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离聚体的结构表征 Ⅲ.EXAFS法测定含氟的铜离聚体的精细结构 被引量:7
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作者 王洪祚 杨延武 +1 位作者 钱保功 姚松年 《高分子学报》 SCIE CAS CSCD 北大核心 1990年第6期667-674,共8页
本文报道了用先进的EXAFS及ESR等方法研究了羧酸型含氟的铜(Ⅱ)离聚体离子微区的内部精细结构,结果表明,铜离聚体的离子微区主要由羧酸根桥键的双核配位结构单元及平面四方形的配位结构单元等聚集而成。在双核配位结构单元中第一层为Cu^... 本文报道了用先进的EXAFS及ESR等方法研究了羧酸型含氟的铜(Ⅱ)离聚体离子微区的内部精细结构,结果表明,铜离聚体的离子微区主要由羧酸根桥键的双核配位结构单元及平面四方形的配位结构单元等聚集而成。在双核配位结构单元中第一层为Cu^(2+)—O配位,配位数为4,配位键键长为1.96A,第二配位层为Gu^(2+)—Cu^(2+)配位,Cu^(2+)—Gu^(2+)间距为2.64A。平面四方形的配位结构单元Cu^(2+)—O的配位数为4,配位键键长为1.96A。共聚物中羧基含量对离聚体的基本配位结构单元和离子微区的精细结构影响较小,但对微区大小有影响。 展开更多
关键词 离聚体 fa-aa 结构
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富马酸-丙烯酸二元共聚物的合成及应用 被引量:2
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作者 杨海涛 周向东 +1 位作者 张桃勇 王哲文 《印染助剂》 CAS 2008年第2期16-18,共3页
以富马酸(FA)与丙烯酸(AA)为原料、过硫酸钠为引发剂,采用溶液聚合法和单体滴加工艺合成了一种二元共聚物P(FA-AA).考察了原料配比、单体质量分数、引发剂质量分数、反应温度、反应时间对共聚物P(FA-AA)性能的影响因素.优选了合成工艺条... 以富马酸(FA)与丙烯酸(AA)为原料、过硫酸钠为引发剂,采用溶液聚合法和单体滴加工艺合成了一种二元共聚物P(FA-AA).考察了原料配比、单体质量分数、引发剂质量分数、反应温度、反应时间对共聚物P(FA-AA)性能的影响因素.优选了合成工艺条件:m(AA)∶m(FA)=12∶1,w(单体)=40%,w(引发剂)=5%,85℃,4 h,用氢氧化钠溶液中和到pH=7~8.测试了P(FA-AA)的主要性能,结果表明:共聚物P(FA-AA)的性能可以满足纺织品皂洗的要求(干摩擦牢度为4~5级,湿摩擦牢度为3级,防沾色牢度为4级). 展开更多
关键词 富马酸(FA) 丙烯酸(AA) 二元共聚物 合成
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COMPARATIVE FATTY ACID COMPOSITION OF FOUR SARGASSUM SPECIES(FUCALES,PHAEOPHYTA) 被引量:3
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作者 吴向春 陆保仁 曾呈奎 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 1995年第4期370-373,共4页
Fatty acid composition of four Sargassum species from Qingdao and Shidao,Shandong Provincewas investigated.16:0(palmitic acid)was the major saturated fatty acid.C<sub>18</sub> and C<sub>20</sub&... Fatty acid composition of four Sargassum species from Qingdao and Shidao,Shandong Provincewas investigated.16:0(palmitic acid)was the major saturated fatty acid.C<sub>18</sub> and C<sub>20</sub>were the mainpolyunsaturated fatty acids(PUFAs).Arachidonic acid and eicosapentaenoic acid predominated amongpolyenoic acids in all the algal species examined.except for Sargassum sp.which had low concentrationof eicosapentaenoic acid. 展开更多
关键词 SARGASSUM SPECIES FATTY ACID (FA) arachidonic ACID (AA or eicosatetraenoic acid) eicosapentaenoic ACID (EPA) polyunsaturated FATTY acids (PUFAs)
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Assessment of sunflower germplasm for phytoremediation of lead-polluted soil and production of seed oil and seed meal for human and animal consumption 被引量:10
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作者 Afsheen Zehra Zulfiqar Ali Sahito +6 位作者 Wenbin Tong Lin Tang Yasir Hamid Muhammad Bilal Khan Zarina Ali Beena Naqui Xiaoe Yang 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2020年第1期24-38,共15页
Phytoremediation is a valuable technology for mitigating soil contamination in agricultural lands,but phytoremediation without economic revenue is unfeasible for land owners and farmers.The use of crops with high biom... Phytoremediation is a valuable technology for mitigating soil contamination in agricultural lands,but phytoremediation without economic revenue is unfeasible for land owners and farmers.The use of crops with high biomass and bioenergy for phytoremediation is a unique strategy to derive supplementary benefits along with remediation activities.Sunflower(Helianthus annuus L.)is a high-biomass crop that can be used for the phytoremediation of polluted lands with additional advantages(biomass and oil).In this study,40 germplasms of sunflower were screened in field conditions for phytoremediation with the possibility for oil and meal production.The study was carried out to the physiological maturity stage.All studied germplasms mopped up substantial concentrations of Pb,with maximum amounts in shoot>root>seed respectively.The phytoextraction efficiency of the germplasm was assessed in terms of the Transfer factor(TF),Metal removal efficiency(MRE)and Metal extraction ratio(MER).Among all assessed criteria,GP.8585 was found to be most appropriate for restoring moderately Pb-contaminated soil accompanied with providing high biomass and high yield production.The Pb content in the oil of GP.8585 was below the Food safety standard of China,with 59.5% oleic acid and 32.1% linoleic acid.Moreover,amino acid analysis in meal illustrated significant differences among essential and nonessential amino acids.Glutamic acid was found in the highest percentage(22.4%),whereas cysteine in the lowest percentage(1.3%).Therefore,its efficient phytoextraction ability and good quality edible oil and meal production makes GP.8585 the most convenient sunflower germplasm for phytoremediation of moderately Pb-contaminated soil,with fringe benefits to farmers and landowners. 展开更多
关键词 Heavy metal Soil contamination Metal removal efficiency(MRE) Germplasm(GP) PHYTOEXTRACTION Edible oil Fatty acids(FA) Amino acids(AAs)
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