摘Two kinds of 980MPa grade cold rolled dual phase steels have been developed by designing C-Si-Mn and C-Si-Mn-Nb alloy systems.The microstructure of martensite in Nb-free steel is consisted of lath martensite and twined martensite with the volume fraction of 67%.However,the main hard phase in Nb-containing one is twined martensit with the volume percent of 59%.The size of martensite islands in Nb-containing steel is from 1μm to 3μm,and the size of NbC precipitates is from 15nm to 40nm.As to Nb-containing steel,the yield strength,tensile strength,yield ratio and elongation are 501MPa,1035MPa,0.48 and 17.5% respectively.Futhermore,Nb-containing steel has higher working hardening rate value above the critical strain 6.5%.And it decreases slowly with increasing the strain.This is mainly because of ultrafine grain size and nano-precipitates in ferrite,which improves the compatibility of phases and reduces the stress concentration at the phase interface.