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复合稀土对Fe-Mn-Si-Ni-C合金形状记忆效应的影响 被引量:8
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作者 司乃潮 贾志宏 祁隆飙 《中国稀土学报》 CAS CSCD 北大核心 2003年第1期53-57,共5页
通过弯曲法测量、热循环训练、扫描电镜、X射线衍射等方法,研究了复合稀土对Fe Mn Si Ni C合金形状记忆效应的影响。研究结果表明,Fe Mn Si Ni C合金中加入复合稀土,能够明显细化合金的金相组织,显著提高合金的形状记忆效应,并使合金表... 通过弯曲法测量、热循环训练、扫描电镜、X射线衍射等方法,研究了复合稀土对Fe Mn Si Ni C合金形状记忆效应的影响。研究结果表明,Fe Mn Si Ni C合金中加入复合稀土,能够明显细化合金的金相组织,显著提高合金的形状记忆效应,并使合金表现出微弱的双程记忆效应。试验结果还表明,第一种训练途径以及加入微量复合稀土是降低应力诱发ε马氏体稳定化行之有效的方法,X射线衍射结果表明,该训练方法有助于提高合金中ε→γ转变的ε逆转变率,对提高合金的记忆性能起积极的作用。 展开更多
关键词 金属材料 fe-mn-si-ni-c合金 细化晶粒 形状记忆效应 热循环训练 稀土
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Effect of Compound Rare Earth on Shape Memory Effect of Fe-Mn-Si-Ni-C Alloys
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作者 司乃潮 贾志宏 祁隆飙 《Journal of Rare Earths》 SCIE EI CAS CSCD 2003年第S1期168-172,共5页
Effect of compound rare earth (RE) on shape memory effect (SME) of Fe-Mn-Si-Ni-C shape memory alloy was studied by bent measurement,thermal cycle training, SEM and XRD etc. The results show that metallurgic microstruc... Effect of compound rare earth (RE) on shape memory effect (SME) of Fe-Mn-Si-Ni-C shape memory alloy was studied by bent measurement,thermal cycle training, SEM and XRD etc. The results show that metallurgic microstructure is refined and SME improved evidently with the addition of compound RE. The alloy appears little two-way shape memory effect. The former training and addition of compound RE are two effective ways to restrain martensitic stability. XRD analysis also indicates that ε→γ reversible transition ratio increases by training greatly help to improve SME of the alloy. 展开更多
关键词 fe-mn-si-ni-c shape memory alloy grain refinement shape memory effect thermal cycle training rare earths
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INFLUENCE OF PROCESSING ON SHAPE MEMORY EFFECT OF Fe-Mn-Si-Ni-C-RE SHAPE MEMORY ALLOY
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作者 N.C. Si, Z.H. Jia and L.B. QiSchool of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, China 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2003年第5期385-394,共10页
Effect of carbon, compound RE, quenching temperature, pre-strain and recovery temperature on shape memory effect (SME) of Fe-Mn-Si-Ni-C-RE shape memory alloy was studied by bent measurement, thermal cycle training, SE... Effect of carbon, compound RE, quenching temperature, pre-strain and recovery temperature on shape memory effect (SME) of Fe-Mn-Si-Ni-C-RE shape memory alloy was studied by bent measurement, thermal cycle training, SEM etc. It was shown that the grains of alloys addition with compound RE became finer and SME increased evidently. SME of the alloy was weakening gradually as carbon content increased under small strain (3%). But in the condition of large strain (more than 6%), SME of the alloy whose carbon content range from 0.1% to 0.12% showed small decreasing range, especially of alloy with the addition of compound RE. Results were also indicated that SME was improved by increasing quenching temperature (>1000℃). The amount of thermal induced martensite increased and the relative shape recovery ratio could be increased to more than 40% after 3-4 times thermal training. The relative shape recovery ratio decreased evidently depending on rising of pre-strain. Furthermore, because speed of martensite transition was extremely great under higher tempering temperature (more than 450℃, ε → γ transition completed in 10s meanwhile the relative shape recovery ratio of the alloy increased rapidly. 展开更多
关键词 fe-mn-si-ni-c-RE shape memory alloy quenching temperature PRE-STRAIN recovery temperature shape memory effect
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Effect of chemical component on shape memory effect of Fe-Mn-Si-Ni-C-RE shape memory alloy
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作者 SI Naichao, JIA Zhihong, and QI Longbiao 《Rare Metals》 SCIE EI CAS CSCD 2004年第1期87-87,共1页
Effect of chemical component on shape memory effect (SME) of Fe-Mn-Si-Ni-C-RE shape memory alloys was studied by bent measurement, thermal cycle training, SEM etc. Results of study indicate that the alloys with high M... Effect of chemical component on shape memory effect (SME) of Fe-Mn-Si-Ni-C-RE shape memory alloys was studied by bent measurement, thermal cycle training, SEM etc. Results of study indicate that the alloys with high Mn content (25%) appeare better SME, especially in lower strain. SME improves evidently when Si is higher content, especially it’s range from 3% up to 4%. But brittleness of Fe-Mn-Si-Ni-C-RE alloy increases by increasing the Si content. SME of the alloy is weakening gradually as carbon content increases under small strain (3%). But in the condition of large strain (above 6%), SME of the alloy whose carbon content ranges from 0.1 % to 0.12% shows small decreasing range, especially of alloy with the addition of compound RE. 展开更多
关键词 chemical component fe-mn-si-ni-c-RE shape memory alloy shape memory effect STRAIN
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Effect of chemical component on shape memory effect of Fe-Mn-Si-Ni-C-RE shape memory alloy
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作者 NaichaoSi ZhihongJia LongbiaoQi 《Journal of University of Science and Technology Beijing》 CSCD 2004年第1期75-80,共6页
Effect of chemical component on shape memory effect (SME) of Fe-Mn-Si-Ni-C-REshape memory alloys was studied by bent measurement, thermal cycle training, SEM etc. Results ofstudy indicate that the alloys with high Mn ... Effect of chemical component on shape memory effect (SME) of Fe-Mn-Si-Ni-C-REshape memory alloys was studied by bent measurement, thermal cycle training, SEM etc. Results ofstudy indicate that the alloys with high Mn content (25%) appeare better SME, especially in lowerstrain. SME improves evidently when Si is higher content, especially it's range from 3% up to 4%.But brittleness of Fe-Mn-Si-Ni-C-RE alloy increases by increasing the Si content. SME of the alloyis weakening gradually as carbon content increases under small strain (3%). But in the condition oflarge strain (above 6%), SME of the alloy whose carbon content ranges from 0.1 % to 0.12% showssmall decreasing range, especially of alloy with the addition of compound RE. 展开更多
关键词 chemical component fe-mn-si-ni-c-RE shape memory alloy shape memory effect STRAIN
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新型奥氏体不锈钢的耐磨性研究 被引量:7
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作者 赖志伟 吴俊良 +2 位作者 文玉华 李宁 王兆昌 《摩擦学学报》 EI CAS CSCD 北大核心 2009年第2期128-133,共6页
为了解决传统奥氏体不锈钢耐磨性较差的问题,本文设计了一种新型的Fe-Mn-Si-Cr-Ni-C奥氏体不锈钢,并研究了其耐磨性能和耐腐蚀性能.研究表明:Fe-Mn-Si-Cr-Ni-C奥氏体不锈钢在干摩擦和油润滑条件下均具有比1Cr18Ni9Ti奥氏体不锈钢更好的... 为了解决传统奥氏体不锈钢耐磨性较差的问题,本文设计了一种新型的Fe-Mn-Si-Cr-Ni-C奥氏体不锈钢,并研究了其耐磨性能和耐腐蚀性能.研究表明:Fe-Mn-Si-Cr-Ni-C奥氏体不锈钢在干摩擦和油润滑条件下均具有比1Cr18Ni9Ti奥氏体不锈钢更好的耐磨性,在NaCl中耐蚀性不如1Cr18Ni9Ti不锈钢,但在NaOH中优于1Cr18Ni9Ti不锈钢.Fe-Mn-Si-Cr-Ni-C奥氏体不锈钢应力作用下发生的应力诱发γ→ε马氏体相变是其具有较高耐磨性的原因. 展开更多
关键词 奥氏体不锈钢 Fe—Mn—Si—Cr—Ni—C不锈钢 耐磨性 应力诱发γ-ε马氏体相变 耐蚀性
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Mn和Ce对Fe-Ni-Mn-C-Si-Ce系合金组织和性能的影响 被引量:4
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作者 卢铃 朱定一 汪才良 《中国有色金属学报》 EI CAS CSCD 北大核心 2007年第6期909-915,共7页
采用熔炼法制备出新型高耐磨的Fe-20Ni-xMn-3.5C-2.5Si系固体自润滑材料,研究稀土元素Ce对Fe-20Ni-xMn-3.5C-2.5Si系合金中石墨的球化作用及Mn含量对力学性能及摩擦磨损性能的影响。结果表明:随着Mn含量的增加,合金凝固组织中奥氏体的... 采用熔炼法制备出新型高耐磨的Fe-20Ni-xMn-3.5C-2.5Si系固体自润滑材料,研究稀土元素Ce对Fe-20Ni-xMn-3.5C-2.5Si系合金中石墨的球化作用及Mn含量对力学性能及摩擦磨损性能的影响。结果表明:随着Mn含量的增加,合金凝固组织中奥氏体的硬度逐渐增大,特别是Fe-20Ni-xMn-3.5C-2.5Si-0.75Ce系合金在摩擦过程中的表面硬度大幅度提高,呈现出高锰钢特有的表面加工硬化性质,通过TEM可以观察到磨损表面生成孪晶型马氏体;添加0.75%(质量分数)的稀土Ce可以使结晶的石墨球化,使抗拉强度和抗弯强度大幅度提高,大约比未经球化处理的提高3~5.8倍;稀土Ce的加入可以促进Fe1.1Mn3.9C2型碳化物的生成,使材料的耐磨性进一步提高,其中Fe-20Ni-16Mn-3.5C-2.5Si-0.75Ce合金的磨损率最低,大约是QT500球墨铸铁的1/13。 展开更多
关键词 Fe-Ni-Mn-C-Si-Ce合金 高锰奥氏体 MnCe 加工硬化 摩擦 磨损
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C-Fe-X(X=Mn,Si,Cr,Ni)熔体中组元活度的解析 被引量:4
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作者 蒋国昌 张晓兵 徐匡迪 《金属学报》 SCIE EI CAS CSCD 北大核心 1992年第6期B240-B246,共7页
将过剩自由能表达为组元的多项式函数。以该体系液相区边界条条件为基础,用拟合法确定碳偏mole自由能表达式中的参数,然后,用“I—D”法给出组元X的活度系数,此法可以确定各C—Fe—X系整个液相区中任一组元的活度,解析结果与文献上的试... 将过剩自由能表达为组元的多项式函数。以该体系液相区边界条条件为基础,用拟合法确定碳偏mole自由能表达式中的参数,然后,用“I—D”法给出组元X的活度系数,此法可以确定各C—Fe—X系整个液相区中任一组元的活度,解析结果与文献上的试验结果吻合得很好。 展开更多
关键词 组元活度系数 C-Fe-X熔体
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不同预变形量对时效Fe13Mn6Si13Cr4Ni0.1C合金组织及形状记忆效应的影响
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作者 杨世洲 李宁 李辉 《功能材料》 EI CAS CSCD 北大核心 2014年第7期7022-7026,共5页
为了进一步提高Fe13Mn6Si13Cr4Ni0.1C合金的形状记忆效应,研究了不同预变形量对1 073K时效合金的组织及形状记忆效应的影响。研究结果表明,10%预变形后再时效的合金,形状回复率在时效300min时达到(86.1±1.0)%,比固溶态32%提高了169... 为了进一步提高Fe13Mn6Si13Cr4Ni0.1C合金的形状记忆效应,研究了不同预变形量对1 073K时效合金的组织及形状记忆效应的影响。研究结果表明,10%预变形后再时效的合金,形状回复率在时效300min时达到(86.1±1.0)%,比固溶态32%提高了169%;5%预变形后再时效的合金,在180min时达到最大值(82.9±1.0)%,比固溶态提高了159%,随后形状回复率随时效时间延长略有下降;直接时效合金(无预变形量),在180min时达到最大值(46.3±1.0)%,比固溶态提高了44.7%,随后形状回复率也随时效时间延长略有下降。经SEM和XRD分析,10%预变形后再时效合金所析出的定向Cr23C6颗粒最多,也最细小,这是此合金比5%预变形后再时效合金以及直接时效合金形状回复率提高幅度更大的原因。 展开更多
关键词 预变形量 形状回复率 Fe-Mn-Si-Cr-Ni-C合金 Cr23 C6 颗粒
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Ni、Cr对Fe-Ni-Mn-C-Si系合金组织和摩擦磨损性能的影响
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作者 杨华珠 朱定一 +1 位作者 叶鑫 张文杰 《热加工工艺》 CSCD 北大核心 2009年第12期4-7,共4页
采用熔炼法制备出新型高耐磨Fe-xNi-10Mn-4C-4Si系固体自滑润材料,研究了元素Ni和Cr对合金凝固组织及摩擦磨损性能的影响。结果表明,几种合金的凝固组织均由奥氏体基体、石墨、碳化物组成;随着Ni含量的增加,合金中石墨面密度逐渐增大,... 采用熔炼法制备出新型高耐磨Fe-xNi-10Mn-4C-4Si系固体自滑润材料,研究了元素Ni和Cr对合金凝固组织及摩擦磨损性能的影响。结果表明,几种合金的凝固组织均由奥氏体基体、石墨、碳化物组成;随着Ni含量的增加,合金中石墨面密度逐渐增大,碳化物形成数量逐渐减少,材料的摩擦系数有所下降;w(Ni)<12%时,3%的Cr加入量使凝固组织中碳化物的数量大幅度增加,合金的耐磨性能大幅度提高。其中Fe-8Ni-10Mn-3Cr-4C-4Si合金的摩擦系数最小(0.18),磨损率仅为QT500球墨铸铁的1/10。 展开更多
关键词 Fe-Ni-Mn-C-Si合金 凝固组织 摩擦磨损
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热处理工艺对Fe-12Mn-xNi-4C-3.5Si铸铁组织与性能的影响
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作者 张文杰 朱定一 +1 位作者 杨华珠 叶鑫 《金属热处理》 CAS CSCD 北大核心 2009年第12期43-47,共5页
熔炼出3种不同镍含量的Fe-12Mn-xNi-4C-3.5Si(x=5%,10%,15%)系合金铸铁,研究了不同的热处理工艺对合金组织和性能的影响。结果表明,合金中碳元素的石墨化倾向随着Ni含量增加而增大;经高温退火处理后,合金组织由奥氏体基体、石墨及少量... 熔炼出3种不同镍含量的Fe-12Mn-xNi-4C-3.5Si(x=5%,10%,15%)系合金铸铁,研究了不同的热处理工艺对合金组织和性能的影响。结果表明,合金中碳元素的石墨化倾向随着Ni含量增加而增大;经高温退火处理后,合金组织由奥氏体基体、石墨及少量点状碳化物组成;合金中Ni含量越高,碳化物在高温下越容易分解。淬火处理后由于获得了单一奥氏体基体,合金的冲击韧度和抗弯强度均有较大提高,Ni含量越高韧性提高越显著,经900℃、8h保温后淬火的Fe-12Mn-15Ni-4C-3.5Si合金,在三点弯曲试验中可弯成120°不裂,冲击韧度提高至50.2J.cm-2,淬火后由于碳化物被消除,合金的硬度下降,磨损率增大。 展开更多
关键词 Fe-Mn-Ni-C-Si合金 热处理 力学性能 摩擦磨损
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