An original idea is reviewed. When a molecule is pumped into a super-excited state, one of its decay channels is neutral dissociation. One or more of the neutral fragments will fluoresce. Hence, if a lower state of su...An original idea is reviewed. When a molecule is pumped into a super-excited state, one of its decay channels is neutral dissociation. One or more of the neutral fragments will fluoresce. Hence, if a lower state of such fluorescing fragments was populated through other channels but with a lower probability, population inversion of the fluorescing fragments would be naturally realized. This idea seems to be validated, so far, by comparing published work on three hydrocarbon molecules, CH4, C2H2, C2H4, and water vapor, H2 O. After super-excitation in a femtosecond laser filament in air mixed with these molecules, the fluorescence from the CH or OH fragments exhibits population inversion, i.e., amplified spontaneous emission was observed in the backscattering direction of the filament.展开更多
基金Project supported by the Canada Research Chairs,the Natural Science and Engineering Research Council of Canada(NSERC),the FRQNT,the Canada Foundation for Innovation(CFI),the National Basic Research Program of China(Grant No.2014CB921300)the National Natural Science Foundation of China(Grant No.61235003)+1 种基金the Research Fund for the Doctoral Program of Higher Education of Chinathe Scientific Research Foundation for Returned Scholars,Ministry of Education of China
文摘An original idea is reviewed. When a molecule is pumped into a super-excited state, one of its decay channels is neutral dissociation. One or more of the neutral fragments will fluoresce. Hence, if a lower state of such fluorescing fragments was populated through other channels but with a lower probability, population inversion of the fluorescing fragments would be naturally realized. This idea seems to be validated, so far, by comparing published work on three hydrocarbon molecules, CH4, C2H2, C2H4, and water vapor, H2 O. After super-excitation in a femtosecond laser filament in air mixed with these molecules, the fluorescence from the CH or OH fragments exhibits population inversion, i.e., amplified spontaneous emission was observed in the backscattering direction of the filament.
基金National Natural Science Foundation of China(Nos.12034013,11904232)Innovation Program of Shanghai Municipal Education Commission(No.2017-01-07-00-07-E00007)。
