Two simple, rapid, accurate, precise, reliable and economical spectrophotometric methods have been proposed for the determination of galanthamine hydrobromide (GH) in bulk and pharmaceutical formulation. First method ...Two simple, rapid, accurate, precise, reliable and economical spectrophotometric methods have been proposed for the determination of galanthamine hydrobromide (GH) in bulk and pharmaceutical formulation. First method is zero order UV spectrophotometry and second is 1st derivative zero crossing spectrophotometry. The developed methods have shown best results in terms of linearity, accuracy, precision, LOD and LOQ for bulk drugs and marketed formulations. Absorbance was measured at 287 nm for zero order and 277.4 nm for first derivative. It obeyed Lambert-Beer’s law in the range of 30-80 μg mL-1. Both methods have good linearity (r2 = 0.9997) and accuracy found to be 100.5% and 101.2% for both methods respectively.展开更多
UV-Vis spectrum and the third-order nonlinear optical properties of the chiral camphor-derived β-diketonate have been studied at the B3LYP/6-31G＊ level. The results showed that the introduction of electron-drawing g...UV-Vis spectrum and the third-order nonlinear optical properties of the chiral camphor-derived β-diketonate have been studied at the B3LYP/6-31G＊ level. The results showed that the introduction of electron-drawing group -CF3 and -C3F7 on β-diketonate made the strongest absorption peak red-shift and the lowest energy absorption blue-shied. Introduction of -OC2H5 on the benzene or pyridine ring made the lowest energy absorption blue-shift. When the -C2H3 was introduced on the benzene or pyridine ring, the lowest energy absorption was red-shifted. Introduction of electron-donating group on β-diketonate can enlarge their nonlinear optical properties. On the contrary, the introduction of electron-drawing group dropped it down.展开更多
通过田间模拟UV-B辐射增强,并采用FieldSpec Pro FR光谱仪进行田间观测,对UV-B辐射增强20%(U)条件下免耕(Z)和深耕(C)两种耕作方式对冬小麦冠层反射光谱和一阶导数光谱的影响进行研究,试验以无UV-B辐射增强(N)为对照,共设4个处理,分别...通过田间模拟UV-B辐射增强,并采用FieldSpec Pro FR光谱仪进行田间观测,对UV-B辐射增强20%(U)条件下免耕(Z)和深耕(C)两种耕作方式对冬小麦冠层反射光谱和一阶导数光谱的影响进行研究,试验以无UV-B辐射增强(N)为对照,共设4个处理,分别为ZU、ZN、CN、CU。结果表明,冬小麦冠层光谱能有效监测UV-B辐射增强和两种耕作方式的复合作用。各处理间小麦冠层反射光谱的差异主要体现在近红外高台,灌浆期是最佳监测生育期。在灌浆期,U处理导致小麦冠层光谱近红外高台反射率明显降低,Z处理的近红外高台反射率明显低于C处理,且其受U处理的影响小于C处理,表明免耕具有延缓叶片衰老的作用。进一步采用一阶导数光谱分析发现,各处理在开花期和灌浆期均有显著差异。U处理导致红峰高度在灌浆期显著降低。Z处理的红峰高度明显低于C处理,红边位置比C处理偏红,并出现多峰情况。在未来UV-B辐射增强情景下,研究结果可为不同耕作方式下冬小麦采用冠层光谱进行无损检测的可行性提供理论参考。展开更多
文摘Two simple, rapid, accurate, precise, reliable and economical spectrophotometric methods have been proposed for the determination of galanthamine hydrobromide (GH) in bulk and pharmaceutical formulation. First method is zero order UV spectrophotometry and second is 1st derivative zero crossing spectrophotometry. The developed methods have shown best results in terms of linearity, accuracy, precision, LOD and LOQ for bulk drugs and marketed formulations. Absorbance was measured at 287 nm for zero order and 277.4 nm for first derivative. It obeyed Lambert-Beer’s law in the range of 30-80 μg mL-1. Both methods have good linearity (r2 = 0.9997) and accuracy found to be 100.5% and 101.2% for both methods respectively.
基金supported by the National Natural Science Foundation of China(21172161)
文摘UV-Vis spectrum and the third-order nonlinear optical properties of the chiral camphor-derived β-diketonate have been studied at the B3LYP/6-31G＊ level. The results showed that the introduction of electron-drawing group -CF3 and -C3F7 on β-diketonate made the strongest absorption peak red-shift and the lowest energy absorption blue-shied. Introduction of -OC2H5 on the benzene or pyridine ring made the lowest energy absorption blue-shift. When the -C2H3 was introduced on the benzene or pyridine ring, the lowest energy absorption was red-shifted. Introduction of electron-donating group on β-diketonate can enlarge their nonlinear optical properties. On the contrary, the introduction of electron-drawing group dropped it down.
文摘通过田间模拟UV-B辐射增强,并采用FieldSpec Pro FR光谱仪进行田间观测,对UV-B辐射增强20%(U)条件下免耕(Z)和深耕(C)两种耕作方式对冬小麦冠层反射光谱和一阶导数光谱的影响进行研究,试验以无UV-B辐射增强(N)为对照,共设4个处理,分别为ZU、ZN、CN、CU。结果表明,冬小麦冠层光谱能有效监测UV-B辐射增强和两种耕作方式的复合作用。各处理间小麦冠层反射光谱的差异主要体现在近红外高台,灌浆期是最佳监测生育期。在灌浆期,U处理导致小麦冠层光谱近红外高台反射率明显降低,Z处理的近红外高台反射率明显低于C处理,且其受U处理的影响小于C处理,表明免耕具有延缓叶片衰老的作用。进一步采用一阶导数光谱分析发现,各处理在开花期和灌浆期均有显著差异。U处理导致红峰高度在灌浆期显著降低。Z处理的红峰高度明显低于C处理,红边位置比C处理偏红,并出现多峰情况。在未来UV-B辐射增强情景下,研究结果可为不同耕作方式下冬小麦采用冠层光谱进行无损检测的可行性提供理论参考。
