主轴转向对再生Al-Si-Fe-Mg合金多道次搅拌摩擦加工区组织和性能的影响

对4.5 mm厚的再生Al-7.0Si-0.85Fe-0.30Mg合金板进行相同主轴转向1~3道次和改变第2道次主轴转向2,3道次的搅拌摩擦加工,研究了主轴转向对搅拌摩擦加工区组织和力学性能的影响。结果表明:随着加工道次的增加,加工区的面积以及前进侧热机影响区的宽度增大,加工核心区的富铁相、共晶硅等第二相颗粒长度减小,圆整度提高,强度和硬度无显著改变,断后伸长率显著提高。改变第2道次主轴转向后加工区面积较相同主轴转向时减小,但组织对称性提高,前进侧热机影响区宽度减小;改变主轴转向后,第二相颗粒尺寸变化不明显,但圆整度显著降低,强度和硬度的变化也不明显,断后伸长率略有提高。

Petrological and Geochemical Constraints on the Protoliths of Serpentine-Magnetite Ores in the Zhaoanzhuang Iron Deposit,Southern North China Craton

The uncommon Mg-rich and Ti-poor Zhaoanzhuang serpentine-magnetite ores within Taihua Group of the North China Craton （NCC） remain unclear whether the protolith was sourced from ultramafic rocks or chemical sedimentary sequences. Here we present integrated petrographic and geochemical studies to characterize the protoliths and to gain insights on the ore-forming processes. Iron ores mainly contain low-Ti magnetite （TiO2 -0.1wt%） and serpentine （Mg#=92.42-96.55）, as well as residual olivine （Fo=89-90）, orthopyroxene （En=89-90） and hornblende. Magnetite in the iron ores shows lower AI, Sc, Ti, Cr, Zn relative to that from ultramafic Fe-Ti-V iron ores, but similar to that from metamorphic chemical sedimentary iron deposit. In addition, interstitial minerals of dolomite, calcite, apatite and anhydrite are intergrown with magnetite and serpentine, revealing they were metamorphic, but not magmatic or late hydrothermal minerals. Wall rocks principally contain magnesian silicates of olivine （Fo=83-87）, orthopyroxene （En=82-86）, humite （Mg#=82-84） and hornblende [XMg=0.87--0.96]. Dolomite, apatite and anhydrite together with minor magnetite, thorianite （Th-rich oxide） and monazite （LREE-rich phosphate） are often seen as relicts or inclusions within magnesian silicates in the wall rocks, revealing that they were primary or earlier metamorphic minerals than magnesian silicates. And olivine exists as subhedral interstitial texture between hornblende, which shows later formation of olivine than hornblende and does not conform with sequence of magmatic crystallization. All these mineralogical features thus bias towards their metamorphic, rather than magmatic origin. The dominant chemical components of the iron ores are SiO2 （4.77-25.23wt%）, Fe203T （32.9-80.39wt%） and MgO （5.72- 27.17wt%） and uniformly, those of the wall rocks are also SiO2 （16.34-48.72wt%）, MgO （16.71- 33.97wt%） and Fe203T （6.98-30.92wt%）. The striking high Fe-Mg-Si contents reveal that protolith of the Zhaoanzhuang iron deposit was more likely to be chemical sedimentary rocks. The distinct high-Mg feature and presence of abundant anhydrite possibly indicate it primarily precipitated in a confined seawater basin under an evaporitic environment. Besides, higher contents of AI, Ti, P, Th, U, Pb, REE relative to other Precambrian iron-rich chemical precipitates （BIF） suggest some clastic terrestrial materials were probably input. As a result, we think the Zhaoanzhuang iron deposit had experienced the initial Fe-Mg-Si marine precipitation, followed by further Mg enrichment through marine evaporated process, subsequent high-grade metamorphism and late-stage hydrothermal fluid modification.

Mg含量对Al-Si-Mg铸造合金微观组织与力学性能的影响

本文研究了Mg含量分别为 0 .0 0wt%、0 .35wt%和 0 .70wt%的Al 7wt%Si Mg铸造合金的微观组织和力学性能。通过变质处理和改变凝固速率 ,可观察到不同的微观组织。DSC试验分析了不同Mg含量合金中相的变化。结果表明 ,在较高Mg含量的合金中 ,未变质的共晶Si粗化 ,变质的共晶Si变质不完全。在Al 7wt%Si 0 .70wt%Mg合金中 ,富Fe相是粗大的π相 (Al9FeMg3Si5)和少量的针状 β相 (Al5FeSi)。相反 ,在Al 7wt%Si 0 .35wt%Mg合金中 ,富Fe相是针状的 β相 (Al5FeSi)。随着合金中Mg含量的增加 ,合金的抗拉强度增大 ,延伸率却降低。

Effect of Ni addition on microstructure and mechanical properties of Al–Mg–Si–Cu–Zn alloys with a high Mg/Si ratio

The effect of adding 0.03wt%Ni on the microstructure and mechanical properties of Al–Mg–Si–Cu–Zn alloys was systematically studied.The results reveal that the number density of spherical Fe-rich phases within grains increases with the addition of Ni,accompanied by the formation of Q(Al3Mg9Si7Cu2)precipitates around the spherical Fe-rich phases.Additionally,Ni addition is beneficial to reducing the grain size in the as-cast state.During the homogenization process,Q phases could be completely dissolved and the grain size could remain basically unchanged.However,compared with the Ni-free alloy,the Fe-rich phase in the Ni-containing alloy is more likely to undergo the phase transformation and further form more spherical particles during homogenization treatment.After thermomechanical processing,the distribution of Fe-rich phases in the Ni-containing alloy was further greatly improved and directly resulted in a greater formability than that of the Ni-free alloy.Accordingly,a reasonable Ni addition positively affected the microstructure and formability of the alloys.

不同浓度富Fe相粒子对Al-Mg-Si-Cu系合金弯边性能的影响

通过弯边变形,拉伸实验,OM,SEM和TEM观察等手段研究了不同浓度富Fe相粒子对Al-Mg-Si-Cu系合金板材弯边性能的影响规律.结果表明,随着富Fe相浓度增加,合金板材沿纵横向的弯边性能存在较大差异,不含富Fe相粒子的合金板材沿2个方向弯边变形180°后外表面粗糙度增加,处于中等浓度(含0.2%Fe)时沿2个方向弯边变形后均具有优异的外表面质量,但是随着富Fe相浓度的进一步增加(至0.5%Fe),合金板材沿横向弯边变形后在外表面出现微裂纹.虽然富Fe相粒子浓度增加对合金板材纵横向延伸率影响不大,但是拉伸断口、弯边和拉伸断裂后的侧表面组织均表明,不含富Fe相的合金板材弯边变形后外表面粗糙度增加与剪切带组织密切相关,而含有较高浓度富Fe相粒子的合金板材弯边变形后外表面出现的微裂纹与粗大富Fe相粒子的尺寸、形态以及分布状态密切相关.此外,根据不同浓度富Fe相粒子与合金弯边性能间的定量关系,提出了合金弯边变形后外表面粗糙度增加和微裂纹形成的模型示意图.

Evolution Behavior of γ-Al_(3.5)FeSi in Mg Melt and a Separation Method of Fe from Al–Si–Fe Alloys

The recycling of high Fe-content Al-Si alloys is a green industry. Eliminating the harmful effect of Fe, achieving the separation of Al and Fe is one of the key problems. Different from traditional methods for iron removal, a novel method using magnesium melt to separate Al and Fe is proposed. By introducing Al-14Si-5Fe alloy into Mg melt, it was found that the γ-Al3.5FeSi phase evolves to Al3SiFe3.5 and Al5Fe2 through the melting and solidification process. Compared with the primary Al-rich γ-Al3.5FeSi phase, the formation of Fe-rich A13SiFe3.5 is quite beneficial for the separation of Al and Fe. Mg-Si-Al and Mg-Si-Fe alloys can be obtained at the top and bottom of the cooled ingot, respectively. The results in this study provide meaningful suggestions for recycling scrap Al-Si-Fe materials.