The rapid development of electric vehicles and portable energy storage systems demands improvements in the energy density and cost-effectiveness of lithium-ion batteries,a domain in which Lithium-rich layered cathode(...The rapid development of electric vehicles and portable energy storage systems demands improvements in the energy density and cost-effectiveness of lithium-ion batteries,a domain in which Lithium-rich layered cathode(LLO)materials inherently excel.However,these materials face practical challenges,such as low initial Coulombic efficiency,inferior cycle/rate performance,and voltage decline during cycling,which limit practical application.Our study introduces a surface multi-component integration strategy that incorporates oxygen vacancies into the pristine LLO material Li1.2Mn_(0.6)Ni_(0.2)O_(2).This process involves a brief citric acid treatment followed by calcination,aiming to explore rate-dependent degradation behavior.The induced surface oxygen vacancies can reduce surface oxygen partial pressure and diminish the generation of O_(2)and other highly reactive oxygen species on the surface,thereby facilitating the activation of Li ions trapped in tetrahedral sites while overcoming transport barriers.Additionally,the formation of a spinel-like phase with 3D Li+diffusion channels significantly improves Li^(+)diffusion kinetics and stabilizes the surface structure.The optimally modified sample boasts a discharge capacity of 299.5 mA h g^(-1)at a 0.1 C and 251.6 mA h g^(-1)at a 1 C during the initial activation cycle,with an impressive capacity of 222.1 mA h g^(-1)at a 5 C.Most notably,it retained nearly 70%of its capacity after 300 cycles at this elevated rate.This straightforward,effective,and highly viable modification strategy provides a crucial resolution for overcoming challenges associated with LLO materials,making them more suitable for practical application.展开更多
Effects of alloy elements on the microstructure and crack resistance of Fe-C-Cr weld surfacing layer were investigated. The results show that microstructures of the layer mainly consist of carbides and austenite matri...Effects of alloy elements on the microstructure and crack resistance of Fe-C-Cr weld surfacing layer were investigated. The results show that microstructures of the layer mainly consist of carbides and austenite matrix. Increasing C and Cr contents impair the crack resistance of the layer due to increased amount of brittle carbides. The addition of Ni, Nb or Mo improves the crack resistance of Fe-C-Cr weld surfacing layer by increasing the amount of austenite and forming fine NbC or M 7C 3 carbides in the layer. But, the excessive Nb (>2.50wt%) or Mo (>1.88wt%) impairs the crack resistance of the layer, which has relation with increased carbides or carbide coarsening and austenite matrix solid solution strengthening. The proper combination of C, Cr, Ni, Nb and Mo can further improve not only the crack resistance of Fe-C-Cr weld surfacing layer but also the erosion resistance as a result of fine NbC and M 7C 3 carbides distributing uniformly in austenite matrix. The optimal layer compositions are 3.05wt%C, 20.58wt%Cr, 1.75wt%Ni, 2.00wt%Nb and 1.88wt%Mo.展开更多
Effects of alloying elements on microstructure and erosion resistance of Fe-C-Cr weld surfacing layer have been studied. The experimental results show that increasing C and Cr content favors improving the erosion resi...Effects of alloying elements on microstructure and erosion resistance of Fe-C-Cr weld surfacing layer have been studied. The experimental results show that increasing C and Cr content favors improving the erosion resistance of the layer, and the excessive C and Cr result in decreasing the erosion resistance at 90 deg. erosion. That Mo, Nb or Ti improves the erosion resistance of Fe-C-Cr weld surfacing layer is mainly attributed to increasing the amount of M7C3 and forming fine NbC or TiC in austenite matrix, but the excessive Mo, Nb or Ti is unfavorable. The addition of Mo, Nb and Ti in proper combination possesses stronger effect on improving the erosion resistance and the erosion resistance (εA) of Fe-C-Cr weld surfacing layer with fine NbC, TiC and M7C3 distributing uniformly in austenite matrix obviously increases to 2.81 at 15 deg. erosion and 2.88 at 90 deg. erosion when the layer composition is 3.05C, 20.58Cr, 1.88Mo, 2.00Nb and 1.05Ti (in wt pct).展开更多
To study the damage to an elastic cylinder immersed in fluid, a model of an elastic cylinder wrapped with a porous medium immersed in fluid is designed. This structure can both identify the properties of guided waves ...To study the damage to an elastic cylinder immersed in fluid, a model of an elastic cylinder wrapped with a porous medium immersed in fluid is designed. This structure can both identify the properties of guided waves in a more practical model and address the relationship between the cylinder damage degree and the surface and surrounding medium. The principal motivation is to perform a detailed quantitative analysis of the longitudinal mode and flexural mode in an elastic cylinder wrapped with a porous medium immersed in fluid. The frequency equations for the propagation of waves are derived each for a pervious surface and an impervious surface by employing Biot theory. The influences of the various parameters of the porous medium wrapping layer on the phase velocity and attenuation are discussed. The results show that the influences of porosity on the dispersion curves of guided waves are much more significant than those of thickness,whereas the phase velocity is independent of the static permeability. There is an apparent “mode switching” between the two low-order modes. The characteristics of attenuation are in good agreement with the results from the dispersion curves.This work can support future studies for optimizing the theory on detecting the damage to cylinder or pipeline.展开更多
Using plasma build-up welding technology, Ni60, WC, Cr3C2, and TiC composite powders were clad on the surface of the substrate in a certain proportion according to the metallurgical bonding method to increase the bond...Using plasma build-up welding technology, Ni60, WC, Cr3C2, and TiC composite powders were clad on the surface of the substrate in a certain proportion according to the metallurgical bonding method to increase the bond strength between the coating and the substrate. Scanning electron microscopy and energy dispersive spectroscopy were used to observe the microstructure of the surfacing layer and the chemical composition of the sample. The hardness and wear resistance of the surfacing layer were tested and analyzed by the HV-1000 hardness tester and the impact wear device. The results showed that in the microstructure, fishbone, spider-web, and floral-like structures appeared in the surfacing layer. When the micro-hardness was tested, the depth of the indentation reflected the hardness of the surfacing layer. When analyzing wear resistance, the amount of wear increases with time.展开更多
Layered oxide is a promising cathode material for sodium-ion batteries because of its high-capacity,high operating voltage,and simple synthesis.Cycling performance is an important criterion for evaluating the applicat...Layered oxide is a promising cathode material for sodium-ion batteries because of its high-capacity,high operating voltage,and simple synthesis.Cycling performance is an important criterion for evaluating the application prospects of batteries.However,facing challenges,including phase transitions,ambient stability,side reactions,and irreversible anionic oxygen activity,the cycling performance of layered oxide cathode materials still cannot meet the application requirements.Therefore,this review proposes several strategies to address these challenges.First,bulk doping is introduced from three aspects:cationic single doping,anionic single doping,and multi-ion doping.Second,homogeneous surface coating and concentration gradient modification are reviewed.In addition,methods such as mixed structure design,particle engineering,high-entropy material construction,and integrated modification are proposed.Finally,a summary and outlook provide a new horizon for developing and modifying layered oxide cathode materials.展开更多
Within the framework of the density functional theory and the pseudopotential method,the electronic structure calculations of the“metal-Si(100)”systems with Li,Be and Al as metal coverings of one to four monolayers(...Within the framework of the density functional theory and the pseudopotential method,the electronic structure calculations of the“metal-Si(100)”systems with Li,Be and Al as metal coverings of one to four monolayers(ML)thickness,were carried out.Calculations showed that band gaps of 1.02 eV,0.98 eV and 0.5 eV,respectively,appear in the densities of electronic states when the thickness of Li,Be and Al coverings is one ML.These gaps disappear with increasing thickness of the metal layers:first in the Li-Si system(for two ML),then in the Al-Si system(for three ML)and then in the Be-Si system(for four ML).This behavior of the band gap can be explained by the passivation of the substrate surface states and the peculiarities of the electronic structure of the adsorbed metals.In common the results can be interpreted as describing the possibility of the formation of a two-dimensional silicide with semiconducting properties in Li-Si(100),Be-Si(100)and Al-Si(100)systems.展开更多
The characteristic of the bond zone between Ni-based alloy light beam surfacing layer(SL)and base metal(BM)was investigated by scanning electron microscope,energy dispersive spectrometer and X-ray diffraction.The resu...The characteristic of the bond zone between Ni-based alloy light beam surfacing layer(SL)and base metal(BM)was investigated by scanning electron microscope,energy dispersive spectrometer and X-ray diffraction.The results show that the bond zone,which consists ofγ-Ni orγ-(Fe,Ni)planar crystal band close to SL andα-Fe bright band close to heat affected zone(HAZ),is actually the transition zone of composition and microstructure between SL and HAZ,and the metallurgical bond interface lies between theα-Fe bright band and HAZ.With the increase of light beam heat input from 2kJ/mm to 4kJ/mm,the width of the bond zone increases from 4μm to 15μm,and the morphology of bond interface changes from zigzag to straight.The formation of bond interface indicates the formation of reliable metallurgical bond between SL and BM.展开更多
Investigation has been made on the causes of hot cracking in the surfacing layer of Ni_3Al basealloy by analysing the solidification process of fusion pool and the distribution of thermal stresses. The re-sults show t...Investigation has been made on the causes of hot cracking in the surfacing layer of Ni_3Al basealloy by analysing the solidification process of fusion pool and the distribution of thermal stresses. The re-sults show that the cracking is directly related to both the occurrence of eutectic phase β' (NiAI) within theinterdendritic region and high thernial stresses in the surfacing layer ,and which are caused by selecting highwelding rate. When the process of electric arc weld is changed from straight line rnovement to that along’Z’pattern,the cracking in the surfacing layer of Ni_3Al base alloy is prevented owing to being reduced of boththe cooling rate of liquid in the fusion liool and the speed of the moving heat source. Lowering the outputpower of the electric arc welding could lead to the reducing of rnelting volume of the base material ,and lowerthe arnount of iron atoms dissolving in the fusion pool ,so that the trend of the eutectic reaction within the in-terdendritic region is reduced,and which is helpful to suppress the cracking in the surfacing layer of Ni_3Albase alloy.展开更多
Investigation has been made into the causes of cracking in the Surfacing welding layer of Ni3Al based alloy by analysing both the liqu id-to-solid transformation in the molten pool and the distribution of thermal stre...Investigation has been made into the causes of cracking in the Surfacing welding layer of Ni3Al based alloy by analysing both the liqu id-to-solid transformation in the molten pool and the distribution of thermal stress within the surfacing welding layer. The results show that cracking in the surfacing welding layer is directly related to the producing of eutectic phase β' (NiAl) in the interdendritic region and high thermal stress within the surfacing welding layer. When the process of electric arc surfacing welding is changed from along straight line to along' Z' pattern, cracking in the surfacing welding layer of Ni3Al based alloy is prevented due to being reduced of both the cooling rate of liquid in the molten pool and the moving speed of the heat source. Reducing the melting volume of the substrate material by lowering the output power of electric arc welding would make the content of iron atoms in the molten pool decrease. and this also can reduce the trend of the eutectic reaction in the interdendfitic region and is helpful to Suppress cracking in the surfacing welding layer.展开更多
This paper uses a Modified Soil-Plant-Atmosphere Scheme (MSPAS) to study the interaction between land surface and atmospheric boundary layer processes. The scheme is composed of two main parts: atmospheric boundary la...This paper uses a Modified Soil-Plant-Atmosphere Scheme (MSPAS) to study the interaction between land surface and atmospheric boundary layer processes. The scheme is composed of two main parts: atmospheric boundary layer processes and land surface processes. Compared with SiB and BATS, which are famous for their detailed parameterizations of physical variables, this simplified model is more convenient and saves much more computation time. Though simple, the feasibility of the model is well proved in this paper. The numerical simulation results from MSPAS show good agreement with reality. The scheme is used to obtain reasonable simulations for diurnal variations of heat balance, potential temperature of boundary layer, and wind field, and spatial distributions of temperature, specific humidity, vertical velocity, turbulence kinetic energy, and turbulence exchange coefficient over desert and oasis. In addition, MSPAS is used to simulate the interaction between desert and oasis at night, and again it obtains reasonable results. This indicates that MSPAS can be used to study the interaction between land surface processes and the atmospheric boundary layer over various underlying surfaces and can be extended for regional climate and numerical weather prediction study.展开更多
The Regional Atmospheric Modeling System (RAMS) and the computational fluid dynamics (CFD) codes known as FLUENT are combinatorially applied in a multi-scale numerical simulation of the urban surface layer (USL)...The Regional Atmospheric Modeling System (RAMS) and the computational fluid dynamics (CFD) codes known as FLUENT are combinatorially applied in a multi-scale numerical simulation of the urban surface layer (USL). RAMS and FLUENT are combined as a multi-scale numerical modeling system, in which the RAMS simulated data are delivered to the computational model for FLUENT simulation in an offline way. Numerical simulations are performed to present and preliminarily validate the capability of the multi-scale modeling system, and the results show that the modeling system can reasonably provide information on the meteorological elements in an urban area from the urban scale to the city-block scale, especially the details of the turbulent flows within the USL.展开更多
Based on specific geology and mining conditions of certain coal working face in China, a series of numerical models under different unconsolidated layers thickness were respectively established by employing FLAC3D. Th...Based on specific geology and mining conditions of certain coal working face in China, a series of numerical models under different unconsolidated layers thickness were respectively established by employing FLAC3D. The relationship between the unconsolidated layers thickness and surface movement laws was studied. Maximum surface subsidence, Maximum horizontal displacement and surface subsidence degree were obtained. Contours of surface subsidence/horizontal displacement and curves were drawn. Some laws of surface subsidence/horizontal displacement were analyzed. The role of the unconsolidated layers in surface subsidence was revealed. It is significant to predict surface subsidence of thick unconsolidated layers for coal mine and take effective measures to control surface subsidence.展开更多
The propagation of surface acoustic waves in layered piezoelectric structureswith initial stresses is investigated. The phase velocity equations are obtained for electricallyfree and shorted cases, respectively. Effec...The propagation of surface acoustic waves in layered piezoelectric structureswith initial stresses is investigated. The phase velocity equations are obtained for electricallyfree and shorted cases, respectively. Effects of the initial stresses on the phase velocity and theelectromechanical coupling coefficient for the fundamental mode of the layered piezoelectricstructures are discussed. Numerical results for the c-axis oriented film of LiNbO_3 on a sapphiresubstrate are given. It is found that the fractional change in phase velocity is a linear functionwith the initial stresses, and the electromechanical coupling factor increases with an increase ofthe absolute values of the compressive initial stresses. The results are useful for the design ofsurface acoustic wave devices.展开更多
In this paper,we proposal stream surface and stream layer.By using classical tensor calculus,we derive 3-D Navier-Stokes Equations(NSE)in the stream layer under semigeodesic coordinate system,Navier-Stokes equation on...In this paper,we proposal stream surface and stream layer.By using classical tensor calculus,we derive 3-D Navier-Stokes Equations(NSE)in the stream layer under semigeodesic coordinate system,Navier-Stokes equation on the stream surface and 2-D Navier-Stokes equations on a two dimensional manifold. After introducing stream function on the stream surface,a nonlinear initial-boundary value problem satisfies by stream function is obtained,existence and uniqueness of its solution are proven.Based this theory we proposal a new method called"dimension split method"to solve 3D NSE.展开更多
As salinity stratification is necessary to form the barrier layer (BL), the quantification of its role in BL interannual variability is crucial. This study assessed salinity variability and its effect on the BL in t...As salinity stratification is necessary to form the barrier layer (BL), the quantification of its role in BL interannual variability is crucial. This study assessed salinity variability and its effect on the BL in the equatorial Pacific using outputs from Beijing Normal University Earth System Model (BNU-ESM) simulations. A comparison between observations and the BNU-ESM simulations demonstrated that BNU-ESM has good capability in reproducing most of the interannual features observed in nature. Despite some discrepancies in both magnitude and location of the interannual variability centers, the displacements of sea surface salinity (SSS), barrier layer thickness (BLT), and SST simulated by BNU-ESM in the equatorial Pacific are realistic. During E1 Nifio, for example, the modeled interannual anomalies of BLT, mixed layer depth, and isothermal layer depth, exhibit good correspondence with observations, including the development and decay of E1 Nifio in the central Pacific, whereas the intensity of the interannual variabilities is weaker relative to observations. Due to the bias in salinity simulations, the SSS front extends farther west along the equator, whereas BLT variability is weaker in the central Pacific than in observations. Further, the BNU-ESM simulations were examined to assess the relative effects of salinity and temperature variability on BLT. Consistent with previous observation-based analyses, the interannual salinity variability can make a significant contribution to BLT relative to temperature in the western-central equatorial Pacific.展开更多
Large eddy simulation (LES) is used to investigate contrasting dynamic characteristics of shear turbulence (ST) and Langmuir circulation (LC) in the surface mixed layer (SML). ST is usually induced by wind for...Large eddy simulation (LES) is used to investigate contrasting dynamic characteristics of shear turbulence (ST) and Langmuir circulation (LC) in the surface mixed layer (SML). ST is usually induced by wind forcing in SML. LC can be driven by wave-current interaction that includes the roles of wind, wave and vortex forcing. The LES results show that LC suppresses the horizontal velocity and greatly modifies the downwind velocity profile, but increases the vertical velocity. The strong downweUing jets of LC accelerate and increase the downward transport of energy as compared to ST. The vertical eddy viscosity Km of LC is much larger than that of ST. Strong mixing induced by LC has two locations. They are located in the 26s-36s (Stokes depth scale) and the lower layer of the SML, respectively. Its value and position change periodically with time. In contrast, maximum Km induced by ST is located in the middle depth of the SML. The turbulent kinetic energy (TKE) generated by LC is larger than that by ST. The differences in vertical distributions of TKE and Krn are evident. Therefore, the parameterization of LC cannot be solely based on TKE. For deep SML, the convection of large-scale eddies in LC plays a main role in downward transport of energy and LC can induce stronger velocity shear (S2) near the SML base. In addition, the large-scale eddies and Sz induced by LC is changing all the time, which needs to be fully considered in the parameterization of LC.展开更多
Plasma rare earth nitriding of nanocrystallized surface layer of 3J33B steel at 350 and 410℃ for different time was studied. The microstructure observation and X-ray diffraction(XRD) analysis show that the nitrid...Plasma rare earth nitriding of nanocrystallized surface layer of 3J33B steel at 350 and 410℃ for different time was studied. The microstructure observation and X-ray diffraction(XRD) analysis show that the nitriding layer consists of compound layer (γ′-Fe4N) and diffusion layer (α-Fe). Lanthanum content profiles in nanocrystallized surface layer were measured using glow discharge spectometry(GDS). The results show that lanthanum can diffuse into the surface layer of the steel to a large depth. Based on the experimental results mentioned above, the diffusion coefficients and activation energy of lanthanum in γ′ phase are calculated to be 1.03×10 -15 cm2/s (350℃), 1.75×10 -15 cm2/s (410℃) and 31.313kJ/mol, respectively.展开更多
In southern China, cold air is a common weather process during the winter season; it can cause strong wind, sharp temperature decreases, and even the snow or freezing rain events. However, the features of the atmosphe...In southern China, cold air is a common weather process during the winter season; it can cause strong wind, sharp temperature decreases, and even the snow or freezing rain events. However, the features of the atmospheric boundary layer during cold air passage are not clearly understood due to the lack of comprehensive observation data, especially regarding turbulence. In this study, four-layer gradient meteorological observation data and one-layer, 10-Hz ultrasonic anemometer-thermometer monitoring data from the northern side of Poyang Lake were employed to study the main features of the surface boundary layer during a strong cold-air passage over southern China. The results show that, with the passage of a cold air front, the wind speed exhibits low-frequency variations and that the wind systematically descends. During the strong wind period, the wind speed increases with height in the surface layer. Regular gust packets are superimposed on the basic strong wind flow. Before the passage of cold air, the wind gusts exhibit a coherent structure. The wind and turbulent momentum fluxes are small, although the gusty wind momentum flux is slightly larger than the turbulent momentum flux. However, during the invasion of cold air, both the gusty wind and turbulent momentum fluxes increase rapidly with wind speed, and the turbulent momentum flux is larger than the gusty wind momentum flux during the strong wind period. After the cold air invasion, this structure almost disappears.展开更多
基金supported by the National Key R&D Program of China(2021YFB2401800)the National Natural Science Foundation of China(21875022,22179008)+4 种基金the Yibin‘Jie Bang Gua Shuai’(2022JB004)the support from the Beijing Nova Program(20230484241)the support from the Postdoctoral Fellowship Program of CPSF(GZB20230931)the support from the 4B7B beam line of Beijing Synchrotron Radiation Facility(2021-BEPC-PT-005924,2021-BEPC-PT-005967)BL08U1A beam line of Shanghai Synchrotron Radiation Facility(2021-SSRF-PT-017710)。
文摘The rapid development of electric vehicles and portable energy storage systems demands improvements in the energy density and cost-effectiveness of lithium-ion batteries,a domain in which Lithium-rich layered cathode(LLO)materials inherently excel.However,these materials face practical challenges,such as low initial Coulombic efficiency,inferior cycle/rate performance,and voltage decline during cycling,which limit practical application.Our study introduces a surface multi-component integration strategy that incorporates oxygen vacancies into the pristine LLO material Li1.2Mn_(0.6)Ni_(0.2)O_(2).This process involves a brief citric acid treatment followed by calcination,aiming to explore rate-dependent degradation behavior.The induced surface oxygen vacancies can reduce surface oxygen partial pressure and diminish the generation of O_(2)and other highly reactive oxygen species on the surface,thereby facilitating the activation of Li ions trapped in tetrahedral sites while overcoming transport barriers.Additionally,the formation of a spinel-like phase with 3D Li+diffusion channels significantly improves Li^(+)diffusion kinetics and stabilizes the surface structure.The optimally modified sample boasts a discharge capacity of 299.5 mA h g^(-1)at a 0.1 C and 251.6 mA h g^(-1)at a 1 C during the initial activation cycle,with an impressive capacity of 222.1 mA h g^(-1)at a 5 C.Most notably,it retained nearly 70%of its capacity after 300 cycles at this elevated rate.This straightforward,effective,and highly viable modification strategy provides a crucial resolution for overcoming challenges associated with LLO materials,making them more suitable for practical application.
文摘Effects of alloy elements on the microstructure and crack resistance of Fe-C-Cr weld surfacing layer were investigated. The results show that microstructures of the layer mainly consist of carbides and austenite matrix. Increasing C and Cr contents impair the crack resistance of the layer due to increased amount of brittle carbides. The addition of Ni, Nb or Mo improves the crack resistance of Fe-C-Cr weld surfacing layer by increasing the amount of austenite and forming fine NbC or M 7C 3 carbides in the layer. But, the excessive Nb (>2.50wt%) or Mo (>1.88wt%) impairs the crack resistance of the layer, which has relation with increased carbides or carbide coarsening and austenite matrix solid solution strengthening. The proper combination of C, Cr, Ni, Nb and Mo can further improve not only the crack resistance of Fe-C-Cr weld surfacing layer but also the erosion resistance as a result of fine NbC and M 7C 3 carbides distributing uniformly in austenite matrix. The optimal layer compositions are 3.05wt%C, 20.58wt%Cr, 1.75wt%Ni, 2.00wt%Nb and 1.88wt%Mo.
文摘Effects of alloying elements on microstructure and erosion resistance of Fe-C-Cr weld surfacing layer have been studied. The experimental results show that increasing C and Cr content favors improving the erosion resistance of the layer, and the excessive C and Cr result in decreasing the erosion resistance at 90 deg. erosion. That Mo, Nb or Ti improves the erosion resistance of Fe-C-Cr weld surfacing layer is mainly attributed to increasing the amount of M7C3 and forming fine NbC or TiC in austenite matrix, but the excessive Mo, Nb or Ti is unfavorable. The addition of Mo, Nb and Ti in proper combination possesses stronger effect on improving the erosion resistance and the erosion resistance (εA) of Fe-C-Cr weld surfacing layer with fine NbC, TiC and M7C3 distributing uniformly in austenite matrix obviously increases to 2.81 at 15 deg. erosion and 2.88 at 90 deg. erosion when the layer composition is 3.05C, 20.58Cr, 1.88Mo, 2.00Nb and 1.05Ti (in wt pct).
基金Project supported by the National Natural Science Foundation of China (Grant No.12174085)the Postgraduate Research and Practice Innovation Program of Jiangsu Province,China (Grant No.KYCX21_0478)。
文摘To study the damage to an elastic cylinder immersed in fluid, a model of an elastic cylinder wrapped with a porous medium immersed in fluid is designed. This structure can both identify the properties of guided waves in a more practical model and address the relationship between the cylinder damage degree and the surface and surrounding medium. The principal motivation is to perform a detailed quantitative analysis of the longitudinal mode and flexural mode in an elastic cylinder wrapped with a porous medium immersed in fluid. The frequency equations for the propagation of waves are derived each for a pervious surface and an impervious surface by employing Biot theory. The influences of the various parameters of the porous medium wrapping layer on the phase velocity and attenuation are discussed. The results show that the influences of porosity on the dispersion curves of guided waves are much more significant than those of thickness,whereas the phase velocity is independent of the static permeability. There is an apparent “mode switching” between the two low-order modes. The characteristics of attenuation are in good agreement with the results from the dispersion curves.This work can support future studies for optimizing the theory on detecting the damage to cylinder or pipeline.
基金Funded by the Scientific Research Foundation of Shandong University of Science and Technology for Recruited Talents(No.2014RCJJ041)the National Natural Science Foundation of China(51774199)
文摘Using plasma build-up welding technology, Ni60, WC, Cr3C2, and TiC composite powders were clad on the surface of the substrate in a certain proportion according to the metallurgical bonding method to increase the bond strength between the coating and the substrate. Scanning electron microscopy and energy dispersive spectroscopy were used to observe the microstructure of the surfacing layer and the chemical composition of the sample. The hardness and wear resistance of the surfacing layer were tested and analyzed by the HV-1000 hardness tester and the impact wear device. The results showed that in the microstructure, fishbone, spider-web, and floral-like structures appeared in the surfacing layer. When the micro-hardness was tested, the depth of the indentation reflected the hardness of the surfacing layer. When analyzing wear resistance, the amount of wear increases with time.
基金the Fundamental Research Funds for the Central Universities,China(No.06500177)the National Natural Science Foundation of China Joint Fund Project(No.U1764255)。
文摘Layered oxide is a promising cathode material for sodium-ion batteries because of its high-capacity,high operating voltage,and simple synthesis.Cycling performance is an important criterion for evaluating the application prospects of batteries.However,facing challenges,including phase transitions,ambient stability,side reactions,and irreversible anionic oxygen activity,the cycling performance of layered oxide cathode materials still cannot meet the application requirements.Therefore,this review proposes several strategies to address these challenges.First,bulk doping is introduced from three aspects:cationic single doping,anionic single doping,and multi-ion doping.Second,homogeneous surface coating and concentration gradient modification are reviewed.In addition,methods such as mixed structure design,particle engineering,high-entropy material construction,and integrated modification are proposed.Finally,a summary and outlook provide a new horizon for developing and modifying layered oxide cathode materials.
文摘Within the framework of the density functional theory and the pseudopotential method,the electronic structure calculations of the“metal-Si(100)”systems with Li,Be and Al as metal coverings of one to four monolayers(ML)thickness,were carried out.Calculations showed that band gaps of 1.02 eV,0.98 eV and 0.5 eV,respectively,appear in the densities of electronic states when the thickness of Li,Be and Al coverings is one ML.These gaps disappear with increasing thickness of the metal layers:first in the Li-Si system(for two ML),then in the Al-Si system(for three ML)and then in the Be-Si system(for four ML).This behavior of the band gap can be explained by the passivation of the substrate surface states and the peculiarities of the electronic structure of the adsorbed metals.In common the results can be interpreted as describing the possibility of the formation of a two-dimensional silicide with semiconducting properties in Li-Si(100),Be-Si(100)and Al-Si(100)systems.
基金Item Sponsored by National Natural Science Foundation of China(59905017)
文摘The characteristic of the bond zone between Ni-based alloy light beam surfacing layer(SL)and base metal(BM)was investigated by scanning electron microscope,energy dispersive spectrometer and X-ray diffraction.The results show that the bond zone,which consists ofγ-Ni orγ-(Fe,Ni)planar crystal band close to SL andα-Fe bright band close to heat affected zone(HAZ),is actually the transition zone of composition and microstructure between SL and HAZ,and the metallurgical bond interface lies between theα-Fe bright band and HAZ.With the increase of light beam heat input from 2kJ/mm to 4kJ/mm,the width of the bond zone increases from 4μm to 15μm,and the morphology of bond interface changes from zigzag to straight.The formation of bond interface indicates the formation of reliable metallurgical bond between SL and BM.
基金supported by the foundation of '863' high technology in China
文摘Investigation has been made on the causes of hot cracking in the surfacing layer of Ni_3Al basealloy by analysing the solidification process of fusion pool and the distribution of thermal stresses. The re-sults show that the cracking is directly related to both the occurrence of eutectic phase β' (NiAI) within theinterdendritic region and high thernial stresses in the surfacing layer ,and which are caused by selecting highwelding rate. When the process of electric arc weld is changed from straight line rnovement to that along’Z’pattern,the cracking in the surfacing layer of Ni_3Al base alloy is prevented owing to being reduced of boththe cooling rate of liquid in the fusion liool and the speed of the moving heat source. Lowering the outputpower of the electric arc welding could lead to the reducing of rnelting volume of the base material ,and lowerthe arnount of iron atoms dissolving in the fusion pool ,so that the trend of the eutectic reaction within the in-terdendritic region is reduced,and which is helpful to suppress the cracking in the surfacing layer of Ni_3Albase alloy.
文摘Investigation has been made into the causes of cracking in the Surfacing welding layer of Ni3Al based alloy by analysing both the liqu id-to-solid transformation in the molten pool and the distribution of thermal stress within the surfacing welding layer. The results show that cracking in the surfacing welding layer is directly related to the producing of eutectic phase β' (NiAl) in the interdendritic region and high thermal stress within the surfacing welding layer. When the process of electric arc surfacing welding is changed from along straight line to along' Z' pattern, cracking in the surfacing welding layer of Ni3Al based alloy is prevented due to being reduced of both the cooling rate of liquid in the molten pool and the moving speed of the heat source. Reducing the melting volume of the substrate material by lowering the output power of electric arc welding would make the content of iron atoms in the molten pool decrease. and this also can reduce the trend of the eutectic reaction in the interdendfitic region and is helpful to Suppress cracking in the surfacing welding layer.
基金supported by the National Natural Science Foundation of China (Grant No.40275004)the State Key Laboratory of Atmosphere Physics and Chemistry,and the City University of Hong Kong(Grant No.8780046)the City University of Hong Kong Strategic Research(Grant No.7001038)
文摘This paper uses a Modified Soil-Plant-Atmosphere Scheme (MSPAS) to study the interaction between land surface and atmospheric boundary layer processes. The scheme is composed of two main parts: atmospheric boundary layer processes and land surface processes. Compared with SiB and BATS, which are famous for their detailed parameterizations of physical variables, this simplified model is more convenient and saves much more computation time. Though simple, the feasibility of the model is well proved in this paper. The numerical simulation results from MSPAS show good agreement with reality. The scheme is used to obtain reasonable simulations for diurnal variations of heat balance, potential temperature of boundary layer, and wind field, and spatial distributions of temperature, specific humidity, vertical velocity, turbulence kinetic energy, and turbulence exchange coefficient over desert and oasis. In addition, MSPAS is used to simulate the interaction between desert and oasis at night, and again it obtains reasonable results. This indicates that MSPAS can be used to study the interaction between land surface processes and the atmospheric boundary layer over various underlying surfaces and can be extended for regional climate and numerical weather prediction study.
基金This study was supported by the National Natural Science Foundation of China (Grant Nos. 40233030, 40405004, 40405014).
文摘The Regional Atmospheric Modeling System (RAMS) and the computational fluid dynamics (CFD) codes known as FLUENT are combinatorially applied in a multi-scale numerical simulation of the urban surface layer (USL). RAMS and FLUENT are combined as a multi-scale numerical modeling system, in which the RAMS simulated data are delivered to the computational model for FLUENT simulation in an offline way. Numerical simulations are performed to present and preliminarily validate the capability of the multi-scale modeling system, and the results show that the modeling system can reasonably provide information on the meteorological elements in an urban area from the urban scale to the city-block scale, especially the details of the turbulent flows within the USL.
基金Project(2007BAK28B03)supported by the National Eleventh-Five Year Research Program of ChinaProject(2010YD05)supported by the Fundamental Research Funds for the Central UniversitiesProject(200911036)supported by the Ministry of Land and Resources Research Special
文摘Based on specific geology and mining conditions of certain coal working face in China, a series of numerical models under different unconsolidated layers thickness were respectively established by employing FLAC3D. The relationship between the unconsolidated layers thickness and surface movement laws was studied. Maximum surface subsidence, Maximum horizontal displacement and surface subsidence degree were obtained. Contours of surface subsidence/horizontal displacement and curves were drawn. Some laws of surface subsidence/horizontal displacement were analyzed. The role of the unconsolidated layers in surface subsidence was revealed. It is significant to predict surface subsidence of thick unconsolidated layers for coal mine and take effective measures to control surface subsidence.
基金Project supported by the National Natural Science Foundation of China(Nos.10132010 and 10072033)
文摘The propagation of surface acoustic waves in layered piezoelectric structureswith initial stresses is investigated. The phase velocity equations are obtained for electricallyfree and shorted cases, respectively. Effects of the initial stresses on the phase velocity and theelectromechanical coupling coefficient for the fundamental mode of the layered piezoelectricstructures are discussed. Numerical results for the c-axis oriented film of LiNbO_3 on a sapphiresubstrate are given. It is found that the fractional change in phase velocity is a linear functionwith the initial stresses, and the electromechanical coupling factor increases with an increase ofthe absolute values of the compressive initial stresses. The results are useful for the design ofsurface acoustic wave devices.
文摘In this paper,we proposal stream surface and stream layer.By using classical tensor calculus,we derive 3-D Navier-Stokes Equations(NSE)in the stream layer under semigeodesic coordinate system,Navier-Stokes equation on the stream surface and 2-D Navier-Stokes equations on a two dimensional manifold. After introducing stream function on the stream surface,a nonlinear initial-boundary value problem satisfies by stream function is obtained,existence and uniqueness of its solution are proven.Based this theory we proposal a new method called"dimension split method"to solve 3D NSE.
基金supported by the National Natural Science Foundation of China(Grant Nos.41376039,41376019 and 41421005)the NSFC-Shandong Joint Fund for Marine Science Research Centers(Grant No.U1406401)+1 种基金the IOCAS through the CAS Strategic Priority Project[the Western Pacific Ocean System(WPOS)]the WPOS in the "Strategic Priority Research Program" of the Chinese Academy of Sciences(Grant No.XDA11010304)
文摘As salinity stratification is necessary to form the barrier layer (BL), the quantification of its role in BL interannual variability is crucial. This study assessed salinity variability and its effect on the BL in the equatorial Pacific using outputs from Beijing Normal University Earth System Model (BNU-ESM) simulations. A comparison between observations and the BNU-ESM simulations demonstrated that BNU-ESM has good capability in reproducing most of the interannual features observed in nature. Despite some discrepancies in both magnitude and location of the interannual variability centers, the displacements of sea surface salinity (SSS), barrier layer thickness (BLT), and SST simulated by BNU-ESM in the equatorial Pacific are realistic. During E1 Nifio, for example, the modeled interannual anomalies of BLT, mixed layer depth, and isothermal layer depth, exhibit good correspondence with observations, including the development and decay of E1 Nifio in the central Pacific, whereas the intensity of the interannual variabilities is weaker relative to observations. Due to the bias in salinity simulations, the SSS front extends farther west along the equator, whereas BLT variability is weaker in the central Pacific than in observations. Further, the BNU-ESM simulations were examined to assess the relative effects of salinity and temperature variability on BLT. Consistent with previous observation-based analyses, the interannual salinity variability can make a significant contribution to BLT relative to temperature in the western-central equatorial Pacific.
基金The National Basic Research Program of China(973 Program)under contract No.2011CB403504the China Postdoctoral Science Foundation under contract No.2013M542216the National Natural Science Foundation of China under contract No.41206011
文摘Large eddy simulation (LES) is used to investigate contrasting dynamic characteristics of shear turbulence (ST) and Langmuir circulation (LC) in the surface mixed layer (SML). ST is usually induced by wind forcing in SML. LC can be driven by wave-current interaction that includes the roles of wind, wave and vortex forcing. The LES results show that LC suppresses the horizontal velocity and greatly modifies the downwind velocity profile, but increases the vertical velocity. The strong downweUing jets of LC accelerate and increase the downward transport of energy as compared to ST. The vertical eddy viscosity Km of LC is much larger than that of ST. Strong mixing induced by LC has two locations. They are located in the 26s-36s (Stokes depth scale) and the lower layer of the SML, respectively. Its value and position change periodically with time. In contrast, maximum Km induced by ST is located in the middle depth of the SML. The turbulent kinetic energy (TKE) generated by LC is larger than that by ST. The differences in vertical distributions of TKE and Krn are evident. Therefore, the parameterization of LC cannot be solely based on TKE. For deep SML, the convection of large-scale eddies in LC plays a main role in downward transport of energy and LC can induce stronger velocity shear (S2) near the SML base. In addition, the large-scale eddies and Sz induced by LC is changing all the time, which needs to be fully considered in the parameterization of LC.
文摘Plasma rare earth nitriding of nanocrystallized surface layer of 3J33B steel at 350 and 410℃ for different time was studied. The microstructure observation and X-ray diffraction(XRD) analysis show that the nitriding layer consists of compound layer (γ′-Fe4N) and diffusion layer (α-Fe). Lanthanum content profiles in nanocrystallized surface layer were measured using glow discharge spectometry(GDS). The results show that lanthanum can diffuse into the surface layer of the steel to a large depth. Based on the experimental results mentioned above, the diffusion coefficients and activation energy of lanthanum in γ′ phase are calculated to be 1.03×10 -15 cm2/s (350℃), 1.75×10 -15 cm2/s (410℃) and 31.313kJ/mol, respectively.
基金supported by the National Natural Science Foundation of China (Grant Nos. 40965001 and 40875008)the open project of State Key Laboratory of Severe Weather,Chinese Academy of Meteorological Sciences (Grant No.2009LASW-A02)
文摘In southern China, cold air is a common weather process during the winter season; it can cause strong wind, sharp temperature decreases, and even the snow or freezing rain events. However, the features of the atmospheric boundary layer during cold air passage are not clearly understood due to the lack of comprehensive observation data, especially regarding turbulence. In this study, four-layer gradient meteorological observation data and one-layer, 10-Hz ultrasonic anemometer-thermometer monitoring data from the northern side of Poyang Lake were employed to study the main features of the surface boundary layer during a strong cold-air passage over southern China. The results show that, with the passage of a cold air front, the wind speed exhibits low-frequency variations and that the wind systematically descends. During the strong wind period, the wind speed increases with height in the surface layer. Regular gust packets are superimposed on the basic strong wind flow. Before the passage of cold air, the wind gusts exhibit a coherent structure. The wind and turbulent momentum fluxes are small, although the gusty wind momentum flux is slightly larger than the turbulent momentum flux. However, during the invasion of cold air, both the gusty wind and turbulent momentum fluxes increase rapidly with wind speed, and the turbulent momentum flux is larger than the gusty wind momentum flux during the strong wind period. After the cold air invasion, this structure almost disappears.