Inhibiting Voltage Decay in Li-Rich Layered Oxide Cathode:From O3-Type to O2-Type Structural Design

Li-rich layered oxide(LRLO)cathodes have been regarded as promising candidates for next-generation Li-ion batteries due to their exceptionally high energy density,which combines cationic and anionic redox activities.However,continuous voltage decay during cycling remains the primary obstacle for practical applications,which has yet to be fundamentally addressed.It is widely acknowledged that voltage decay originates from the irreversible migration of transition metal ions,which usually further exacerbates structural evolution and aggravates the irreversible oxygen redox reactions.Recently,constructing O2-type structure has been considered one of the most promising approaches for inhibiting voltage decay.In this review,the relationship between voltage decay and structural evolution is systematically elucidated.Strategies to suppress voltage decay are systematically summarized.Additionally,the design of O2-type structure and the corresponding mechanism of suppressing voltage decay are comprehensively discussed.Unfortunately,the reported O2-type LRLO cathodes still exhibit partially disordered structure with extended cycles.Herein,the factors that may cause the irreversible transition metal migrations in O2-type LRLO materials are also explored,while the perspectives and challenges for designing high-performance O2-type LRLO cathodes without voltage decay are proposed.

Structural design and experimental research of microwave radiation heater for asphalt pavements

In order to improve the efficiency of heating and the uniformity of temperature distribution in recycling asphalt mixtures, a pyramidal radiation heater is designed. The principles of designing horn surface size and antenna length are established according to the law of energy conservation and microwave antenna radiation theory. Modeling and simulation are carried out using IE3D software. The simulation results demonstrate that, with a fixed horn surface size, the shortened electric antenna length is the main factor leading to the improved heating uniformity. On the other hand, with a fixed antenna length and diminished surface size, the standing wave ratio decreases with the improved radiation efficiency. Furthermore, the efficiency of radiation drops with increased distance between the horn surface and the asphalt pavement. Microwave heating experiments are carried out using this type of heater. The temperature distribution of asphalt samples is obtained by the grid temperature measurement method, and Matlab simulation is performed. The experimental results are in good agreement with the simulation.

Structural Design of Roadbed and Pavement in Transition Section of Roads and Bridges

As the lifeline of social development,road and bridge projects are the main channel to realize resource transportation and economic circulation.Ensuring the quality of road and bridge project construction is crucial for the development of society,the economy,and people’s livelihoods.This paper studies the design of roadbed pavement structures in road and bridge transition sections.It aims to provide technical references and significance for China’s road and bridge engineering design and construction units,promoting scientific and standardized design in these actions.This will contribute to the safety and stable operation of road and bridge projects,offering effective technical support.Furthermore,it seeks to foster the sustainable and healthy development of China’s road and bridge engineering on a macro level.

Structural Carpentry in Qing Dynasty-A Framework for the Hierarchically Modularized Chinese Timber Structural Design

This article, by using mathematical expressions, offers a scientific framework for understanding how the grading system of Qing′s structural carpentry determines the design and construction in the grand style timber architecture.The Qing′s grand style timber structure, which is ready for prefabrication and assembly, is extremely hierarchical oriented and significantly standardized. The general procedure in designing a grand style timber structure is to start with the grade that defines the basic module (dou kou); next comes with the number of bracket set (cuan), the number of longitudinal bays and the number of purlins which affect its plan and cross section; thirdly choose a roof type that determines its longitudinal section and the facade as well. A series of formulae are conducted to help depict the layout, cross sectional roof curvature and special longitudinal treatments in 4 sloped and 9 spined roofs respectively.

An Expert System in FRP Composite Material Design

An expert system prototype for fibre-reinforced plastic matrix (FRP) composite material design, ESFRP, has been developed. The system consists of seven main functional parts: a general inference engine, a set of knowledge bases, a material properties algorithm base, an explanation engine, various data bases, several function models and the user interface. The ESFRP can simulate human experts to make design scheme for fibre-reinforced plastics design, FRP layered plates design and FRP typical engineering components design. It can also predict the material properties and make strength analysis according to the micro and macro mechanics of composite materials. A satisfied result can be gained through the reiterative design.

Structural Design Strategies of Polymer Matrix Composites for Electromagnetic Interference Shielding:A Review

With the widespread application of electronic communication technology,the resulting electromagnetic radiation pollution has been significantly increased.Metal matrix electromagnetic interference(EMI)shielding materials have disadvantages such as high density,easy corrosion,difficult processing and high price,etc.Polymer matrix EMI shielding composites possess light weight,corrosion resistance and easy processing.However,the current polymer matrix composites present relatively low electrical conductivity and poor EMI shielding performance.This review firstly discusses the key concept,loss mechanism and test method of EMI shielding.Then the current development status of EMI shielding materials is summarized,and the research progress of polymer matrix EMI shielding composites with different structures is illustrated,especially for their preparation methods and evaluation.Finally,the corresponding key scientific and technical problems are proposed,and their development trend is also prospected.

Structural Design and Protective Methods for the 100 kW Shoreline Wave Power Station

The structural design and protective methods for the 100 kW shoreline wave power station in China are described in detail. The proper structural type is designed for effective minimization of wave loads and bending stress. Various protective devices are adopted to protect the station in the extreme conditions against excessive power of airflow, excessive torsion of the shaft, over-pressure of the chamber, over-speed of rotation, power failure, and so on. It turns out that the structural design and protective methods for the 100 kW shoreline wave power station are successful.

Practical Structural Design Approach of Multiconfiguration Planar Single‑Loop Metamorphic Mechanism with a Single Actuator

As a type of multiconfiguration mechanism that can operate in an under-actuated state,metamorphic mechanisms were proposed more than two decades ago and attracted significant interest.Studies on structural synthesis of metamorphic mechanisms tend to focus more on metamorphic techniques and the structural synthesis of source mechanisms for metamorphic mechanisms.By designing different constraint architectures of metamorphic joints,multistructures can be obtained from the same source metamorphic mechanism.To determine the constraint architectures of metamorphic joints and their different assembly combinations,a kinematic status matrix and a corresponding constraint status matrix are constructed based on the metamorphic cyclogram of a source mechanism.According to the equivalent resistance gradient model and the constraint status matrix,an equivalent resistance matrix for the metamorphic joints is proposed.A structural synthesis matrix of the metamorphic mechanism is then obtained from the equivalent resistance matrix by deducing the constraint form vectors of the metamorphic joints.Furthermore,a kinematic diagram synthesis of the source metamorphic mechanism of a planar single-loop metamorphic mechanism is proposed,which is based on only the 14 one-or zero-degrees-of-freedom linkage groups.The entire structural design method of a metamorphic mechanism is based on the structural synthesis matrix and is presented as a systematic process.Finally,the proposed structural design approach is illustrated by two examples to verify its feasibility and practicality.This study provides an effective method for designing a practical multi-mobility and multiconfiguration planar single-loop metamorphic mechanism with a single actuator.

Data-Driven Structural Design Optimization for Petal-Shaped Auxetics Using Isogeometric Analysis

Focusing on the structural optimization of auxetic materials using data-driven methods,a back-propagation neural network(BPNN)based design framework is developed for petal-shaped auxetics using isogeometric analysis.Adopting a NURBSbased parametric modelling scheme with a small number of design variables,the highly nonlinear relation between the input geometry variables and the effective material properties is obtained using BPNN-based fitting method,and demonstrated in this work to give high accuracy and efficiency.Such BPNN-based fitting functions also enable an easy analytical sensitivity analysis,in contrast to the generally complex procedures of typical shape and size sensitivity approaches.

Crystal chemistry and structural design of iron-based superconductors

The second class of high-temperature superconductors （HTSCs）, iron-based pnictides and chalcogenides, necessarily contain Fe2X2 （＂X＂ refers to a pnictogen or a chalcogen element） layers, just like the first class of HTSCs which possess the essential CuO2 sheets. So far, dozens of iron-based HTSCs, classified into nine groups, have been discovered. In this article, the crystal-chemistry aspects of the known iron-based superconductors are reviewed and summarized by employing ＂hard and soft acids and bases （HSAB）＂ concept. Based on these understandings, we propose an alternative route to exploring new iron-based superconductors via rational structural design.

Structural design and mechanical performance of composite vascular grafts

This study reviews the state of the art in structural design and the corresponding mechanical behaviours of composite vascular grafts. We critically analyse surface and matrix designs composed of layered, embedded, and hybrid structures along the radial and longitudinal directions;materials and manufacturing techniques, such as tissue engineering and the use of textiles or their combinations;and the corresponding mechanical behaviours of composite vascular grafts in terms of their physical–mechanical properties, especially their stress–strain relationships and elastic recovery. The role of computational studies is discussed with respect to optimizing the geometrics designs and the corresponding mechanical behaviours to satisfy specialized applications, such as those for the aorta and its subparts. Natural and synthetic endothelial materials yield improvements in the mechanical and biological compliance of composite graft surfaces with host arteries. Moreover,the diameter, wall thickness, stiffness, compliance, tensile strength, elasticity, and burst strength of the graft matrix are determined depending on the application and the patient. For composite vascular grafts, hybrid architectures are recommended featuring multiple layers, dimensions, and materials to achieve the desired optimal flexibility and function for complying with user-specific requirements. Rapidly emerging artificial intelligence and big data techniques for diagnostics and the threedimensional(3D) manufacturing of vascular grafts will likely yield highly compliant, subject-specific, long-lasting, and economical vascular grafts in the near-future.

Structural design for electrocatalytic water splitting to realize industrial-scale deployment: Strategies, advances, and perspectives

The green hydrogen generation powered by renewable electricity promises the potential decarbonization of the hard-to-abate sector and is essential for the fulfillment of the Paris Agreement that attempts to limit the global average temperature rise in the range of 1.5–2.0 ℃ above the pre-industrial level by the end of this century. Tremendous efforts have been devoted to the optimization of the electrocatalytic performance of the catalysts under industrial-relevant current densities via rational structure design,which induces a preferential electron distribution that favors the adsorption/desorption behavior of the key intermediates, thus accelerating the reaction kinetics. In this review, a brief introduction of the current energy status will be first presented to necessitate the importance of green hydrogen.Followed by the basic concepts and fundamental understanding of the reaction mechanisms, we present efficient strategies for the enhancement of the electrocatalytic performance of the catalysts to meet the rigorous requirement under industrial conditions and the in-depth understanding behind the reinforcement will be briefly discussed next. Then the recent advances regarding the rational design of electrocatalysts operating at an industrial scale will be summarized. Finally, the challenges and perspectives in this thriving field will be proposed from our point of view.

Structural design and modal behaviors analysis of a new swept baffled inflatable wing

Inflatable wing has significant application value in the design of loitering munitions because of its advantages such as lightweight and foldability.However,due to the flexible characteristics,aeroelastic behaviors of inflatable wings such as flutter are nonnegligible in flight.By designing a certain angle between the inflatable beam and the wing span,the structural dynamic and even the aeroelastic performance of the inflatable wing can be effectively improved.Based on the analysis of the mechanical and geometric characteristics of the inflatable structure,a new inflatable wing with sweep arranged inflatable beams is proposed,and the main design variables and methods are analyzed.For purpose of investigating the aeroelastic performance of the swept baffled inflatable wing,the modal behaviors by considering the wet mode are studied.In consideration of the deficiencies of the traditional wet modal analysis method,by introducing the influence on the additional stiffness of flow field,an added massstiffness method is proposed in this paper,and the advantages are verified by ground vibration experiments.On this basis,the effects of baffles sweep angle,pressure,and boundary conditions on the modal parameters and aeroelastic performance of inflatable wing are analyzed.The results show that the aeroelastic performance of the inflatable wing can be designed by changing the baffles sweep angle,which is enlightened for the aeroelastic tailoring design on inflatable wings.

FRP与混凝土组合结构研究综述

本文从FRP约束混凝土的试验研究、FRP约束混凝土柱的强度模型、其他形式的FRP与混凝土组合结构三方面阐述FRP与混凝土组合结构的研究现状,并提出现阶段需要继续深入的一些问题。

FRP筋混凝土柱及框架抗震性能的研究进展

与普通钢筋相比,FRP筋具有轻质高强、耐腐蚀性能好等优点,但是FRP筋弹性模量较低、为线弹性材料、破坏时脆性大等特性限制了其在混凝土柱,特别是在地震地区结构工程中的应用。介绍了国内外关于FRP筋混凝土柱及框架抗震性能的研究成果,其中包括试验研究和数值模拟研究。国内外研究表明,FRP筋取代钢筋应用于混凝土柱、混凝土框架及其节点是可行的。通过适当配置FRP筋,保证其在弹性范围内工作,则FRP筋混凝土结构能够获得较大的延性和变形能力。最后建议研究FRP筋混凝土柱的破坏模式、抗剪承载力计算、延性评价和设计理论等。系统研究FRP筋混凝土柱基本理论和设计方法具有重要的理论意义和实用价值。

BIM Methodology Applied in Structural Design: Analysis of Interoperability in ArchiCAD/ETABS Process

The Building Information Modeling (BIM) methodology considers the representation of the building as a virtual BIM model and its main concept is to centralize all the information generated throughout the development of the project. Structural design involves a set of tasks, namely, structure definition, structural analyses, and after the generation of drawings and technical documentation. In all processes, it is required confidence in data transferred between the BIM systems used, and to support this, a high level of interoperability is claimed. The present study aims to evaluate the degree of interoperability between the BIM-based platforms, ArchiCAD (Graphisoft), Revit (Autodesk), and ETABS (CSI). Two-way data flows between these systems were explored using distinct transfer strategies: add-in applications;Industry Foundation Classes (IFC) standard data format. The research made allows identifying the most appropriate procedure to be adopted by structural engineers, given the interoperability limitations verified, enabling the establishment of a practical guide of sequential procedures on the development of structural designs using BIM tools.

Structural Design of a Tall Building with Underpinning Structure in Guangzhou

This paper introduces the structural design optimization of a tall building with reinforced concrete frame-core shear walls in Guangzhou downtown.To decrease the construction cost,wide flat beam with 400 mm ×650 mm rectangular cross-section are adopted for main beam.Special measures are used to decrease noncoincident centers of mass and stiffness.Because subway tunnels cross the building underground,inclined columns,the second and third floor underground together function as the underpinning structures.Different from traditional transform beam,the proposed underpinning structures show good performance without using large dimensional bending members.Special attentions should be paid to the beams connecting with the inclined column in the underpinning structures,and these beams show large tensile or compressive forces.Settlement observations after completion construction indicate that the building as well as the proposed design measures work well.

Structural Design of Asphalt Pavement for Low Cost Rural Roads

On the basis of the equivalent axle load action frequency, the traffic classifications of rural roads as well as their corresponding types are classified. The asphalt pavement structure, road surface types and thickness of the rural roads are suggested for the various action frequency of the equivalent axle load. Furthermore, the roadbase thickness graphs are provided according to different equivalent axle load action frequency with different roadbed modulus and road surface modulus taken into account.

Structural Design and Experiment of Narrow-Band Response GaAlAs Photocathodes

To obtain the peak response at 532nm, narrow-band response GaA1As photocathodes with two GaAIAs ac- tive layers of different aluminum compositions are designed in consideration of the maximum absorptivity and quantum efficiency. The transmission-mode and the corresponding reflective-mode photocathodes are grown by metalorganic chemical vapor deposition. The results indicate that the peak response and the cut-off wavelength occur at 532nm for the two kinds of photocathodes respectively. The response of the reflection-mode photoeath- ode is an order of magnitude higher than that of the transmission-mode photocathode, whereas the better growth quality and the thicker second GaAIAs active layer can improve the transmission-mode response.

Optimum structural design of full-scale steel buildings using drift-tribe-charged system search

In this paper,the potential of utilizing improved metaheuristic approaches in optimal design of building structures is concerned.In this regard,the drift-tribe-charged system search algorithm is proposed that the position and velocity updating processes of the charged system search is developed by implementing the mathematical presentation of the free-electron model utilized for metal conductors.In addition,the searching phase of the developed algorithm is also divided into three separate phases in order to improve the convergence capability of the algorithm.By means of these modifications,the exploitation and exploration rates of the standard algorithm are enhanced.In order to determine the ability of the proposed improved metaheuristic method considering some complex optimization problems,a 10-story steel building structure with 1026 structural members alongside a 60-story structure with 8272 members are utilized as numerical examples.The overall capability of the developed metaheuristic approach is compared with other metaheuristics.A total number of 30 independent runs have been conducted for each of the standard and proposed methods while a statistical analysis is also conducted for comparative purposes.The obtained optimum results demonstrated that the proposed metaheuristic approach is capable of preparing better outcomes than other metaheuristics.