Amorphous alloys have properties that differ apparently from those of crystalline materials, such as superior magnetic, mechanical properties and the improved resistance to corrosion. There exist a number of methods o...Amorphous alloys have properties that differ apparently from those of crystalline materials, such as superior magnetic, mechanical properties and the improved resistance to corrosion. There exist a number of methods of preparing amorphous alloys, of which the most commonly employed one is rapid solidification. Recently, some new techniques have been developed, e.g. chemical reduction. Although fine powder produced by this method was reported in the early literature, it began to attract great attention only after展开更多
由单一还原剂 NaH_2PO_2或 NaH_2PO_3与 KBH_4的复合还原剂分别在类镍溶液中获得 Ni-Fe-P 以及 Ni-Fe-P-B 合金膜,研究了这些新型合金膜的磁性。结果发现,铁磁性元素 Fe 含量增加导致原子平均磁矩及饱和磁化强度 Ms 增大;结构为非晶态...由单一还原剂 NaH_2PO_2或 NaH_2PO_3与 KBH_4的复合还原剂分别在类镍溶液中获得 Ni-Fe-P 以及 Ni-Fe-P-B 合金膜,研究了这些新型合金膜的磁性。结果发现,铁磁性元素 Fe 含量增加导致原子平均磁矩及饱和磁化强度 Ms 增大;结构为非晶态的合金膜具有较优的矫顽力 Hc 值;合金膜磁滞回线出现较低的矩形比说明化学镀制备态样品不够均匀;热处理温度高于400℃后,合金膜的饱和磁化强度连续减小,矫顽力急剧增大;同时,镀层的均匀性明显得到改善。展开更多
基金Project supported by State Key Laboratory for Rapidly Solidified Non-equilibrium Alloys.
文摘Amorphous alloys have properties that differ apparently from those of crystalline materials, such as superior magnetic, mechanical properties and the improved resistance to corrosion. There exist a number of methods of preparing amorphous alloys, of which the most commonly employed one is rapid solidification. Recently, some new techniques have been developed, e.g. chemical reduction. Although fine powder produced by this method was reported in the early literature, it began to attract great attention only after
文摘由单一还原剂 NaH_2PO_2或 NaH_2PO_3与 KBH_4的复合还原剂分别在类镍溶液中获得 Ni-Fe-P 以及 Ni-Fe-P-B 合金膜,研究了这些新型合金膜的磁性。结果发现,铁磁性元素 Fe 含量增加导致原子平均磁矩及饱和磁化强度 Ms 增大;结构为非晶态的合金膜具有较优的矫顽力 Hc 值;合金膜磁滞回线出现较低的矩形比说明化学镀制备态样品不够均匀;热处理温度高于400℃后,合金膜的饱和磁化强度连续减小,矫顽力急剧增大;同时,镀层的均匀性明显得到改善。