In this work, a novel hollow fiber membrane extractor was set up to extract inorganic anions from ethyl acetate using deionized water. Inorganic anions in slightly soluble organic solvents can be determined by the in-...In this work, a novel hollow fiber membrane extractor was set up to extract inorganic anions from ethyl acetate using deionized water. Inorganic anions in slightly soluble organic solvents can be determined by the in-line hollow fiber membrane extractor coupled with ion chromatography at first time. Different aspects of the extraction procedure such as magnetic stirring speed, extraction flow rate and extraction time were optimized to achieve high extraction efficiency and good separation results. Satisfactory linear range, limits of detection and good repeatability were obtained. The procedure was applied to analyze inorganic anions in two commercial ethyl acetate samples.展开更多
A novel idea of transport of yttrium(Ⅲ) metal ions through fibers supported liquid membrane in two stage processes namely source to membrane and membrane to receiving phase has been proposed.The fibers supported liqu...A novel idea of transport of yttrium(Ⅲ) metal ions through fibers supported liquid membrane in two stage processes namely source to membrane and membrane to receiving phase has been proposed.The fibers supported liquid membrane was impregnated with different concentrations carrier.The experimental variables explored were concentration of yttrium(Ⅲ) ions,pH of source phase,PC-88A concentration in membrane phase,acid concentration in receiving phase and stirring speed.The pre-concentration of yttrium(Ⅲ) ions ...展开更多
Extraction and interfacial kinetics of Nd 3+ and Sm 3+ with HEH/EHP kerosene in a hollow fiber membrane extractor were studied. The results show that the extraction reactions in the hollow fiber membrane e...Extraction and interfacial kinetics of Nd 3+ and Sm 3+ with HEH/EHP kerosene in a hollow fiber membrane extractor were studied. The results show that the extraction reactions in the hollow fiber membrane extractor are the same as those in the liquid liquid extraction, which can be expressed as a quasi first order reaction. The effect of acidity in aqueous phase, concentrations of extractant, Nd 3+ and Sm 3+ on extraction rate were discussed and the corresponding reaction series were obtained. The reaction equations, reaction rate constants and the separation constant were obtained.展开更多
基金supported by National Natural Science Foundation of China(No.20775070)by Zhejiang Provincial Natural Science Foundation of China(No.R4080124)Zhejiang Qianjiang Project of Science and Technology for Competent People(No.2008R10028).
文摘In this work, a novel hollow fiber membrane extractor was set up to extract inorganic anions from ethyl acetate using deionized water. Inorganic anions in slightly soluble organic solvents can be determined by the in-line hollow fiber membrane extractor coupled with ion chromatography at first time. Different aspects of the extraction procedure such as magnetic stirring speed, extraction flow rate and extraction time were optimized to achieve high extraction efficiency and good separation results. Satisfactory linear range, limits of detection and good repeatability were obtained. The procedure was applied to analyze inorganic anions in two commercial ethyl acetate samples.
基金supported by Department of Science and Technology,Government of India (GAP 271526)
文摘A novel idea of transport of yttrium(Ⅲ) metal ions through fibers supported liquid membrane in two stage processes namely source to membrane and membrane to receiving phase has been proposed.The fibers supported liquid membrane was impregnated with different concentrations carrier.The experimental variables explored were concentration of yttrium(Ⅲ) ions,pH of source phase,PC-88A concentration in membrane phase,acid concentration in receiving phase and stirring speed.The pre-concentration of yttrium(Ⅲ) ions ...
文摘Extraction and interfacial kinetics of Nd 3+ and Sm 3+ with HEH/EHP kerosene in a hollow fiber membrane extractor were studied. The results show that the extraction reactions in the hollow fiber membrane extractor are the same as those in the liquid liquid extraction, which can be expressed as a quasi first order reaction. The effect of acidity in aqueous phase, concentrations of extractant, Nd 3+ and Sm 3+ on extraction rate were discussed and the corresponding reaction series were obtained. The reaction equations, reaction rate constants and the separation constant were obtained.
