The effects of the calorimetric buffer solutions were investigated while the two colorimetric reactions of AI-ferron complex and Fe-ferron complex occurred individually, and the effects of the testing wavelength and t...The effects of the calorimetric buffer solutions were investigated while the two colorimetric reactions of AI-ferron complex and Fe-ferron complex occurred individually, and the effects of the testing wavelength and the pH of the solutions were also investigated. A timed complexatian colorimetric analysis method of Al-Fe-ferron in view of the total concentration of {AI + Fe} was then established to determine the species distribution of polymeric Al-Fe. The testing wavelength was recommended at 362 net and the testing pH value was 5. With a comparison of the ratios of n(Al)/n(Fe), the standard adsorption curves of the polymeric Al-Fe solutions were derived from the experimental results. Furthermore, the solutions' composition were carious in both the molar n(Al)/n(Fe) ratios, i.e. 0/0, 5/5, 9/1 and 0/10, and the concentrations associated with the total ( Al + Fe which ranged from 10(-5) to 10(-4) mol/L..展开更多
Fe-based carbon materials are widely considered promising to replace Pt/C as next-generation electrocatalysts towards oxygen reduction reaction (ORR). However, the preparation of Fe-based carbon materials is still car...Fe-based carbon materials are widely considered promising to replace Pt/C as next-generation electrocatalysts towards oxygen reduction reaction (ORR). However, the preparation of Fe-based carbon materials is still carried out by conventional heating method (CHM). Herein, a novel microwave-assisted carbon bath method (MW-CBM) was proposed, which only took 35 min to synthesize Fe/Fe3C nanoparticles encapsulated in N-doped carbon layers derived from Prussian blue (PB). The catalyst contained large specific surface area and mesoporous structure, abundant Fe-Nx and C–N active sites, unique core-shell structure. Due to the synergistic effects of these features, the as-prepared Fe/Fe3C@NC-2 displayed outstanding ORR activity with onset potential of 0.98 VRHE and halfwave potential of 0.87 VRHE, which were more positive than 20 wt.% Pt/C (0.93 VRHE and 0.82 VRHE). Besides, Fe/Fe3C@NC-2 gave a better stability and methanol tolerance than Pt/C towards ORR in alkaline media, too.展开更多
The present study deals with the effects of both tin (Sn) and graphite (Gr) powders on the cold extrudability of Fe-TiC nanocomposites as lubricant. The production process includes low-energy ball milling, powder meta...The present study deals with the effects of both tin (Sn) and graphite (Gr) powders on the cold extrudability of Fe-TiC nanocomposites as lubricant. The production process includes low-energy ball milling, powder metallurgy and cold direct Extrusion. Due to various factors influencing the extrudability of the Fe-TiC nanocomposites, such as milling time, rate of extrusion, type and content of lubricant and etc, Taguchi robust design method of system optimization was used to determine the approximate contribution percent (% ρ) of each factor. In order to investigation of Fe-TiC properties, samples with best quality of extrusion were analyzed by XRD and SEM investigations. The results indicate that, sitting the atomic layers of Sn lubricant between Fe and TiC particles leads to decreasing the friction. In this case sliding the particles on each other is easier and a part of the load is applied on lubricant. The results of extrusion of samples indicate that using 2% Sn admixed and die wall graphite lubrication can improve cold extrudability of Fe-TiC nanocomposites.展开更多
To solve the coupled vibration of a gravity dam-reservoir systemwith variable water depth by using a hybrid element method, the fluidregion with variable water depth needs to be dis- cetized by FEmeshes. However, such...To solve the coupled vibration of a gravity dam-reservoir systemwith variable water depth by using a hybrid element method, the fluidregion with variable water depth needs to be dis- cetized by FEmeshes. However, such a method asks for a great computational costowing to the ex- cessive unknowns, especially when the fluid regionwith variable water depth is relatively large. To overcome theshortcoming, a refined boundary element method is proposed to analyzethe fluid field, in which only the discretization for the boundary ofthe variable depth region is required. But as a basis of thisapproach, it is necessary to construct a new Green's functioncorresponding to an infinite strip region.展开更多
基金TheNationalNaturalScienceFoundationofChina (No .2 96 770 0 4)
文摘The effects of the calorimetric buffer solutions were investigated while the two colorimetric reactions of AI-ferron complex and Fe-ferron complex occurred individually, and the effects of the testing wavelength and the pH of the solutions were also investigated. A timed complexatian colorimetric analysis method of Al-Fe-ferron in view of the total concentration of {AI + Fe} was then established to determine the species distribution of polymeric Al-Fe. The testing wavelength was recommended at 362 net and the testing pH value was 5. With a comparison of the ratios of n(Al)/n(Fe), the standard adsorption curves of the polymeric Al-Fe solutions were derived from the experimental results. Furthermore, the solutions' composition were carious in both the molar n(Al)/n(Fe) ratios, i.e. 0/0, 5/5, 9/1 and 0/10, and the concentrations associated with the total ( Al + Fe which ranged from 10(-5) to 10(-4) mol/L..
基金supported by the National Natural Science Foundation of China (U1303291)the Program for Changjiang Scholars and Innovative Research Team in University (No. IRT_15R46)
文摘Fe-based carbon materials are widely considered promising to replace Pt/C as next-generation electrocatalysts towards oxygen reduction reaction (ORR). However, the preparation of Fe-based carbon materials is still carried out by conventional heating method (CHM). Herein, a novel microwave-assisted carbon bath method (MW-CBM) was proposed, which only took 35 min to synthesize Fe/Fe3C nanoparticles encapsulated in N-doped carbon layers derived from Prussian blue (PB). The catalyst contained large specific surface area and mesoporous structure, abundant Fe-Nx and C–N active sites, unique core-shell structure. Due to the synergistic effects of these features, the as-prepared Fe/Fe3C@NC-2 displayed outstanding ORR activity with onset potential of 0.98 VRHE and halfwave potential of 0.87 VRHE, which were more positive than 20 wt.% Pt/C (0.93 VRHE and 0.82 VRHE). Besides, Fe/Fe3C@NC-2 gave a better stability and methanol tolerance than Pt/C towards ORR in alkaline media, too.
文摘The present study deals with the effects of both tin (Sn) and graphite (Gr) powders on the cold extrudability of Fe-TiC nanocomposites as lubricant. The production process includes low-energy ball milling, powder metallurgy and cold direct Extrusion. Due to various factors influencing the extrudability of the Fe-TiC nanocomposites, such as milling time, rate of extrusion, type and content of lubricant and etc, Taguchi robust design method of system optimization was used to determine the approximate contribution percent (% ρ) of each factor. In order to investigation of Fe-TiC properties, samples with best quality of extrusion were analyzed by XRD and SEM investigations. The results indicate that, sitting the atomic layers of Sn lubricant between Fe and TiC particles leads to decreasing the friction. In this case sliding the particles on each other is easier and a part of the load is applied on lubricant. The results of extrusion of samples indicate that using 2% Sn admixed and die wall graphite lubrication can improve cold extrudability of Fe-TiC nanocomposites.
文摘To solve the coupled vibration of a gravity dam-reservoir systemwith variable water depth by using a hybrid element method, the fluidregion with variable water depth needs to be dis- cetized by FEmeshes. However, such a method asks for a great computational costowing to the ex- cessive unknowns, especially when the fluid regionwith variable water depth is relatively large. To overcome theshortcoming, a refined boundary element method is proposed to analyzethe fluid field, in which only the discretization for the boundary ofthe variable depth region is required. But as a basis of thisapproach, it is necessary to construct a new Green's functioncorresponding to an infinite strip region.
