In the practice of petroleum industry, adding cold flow improver （CFI） to lower the fuel＇s cold filter plugging point （CFPP） is an effective and economic way for improving the cold flow performance of diesel fuel...In the practice of petroleum industry, adding cold flow improver （CFI） to lower the fuel＇s cold filter plugging point （CFPP） is an effective and economic way for improving the cold flow performance of diesel fuel. This paper described the synthesis and evaluation of the performance of dibehenyl fumarate-vinyl acetate （FV） copolymer for improving the cold flow performance of the tested diesel fuels. The carbon distribution in n-alkanes of the tested diesel samples were analyzed by gas phase chromatography. The structure of the copolymer was confirmed by the 1H NMR spectroscopy. The wax crystals morphologies with and without adding the FV additive were investigated by means of polarizing microscope. The test results indicated that the FV additive could depress CFPP of the tested diesel samples by 2℃ and 4℃, respectively, when dosage of the additive was 0.08 m%. The additive can modify the size and shape of the wax crystals and inhibit the formation of larger wax crystal lattices.展开更多
In view of the fact that most of the filter media of existing plugging evaluation instruments use steel plates or steel balls, which cannot truly simulate the characteristics of the formation, a new type of TL-1 high ...In view of the fact that most of the filter media of existing plugging evaluation instruments use steel plates or steel balls, which cannot truly simulate the characteristics of the formation, a new type of TL-1 high temperature and high pressure plugging instrument has been developed. The filter medium of the instrument is the natural stone with different cracks and quartz sand beds with different particle sizes, which can better simulate the adsorption and hang-up effect of the formation on the plugging agent. It is possible to evaluate the plugging effect, pressure-bearing capacity and return pressure of the plugging slurry for different cracks and sand beds of different sizes under different temperatures and pressures. Using new and old instruments to evaluate the plugging effect of the same plugging slurry, it is found that the plugging effect is different from the distribution of the plugging material on the crack surface, the plugging effect and the pressure bearing capacity. The instrument is stable and reliable in operation and simple in operation. It is a new instrument for conducting research on anti-leakage plugging materials and anti-leakage plugging drilling fluid systems.展开更多
基金supported by the Basic Research Program of the State Key Laboratory of Heavy Oil Processing(200310),China University of Petroleum,Beijing,China.
文摘In the practice of petroleum industry, adding cold flow improver （CFI） to lower the fuel＇s cold filter plugging point （CFPP） is an effective and economic way for improving the cold flow performance of diesel fuel. This paper described the synthesis and evaluation of the performance of dibehenyl fumarate-vinyl acetate （FV） copolymer for improving the cold flow performance of the tested diesel fuels. The carbon distribution in n-alkanes of the tested diesel samples were analyzed by gas phase chromatography. The structure of the copolymer was confirmed by the 1H NMR spectroscopy. The wax crystals morphologies with and without adding the FV additive were investigated by means of polarizing microscope. The test results indicated that the FV additive could depress CFPP of the tested diesel samples by 2℃ and 4℃, respectively, when dosage of the additive was 0.08 m%. The additive can modify the size and shape of the wax crystals and inhibit the formation of larger wax crystal lattices.
文摘In view of the fact that most of the filter media of existing plugging evaluation instruments use steel plates or steel balls, which cannot truly simulate the characteristics of the formation, a new type of TL-1 high temperature and high pressure plugging instrument has been developed. The filter medium of the instrument is the natural stone with different cracks and quartz sand beds with different particle sizes, which can better simulate the adsorption and hang-up effect of the formation on the plugging agent. It is possible to evaluate the plugging effect, pressure-bearing capacity and return pressure of the plugging slurry for different cracks and sand beds of different sizes under different temperatures and pressures. Using new and old instruments to evaluate the plugging effect of the same plugging slurry, it is found that the plugging effect is different from the distribution of the plugging material on the crack surface, the plugging effect and the pressure bearing capacity. The instrument is stable and reliable in operation and simple in operation. It is a new instrument for conducting research on anti-leakage plugging materials and anti-leakage plugging drilling fluid systems.
