Atmospheric air dielectric barrier discharge excited by nanosecond pulse and AC used for improving the hydrophilicity of aramid fibers

In this paper, a long line-shape dielectric barrier discharge excited by a nanosecond pulse and AC is generated in atmospheric air for the purpose of discussing the uniformity, stability and ability of aramid fiber treatment. The discharge images, waveforms of current and voltage,optical emission spectra, and gas temperatures of both discharges are compared. It is found that nanosecond pulsed discharge has a more uniform discharge morphology, higher energy efficiency and lower gas temperature, which indicates that nanosecond pulsed discharge is more suitable for surface modification. To reduce the water contact angle from 96° to about 60°, the energy cost is only about 1/7 compared with AC discharge. Scanning electron microscopy,Fourier transform infrared spectroscopy and x-ray photoelectron spectroscopy are employed to understand the mechanisms of hydrophilicity improvement.

Analysis of Microstructure of Silicon Carbide Fiber by Raman Spectroscopy

The SiC fiber was prepared by chemical vapour depostion, which consists of tungsten core, SiC layer and carbon coating. The microstructure of the fiber was investigated using Raman spectroscopy, illustrating SiC variation in different region of the fiber. The result shows that the SiC layer can be subdivided into two parts in the morphologies of SiC grains; their sizes increase and their orientations become order with increasing distance from the fiber center. It is demonstrated that the mount of free carbon in the fiber is responsible for the variation of SiC grains in sizes and morphologies. The analysis of Raman spectra shows that the predominant β-SiC has extensive stacking faults within the crystallites and mixes other polytypes and amorphous SiC into the structure in the fiber.

Powerful 2 μm Silica Fiber Sources: A Review of Recent Progress and Prospects

A review on the progress of powerful 2 μm silica fiber sources in past decades is presented. We review the state-of-the-art records and representative achievements of 2 μm high-average-power continuous- wave, pulsed fiber lasers and amplifiers, and powerful superfluorescent sources. Challenges which limit the further power scaling of 2 μm silica fiber sources are discussed, including pumping brightness limitation, thermal problem and nonlinear effects. Potential and promising roadmaps to go beyond these limitations, like tandem pumping and beam combining, are discussed. Prospects of powerful 2 μm silica fiber sources are also presented in the end of paper.

Identification of Bamboo Viscose Fibers and Conventional Viscose Fibers

Bamboo viscose fibers and conventional viscose fibers were measured by optical microscopy, scanning electron microscopy (SEM), Fourier transform infrared spectrometer (FTIR), and thermogravimetric analyzer/FTIR spectrometer (TG-FTIR) respectively. At last, the method based on the testing of the Fourier transform near infrared (NIR) spectra was proposed to identify these two kinds of fibers. The discrimination models between bamboo viscose fibers with conventional viscose fibers were built by means of Ward's algorithm and Hierarchical cluster analysis(HCA) after the first derivative and vector normalization pretreatment, and were verified finally. The results indicate that these two kinds of fibers are similar in their morphology both of cross-section and longitudinal direction. What's more, the FTIR spectra, the thermostability, and decomposition products of TG-FTIR experiment are similar, and the testing results contribute little to the effective identification of the two fibers. However, the accuracy of the NIR spectra model is high, and the two kinds of fibers can be classified into two separated groups to achieve the identification simply and exactly.

FTIR and Raman Studies of Cellulose Fibers of <i>Luffa cylindrica</i>

In view of biomedical applications of cellulose fibers in orthopedics, dentistry and reconstructive surgery, Luffa cylindrica (LC), a local forest product of Orissa, India, has been used for preparation of alkali treated LC fiber modified with calcium carbonate and calcium phosphate separately by following standard procedures. FTIR and Raman spectra were obtained for these samples at wavelength range 500 - 4000 cm–1 and 300 - 3000 cm–1 respectively. Lattice structures of cellulose i.e., crystalline cellulose and amorphous cellulose were detected using Raman spectroscopy and discussed. The property of cellulose such as its degree of crystallinity was determined from intensity of FT IR peaks and was found to be 74.12%. The presence of calcite and hydroxy apatite, polymorphs of calcium carbonate and calcium phosphate respectively were confirmed in the treated modified LC fibers which can be used as bioactive materials.

Magneto-Optic Fiber Bragg Gratings with Application to High-Resolution Magnetic Field Sensors

Magneto-optic fiber Bragg gratings （MFBG） based on magneto-optic materials have a lot of potential applications for sensing and optical signal processing. The transmission and reflection spectra of guided optical waves in the MFBG are investigated. According to the sensitivity of MFBG spectral lines to the magneto-optic coupling intensity varying with applied magnetic field, a novel magnetic field sensor of high-resolution up to 0.01 nm/（kA/m） is predicted.

不同生长阶段香菇栽培料木质纤维素降解利用研究

为深入了解香菇生长发育过程中栽培料木质纤维素的变化,对不同生长阶段香菇栽培料中木质纤维素含量及其相关降解酶活性进行了测定,利用傅里叶变换红外光谱(FTIR)、X-射线衍射法(XRD)和显微镜观察研究了木质纤维素微观结构分子基团、纤维素相对结晶度(CrI)和纤维表面形态的变化。结果表明,在香菇生长发育过程中,栽培料中的纤维素、半纤维素和木质素含量显著下降,木质纤维素含量(w,后同)由85.27%降低至52.23%,其与相应的降解酶系活性负相关,木质纤维素降解与纤维破坏程度呈现一定的相关性。FTIR结果显示,不同生长阶段香菇栽培料中木质纤维素特征官能团峰值发生变化,木质素降解速率高于半纤维素、低于纤维素。随着香菇的生长发育,栽培料中CrI显著降低,纤维素晶体结构受到了一定程度的破坏。结果表明,香菇首先利用栽培料中非木质纤维素组分供菌丝生长,同时分泌胞外降解酶破坏纤维结构,将大分子组分降解为小分子组分,从而满足其生长所需,高木质纤维素降解酶活性对应高木质纤维素降解率。该研究结果可为促进香菇栽培料中木质纤维素的降解利用提供依据。

Identification of Silver Nanoparticles on Polyester Fiber on Raman Spectrograms of the in the Conditions of Information Uncertainty

The paper shows the results of method development identification of colloidal silver nanoparticles on the components of the Raman spectra, using the conditions information uncertainty decision to increase the reliability evaluating the presence nanoparticles at the surface polyester fibers.

基于掺铒氟化物光纤的22.8μm可调谐激光输出

采用高浓度掺杂的掺铒氟化物光纤可以增强铒离子的能量转移上转换过程,从而产生2.8μm波段的中红外激光。铒离子的全波段发射光谱范围覆盖0.5~3.0μm,其发射波长与相应能级之间的跃迁相吻合。对铒离子全波段的激光输出开展了实验研究。由于氟化物掺铒光纤的高掺杂浓度, 2.8μm激光占据主导地位。当泵浦功率为2~4 W时,激光输出在2714~2784 nm范围内可调谐,这是由增益竞争和腔内选择性以及非均匀加宽效应造成的。当泵浦功率增加到3 W以上时,可以观察到激光的谱分裂现象。实验获得了2.8μm波段的高稳定中红外激光,最大输出功率为0.7 W,斜率效率为12%。

应用衰减全反射红外光谱无损鉴别中国传统手工纸的方法研究

纤维种类鉴别是古代纸张保护的重要基础工作。探究中国传统手工纸的无损纤维鉴别的方法对中国古籍、档案及纸质文物的研究和保护具有重要意义。该研究应用衰减全反射傅里叶变换红外光谱(ATRFTIR)对已知纤维成分的17类64种中国传统手工纸标准样品进行了无损分析,参考纤维素和木质素的红外峰位及部分纸样的X射线衍射(XRD)分析结果确认纸样中的所有红外谱峰归属;并采用分波段比较分析的方法对相似度极高的谱图进行比对分析,分别总结各类纸张在4000~1800、1800~1500、1500~1200和1200~600cm^(-1)四个波段的谱图特征;同时对4cm^(-1)精度的谱图进行二阶导数处理,分别总结各类纸张在1500~1200和1200~900cm^(-1)两个波段的二阶导数谱图特征;最后通过红外结晶指数及其他峰高和峰面积比值计算结果实现对纸类更细致的区分。应用上述方法对16个盲测样品进行了有效性测试,红外分析结果与显微纤维鉴别结果一致,初步证明了该方法在中国传统手工纸无损纤维鉴别上的可行性和有效性。实验结果表明,应用ATR-FTIR无损分析法可对麻、桑构皮、檀皮、瑞香皮和竹几大类原料的传统手工纸纤维类型作出快速而准确的鉴别,对于混料的宣纸也同样适用;但对于显微分析也难以鉴别的亲缘关系较近的植物原料如桑、构皮之间的精细鉴别仍有一定局限性。

基于多模干涉的光纤冰体应变传感器

基于“单模-无芯-单模”光纤传感器对冰体进行应变测量研究。传感器以“分层冰冻”的方法植入冰体,冰体应变变化导致传感器干涉光谱波长偏移,通过监测光谱波长实现冰体应变测量。对于实际环境中已经存在的冰体,对“分层冰冻”方法进行优化,通过在冰面上铺设光纤,之后注水冰冻的方式,实现光纤在已有冰体中的植入。利用光谱相邻波谷温度灵敏度相近的特点,将相邻波谷波长差应用于应变测量,可以不受冰体温度变化影响。实验结果显示,冰体承载力大于500 g时,其应变显著增加,当承载力大于600 g时,冰体出现脆性断裂,传感器有效提取了该区间内冰体“韧-脆”转变过程中的应变信号。融化实验显示,传感器可以监测到冰体自然融化过程中完整的应变变化过程,测量结果不受冰体内部温度变化的影响。

光纤转动引起光纤光谱效率变化与改正

光纤的焦比退化(focal ratio degradation)是光纤光谱效率损失的重要原因之一。光纤在安装和每次定位过程中,光纤的转动和扭曲会引起光纤焦比退化发生变化,从而改变光纤的传输效率,每根光纤由此造成的传输效率变化都会存在差异。而这样的效率差异无法用通常天文观测中使用的晨昏天光平场或者圆顶平场改正。减天光是光纤光谱数据处理中决定光谱质量的重要环节。减天光处理要求对不同光纤的传输效率进行归一化处理,以扣除不同光纤之间传输效率差异导致的天光背景测量的误差。对于与天光背景亮度接近乃至更暗的观测目标而言,光纤传输效率的改正精度决定了减天光的精度。测试了LAMOST望远镜光纤转动对光纤传输效率的影响情况。在检查了光谱中天光发射线强度与光纤传输效率的关系,和验证了光纤效率变化与波长变化相对独立的基础上,提出并且证实了通过测量各光纤中天光发射线强度作为光纤相对效率变化量来改正光纤效率差异的方法是可行的。这种方法已经被应用到LAMOST二维光谱处理当中。

PAN基碳纤维在石墨化过程中的拉曼光谱

采用激光拉曼光谱研究了PAN基碳纤维在石墨化(2000～3000℃)过程中的结构变化;比较了石墨化前后纤维表面和断面拉曼光谱特征。结果表明:高温石墨化后,碳纤维的一级拉曼光谱有3个峰(D,G和D′),表征碳纤维结构有序程度的拉曼参数主要有D和G峰的半高宽(FWHM)、G峰的拉曼位移和D与G峰的积分强度比R(ID/IG)。随着热处理温度的提高,D和G峰的半高宽、G峰的拉曼位移和R值均逐渐减小,即使经过3000℃高温处理后,D峰仍然存在,R值为0.19,说明纤维中仍存在无序结构。另外,R值与纤维中石墨微晶的基面宽度La成反比,石墨化后纤维取向性的增加使得表面和断面的拉曼光谱有明显的差异。因此,可利用激光拉曼光谱来定量表征碳纤维的石墨化程度和取向。

PAN基碳纤维在表面处理中的拉曼光谱研究

采用激光拉曼光谱研究了PAN基碳纤维在表面处理中的微结构变化,分析了表面处理前后碳纤维的一级拉曼光谱特性。结果表明:拉曼光谱中主要的D峰和G峰的拉曼频移、半高宽以及各个不同拉曼频移位置对应肩峰的积分面积比是表征碳纤维物相结构变化的重要参数。经过不同的表面处理,PAN基碳纤维的一级拉曼光谱参数发生了一定程度变化,D峰和G峰的拉曼峰位向高波数偏移,表征石墨微晶尺寸的R值有所提高,这说明在表面处理后碳纤维的石墨微结构受到刻蚀,微晶尺寸有所减小,石墨微晶的边界活性增大;此外,表征碳纤维结构有序程度和缺陷多少的D峰和G峰的半高宽均有减小,表征无定型碳结构或某种有机官能团的A峰和D″峰的相对积分面积减小,这说明与乱层石墨结构相比,碳纤维中存在的无定型碳结构更容易被刻蚀,经过表面处理之后无定型碳的物相比例减小,这与碳纤维XRD图谱中表观结晶度提高的规律相一致。因此,利用激光拉曼光谱可研究碳纤维物相结构的变化规律。

碳纤维在电化学处理中的拉曼光谱研究

采用激光拉曼光谱研究了电化学改性处理过程中聚丙烯腈基碳纤维的表面微结构变化,分析了不同处理时间下碳纤维的一级拉曼光谱特性。结果表明:碳纤维的一级拉曼光谱可以拟合为4个峰,即D(D_1),G,D_2和D_3,表征碳纤维表面微结构变化的拉曼参数主要有D线和G线的积分面积比R(I_D/I_G),D_2线与G线的积分面积比I__(D_3)/I_G,D_3线与G线比I_(D_3)/I_G以及所有无序结构积分面积总和与G线积分面积的比值I_(D_S)/I_G。电化学处理后,碳纤维表面无序度增大,D线和G线交叠度减小,R增大,I_(D_3)/I_G增大,I_(D_2)/I_G减小。随着处理时间的增加,I_(D_S)/I_G不断增大,它与R值的变化趋势基本一致,并且可以更全面表征碳纤维表面结构有序性的变化。因此,利用激光拉曼光谱可以研究电化学改性处理过程中碳纤维表面的微结构变化规律。

监测氨基甲酸酯类农药的光纤荧光光谱仪的研究

根据西维因、克百威等氨基甲酸酯类农药的荧光性质 ,光谱仪采用氙灯作为激发光源 ,用光纤进行传光并结合CCD光谱探测技术 ,实现了对氨基甲酸酯类农药的快速测定。此仪器结构简单 ,操作灵活 ,线性度好 ,灵敏度高。实验结果表明 ,西维因和克百威的浓度线性范围为 0～ 12 0ppb ,最低检出限LOD分别为 2 7ppb和 7 0ppb。在实际取样的测量中 ,还要考虑到腐殖酸的猝灭作用 ,通过对仪器进行校正得到准确的测量值。

太赫兹时域光谱技术在纺织纤维鉴别中的应用

提出了一种基于太赫兹时域光谱(THz-TDS)的纺织品鉴别方法,并以几种常见的合成纤维作为实验介质证明该方法的可行性。利用THz-TDS系统测得了这些介质在大赫兹波段的时域光谱信号,得到了它们在太赫兹波段吸收系数谱。实验结果表明,涤纶、锦纶和维纶分别在0.98、1.51和1.16THz有明显不同的特征吸收峰,芳纶、腈纶和天丝的吸收谱也存在明显差别。研究表明,利用太赫兹时域光谱技术进行合成纤维鉴别是可行的,为进一步将太赫兹波技术应用于纺织品检测提供了依据。

光子晶体光纤光栅反射谱及时延特性研究

利用多极法对包层空气孔为正六边形对称结构光子晶体光纤的模式场进行了分析,计算出不同波长下基模的有效折射率,结合使用模式耦合理论和传输矩阵法对基于光子晶体光纤的布拉格光栅特性进行了计算和仿真,对比了常规单模光纤所成光栅与相同光栅周期的光子晶体光纤布拉格光栅反射谱及时延特性之间的差异。在此基础上,对光纤光栅的切趾特性进行了研究,选择不同的切趾函数,得出最佳切趾函数下光栅传输谱。理论计算和仿真结果表明,随波长增加,基模有效折射率下降,光栅谐振波长出现蓝移,采用啁啾化处理后,10cm长光子晶体光纤光栅可以提供1200ps以上的线性时延。

低浓度样品拉曼光谱的实验研究

在液芯光纤内产生共振拉曼效应，可以提高拉曼光谱强度１０９倍。测定了 １０－１０～１０－５ ｍｏｌ／Ｌ浓度样品的拉曼光谱。实验结果表明，β－胡罗卜素在ＣＳ２中 １５２０ ｃｍ－１拉曼线的强度（散射系数）、频移、线宽随浓度降低而发生变化。

羊毛纤维表面处理的拉曼光谱研究

结合轻碱洗毛法、中性洗毛法和超声助剂洗毛法,设计出一个表面处理工艺.该工艺既能减少资源的浪费,又可缩短洗毛时间.对羊毛的表面处理工艺流程主要分为润湿、洗涤、超声波空化、炭化4步,实验证明该方法简单、快捷,洗毛干净.在工艺流程的最后应用拉曼光谱仪对羊毛纤维表面结构进行检测、分析,确定了洗毛工艺中润湿阶段的最佳温度和炭化过程的最佳时间.结果表明,润湿阶段的最佳温度为60℃左右,炭化时烘焙的最佳时间在25 ～ 30 min之间.