Based on the pyrolysis products for the Jurassic low-mature coal under programmed temperature,and chemical and carbon isotopic compositions of natural gas from the Kuqa Depression, the genetic origin of natural gas wa...Based on the pyrolysis products for the Jurassic low-mature coal under programmed temperature,and chemical and carbon isotopic compositions of natural gas from the Kuqa Depression, the genetic origin of natural gas was determined,and then a gas filling model was established,in combination with the geological background of the Kuqa Depression.The active energy of CH_4,C_2H_6 and C_3H_8 was gotten after the data of pyrolysis gas products under different heating rates(2℃/h and 20℃/h)were fitted by the Gas Oil Ratio(GOR)Isotope Model soft.When the frequency factor(Af)was chosen as 1×10^(14),the active energy of CH_4,C_2H_6 and C_3H_8 was 58 kcal/mol,57 kcal/mol and 54 kcal/ mol,respectively.The distributive ranges of theδ^(13)C_1,δ^(13)C_2 andδ^(13)C_3 values for the pyrolysis gas products are-35.9‰to-30.7‰,-26.2‰to-21.3‰and-26.4‰to-22.7‰,respectively.All of the natural gases from the Kuqa Depression are dominated by hydrocarbon gases,with the high gas dryness(C_1/C_(1-4))at the middle and northern parts of the depression and the low values at both east and west sides and the southern part.The carbon isotopes of methane and its homologs as a typical coal-type gas are enriched in ^(13)C,and the distributive range of theδ^(13)C_1,δ^(13)C_2 andδ^(13)C_3 value is-32‰to -38‰,-22‰to-24‰and-20‰to-22‰,respectively,with the carbon isotopes of gaseous alkanes being less negative with the carbon number.With the ethane being enriched in ^(13)C the increasing tendency of the geological reserve of natural gas in the Kuqa Depression is observed.This observed change is consistent with the results of pyrolysate gas yield of coal as a potential gas source in the Kuqa Depression,suggesting natural gas was thermally derived from the humic organic matters and the carbon isotopes of gaseous alkanes would coarsely predict the geological reserve of gas in the Kuqa Depression.Through the simulation of kinetic processes of gas generation for the Jurassic coal in the Kuqa Depression,the gas in the Kela 2 gas field would get the threshold of gas expulsion after 27 Ma,be expelled out of source rocks as"pulse action",and then filled in the gas reservoir.The peak gas-filling history took place during the past 2 Ma.展开更多
Through basin-filling analysis, one coarsening-upward and two fining-upward sequences have been identified in Zhu Ⅲ depression. In accondance with the general model proposed by Ravnas and Steel (1998), the basin-fil...Through basin-filling analysis, one coarsening-upward and two fining-upward sequences have been identified in Zhu Ⅲ depression. In accondance with the general model proposed by Ravnas and Steel (1998), the basin-filling has two large cycles—rift (sediment-balanced and -overfilled) and postrift (sedimentunderfilled and starved). During the rifting process, the rifted lake developed through three stages: early, climax and late. The sedimentary characteristics of reservoir rocks show that barrier bar, lagoon and tidal channel facies well developed in Zhuhai Formation; offshore, tidal and barrier bar well developed in Zhujiang Formation. Neighborly, Shenhu, Wenchang and Enping formations deposited in rifted lakes during Paleogene time; Zhujiang Formation deposited in bay, lagoon and shoreface in late Paleogene. Zhujiang and other formations deposited in offshore and open shallow sea to shelf.展开更多
Condensates and light oils are generally characterized by high maturity, low concentration of sterane and terpane biomarkers and low content of non-hydrocarbon fraction. As a result, some commonly-used sterane, terpan...Condensates and light oils are generally characterized by high maturity, low concentration of sterane and terpane biomarkers and low content of non-hydrocarbon fraction. As a result, some commonly-used sterane, terpane and carbazole migration parameters in conventional oil reservoirs may have a certain limitation in condensate and light oil reservoirs for their poor signal-noise ratios in the gas chromatography-mass spectrometry (GC-MS). Naphthalene, phenanthrene and their methylated substituents, however, are present in significant concentrations in condensates and light oils. Taking the Fushan depression (in the Beibuwan Basin, Northern South China Sea) as an example, this paper attempts for the first time to use polycyclic aromatic hydrocarbon (PAH)-related parameters to trace migration directions and filling pathways for condensate and light oil reservoirs. The result shows that TMNr (i.e. 1, 3, 7-TMN/(1, 3, 7-TMN + 1, 2, 5-TMN), TMN: trimethylnaphthalene)), MPI-1 (i.e. 1.5×(2-MP + 3-MP)/(P + 1-MP + 9-MP), P: phenanthrene MP: methyiphenanthrene), MN/DMN (∑methylnaphthalene/∑dimethylnaphthalene, %) and MN/TMN (∑nethylnaphthalene/∑trimethylna- phthalene, %) can be used to trace the filling pathways of condensate and light oil reservoirs. These parameters, together with geological consideration and other bulk oil properties (e.g. the gas to oil ratio and density), suggest that the condensates and light oils in the Huachang oil and gas field are mainly sourced from the Bailian sag that is located to the northeast of the Huachang uplift in the Fushan depression.展开更多
The condensates are generally characterized by high maturity,low concentration of steranes and ter-panes biomarkers and low content of non-hydrocarbon fraction. In this case commonly used steranes,terpanes and carbazo...The condensates are generally characterized by high maturity,low concentration of steranes and ter-panes biomarkers and low content of non-hydrocarbon fraction. In this case commonly used steranes,terpanes and carbazoles parameters cannot be effectively applied in the reservoir-filling tracing. The hydrogen bond formed by sulfur atom in the dibenzothiophenes (DBTs) results in molecule adsorption and fractionation during oil migration in reservoir. Like carbazoles,total DBTs content decreases with the increasing of oil migration distance. Therefore,a new parameter——total DBTs content is proposed to be used to trace the oil migration orientation and filling pathway. In present study,total DBTs con-tents of condensates and light oils are obtained by adding internal standard——eight deuterium atoms substituted DBT during Gas Chromatography-Mass Spectrometry analysis of aromatic fraction. Except for a few samples with much lower content of non-hydrocarbon fraction,the total DBTs content shows a fine positive correlation with that of carbazoles. Large errors can be caused in the process of pyrrolic nitrogen compounds separation. The application of this new parameter in the Fushan Depression of Beibu Gulf Basin,South China Sea indicates that this parameter is a reliable one to trace filling pathway in condensate reservoirs. Combined with other DBTs-related parameters,such as 4-/1-methydibenzo-thiophene and 2,4-/1,4-dimethyldibenzothiophene,oil migration orientation and filling pathway of the Fushan Depression was determined. The accumulations of Huachang oil field in the Fushan Depres-sion are mainly migrated and charged from northeast to southeast along the Huachang uplift. It can be predicated that the light oil and condensates in the Huachang oil field should be sourced from the source kitchen at the Bailian Sag. It shows that total DBTs content is an effective parameter to tracing oil migration orientation and filling pathway.展开更多
The Cretaceous system of the Kuqa depression is a regional scale (second order) depositional sequence defined by parallel unconformities or minor angular unconformities. It can be divided into four third-order sequenc...The Cretaceous system of the Kuqa depression is a regional scale (second order) depositional sequence defined by parallel unconformities or minor angular unconformities. It can be divided into four third-order sequence sets, eleven third-order sequences and tens of fourth- and fifth-order sequences. It consists generally of a regional depositional cycle from transgres-sion to regression and is composed of three sets of facies associations: alluvial-fluvial, braided river-deltaic and lacustrine-deltaic facies associations. They represent the lowstand, transgres-sive and highstand facies tracts within the second-order sequence. The tectonic subsidence curve reconstructed by backstripping technique revealed that the Cretaceous Kuqa depression underwent a subsidence history from early accelerated subsidence, middle rapid subsidence and final slower subsidence phases during the Cretaceous time, with the correspondent tectonic subsidence rates being 3035 m/Ma, 4045 m/Ma and 510 m/Ma obtained from northern foredeep. This is likely attributed to the foreland dynamic process from early thrust flexural sub-sidence to late stress relaxation and erosion rebound uplift. The entire sedimentary history and the development of the three facies tracts are a response to the basin subsidence process. The slower subsidence foreland gentle slope was a favorable setting for the formation of braided flu-vial deltaic systems during the late period of the Cretaceous, which comprise the important sandstone reservoirs in the depression. Sediment records of impermanent marine transgression were discovered in the Cretaceous and the major marine horizons are correctable to the high-stands of the global sea level during the period.展开更多
Recently,volcanic gas reservoirs in Yaoyingtai (腰英台) and Daerhan (达尔罕) tectonic belts in Changling (长岭) faulted depression of southeastern Songliao (松辽) basin have been discovered.Based on the compos...Recently,volcanic gas reservoirs in Yaoyingtai (腰英台) and Daerhan (达尔罕) tectonic belts in Changling (长岭) faulted depression of southeastern Songliao (松辽) basin have been discovered.Based on the compositions and isotopic values,the natural gas is characterized by high content of methane,low content of C2+,and C1/C1-5 beyond 0.95.Also,the natural gas contains nonhydrocarbons including carbon dioxide with the content from 20% to 40% and minor amount of N2.Combined with the isotopic values,the natural gas is generated by humic kerogen and coal-derived type,but in Daerhan,the natural gas is probably mixed by oil type gas.From the measurement of lithology and fluid inclusions in volcanic rocks,the bitumen,liquid hydrocarbon,and gas hydrocarbon inclusions are present.Through the analysis of the single gas inclusion in volcanic reservoir,the content of carbon dioxide is low,so the carbon dioxide and hydrocarbon gas of the reservoirs are not accumulated at the same time.In addition,minor amount of bitumen in the reservoirs is formed by thermal evolution of the crude oils sourced from the Yingcheng (营城) Formation mudstones through the characterizations of the biomarkers.The distribution of homogenization temperatures presents two peaks,one with the liquid hydrocarbon filling stage,and the other with gas filling stage.However,in Daerhan tectonic belt,the second peak is gas and carbon dioxide mixed filling period probably.Combined with the homogenization temperatures of salt water inclusions,the oil and gas filling period is from Qingshankou (青山口) Formation to Nenjiang (嫩江) Formation in the research area.During the charging period,minor amount of inorganic carbon dioxide filled into the trap,but plenty of inorganic carbon dioxide from the end of Sifangtai (四方台) to Eogene periods was related with the structural movement.展开更多
Depressions in raster digital elevation models(DEM)present a challenge for extracting hydrological networks.They are commonly filled before subsequent algorithms are further applied.Among existing algorithms for filli...Depressions in raster digital elevation models(DEM)present a challenge for extracting hydrological networks.They are commonly filled before subsequent algorithms are further applied.Among existing algorithms for filling depressions,the Priority-Flood algorithm runs the fastest.In this study,we propose an improved variant over the fastest existing sequential variant of the Priority-Flood algorithm for filling depressions in floating-point DEMs.The proposed variant introduces a series of improvements and greatly reduces the number of cells that need to be processed by the priority queue(PQ),the key data structure used in the algorithm.The proposed variant is evaluated based on statistics from 30 experiments.On average,our proposed variant reduces the number of cells processed by the PQ by around 70%.The speed-up ratios of our proposed variant over the existing fastest variant of the Priority-Flood algorithm range from 31%to 52%,with an average of 45%.The proposed variant can be used to fill depressions in large DEMs in much less time and in the parallel implementation of the Priority-Flood algorithm to further reduce the running time for processing huge DEMs that cannot be dealt with easily on single computers.展开更多
以某公司电镀填盲孔的电镀液体系为研究对象,在500 m L哈林槽中模拟电镀线,系统地考察了电镀液配方(硫酸铜、硫酸、湿润剂、光亮剂、整平剂和氯离子的浓度以及添加剂相互作用)、电镀参数(电流密度和电镀时间)以及盲孔几何尺寸(深径比0.6...以某公司电镀填盲孔的电镀液体系为研究对象,在500 m L哈林槽中模拟电镀线,系统地考察了电镀液配方(硫酸铜、硫酸、湿润剂、光亮剂、整平剂和氯离子的浓度以及添加剂相互作用)、电镀参数(电流密度和电镀时间)以及盲孔几何尺寸(深径比0.6∶1和1.07∶1)等化学和物理因素对FR-4基材盲孔电镀填孔的影响。以盲孔填孔率、凹陷度、表层镀铜厚度等指标综合评价盲孔填孔效果并用金相显微镜观察孔的横截面。结果表明,在适宜的电镀条件下,该电镀液体系对印制电路板盲孔的填孔效果良好。但是,适宜的电镀参数和电镀液配方与盲孔几何尺寸显著相关。展开更多
基金financially supported by the Chinese National Natural Science Foundation(Grant No:40802028)the National Key Foundational Research and Development Project (Grant No:2005CB422108)+1 种基金the National Science and Technology Special Project(2008ZX05005-004-004)supported by the Opening Project of Key Laboratory of Marine Reservoir Evolution and Hydrocarbon Accumulation Mechanism,Ministry of Education,China.
文摘Based on the pyrolysis products for the Jurassic low-mature coal under programmed temperature,and chemical and carbon isotopic compositions of natural gas from the Kuqa Depression, the genetic origin of natural gas was determined,and then a gas filling model was established,in combination with the geological background of the Kuqa Depression.The active energy of CH_4,C_2H_6 and C_3H_8 was gotten after the data of pyrolysis gas products under different heating rates(2℃/h and 20℃/h)were fitted by the Gas Oil Ratio(GOR)Isotope Model soft.When the frequency factor(Af)was chosen as 1×10^(14),the active energy of CH_4,C_2H_6 and C_3H_8 was 58 kcal/mol,57 kcal/mol and 54 kcal/ mol,respectively.The distributive ranges of theδ^(13)C_1,δ^(13)C_2 andδ^(13)C_3 values for the pyrolysis gas products are-35.9‰to-30.7‰,-26.2‰to-21.3‰and-26.4‰to-22.7‰,respectively.All of the natural gases from the Kuqa Depression are dominated by hydrocarbon gases,with the high gas dryness(C_1/C_(1-4))at the middle and northern parts of the depression and the low values at both east and west sides and the southern part.The carbon isotopes of methane and its homologs as a typical coal-type gas are enriched in ^(13)C,and the distributive range of theδ^(13)C_1,δ^(13)C_2 andδ^(13)C_3 value is-32‰to -38‰,-22‰to-24‰and-20‰to-22‰,respectively,with the carbon isotopes of gaseous alkanes being less negative with the carbon number.With the ethane being enriched in ^(13)C the increasing tendency of the geological reserve of natural gas in the Kuqa Depression is observed.This observed change is consistent with the results of pyrolysate gas yield of coal as a potential gas source in the Kuqa Depression,suggesting natural gas was thermally derived from the humic organic matters and the carbon isotopes of gaseous alkanes would coarsely predict the geological reserve of gas in the Kuqa Depression.Through the simulation of kinetic processes of gas generation for the Jurassic coal in the Kuqa Depression,the gas in the Kela 2 gas field would get the threshold of gas expulsion after 27 Ma,be expelled out of source rocks as"pulse action",and then filled in the gas reservoir.The peak gas-filling history took place during the past 2 Ma.
基金National Natural Science Foundation of China!(No.49732005-01)
文摘Through basin-filling analysis, one coarsening-upward and two fining-upward sequences have been identified in Zhu Ⅲ depression. In accondance with the general model proposed by Ravnas and Steel (1998), the basin-filling has two large cycles—rift (sediment-balanced and -overfilled) and postrift (sedimentunderfilled and starved). During the rifting process, the rifted lake developed through three stages: early, climax and late. The sedimentary characteristics of reservoir rocks show that barrier bar, lagoon and tidal channel facies well developed in Zhuhai Formation; offshore, tidal and barrier bar well developed in Zhujiang Formation. Neighborly, Shenhu, Wenchang and Enping formations deposited in rifted lakes during Paleogene time; Zhujiang Formation deposited in bay, lagoon and shoreface in late Paleogene. Zhujiang and other formations deposited in offshore and open shallow sea to shelf.
基金supported by the Natural Science Foundation of China(Grant No.40972089),CNPC Innovation Fund(Grant No.07E1001)the State Key Laboratory of the Petroleum Resources and Prospecting(Grant No.PRPDX2008-01)
文摘Condensates and light oils are generally characterized by high maturity, low concentration of sterane and terpane biomarkers and low content of non-hydrocarbon fraction. As a result, some commonly-used sterane, terpane and carbazole migration parameters in conventional oil reservoirs may have a certain limitation in condensate and light oil reservoirs for their poor signal-noise ratios in the gas chromatography-mass spectrometry (GC-MS). Naphthalene, phenanthrene and their methylated substituents, however, are present in significant concentrations in condensates and light oils. Taking the Fushan depression (in the Beibuwan Basin, Northern South China Sea) as an example, this paper attempts for the first time to use polycyclic aromatic hydrocarbon (PAH)-related parameters to trace migration directions and filling pathways for condensate and light oil reservoirs. The result shows that TMNr (i.e. 1, 3, 7-TMN/(1, 3, 7-TMN + 1, 2, 5-TMN), TMN: trimethylnaphthalene)), MPI-1 (i.e. 1.5×(2-MP + 3-MP)/(P + 1-MP + 9-MP), P: phenanthrene MP: methyiphenanthrene), MN/DMN (∑methylnaphthalene/∑dimethylnaphthalene, %) and MN/TMN (∑nethylnaphthalene/∑trimethylna- phthalene, %) can be used to trace the filling pathways of condensate and light oil reservoirs. These parameters, together with geological consideration and other bulk oil properties (e.g. the gas to oil ratio and density), suggest that the condensates and light oils in the Huachang oil and gas field are mainly sourced from the Bailian sag that is located to the northeast of the Huachang uplift in the Fushan depression.
基金Supported by the National Natural Science Foundation of China (Grant No.40672093)the CNPC Innovation Fund (Grant No.07E1001)
文摘The condensates are generally characterized by high maturity,low concentration of steranes and ter-panes biomarkers and low content of non-hydrocarbon fraction. In this case commonly used steranes,terpanes and carbazoles parameters cannot be effectively applied in the reservoir-filling tracing. The hydrogen bond formed by sulfur atom in the dibenzothiophenes (DBTs) results in molecule adsorption and fractionation during oil migration in reservoir. Like carbazoles,total DBTs content decreases with the increasing of oil migration distance. Therefore,a new parameter——total DBTs content is proposed to be used to trace the oil migration orientation and filling pathway. In present study,total DBTs con-tents of condensates and light oils are obtained by adding internal standard——eight deuterium atoms substituted DBT during Gas Chromatography-Mass Spectrometry analysis of aromatic fraction. Except for a few samples with much lower content of non-hydrocarbon fraction,the total DBTs content shows a fine positive correlation with that of carbazoles. Large errors can be caused in the process of pyrrolic nitrogen compounds separation. The application of this new parameter in the Fushan Depression of Beibu Gulf Basin,South China Sea indicates that this parameter is a reliable one to trace filling pathway in condensate reservoirs. Combined with other DBTs-related parameters,such as 4-/1-methydibenzo-thiophene and 2,4-/1,4-dimethyldibenzothiophene,oil migration orientation and filling pathway of the Fushan Depression was determined. The accumulations of Huachang oil field in the Fushan Depres-sion are mainly migrated and charged from northeast to southeast along the Huachang uplift. It can be predicated that the light oil and condensates in the Huachang oil field should be sourced from the source kitchen at the Bailian Sag. It shows that total DBTs content is an effective parameter to tracing oil migration orientation and filling pathway.
基金supported by the Ministry of Science and Technology of China(Grant No.G1999043304)the National Natural Science Foundation of China(Grant No.40372056).
文摘The Cretaceous system of the Kuqa depression is a regional scale (second order) depositional sequence defined by parallel unconformities or minor angular unconformities. It can be divided into four third-order sequence sets, eleven third-order sequences and tens of fourth- and fifth-order sequences. It consists generally of a regional depositional cycle from transgres-sion to regression and is composed of three sets of facies associations: alluvial-fluvial, braided river-deltaic and lacustrine-deltaic facies associations. They represent the lowstand, transgres-sive and highstand facies tracts within the second-order sequence. The tectonic subsidence curve reconstructed by backstripping technique revealed that the Cretaceous Kuqa depression underwent a subsidence history from early accelerated subsidence, middle rapid subsidence and final slower subsidence phases during the Cretaceous time, with the correspondent tectonic subsidence rates being 3035 m/Ma, 4045 m/Ma and 510 m/Ma obtained from northern foredeep. This is likely attributed to the foreland dynamic process from early thrust flexural sub-sidence to late stress relaxation and erosion rebound uplift. The entire sedimentary history and the development of the three facies tracts are a response to the basin subsidence process. The slower subsidence foreland gentle slope was a favorable setting for the formation of braided flu-vial deltaic systems during the late period of the Cretaceous, which comprise the important sandstone reservoirs in the depression. Sediment records of impermanent marine transgression were discovered in the Cretaceous and the major marine horizons are correctable to the high-stands of the global sea level during the period.
基金supported by East China Branch of SINOPEC (No. G1414-06-KK-0230)
文摘Recently,volcanic gas reservoirs in Yaoyingtai (腰英台) and Daerhan (达尔罕) tectonic belts in Changling (长岭) faulted depression of southeastern Songliao (松辽) basin have been discovered.Based on the compositions and isotopic values,the natural gas is characterized by high content of methane,low content of C2+,and C1/C1-5 beyond 0.95.Also,the natural gas contains nonhydrocarbons including carbon dioxide with the content from 20% to 40% and minor amount of N2.Combined with the isotopic values,the natural gas is generated by humic kerogen and coal-derived type,but in Daerhan,the natural gas is probably mixed by oil type gas.From the measurement of lithology and fluid inclusions in volcanic rocks,the bitumen,liquid hydrocarbon,and gas hydrocarbon inclusions are present.Through the analysis of the single gas inclusion in volcanic reservoir,the content of carbon dioxide is low,so the carbon dioxide and hydrocarbon gas of the reservoirs are not accumulated at the same time.In addition,minor amount of bitumen in the reservoirs is formed by thermal evolution of the crude oils sourced from the Yingcheng (营城) Formation mudstones through the characterizations of the biomarkers.The distribution of homogenization temperatures presents two peaks,one with the liquid hydrocarbon filling stage,and the other with gas filling stage.However,in Daerhan tectonic belt,the second peak is gas and carbon dioxide mixed filling period probably.Combined with the homogenization temperatures of salt water inclusions,the oil and gas filling period is from Qingshankou (青山口) Formation to Nenjiang (嫩江) Formation in the research area.During the charging period,minor amount of inorganic carbon dioxide filled into the trap,but plenty of inorganic carbon dioxide from the end of Sifangtai (四方台) to Eogene periods was related with the structural movement.
基金the National Natural Science Foundation of China[grant number 41671427]the Open Fund of the State Key Laboratory of Soil Erosion and Dryland Farming on the Loess Plateau[grant number A314021402-1710]the Fundamental Research Funds for the Central Universities[grant number ZYGX2016J148]。
文摘Depressions in raster digital elevation models(DEM)present a challenge for extracting hydrological networks.They are commonly filled before subsequent algorithms are further applied.Among existing algorithms for filling depressions,the Priority-Flood algorithm runs the fastest.In this study,we propose an improved variant over the fastest existing sequential variant of the Priority-Flood algorithm for filling depressions in floating-point DEMs.The proposed variant introduces a series of improvements and greatly reduces the number of cells that need to be processed by the priority queue(PQ),the key data structure used in the algorithm.The proposed variant is evaluated based on statistics from 30 experiments.On average,our proposed variant reduces the number of cells processed by the PQ by around 70%.The speed-up ratios of our proposed variant over the existing fastest variant of the Priority-Flood algorithm range from 31%to 52%,with an average of 45%.The proposed variant can be used to fill depressions in large DEMs in much less time and in the parallel implementation of the Priority-Flood algorithm to further reduce the running time for processing huge DEMs that cannot be dealt with easily on single computers.
文摘以某公司电镀填盲孔的电镀液体系为研究对象,在500 m L哈林槽中模拟电镀线,系统地考察了电镀液配方(硫酸铜、硫酸、湿润剂、光亮剂、整平剂和氯离子的浓度以及添加剂相互作用)、电镀参数(电流密度和电镀时间)以及盲孔几何尺寸(深径比0.6∶1和1.07∶1)等化学和物理因素对FR-4基材盲孔电镀填孔的影响。以盲孔填孔率、凹陷度、表层镀铜厚度等指标综合评价盲孔填孔效果并用金相显微镜观察孔的横截面。结果表明,在适宜的电镀条件下,该电镀液体系对印制电路板盲孔的填孔效果良好。但是,适宜的电镀参数和电镀液配方与盲孔几何尺寸显著相关。