利用溶胶—凝胶法制备了(FePt)100-x Au x(x=0%,5%,10%,20%)纳米颗粒,并且研究了不同含量的Au对FePt纳米颗粒磁性和结构的影响.实验发现,添加Au可以有效降低FePt合金从无序相到有序相的相转变温度,增加L10相FePt颗粒的有序化程度,并且...利用溶胶—凝胶法制备了(FePt)100-x Au x(x=0%,5%,10%,20%)纳米颗粒,并且研究了不同含量的Au对FePt纳米颗粒磁性和结构的影响.实验发现,添加Au可以有效降低FePt合金从无序相到有序相的相转变温度,增加L10相FePt颗粒的有序化程度,并且会增加FePt颗粒的晶粒尺寸.磁性测试结果表明,在600℃时,掺杂Au后(FePt)90Au10样品的矫顽力可以达到9 585 Oe,比不添加时的5 250 Oe提高了很多,这可能是由于掺杂Au使FePt的有序化程度增加,并且使颗粒的尺寸增大.展开更多
Dispersible FePt intermetallic nanopartides （NPs） with tunable composition were synthesized by thermal annealing of MgO coated A1-FePt （or A1-FePt-Fe304） NPs followed by an acid treatment to remove MgO. High-tem- ...Dispersible FePt intermetallic nanopartides （NPs） with tunable composition were synthesized by thermal annealing of MgO coated A1-FePt （or A1-FePt-Fe304） NPs followed by an acid treatment to remove MgO. High-tem- perature annealing facilitates the conversion of FePt from disordered alloy to ordered intermetaUics. Under the protec- tion of MgO, the diffusion of Fe and Pt atoms was limited, making it possible for the atom reconstruction in the lattice to give discrete FePt intermetaUic NPs after a facile acid etching process. FePt intermetallic NPs formed face-centered cubic and face-centered tetragonal structures with their magnetic properties tuned by composition. The saturation magnetiza- tion was adjusted from 8 to 52 emu g^-1 by increasing the Fe concentration, while the coercivity reached a max/mum of 33 kOe when Fe concentration was 44%. After surface mod- ifications by hydrophilic or hydrophobic molecules containing thiol groups, FePt intermetallic NPs could be dissolved into water or hydrocarbon solvents. The hydrophilic L10-FePt in- termetallic NPs were applied as contrast agents for magnetic resonance imaging, showing a high transverse relaxivity of 328.6 mmo1^-1 L s^-l, which indicated the great potential of FePt intermetallic NPs as molecular probes for cancer diagnosis.展开更多
基金supported by the National Natural Science Foundation of China (51602285, 51590882, 51631001, 51672010 and 81421004)the National Key R&D Program of China (2017YFA0206301)the Key Laboratory of Biomedical Effects of Nanomaterials and Nanosafety, National Center for Nanoscience and technology, Chinese Academy of Sciences (NSKF201607)
文摘Dispersible FePt intermetallic nanopartides （NPs） with tunable composition were synthesized by thermal annealing of MgO coated A1-FePt （or A1-FePt-Fe304） NPs followed by an acid treatment to remove MgO. High-tem- perature annealing facilitates the conversion of FePt from disordered alloy to ordered intermetaUics. Under the protec- tion of MgO, the diffusion of Fe and Pt atoms was limited, making it possible for the atom reconstruction in the lattice to give discrete FePt intermetaUic NPs after a facile acid etching process. FePt intermetallic NPs formed face-centered cubic and face-centered tetragonal structures with their magnetic properties tuned by composition. The saturation magnetiza- tion was adjusted from 8 to 52 emu g^-1 by increasing the Fe concentration, while the coercivity reached a max/mum of 33 kOe when Fe concentration was 44%. After surface mod- ifications by hydrophilic or hydrophobic molecules containing thiol groups, FePt intermetallic NPs could be dissolved into water or hydrocarbon solvents. The hydrophilic L10-FePt in- termetallic NPs were applied as contrast agents for magnetic resonance imaging, showing a high transverse relaxivity of 328.6 mmo1^-1 L s^-l, which indicated the great potential of FePt intermetallic NPs as molecular probes for cancer diagnosis.
