A simple synthesis of novel and known calix[4]resorcinarenes derivatives has been achieved by the condensation of resorcinol and different aromatic aldehydes in the presence of catalytic amounts of Fe_3O_4 nanoparticl...A simple synthesis of novel and known calix[4]resorcinarenes derivatives has been achieved by the condensation of resorcinol and different aromatic aldehydes in the presence of catalytic amounts of Fe_3O_4 nanoparticles under solvent-free conditions.The experimental conditions have been thoroughly optimized and established,allowing significant rate enhancements and good to excellent yields.The reactions can be run safely without using any toxic organic solvents under mild reaction conditions.The Fe_3O_4 nanoparticles were characterized by powdered X-ray diffraction（XRD）,transmission electron microscopy（TEM） and FT-IR spectroscopy.展开更多
文摘A simple synthesis of novel and known calix[4]resorcinarenes derivatives has been achieved by the condensation of resorcinol and different aromatic aldehydes in the presence of catalytic amounts of Fe_3O_4 nanoparticles under solvent-free conditions.The experimental conditions have been thoroughly optimized and established,allowing significant rate enhancements and good to excellent yields.The reactions can be run safely without using any toxic organic solvents under mild reaction conditions.The Fe_3O_4 nanoparticles were characterized by powdered X-ray diffraction（XRD）,transmission electron microscopy（TEM） and FT-IR spectroscopy.
