When soldering electronic components onto circuit boards,the temperature curves of the reflow ovens across different zones and the conveyor belt speed significantly influence the product quality.This study focuses on ...When soldering electronic components onto circuit boards,the temperature curves of the reflow ovens across different zones and the conveyor belt speed significantly influence the product quality.This study focuses on optimizing the furnace temperature curve under varying settings of reflow oven zone temperatures and conveyor belt speeds.To address this,the research sequentially develops a heat transfer model for reflow soldering,an optimization model for reflow furnace conditions using the differential evolution algorithm,and an evaluation and decision model combining the differential evolution algorithm with the Technique for Order Preference by Similarity to Ideal Solution(TOPSIS)method.This approach aims to determine the optimal furnace temperature curve,zone temperatures of the reflow oven,and the conveyor belt speed.展开更多
In this work, a parametric approach is presented and utilized to determine the creep properties of weldments; then the model of creep strain for cross weld specimen is given. On the basis of the experimental results, ...In this work, a parametric approach is presented and utilized to determine the creep properties of weldments; then the model of creep strain for cross weld specimen is given. On the basis of the experimental results, attempt has been made to establish equations of the isochronous stress-strain for weld joint that can predict the function of loading and service time in use of the creep data of base metal and weld metal.展开更多
Initial firing temperatures play an important role on the combustion rate of propellant. In gun propellants, initial temperature is a key factor for both accuracy and safety. Ideally, the initial temperature of the pr...Initial firing temperatures play an important role on the combustion rate of propellant. In gun propellants, initial temperature is a key factor for both accuracy and safety. Ideally, the initial temperature of the propellant should not influence the ballistic properties of the round. Nevertheless, constant initial temperature coefficients can not be achieved easily. This work focuses on the influence of the firing temperature on the ballistic properties, the mechanical integrity and the sensitivity to impact of nitrocellulose based propellants. Combustion rates have been determined by closed vessel tests. Ballistic properties have been investigated by firing 5.56 cartridges. The propellants have been conditioned at temperatures ranging from -54 ℃ to +71 ℃ before firing. The largest temperature coefficient is observed at high temperatures. The temperature sensitivity of the peak pressure in the combustion chamber can not be fully explained by the results from the closed vessel test. The authors speculated that the mechanical behaviour of the propellant grains at low temperatures influences also the overall ballistic properties of the round. Impact tests with propellants conditioned at low and high temperatures permit to investigate their mechanical strength under extreme temperatures and to better understand the propellant performance during firing. Tests on aged propellants have been conducted as well.展开更多
This work studied the effects of firing temperatures on the refractory properties of insulating firebricks produced from a blend of hydrometallurgically purified clay, high alumina cement and sawdust. Twenty grams out...This work studied the effects of firing temperatures on the refractory properties of insulating firebricks produced from a blend of hydrometallurgically purified clay, high alumina cement and sawdust. Twenty grams out of a bulk (1000 Kg) of clay obtained from Ipetumodu in Nigeria was analyzed for size range, consequent upon which the remaining bulk was sieved to 100 μm, being the average size. The bulk was there after leached under a predetermined condition (1.6 mol/dm3 of oxalic acid at 70oC for 150 min and 200 rev/min agitation speed) and cylindrical samples (5 cm diameter by 5 cm high) containing different quantities of high alumina cement (5% - 20%) and sawdust (1% - 5%) were prepared, dried at 110oC and subsequently fired at 900oC, 1100oC, 1300oC and 1500oC, at the rate of 4oC/min and soaked for 2 hrs. These samples were subjected to different refractory tests (permanent linear change, modulus of rupture, bulk density, cold crushing strength and apparent porosity). Even though samples containing more than 20% alumina crumbled at elevated temperatures, it was still observed that the bricks performed to expectations at lower alumina contents, even at 1500oC. The sample containing 3% sawdust and 10% alumina cement however, gave the desired requirement for preparing good insulating firebricks with reliable phase integrity, as revealed by scanning electron microscopy (SEM).展开更多
The purpose of this research is to characterize shapes in thermodynamic terms, namely, in terms of total energy, dissipative energy, entropy, and temperature. As case studies, polygons and some well-known curves were ...The purpose of this research is to characterize shapes in thermodynamic terms, namely, in terms of total energy, dissipative energy, entropy, and temperature. As case studies, polygons and some well-known curves were taken, and they were characterized using physical terms. The relation between entropy and curvature was elucidated, and the black hole surface gravity and temperature were criticized and reinterpreted from this point of view. Particular energy attributions were evaluated by comparing the position of any edge of a polygon (<em>i</em>.<em>e</em>. its angle with the horizontal axis) with a broken crystal surface. Energies of all edges were added up at all positions between 0<span style="white-space:nowrap;">˚ </span>- 360<span style="white-space:nowrap;">˚</span>. In regular polygons, the total energy decreases with the increase of the number of edges. Entropy increases in the reverse order, and the increase of the number of edges increases entropy. It implies that the circle has the lowest energy but the highest surface entropy. In curves (circle, sine-curve, spiral, and exponential curve), the total energy, dissipative energy, and entropy all depend on amplitude and also on specific variables. Black hole entropy expressed in terms of the surface area is a configurational entropy and not thermal entropy;therefore, it does not involve a varying temperature term. The surface gravity of a black hole is connected to acceleration and thus to curvature. To relate it with the temperature needs to be reinterpreted, because, surface gravity behaves like an attractive force not exactly like temperature. Hawking radiation is still possible, but the black hole does not get warmer as it evaporates. Material loss from the black hole gets faster as its radius decreases due to the curvature effect, <em>i</em>.<em>e</em>. by a mechanism similar to the Gibbs-Thomson effect.展开更多
Using purified bovine liver tRNA ̄(Ile) and yeast tRNA ̄(Phe), we studied the effects of spermine on the melting curve and melting temperature(Tm) of the tRNAs. The results showed that the absorbance at 260 nm of tRNA...Using purified bovine liver tRNA ̄(Ile) and yeast tRNA ̄(Phe), we studied the effects of spermine on the melting curve and melting temperature(Tm) of the tRNAs. The results showed that the absorbance at 260 nm of tRNAs decreases with the increase of temperature in the presence of 2 mmol/L spermine. We called this phenomenon hypochromism and reverse-Tm of the tRNAs. It is suggested that spermine binds to tRNAs and stabilizes the secondary structure of the tRNAs.展开更多
To reduce production costs and make full and reasonable use of raw materials,high alumina bricks were prepared using tabular corundum and mullite as aggregates,sillimanite as intermediate particles,and white fused cor...To reduce production costs and make full and reasonable use of raw materials,high alumina bricks were prepared using tabular corundum and mullite as aggregates,sillimanite as intermediate particles,and white fused corundum powder,α-alumina micropowder,and Suzhou soil as the matrix,firing at different temperatures(1420,1440,1460,1480,1500 and 1520℃)for 4 h.The apparent porosity(AP),the bulk density(BD),the cold crushing strength(CCS),the thermal shock resistance(TSR),the refractoriness under load(RUL)and the creep rate of the samples were tested.The effects of the firing temperature on the creep rate(1450℃×50 h,under a load of 0.2 MPa)of the samples were studied.The results show that with the sillimanite addition of 22.5 mass%,the sample fired at 1460℃for 4 h performs the best comprehensive properties:the AP of 17.5%,the BD of 2.75 g·cm^(-3),the CCS of 100.5 MPa,the TSR number of 35 cycles,the RUL of 1682℃,and the creep rate of-0.428%,which can prolong the service life of furnaces.展开更多
Global warming has attracted much concern about the worldwide organization, civil society groups, researchers, and so forth because the worldwide surface temperature has been expanding. This investigation intends to a...Global warming has attracted much concern about the worldwide organization, civil society groups, researchers, and so forth because the worldwide surface temperature has been expanding. This investigation intends to assess and compare the ability of a combination of land cover indices to predict the future distribution of land surface temperatures in Freetown using the Polynomial model analysis. Landsat satellite images of 1988, 1998, 2000, 2010, and 2018 of the Freetown Metropolitan zone were utilized for analysis. The investigation had adopted two land covers indices, Modification of normalized difference water index and Urban Index (UI) (e.g., MNDWI and UI) and applied a multi regression equation for forecasting the future LST. The stimulation results propose that the development will be accompanied by surface temperature increases, especially in Freetown’s western urban area. The temperature prevailing in the west of the metropolitan area may increase in the city somewhere in the range </span></span><span><span><span>from</span></span></span><span><span><span> 1988 to 2018. Additionally, the results of the LST prediction show that the model is perfect. Our discoveries can be represented as a helpful device for policymakers and community awareness by giving a scientific basis for sustainable urban planning and management.展开更多
This study investigated the microstructure and hydrogen absorption properties of a rare-earth high-entropy alloy(HEA),YGdTbDyHo.Results indicated that the YGdTbDyHo alloy had a microstructure of equiaxed grains,with t...This study investigated the microstructure and hydrogen absorption properties of a rare-earth high-entropy alloy(HEA),YGdTbDyHo.Results indicated that the YGdTbDyHo alloy had a microstructure of equiaxed grains,with the alloy elements distributed homogeneously.Upon hydrogen absorption,the phase structure of the HEA changed from a solid solution with an hexagonal-close-packed(HCP)structure to a high-entropy hydride with an faced-centered-cubic(FCC)structure without any secondary phase precipitated.The alloy demonstrated a maximum hydrogen storage capacity of 2.33 H/M(hydrogen atom/metal atom)at 723 K,with an enthalpy change(ΔH)of-141.09 kJ·mol^(-1)and an entropy change(ΔS)of-119.14 J·mol^(-1)·K^(-1).The kinetic mechanism of hydrogen absorption was hydride nucleation and growth,with an apparent activation energy(E_(a))of 20.90 kJ·mol^(-1).Without any activation,the YGdTbDyHo alloy could absorb hydrogen quickly(180 s at 923 K)with nearly no incubation period observed.The reason for the obtained value of 2.33 H/M was that the hydrogen atoms occupied both tetrahedral and octahedral interstices.These results demonstrate the potential application of HEAs as a high-capacity hydrogen storage material with a large H/M ratio,which can be used in the deuterium storage field.展开更多
A rational equation of state of the perturbation type with a repulsion and attraction term has been applied to reproduce critical curves of six different binary systems up to high temperatures and pressures. A square ...A rational equation of state of the perturbation type with a repulsion and attraction term has been applied to reproduce critical curves of six different binary systems up to high temperatures and pressures. A square well potential for intermolecular interaction is used. With pairwise combination rules for these potentials three adjustable parameters are needed. The experimental critical point and phase equilibrium data are compared with the values predicted using the equation of state. Good agreement is obtained for the analysis of the critical pressure composition data and molar volumes.展开更多
文摘When soldering electronic components onto circuit boards,the temperature curves of the reflow ovens across different zones and the conveyor belt speed significantly influence the product quality.This study focuses on optimizing the furnace temperature curve under varying settings of reflow oven zone temperatures and conveyor belt speeds.To address this,the research sequentially develops a heat transfer model for reflow soldering,an optimization model for reflow furnace conditions using the differential evolution algorithm,and an evaluation and decision model combining the differential evolution algorithm with the Technique for Order Preference by Similarity to Ideal Solution(TOPSIS)method.This approach aims to determine the optimal furnace temperature curve,zone temperatures of the reflow oven,and the conveyor belt speed.
基金supports provided by Natural Science Foundation of Shanghai(contract No.03ZR14022)the“Tenth Five”National Key Technological Research and Development Program(contract No.2001BA803B03)National Natural Science Foundation of China(contract No.50225517)are gratefully acknowledged.
文摘In this work, a parametric approach is presented and utilized to determine the creep properties of weldments; then the model of creep strain for cross weld specimen is given. On the basis of the experimental results, attempt has been made to establish equations of the isochronous stress-strain for weld joint that can predict the function of loading and service time in use of the creep data of base metal and weld metal.
文摘Initial firing temperatures play an important role on the combustion rate of propellant. In gun propellants, initial temperature is a key factor for both accuracy and safety. Ideally, the initial temperature of the propellant should not influence the ballistic properties of the round. Nevertheless, constant initial temperature coefficients can not be achieved easily. This work focuses on the influence of the firing temperature on the ballistic properties, the mechanical integrity and the sensitivity to impact of nitrocellulose based propellants. Combustion rates have been determined by closed vessel tests. Ballistic properties have been investigated by firing 5.56 cartridges. The propellants have been conditioned at temperatures ranging from -54 ℃ to +71 ℃ before firing. The largest temperature coefficient is observed at high temperatures. The temperature sensitivity of the peak pressure in the combustion chamber can not be fully explained by the results from the closed vessel test. The authors speculated that the mechanical behaviour of the propellant grains at low temperatures influences also the overall ballistic properties of the round. Impact tests with propellants conditioned at low and high temperatures permit to investigate their mechanical strength under extreme temperatures and to better understand the propellant performance during firing. Tests on aged propellants have been conducted as well.
文摘This work studied the effects of firing temperatures on the refractory properties of insulating firebricks produced from a blend of hydrometallurgically purified clay, high alumina cement and sawdust. Twenty grams out of a bulk (1000 Kg) of clay obtained from Ipetumodu in Nigeria was analyzed for size range, consequent upon which the remaining bulk was sieved to 100 μm, being the average size. The bulk was there after leached under a predetermined condition (1.6 mol/dm3 of oxalic acid at 70oC for 150 min and 200 rev/min agitation speed) and cylindrical samples (5 cm diameter by 5 cm high) containing different quantities of high alumina cement (5% - 20%) and sawdust (1% - 5%) were prepared, dried at 110oC and subsequently fired at 900oC, 1100oC, 1300oC and 1500oC, at the rate of 4oC/min and soaked for 2 hrs. These samples were subjected to different refractory tests (permanent linear change, modulus of rupture, bulk density, cold crushing strength and apparent porosity). Even though samples containing more than 20% alumina crumbled at elevated temperatures, it was still observed that the bricks performed to expectations at lower alumina contents, even at 1500oC. The sample containing 3% sawdust and 10% alumina cement however, gave the desired requirement for preparing good insulating firebricks with reliable phase integrity, as revealed by scanning electron microscopy (SEM).
文摘The purpose of this research is to characterize shapes in thermodynamic terms, namely, in terms of total energy, dissipative energy, entropy, and temperature. As case studies, polygons and some well-known curves were taken, and they were characterized using physical terms. The relation between entropy and curvature was elucidated, and the black hole surface gravity and temperature were criticized and reinterpreted from this point of view. Particular energy attributions were evaluated by comparing the position of any edge of a polygon (<em>i</em>.<em>e</em>. its angle with the horizontal axis) with a broken crystal surface. Energies of all edges were added up at all positions between 0<span style="white-space:nowrap;">˚ </span>- 360<span style="white-space:nowrap;">˚</span>. In regular polygons, the total energy decreases with the increase of the number of edges. Entropy increases in the reverse order, and the increase of the number of edges increases entropy. It implies that the circle has the lowest energy but the highest surface entropy. In curves (circle, sine-curve, spiral, and exponential curve), the total energy, dissipative energy, and entropy all depend on amplitude and also on specific variables. Black hole entropy expressed in terms of the surface area is a configurational entropy and not thermal entropy;therefore, it does not involve a varying temperature term. The surface gravity of a black hole is connected to acceleration and thus to curvature. To relate it with the temperature needs to be reinterpreted, because, surface gravity behaves like an attractive force not exactly like temperature. Hawking radiation is still possible, but the black hole does not get warmer as it evaporates. Material loss from the black hole gets faster as its radius decreases due to the curvature effect, <em>i</em>.<em>e</em>. by a mechanism similar to the Gibbs-Thomson effect.
文摘Using purified bovine liver tRNA ̄(Ile) and yeast tRNA ̄(Phe), we studied the effects of spermine on the melting curve and melting temperature(Tm) of the tRNAs. The results showed that the absorbance at 260 nm of tRNAs decreases with the increase of temperature in the presence of 2 mmol/L spermine. We called this phenomenon hypochromism and reverse-Tm of the tRNAs. It is suggested that spermine binds to tRNAs and stabilizes the secondary structure of the tRNAs.
文摘To reduce production costs and make full and reasonable use of raw materials,high alumina bricks were prepared using tabular corundum and mullite as aggregates,sillimanite as intermediate particles,and white fused corundum powder,α-alumina micropowder,and Suzhou soil as the matrix,firing at different temperatures(1420,1440,1460,1480,1500 and 1520℃)for 4 h.The apparent porosity(AP),the bulk density(BD),the cold crushing strength(CCS),the thermal shock resistance(TSR),the refractoriness under load(RUL)and the creep rate of the samples were tested.The effects of the firing temperature on the creep rate(1450℃×50 h,under a load of 0.2 MPa)of the samples were studied.The results show that with the sillimanite addition of 22.5 mass%,the sample fired at 1460℃for 4 h performs the best comprehensive properties:the AP of 17.5%,the BD of 2.75 g·cm^(-3),the CCS of 100.5 MPa,the TSR number of 35 cycles,the RUL of 1682℃,and the creep rate of-0.428%,which can prolong the service life of furnaces.
文摘Global warming has attracted much concern about the worldwide organization, civil society groups, researchers, and so forth because the worldwide surface temperature has been expanding. This investigation intends to assess and compare the ability of a combination of land cover indices to predict the future distribution of land surface temperatures in Freetown using the Polynomial model analysis. Landsat satellite images of 1988, 1998, 2000, 2010, and 2018 of the Freetown Metropolitan zone were utilized for analysis. The investigation had adopted two land covers indices, Modification of normalized difference water index and Urban Index (UI) (e.g., MNDWI and UI) and applied a multi regression equation for forecasting the future LST. The stimulation results propose that the development will be accompanied by surface temperature increases, especially in Freetown’s western urban area. The temperature prevailing in the west of the metropolitan area may increase in the city somewhere in the range </span></span><span><span><span>from</span></span></span><span><span><span> 1988 to 2018. Additionally, the results of the LST prediction show that the model is perfect. Our discoveries can be represented as a helpful device for policymakers and community awareness by giving a scientific basis for sustainable urban planning and management.
基金financially supported by the National Natural Science Foundation of China(Nos.21171018 and 51271021)the State Key Laboratory for Advanced Metals and Materials。
文摘This study investigated the microstructure and hydrogen absorption properties of a rare-earth high-entropy alloy(HEA),YGdTbDyHo.Results indicated that the YGdTbDyHo alloy had a microstructure of equiaxed grains,with the alloy elements distributed homogeneously.Upon hydrogen absorption,the phase structure of the HEA changed from a solid solution with an hexagonal-close-packed(HCP)structure to a high-entropy hydride with an faced-centered-cubic(FCC)structure without any secondary phase precipitated.The alloy demonstrated a maximum hydrogen storage capacity of 2.33 H/M(hydrogen atom/metal atom)at 723 K,with an enthalpy change(ΔH)of-141.09 kJ·mol^(-1)and an entropy change(ΔS)of-119.14 J·mol^(-1)·K^(-1).The kinetic mechanism of hydrogen absorption was hydride nucleation and growth,with an apparent activation energy(E_(a))of 20.90 kJ·mol^(-1).Without any activation,the YGdTbDyHo alloy could absorb hydrogen quickly(180 s at 923 K)with nearly no incubation period observed.The reason for the obtained value of 2.33 H/M was that the hydrogen atoms occupied both tetrahedral and octahedral interstices.These results demonstrate the potential application of HEAs as a high-capacity hydrogen storage material with a large H/M ratio,which can be used in the deuterium storage field.
文摘A rational equation of state of the perturbation type with a repulsion and attraction term has been applied to reproduce critical curves of six different binary systems up to high temperatures and pressures. A square well potential for intermolecular interaction is used. With pairwise combination rules for these potentials three adjustable parameters are needed. The experimental critical point and phase equilibrium data are compared with the values predicted using the equation of state. Good agreement is obtained for the analysis of the critical pressure composition data and molar volumes.