双金属MOFs碳化材料的结构对锂硫电池正极性能的影响

利用硝酸钴和铁氰化钾在水溶液中沉淀反应以及ZIF-8在水溶液中的部分分解,分别制备了2种组成相近但结构不同的双金属有机框架前驱体Co-Fe precursor和ZCF precursor。经过多巴胺包覆,对2种产品在氩气气氛下退火获得碳化产物。将碳化产物与纳米硫粉混合得到的碳/硫复合材料(E-CoFeCN@C/S、E-ZCF@C/S)分别作为正极,组装扣式锂硫电池并测试电化学性能。利用X射线衍射仪、扫描电子显微镜、透射电子显微镜、热重分析仪进行形貌和结构分析。在组成相似的情况下,核壳结构碳载体(E-CoFeCN@C)与发散式结构碳载体(E-ZCF@C)对锂硫电池性能的影响呈现出“此消彼长”的特点:E-ZCF@C/S在循环伏安测试中表现出更小的极化以及更强的电流响应,在电化学阻抗测试中表现出更低的电荷转移阻抗,表明该材料有利于促进正极电荷传递过程,即加快电极反应动力学。E-ZCF@C/S在0.2C倍率下放电初始比容量为1211.3mAh/g,在2C倍率下放电初始比容量为794mAh/g,均优于E-CoFeCN@C/S。而核壳结构的优势主要体现在容量衰减方面,E-CoFeCN@C/S在0.2C倍率下经过100次循环后平均衰减率为0.074%(E-ZCF@C/S为0.26%),在2C倍率下循环300次后平均衰减率为0.047%(E-ZCF@C/S为0.13%),说明核壳结构对活性物质的锚固作用明显而对电荷转移不利。

高压管汇材料疲劳性能测试及P-S-N模型曲线的拟合

高压管汇作为压裂设备中的主要易损件之一,其失效危害较大。它的失效原因主要是疲劳、冲蚀、腐蚀或者材料缺陷引起的刺漏和爆裂,其中尤以疲劳失效最不可预估。目前,对于高压管汇材料的疲劳性能研究不够深入,为解决高压管汇材料疲劳寿命的准确描述问题,以某国产高压管汇材料为例,进行了一系列疲劳试验,并基于试验数据,采用多种分布模型和不同S-N模型进行拟合分析,得出综合评价拟合能力最强的P-S-N模型。结果表明,该材料在中长疲劳寿命区,Weibull三参数模型在7级应力水平下综合评价能力最好;在存活率分别为50%、90%、99%、99.9%时,指数S-N模型的拟合系数均大于0.98,拟合能力最好。得出的P-S-N模型曲线可以为高压管汇的疲劳寿命以及安全设计提供依据。

基于哨兵函数和S变换的风力机叶片材料损伤特性研究

利用声发射检测技术研究玻璃纤维增强环氧树脂复合材料的损伤特性,在此过程中,采用哨兵函数来表征该材料的损伤程度,并通过S变换和模糊C均值(FCM)聚类来分析声发射信号,从而获得材料的损伤特征。三点弯曲实验结束后对试件断口进行扫描电子显微镜(SEM)拍照来验证,可得:通过对SEM照片的分析得到基体开裂、纤维脱粘、分层破坏、纤维断裂4种损伤模式;对整个声发射事件进行哨兵函数分析,观察到试件在弯曲过程中哨兵函数曲线呈明显下降趋势;对依据哨兵函数划分的不同阶段的信号进行VMD降噪处理,然后采用S变换进行时频分析得到不同损伤的特征频率,最后采用FCM聚类进行验证。结果表明:哨兵函数值的突变可作为材料断裂的预警信号,材料损伤类型的识别可依据S变换的频率分布结果进行确定。

Template-Free Synthesis of Sb_2S_3 Hollow Microspheres as Anode Materials for Lithium-Ion and Sodium-Ion Batteries

Hierarchical Sb_2S_3 hollow microspheres assembled by nanowires have been successfully synthesized by a simple and practical hydrothermal reaction. The possible formation process of this architecture was investigated by X-ray diffraction, focused-ion beam-scanning electron microscopy dual-beam system, and transmission electron microscopy. When used as the anode material for lithium-ion batteries, Sb_2S_3 hollow microspheres manifest excellent rate property and enhanced lithium-storage capability and can deliver a discharge capacity of 674 m Ah g^(-1) at a current density of 200 m A g^(-1) after 50 cycles. Even at a high currentdensity of 5000 m A g^(-1), a discharge capacity of541 m Ah g^(-1) is achieved. Sb_2S_3 hollow microspheres also display a prominent sodium-storage capacity and maintain a reversible discharge capacity of 384 m Ah g^(-1) at a current density of 200 m A g^(-1) after 50 cycles. The remarkable lithium/sodium-storage property may be attributed to the synergetic effect of its nanometer size and three-dimensional hierarchical architecture, and the outstanding stability property is attributed to the sufficient interior void space,which can buffer the volume expansion.

Tempura-like carbon/carbon composite as advanced anode materials for K-ion batteries

Graphite as a promising anode candidate of K-ion batteries(KIBs)has been increasingly studied currently,but corresponding rate performance and cycling stability are usually inferior to amorphous carbon materials.To protect the layer structure and further boost performance,tempura-like carbon/carbon nanocomposite of graphite@pitch-derived S-doped carbon(G@PSC)is designed and prepared by a facile and low-temperature modified molten salt method.This robust encapsulation structure makes their respective advantages complementary to each other,showing mutual promotion of electrochemical performances caused by synergy effect.As a result,the G@PSC electrode is applied in KIBs,delivering impressive rate capabilities(465,408,370,332,290,and 227 m A h g^(-1)at 0.05,0.2,0.5,1,2,and 5 A g^(-1))and ultralong cyclic stability(163 m A g^(-1)remaining even after 8000 cycles at 2 A g^(-1)).On basis of ex-situ studies,the sectionalized K-storage mechanism with adsorption(pseudocapacitance caused by S doping)-intercalation(pitch-derived carbon and graphite)pattern is revealed.Moreover,the exact insights into remarkable rate performances are taken by electrochemical kinetics tests and density functional theory calculation.In a word,this study adopts a facile method to synthesize high-performance carbon/carbon nanocomposite and is of practical significance for development of carbonaceous anode in KIBs.

Local resonance phononic band gaps in modifiedtwo-dimensional lattice materials

In this paper, modified two-dimensional peri- odic lattice materials with local resonance phononic band gaps are designed and investigated. The design concept is to introduce some auxiliary structures into conventional pe- riodic lattice materials. Elastic wave propagation in this kind of modified two-dimensional lattice materials is studied us- ing a combination of Bloch＇s theorem with finite element method. The calculated frequency band structures of illus- trative modified square lattice materials reveal the existence of frequency band gaps in the low frequency region due to the introduction of the auxiliary structures. The mechanism underlying the occurrence of these frequency band gaps is thoroughly discussed and natural resonances of the auxiliary structures are validated to be the origin. The effect of geo- metric parameters of the auxiliary structures on the width of the local resonance phononic band gaps is explored. Finally, a conceptual broadband vibration-insulating structure based on the modified lattice materials is designed and its capabil- ity is demonstrated. The present work is anticipated to be useful in designing structures which can insulate mechanical vibrations within desired frequency ranges.

Green's function solution for transient heat conduction in annular fin during solidification of phase change material

The Green＇s function method is applied for the transient temperature of an annular fin when a phase change material （PCM） solidifies on it. The solidification of the PCMs takes place in a cylindrical shell storage. The thickness of the solid PCM on the fin varies with time and is obtained by the Megerlin method. The models are found with the Bessel equation to form an analytical solution. Three different kinds of boundary conditions are investigated. The comparison between analytical and numerical solutions is given. The results demonstrate that the significant accuracy is obtained for the temperature distribution for the fin in all cases.

THE CHANGING ROLE OF THE NATIONAL LABORATORIES IN MATERIALS RESEARCH

The role of the National Laboratories is summarized from the era of post World War II to the present time. The U.S. federal government policy for the National Laboratories and its influence on their materials science infrastructure is reviewed with respect to .determining overall research strategies, various initiatives to interact with industry (especially in recent years),building facilities that serve the nation, and developing leading edge research in the materials sciences. Despite reductions in support for research in the U.S. in recent years, and uncertainties regarding the specific policies for Research &Development (R&D) in the U.S., there are strong roles for materials research at the National Laboratories. These roles will be centered on the abilities of the National Laboratories to field multidisciplinary teams, the use of unique cutting edge facilities, a focus on areas of strength within each of the labs,increased teaming and partnerships, and the selection of motivated research areas. It is hoped that such teaming opportunities will include new alliances with China, in a manner similar, perhaps, to those recently achieved between the U.S. and other countries.

g-C_(3)N_(4)基S型异质结的构建及其光催化性能研究

为了解决日益严重的环境污染和能源短缺等问题,基于半导体的光催化技术利用太阳能为环境修复和能源储存提供了一种“绿色”可持续的方案。首先介绍了g-C_(3)N_(4)的优点和局限性,以及S型半导体的优势与不足,接着介绍了g-C_(3)N_(4)基S型异质结的电子结构和光催化性质,综述了基于不同类型g-C_(3)N_(4)的S型异质结光催化材料构建和光催化性能的提升策略,并梳理了其部分应用。最后,综述了基于g-C_(3)N_(4)的S型异质结面临的挑战和未来发展趋势,有望为g-C_(3)N_(4)基S型异质结光催化材料的开发和实际应用提供重要的参考。

Nonlinear oscillations of sigmoid functionally graded material plates moving in longitudinal direction

Geometrically nonlinear oscillations are investigated on sigmoid functionally graded material （S-FGM） plates with a longitudinal speed. The material properties of the plates obey a sigmoid distribution rule along the thickness direction. Based on the D＇Alembert＇s principle, a nonlinear equation of motion is derived for the moving S-FGM plates, where the von K^rm^n nonlinear plate theory is adopted. Utilizing the Galerkin method, the equation of motion is discretized and solved via the method of harmonic bal- ance. The approximate analytical solutions are validated through the adaptive step-size fourth-order Runge-Kutta method. Besides, the stability of the steady-state solutions is examined. The results reveal that the mode interaction behavior can happen between the first two modes of the moving S-FGM plates, leading to a complex nonlinear frequency response. It is further found that the power-law index, the longitudinal speed, the exci- tation amplitude, and the in-plane pretension force can significantly affect the nonlinear frequency-response characteristics of longitudinally traveling S-FGM plates.

稀土元素Tm掺杂对Cu_(2)S热电性能影响研究

Cu_(2)S具有较低的晶格热导率和窄禁带宽度,它热电性能优异、成本低廉且无毒等优点引起了热电材料相关研究领域的广泛关注。采用水热合成法与真空烧结法相结合的方式制备Cu_(2)S基热电材料,通过物相、成分表征和热电性能测试等手段,研究稀土元素Tm掺杂对Cu_(2)S基材料热电性能的影响规律,并采用第一性原理开展掺杂后Cu_(2)S能带结构和态密度计算。研究结果表明,水热合成法可以获得Cu_(31)S_(16)粉体,在真空烧结过程中物相发生了转变,从原来的Cu_(31)S_(16)转变为Cu_(2)S。掺杂Tm元素可显著提高Cu_(2)S粉体的结晶性能,随着掺杂含量的增加,Cu_(2)S团聚现象逐渐消失。Cu_(2)S塞贝克系数随Tm掺杂量的增加有所提升,其中掺杂2%Tm的Cu_(2)S在350℃处于相变温度,塞贝克系数达到峰值1589.71μV/K;随掺杂元素的增加和温度的升高,Cu_(2)S电导率逐渐下降。Tm掺杂后的Cu_(2)S在中高温度范围内,热导率κ随着温度的上升呈现逐渐下降的趋势。结果表明掺杂2%Tm的Cu_(2)S热电优值从0.1增加到0.4,提高了300%。

Theoretical study of mutual control mechanism between magnetization and polarization in multiferroic materials

The mutual control mechanism between magnetization and polarization in multiferroic materials is studied. The system contains a ferromagnetic sublattice and a ferroelectric sublattice. To describe the magneto–electric coupling, we propose a linear coupling Hamiltonian between ferromagnetism and ferroelectricity without microscopic derivation. This coupling enables one to retrieve the hysteresis loops measured experimentally. The thermodynamic properties of the system are calculated, such as the temperature dependences of the magnetization, polarization, internal energy and free energy.The ferromagnetic and ferroelectric hysteresis loops driven by either a magnetic or an electric field are calculated, and the magnetic spin and pseudo-spin are always flipped synchronously under the external magnetic and electric field. Our theoretical results are in agreement with the experiments.

Powell's optimal identification of material constants of thin-walled box girders based on Fibonacci series search method

A dynamic Bayesian error function of material constants of the structure is developed for thin-walled curve box girders. Combined with the automatic search scheme with an optimal step length for the one-dimensional Fibonacci series, Powell＇s optimization theory is used to perform the stochastic identification of material constants of the thin-walled curve box. Then, the steps in the parameter identification are presented. Powell＇s identification procedure for material constants of the thin-walled curve box is compiled, in which the mechanical analysis of the thin-walled curve box is completed based on the finite curve strip element （FCSE） method. Some classical examples show that Powell＇s identification is numerically stable and convergent, indicating that the present method and the compiled procedure are correct and reliable. During the parameter iterative processes, Powell＇s theory is irrelevant with the calculation of the FCSE partial differentiation, which proves the high computation efficiency of the studied methods. The stochastic performances of the system parameters and responses axe simultaneously considered in the dynamic Bayesian error function. The one-dimensional optimization problem of the optimal step length is solved by adopting the Fibonacci series search method without the need of determining the region, in which the optimized step length lies.

基于TDLAS的H_(2)S气体材料表面吸附特性研究

在H_(2)S气体浓度在线监测过程中,因其具有粘附性强的特点,容易发生管线吸附,从而导致测量结果存在偏差,尤其在痕量H_(2)S检测过程中表现最为明显,所以开展H_(2)S气体管线材料表面吸附特性研究尤为必要。本文基于可调谐二极管激光吸收光谱技术(TDLAS),设计并搭建了一套H_(2)S浓度在线测定系统,并对该系统进行了测量性能检验,在此基础上进行了H_(2)S在不锈钢材料表面常温吸附特性探究。实验结果表明,所搭建H_(2)S浓度在线测定系统具有稳定性强、检测限低和灵敏度高的特点,利用此系统可以实现痕量H_(2)S浓度的在线连续测定。经过一系列探究试验,证明了H_(2)S在不锈钢材料表面存在明显且稳定的吸附作用,得出了H_(2)S在不锈钢材料表面的单位面积吸附量在10^(14)(个/cm^(2))量级。实验结果可以为痕量硫化氢在线精准测量提供一定参考。

The Strength Characters of C/C Composite Material with Opening Hole and Typical Application

Research on the opening hole and connecting problem of C/C composite material was conducted. The strength characteristics of plate with opening hole were tested and the applicability of strength criteria focused on particular point was analyzed. Conclusion is obtained that obviously conservative to evaluate open hole and joint strength by hole-edge stress. Based on these, high and nor-mal temperature strength test of typical circular shaft was completed, proving that comprehensive joint performance can be significantly improved by appropriately optimized design.

Frictional contact problem for elastic-viscoplastic materials with thermal effect

A dynamic contact problem for elastic-viscoplastic materials with thermal effects is investigated. The contact is bilateral, and the friction is modeled with Tresca＇s friction law with heat exchange. A variational formulation of the model is derived, and the existence of a unique weak solution is proved. The proofs are based on the classical result of nonlinear first order evolution inequalities, the equations with monotone operators, and the fixed point arguments. Finally, the continuous dependence of the solution on the friction yield limit is studied.

Higher-order crack tip fields for functionally graded material plate with transverse shear deformation

The crack tip fields are investigated for a cracked functionally graded material （FGM） plate by Reissner＇s linear plate theory with the consideration of the transverse shear deformation generated by bending. The elastic modulus and Poisson＇s ratio of the functionally graded plates are assumed to vary continuously through the coordinate y, according to a linear law and a constant, respectively. The governing equations, i.e., the 6th-order partial differential equations with variable coefficients, are derived in the polar coordinate system based on Reissner＇s plate theory. Furthermore, the generalized displacements are treated in a separation-of-variable form, and the higher-order crack tip fields of the cracked FGM plate are obtained by the eigen-expansion method. It is found that the analytic solutions degenerate to the corresponding fields of the isotropic homogeneous plate with Reissner＇s effect when the in-homogeneity parameter approaches zero.

Preparation of Single Crystals of Co_xZn_(1-x)S and Co_xZn_(1-x)Se—New Materials of Dilute Magnetic Semiconductors

In this paper, we report the growth of single crystals of Co_x Zn_(1-x)S and Co_x Zn_(1-x)Se (0<x<0.3) by the method of chemical transport, using iodine as a transport agent. The light green color of single crystal Co_xZn_(1-x)S as well as the light brown color of Co_xZn_(1-x)Se become deep with an increase in x. The compositions of the single crystals were nearly stoichiometric. The transfer rate decreases with an increase of the x value. The growth rate was related to the temperature difference. The large temperature difference speed up the growth rate, but the size of crystal obtained was small. In general, the optimal temperature difference was 15℃. From X-ray diffraction measurements, the structures of crystals Co_xZn_(1-x)S and Co_xZn_(1-x)Se (0<x<0.1) were identified to be zinc blende structure similar to that of ZnS and ZnSe.

Towards the Development of Mechanical Systems Entirely Based on Natural Materials

In order to mitigate the risks stemming from the utilization of mineral and synthetic organic substances,consensus exists in the literature that additional efforts should be devoted to the identification of adequate equivalent natural(ecological)materials.This work presents the outcomes of a preliminary study where the physical,mechanical,chemical and thermal properties of natural fibers have been considered.Initially,areca,and materials such as Moroccan doum and jute are considered.As a case study,a brake pad based on natural fibers is critically assessed.

China's Building Materials Industry

China’s building materials industry experienced great development in 1993 with rapid increases in production and record output and profits. The industry produced 360 million tons of cement, 96.163 million cases of plate glass, 20.4 million pieces of sanitation ceramics and 173 million square metres of construction ceramics, showing rises of 12.89, 12.83, 123.8 and 127 percent respectively over the previous year. The output of cement and