退火过程中Fe-6.5%Si冷轧薄板组织及织构的演变

观察分析了Fe-6.5%Si合金冷轧前后及在不同再结晶退火过程中的组织、织构及有序结构的特点及其演变规律,用以分析织构形成机制及其影响因素。结果表明,间隙溶质原子偏聚于{110}面的概率大于{112}面,明显提高位错在{110}面滑移的临界分切应力;代位溶质原子有可能同步提高{110}和{112}面的临界分切应力,降低这两面的临界分切应力差;因此溶质原子都会导致{112}面更活跃的滑移和更强的{100}<110>冷轧织构。退火过程中{111}<112>取向晶粒易于长入{001}<110>和{112}<110>取向形变晶粒,使{111}<112>再结晶织构增强。冷变形会降低合金的有序化程度;D03有序化过程的二级相变特点使之在退火加热过程中先于再结晶出现,再结晶之前的回复会促进有序化过程。

温轧工艺制备的Fe-6.5wt%Si-0.5wt%Cu合金薄板的结构与性能

采用热轧-温轧工艺制备了表面质量良好的0.35mm厚Fe-6.5%Si-0.5%Cu合金薄板。通过对热轧态和温轧态试样的显微组织观察和硬度测试,研究了Fe-6.5%Si-0.5%Cu合金轧制后的结构及性能;同时测量了该合金温轧薄板的磁性能。研究表明,温轧态试样中含有较多的滑移带,同时含有少量的B2有序相。Fe-6.5%Si-0.5%Cu合金薄板经热轧-温轧后板材成型性较好,饱和磁感较高,铁损较低。

有序度与残余应力对Fe-6.5%Si合金塑性变形性能的影响

为了进一步提高Fe-6.5%Si合金的塑性变形性能,以1100℃保温1 h油淬处理后的Fe-6.5%Si合金为对象,重点研究了不同回火温度和保温时间下合金的有序结构回复和残余应力松弛行为及其对三点弯曲力学性能的影响。结果表明,合理的回火处理工艺可在有效抑制有序结构回复的情况下显著松弛合金的淬火残余应力,进而提升淬火试样的塑性变形性能。300℃回火60 min、400℃回火10 min和500℃回火10 min试样的最大弯曲断裂挠度与淬火态试样相比分别提高了20.7%,31.3%,21.8%。合金塑性变形性能提高的原因与回火处理导致合金无序-有序结构回复以及试样表面微观残余应力的松弛有关。以400℃回火处理保温10 min为例,合金试样的有序相畴尺寸由淬火试样的20~200 nm提高到50~300 nm,表面残余拉和压应力分别降低了16.5%和19.4%。

PVD法制备6.5%Si高硅钢过程合金磁性能演化机理研究

PVD法制备Fe-6.5%Si（质量分数,下同）高硅钢过程基片预处理工艺以及Si渗入对合金的软磁性能均有显著影响.采用磁损耗分离的方法剖析铁硅合金磁性变化的内在机理.采用四探针方法测试合金的电阻率;采用基于热分析仪（DSC）配置永磁场技术测量热重（TG）曲线确定合金的居里温度;采用振动样品磁强计（VSM）测定了材料的饱和质量磁矩;采用直流测试装置和硅钢测试仪测试合金的直流交流软磁性能.PVD法制备6.5%Si高硅钢最大磁导率达到16400,相比于初始态3%低硅钢基片,铁损值降低40%-50%.

Shape Memory Effect of As-aged Fe-14Mn-5Si-8Cr-4Ni-0.2C Alloy

The effects of aging temperature on shape memory effect, mechanical properties and microstruc-ture of Fe-14Mn-5Si-8Cr-4Ni-0.2C shape memory alloy have been studied. The results showed that the second phase particles rich in chromium, manganese and silicon precipitate during aging, and thereby increase the hardness and strength of the alloy. The shape recovery ratio can be remarkably improved by aging and a maximum value can be obtained at 1223 K, which is 68% higher than that of the specimen in solid solution state. When the aging temperature is below 1223 K, the amount of second phase particles increases as the aging temperature increases. The size of austenite grain increases with increasing aging temperature. When the temperature is over 1223 K, the second phase particles can not precipitate. The lack of second phase particles and the increase of grain size make the hardness and shape recovery ratio drastically decrease, when the temperature is over 1223 K.

Fe-6.5Si合金粉末形貌特征对磁粉芯性能的影响

通过分析不同制粉方法制取的Fe-6.5Si合金粉末形貌特征,探索其对Fe-6.5Si合金磁粉芯性能的影响.结果表明:采用多角球磨机制取的Fe-6.5Si合金粉末颗粒粒度分布较均匀、多数呈类球形状.该种粉料流动性好、松装密度高,易成型,其制作的Fe-6.5Si合金粉芯磁性能较佳.

Influence of elevated Fe,Ni and Cr levels on tensile properties of SSM-HPDC Al-Si-Mg alloy F357

The microstructures and tensile properties of semi-solid metal high pressure die cast(SSM-HPDC) F357 alloys with low and high levels of Fe,Ni and Cr were compared in different temper conditions.ThermoCalc software was used to predict the different intermetallics that can be expected in the alloys,and scanning electron microscopy(SEM) with energy dispersive spectroscopy(EDS) was used to investigate the actual intermetallics that formed.The influence of these intermetallics on tensile properties was quantified.The results show that lower strength is obtained in the alloy with high Fe,Ni and Cr levels.This is attributed mainly to the formation of more π-Al8FeMg3Si6 phase,which removes strengthening Mg atoms from solid solution.Also,the ductility of the high Fe,Ni and Cr levels alloy is decreased significantly due to microcracking of the higher volume fraction π-Al8FeMg3Si6 and Al9FeNi phases.The combination of lower strength and ductility results in a decrease of the quality index of this alloy compared with the alloy with low levels of Fe,Ni and Cr.