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基于FDFO的反渗透浓水处理试验 被引量:3
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作者 刘娟 田军仓 李明 《农业工程学报》 EI CAS CSCD 北大核心 2021年第16期65-71,共7页
针对目前反渗透、膜蒸馏等众多高能耗的苦咸水淡化技术,该研究采用无需加压无需再生的肥料汲取液正渗透技术对苦咸水进行处理。对KCl、KNO_(3)、NaNO_(3)、NH_(4)HCO_(3)、(NH_(4))2SO_(4)、NH_(4)Cl进行肥料汲取液正渗透(Fertilizer Dr... 针对目前反渗透、膜蒸馏等众多高能耗的苦咸水淡化技术,该研究采用无需加压无需再生的肥料汲取液正渗透技术对苦咸水进行处理。对KCl、KNO_(3)、NaNO_(3)、NH_(4)HCO_(3)、(NH_(4))2SO_(4)、NH_(4)Cl进行肥料汲取液正渗透(Fertilizer Draw Forward Osmosis,FDFO)单因素试验,通过改变汲取液种类、浓度、温度及原料液浓度,分析正渗透过程的正向水通量和反向盐通量的影响因素。结果表明汲取液种类不同,其正向水通量和反向盐通量差别较大,6种汲取液的正向水通量从大到小依次为KCl、NH_(4)Cl、NaNO_(3)、NH_(4)HCO_(3)、(NH_(4))2SO_(4)、KNO_(3),反向盐通量为NaNO_(3)、NH_(4)HCO_(3)、KNO_(3)、KCl、NH_(4)Cl、(NH_(4))2SO_(4)。KCl、NH_(4)Cl的正向水通量最大,反向盐通量较小,因此优先选用KCl和NH_(4)Cl作为肥料汲取液。改变KCl汲取液的浓度和温度进行正渗透试验。结果表明,2 mol/L的KCl汲取液其正向水通量是0.5 mol/L的3.56倍,55℃条件下的KCl汲取液其正向水通量大约是25℃条件下正向水通量的2倍,因此随着汲取液浓度的增加和温度的升高,正向水通量增加。改变NaNO_(3)汲取液的浓度和温度进行正渗透试验,结果表明,汲取液浓度从0.5 mol/L增大到2 mol/L,反向盐通量增大了2.94倍,汲取液温度从25℃上升到55℃,反向盐通量增大了1.64倍,因此随着汲取液浓度的增加和温度的升高,反向盐通量增加。 展开更多
关键词 肥料 渗透 废水 肥料汲取液 反渗透浓水 苦咸水淡化 fdfo
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Fertilizer drawn forward osmosis as an alternative to 2nd pass seawater reverse osmosis: Estimation of boron removal and energy consumption 被引量:1
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作者 Hailan Wang Baoyu Gao +3 位作者 Li’an Hou Ho Kyong Shon Qinyan Yue Zhining Wang 《Frontiers of Environmental Science & Engineering》 SCIE EI CSCD 2021年第6期433-445,共13页
Agriculture is the largest consumer of freshwater.Desalinated seawater is an important alternative water source for sustainable irrigation.However,some issues of the current desalination technology hinder its use for ... Agriculture is the largest consumer of freshwater.Desalinated seawater is an important alternative water source for sustainable irrigation.However,some issues of the current desalination technology hinder its use for agriculture irrigation,including low boron removal and high energy consumption.This study systematically explored the feasibility of employing fertilizer drawn forward osmosis(FDFO)as an alternative to 2nd pass reverse osmosis(RO)by considering the boron removal performance and specific energy consumption(SEC).Different operating conditions were investigated,such as the boron and NaCl concentrations in feed solution(FS),draw solution(DS)concentration,pH,the volume ratio of FS to DS,membrane orientation,flow rate,and operating temperature.The results indicated that a low boron concentration in FS and high DS pH(pH=11.0)decreased the boron solute flux,and led to low final boron concentration in the DS.The other operating conditions had negligible influence on the final DS boron concentration.Also,a lower flow rate and higher specific water flux with certain permeate water volumes were conducive to reducing the SEC of the FDFO process.Overall,our study paves a new way of using FDFO in irrigation,which avoids the phytotoxicity and human health risk of boron.The results show the potential of FDFO as an alternative to 2nd pass RO for irrigation water production. 展开更多
关键词 Fertilizer drawn forward osmosis(fdfo) Boron removal Specific energy consumption(SEC) Seawater reverse osmosis(SWRO) Irrigation water production
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