Li-F granites all over the world can be represented by three end members, i. e., theNa-rich ongonite (O), the K-rich xianghualingite (X) and the Si-rich topazite (T). Charac-ters and criteria are presented for these e...Li-F granites all over the world can be represented by three end members, i. e., theNa-rich ongonite (O), the K-rich xianghualingite (X) and the Si-rich topazite (T). Charac-ters and criteria are presented for these end-member rocks. Vertical zoning in Li-F granites, asreflected by increasing normative Q and C (corundum) and decreasing ALK (K2O + Na2O)with increasing content of fluorine, can be explained using the three-end-member scheme interms of petrochemistry and norms. Considering the difference in melt structure, viscosity anddensity between the end members, in couple with the reguarities that govern the Na-K and Si-ALK segregation known from field evidence and experiments, it is suggested that the three endmembers may have resulted from liquid segregation (immiscibility) rather than from crystalfractionation as commonly believed.展开更多
MXene has shown distinctive advantages as anode materials of lithium-ion batteries. However, local surface chemistry, which was confirmed that can block ion transfer and limit redox reaction, has a significant effect ...MXene has shown distinctive advantages as anode materials of lithium-ion batteries. However, local surface chemistry, which was confirmed that can block ion transfer and limit redox reaction, has a significant effect on electrochemical performance. Herein, annealing MXene under hydrogen was employed for removing-F and turning-OH to-O terminations. We demonstrate that it improves the kinetics of Li-ion transport between the electrolyte and electrode. As a result, a lower interfacial charge transfer impedance was obtained. The electrochemical measurement exhibited that a nearly 2-fold increase of specific capacity was achieved for the annealed MXene.展开更多
LiMn 2O 4-x F x prepared by the sol gel method has a perfect crystal formation .The crystal particle size of the material was medium and distributed uniformly. The substitution of F for O increased the specific...LiMn 2O 4-x F x prepared by the sol gel method has a perfect crystal formation .The crystal particle size of the material was medium and distributed uniformly. The substitution of F for O increased the specific capacity of the material at the cost of the cycleability .The explanation of this results is that the F decreases the valence of Mn,that is,more Mn 3+ and less Mn 4+ exist in the material.The increase of Mn 3+ will improve the initial specific capacity and Mn 3+ is the original reason for Jahn Teller effect that caused the poor cycleability of the cathode material by the micro distortion of the crystal structure. In addition, the expanded measurement of the crystal lattice is also the reason for the poor cycleability.Therefore,the results of F substitution and cation substitution are opposite.If the two methods are combined,they can compensate the inability each other and the satisfactory results may be obtained.展开更多
文摘Li-F granites all over the world can be represented by three end members, i. e., theNa-rich ongonite (O), the K-rich xianghualingite (X) and the Si-rich topazite (T). Charac-ters and criteria are presented for these end-member rocks. Vertical zoning in Li-F granites, asreflected by increasing normative Q and C (corundum) and decreasing ALK (K2O + Na2O)with increasing content of fluorine, can be explained using the three-end-member scheme interms of petrochemistry and norms. Considering the difference in melt structure, viscosity anddensity between the end members, in couple with the reguarities that govern the Na-K and Si-ALK segregation known from field evidence and experiments, it is suggested that the three endmembers may have resulted from liquid segregation (immiscibility) rather than from crystalfractionation as commonly believed.
基金financial support provided by the National Key R&D Program of China (2016YFA0200400)the Jilin Province/Jilin University co-Construction Project-Funds for New Materials (SXGJSF2017-3, Branch-2/440050316A36)+4 种基金the National Natural Science Foundation of China (Grant nos. 91545119, 21761132025, 21773269 and 51372095)the Youth Innovation Promotion Association CAS (Grant no. 2015152)Strategic Priority Research Program of the Chinese Academy of Sciences Chinese Academy of Sciences (Grant nos. XDA09030103 and XDA09040203)the Program for JLU Science and Technology Innovative Research Team (JLUSTIRT)"Double-First Class" Discipline for Materials Science & Engineering
文摘MXene has shown distinctive advantages as anode materials of lithium-ion batteries. However, local surface chemistry, which was confirmed that can block ion transfer and limit redox reaction, has a significant effect on electrochemical performance. Herein, annealing MXene under hydrogen was employed for removing-F and turning-OH to-O terminations. We demonstrate that it improves the kinetics of Li-ion transport between the electrolyte and electrode. As a result, a lower interfacial charge transfer impedance was obtained. The electrochemical measurement exhibited that a nearly 2-fold increase of specific capacity was achieved for the annealed MXene.
文摘LiMn 2O 4-x F x prepared by the sol gel method has a perfect crystal formation .The crystal particle size of the material was medium and distributed uniformly. The substitution of F for O increased the specific capacity of the material at the cost of the cycleability .The explanation of this results is that the F decreases the valence of Mn,that is,more Mn 3+ and less Mn 4+ exist in the material.The increase of Mn 3+ will improve the initial specific capacity and Mn 3+ is the original reason for Jahn Teller effect that caused the poor cycleability of the cathode material by the micro distortion of the crystal structure. In addition, the expanded measurement of the crystal lattice is also the reason for the poor cycleability.Therefore,the results of F substitution and cation substitution are opposite.If the two methods are combined,they can compensate the inability each other and the satisfactory results may be obtained.
