The Condensation of Aromatic Aldehydes with Acidic Methylene Compounds in Water

The condensation of aromatic aldehydes with acidic methylene compounds such as malononitrile, methyl cyanoacetate, cyanoacetamide, 5,5-dimethyl-1,3-cyclohexanedione, bartbituric acid and 2-thiobarbituric acid proceeded very efficiently in water in the presence of triethylbenzylammonium chloride (TEBA) and the products were isolated simply by filtration.

Transient Heat Transfer Study of Direct Contact Condensation of Steam in Spray Cooling Water

We conducted a transient experimental investigation of steam–water direct contact condensation in the absence of noncondensible gas in a laboratory-scale column with the inner diameter of 325 mm and the height of 1045 mm. We applied a new analysis method for the steam state equation to analyze the molar quantity change in steam over the course of the experiment and determined the transient steam variation. We also investigated the influence of flow rates and temperatures ofcooling water on the efficiency ofsteam condensation. Our experimental results show that appropriate increasing of the cooling water flow rate can significantly accelerate the steam condensation. We achieved a rapid increase in the total volumetric heat transfer coefficient by increasing the flow rate of cooling water, which indicated a higher thermal convection between the steam and the cooling water with higher flow rates. We found that the temperature ofcooling water did not play an important role on steam condensation. This method was confirmed to be effective for rapid recovering ofsteam.

Performance Analysis of Automated Control System for Condenser Water Treatment Unit

The air conditioning system in the Umm Al-Qura University (Albdiya Campus) was conceived to be a district cooling by a remote chilled water plant. Recently, there are two chilled water plants in the university installed strategically to provide chilled water to all the academic and administrative buildings of the university through distribution network with total capacity approximately of 12,000 tons of refrigeration. The plants were built based on cooling towers with open water cycle as heat rejection system. Water treatment chemicals has been used to protect the cooling systems from corrosion, scaling and microbiological fouling accompanied with dissolved and suspended water impurities. Different methods are being used to determine and control the treatment chemical concentrations and system performance indicators. Traditional chemical controller has drawback of indirect measurements and set points. The purpose of this paper is to present a solution to overcome the problems of traditional and conventional chemical treatment and control sys-tems. Central cooling plant number (1) assigned to perform experimental setup using new chemical treatment technology. Advanced automatic chemical treatment controller installed on condensers (1, 2 and 3), and certain key performance indicators were selected and monitored such as chemical and water consumption, power, energy saving, and maintaining system integrity and efficiency. Satisfactory results were obtained in terms of performance and cost of operation.

Enhancement of freshwater production of the seawater greenhouse condenser

Seawater greenhouse(SWGH)is a technology established to overcome issues related to open field cultivation in arid areas,such as the high ambient temperature and the shortage of freshwater.It adopts the humidification-dehumidification concept where evaporated moisture from a saline water source is condensed to produce freshwater within the greenhouse body.Various condenser designs are adopted to increase freshwater production in order to meet the irrigation demand.The aim of this study was to experimentally investigate the practicality of using the packed-type direct contact condenser in the SWGH to produce more freshwater at low costs,simple design and high efficiency,and to explore the impact of the manipulating six operational variables(inlet air temperature of the humidifier,air mass flowrate of the humidifier,inlet water temperature of the humidifier,water mass flowrate of the humidifier,inlet water temperature of the dehumidifier and water mass flowrate of the dehumidifier)on freshwater condensation rate.For this purpose,a direct contact condenser was designed and manufactured.Sixty-four full factorial experiments were conducted to study the effect of the six operational variables.Each variable was operated at two levels(high and low flowrate),and each experiment lasted for 10 min and followed by a 30-min waiting time.Results showed that freshwater production varied between 0.257 and 2.590 L for every 10 min.When using Minitab statistical software to investigate the significant variables that contributed to the maximum freshwater production,it was found that the inlet air temperature of the humidifier had the greatest influence,followed by the inlet water temperature of the humidifier;the former had a negative impact while the latter had a positive impact on freshwater production.The response optimizer tool revealed that the optimal combination of variables contributed to maximize freshwater production when all variables were in the high mode and the inlet air temperature of the humidifier was in the low mode.The comparison between the old plastic condenser and the new proposed direct contact condenser showed that the latter can produce 75.9 times more freshwater at the same condenser volume.

Impact of formation water on the generation of H2S in condensate reservoirs： a case study from the deep Ordovician in the Tazhong Uplift of the Tarim Basin, NW China

A number of condensate reservoirs with high concentrations of H2S have been discovered in the deep dolomite reservoirs of the lower Ordovician Yingshan Formation（O1y） in the Tazhong Uplift, where the formation water has a high p H value. In the O1y reservoir, the concentrations of Mg^2＋ and SO4^2-in the formation water are higher than those in the upper Ordovician formation.The concentration of H2 S in the condensate reservoirs and the concentration of Mg^2＋in the formation water correlate well in the O1y reservoirs of the Tazhong Uplift, which indicates a presumed thermochemical sulfate reduction（TSR） origin of H2S according to the oxidation theory of contact ion-pairs（CIPs）. Besides, the p H values of the formation water are positively correlated with the concentration of H2S in the condensate reservoirs, which may indicate that high p H might be another factor to promote and maintain TSR. Oil–source correlation of biomarkers in the sulfuretted condensates indicates the Cambrian source rocks could be the origin of condensates. The formation water in the condensate reservoirs of O1y is similar to that in the Cambrian; therefore, the TSR of sulfate-CIPs likelyoccurred in the Cambrian. High H2S-bearing condensates are mainly located near the No. 1 Fault and NE-SW strikeslip faults, which are the major migration pathway of deep fluids in the Tazhong Uplift. The redox between sulfateCIPs and hydrocarbons is the generation mechanism of H2S in the deep dolomite condensate reservoirs of the Tazhong Uplift. This finding should be helpful to predict the fluid properties of deep dolomite reservoirs.

Quality Testing of Air Conditioner Condensate and Its Potential in Water Conservation

A major part of world is facing water shortages today. While the world’s population has grown to more than 7.75 billion, the quantity of sweet water has remained the same. The ever increasing use of water by such a large population has resulted in pollution of many water sources. The developing world where a large fraction of total world population is located faces water scarcity in a more severe manner than the developed world. The developed world has managed to control human population and preserve natural water resources more effectively. As a result of this and also due to stabilized population, they face lesser problems for water availability. Indian population stands at 1.386 billion as nowadays. The erratic monsoon rains over last few years have resulted in floods and subsequent water shortages in summer months in major part of the country. A similar situation is faced by many Asian and African countries. The means of recycling and using every possible source of water are always welcome in these countries. Since many of these countries lie in tropical or semitropical zone, the average relative humidity is more than 50% for most of the year. Changing life styles in these countries and spread of information technology based sectors have resulted in a growth spurt in air conditioning facilities. An air conditioner draws heat from surrounding air and cools the premises to desired temperature. During this process, a large amount of moisture in the atmosphere gets condensed and is drained out. There are no efforts made to recover this water in India and neighbouring countries. We have undertaken studies to check the quality of this water and see the feasibility of its use in a decentralized but effective manner. The results show that this water condensate from air conditioners is highly pure, substantial and available almost round the year. This can help in recovering millions of litres of good quality water daily. This water would find uses in industries, laboratories, households and farming. It would also create good business opportunities.

A review on eco-hydrological effects of condensation water

Almost half the world is suffering from drought at different levels. Since arid and semi-arid regions are characterized by extreme shortage and precipitation uncertainty, water availability is the most impo~.nt limiting factor in arid lands, and any additional source of moisture, such as condensation water, may have a positive impact upon the ecosystem. Therefore, extensive research has been carried out on condensation. Based on articles and relevant documents on the subject, this paper reviews systemati- cally and comprehensively the latest research achievements in several main aspects, including eco-hydrological effects of condensation water on plants, small animals, microbiotic crusts, soil moisture balance, ground water recharge and anthropo- genic utilization. History and trends of research about eco-hydrological effects of condensation water are intensively analyzed in order to summarize existing problems and offer opinions and suggestions for future study.

SYNTHESIS OF SPHERICAL MACROPOROUS ADSORBENT BASED ON UREA-FORMALDEHYDE CONDENSED POLYMER

Spherical macroporous adsorbents with active sites capable of hydrogen bonding adsorption based on urea-formaldehyde condensed polymer were synthesized via reversed suspension polymerization. The properties of the obtained adsorbent were also investigated in detail. The results showed that the water permeability could be improved by adding hydroxyl-containing organic compound moiety into the adsorbent. The specific surface area and average pore diameter of these adsorbents increased while the porosity first increased then decreased with the increase of the amount of the added hydroxyl-containing compound.

A New Method for the Dynamic Reserves of Gas Condensate Reservoir Using Cyclic Gas Injection Based on the Effects of Reinjection Ratio and Water Influx

As we all know, cyclic gas injection is one of the most effective development methods to improve condensate oil recovery. When dealing with the calculation of the reserves, the injection-production differences and water influx create great influence on the accuracy. Based on the existing research, we proposed a new material balance equation which considered the differences of composition between produced and injected fluids and the effect of water influx, and a solution was provided in this paper. The results of the method are closer to the actual situation because they are built on the law of conservation of mass, and the using of curve fitting method can not only avoid the use of water influx coefficient but also obtain the water influx rate and reserves at the same time. The YH-23 gas condensate reservoir is taking as a typical subject to do the research, which has been exploited by cycle gas injection for 14 years. Three different methods are used to calculate the reserves, and the results show that the method proposed in this paper has minimum error of 2.96%.

Condensation of Water Steam with and without Chemical Impurity in a Nozzle

A nucleation of two types can occur in the water steam flowing in a nozzle or in a turbine： homogeneous （spontaneous） and heterogeneous. The effects of chemistry on the flowing steam nucleation and condensation are not quite explained. An approach is used in the paper which is based on binary nucleation of main impurity NaC1 and water. Physical and mathematical models are described and are applied on the steam flow with condensation in convergent-divergent nozzle. Binary nucleation numerical model is applied for the calculation of the flow with condensation in the nozzle with low expansion rate in divergent nozzle part ^- = 1,000 s^-1. Calculation results of pressure distribution are compared with experiments. The agreement between calculations and experiments is very good. The homogeneous nucleation and condensation of pure water steam in the same nozzle is also calculated. The results are discussed. Main features of the binary nucleation and condensation of water and NaCI and of the homogeneous nucleation of pure water are compared.

Towards high-performance and robust anion exchange membranes(AEMs)for water electrolysis:Super-acid-catalyzed synthesis of AEMs

The increasing demand for hydrogen energy to address environmental issues and achieve carbon neutrality has elevated interest in green hydrogen production,which does not rely on fossil fuels.Among various hydrogen production technologies,anion exchange membrane water electrolyzer(AEMWE)has emerged as a next-generation technology known for its high hydrogen production efficiency and its ability to use non-metal catalysts.However,this technology faces significant challenges,particularly in terms of the membrane durability and low ionic conductivity.To address these challenges,research efforts have focused on developing membranes with a new backbone structure and anion exchange groups to enhance durability and ionic conductivity.Notably,the super-acid-catalyzed condensation(SACC)synthesis method stands out due to its user convenience,the ability to create high molecular weight(MW)polymers,and the use of oxygen-tolerant organic catalysts.Although the synthesis of anion exchange membranes(AEMs)using the SACC method began in 2015,and despite growing interest in this synthesis approach,there remains a scarcity of review papers focusing on AEMs synthesized using the SACC method.The review covers the basics of SACC synthesis,presents various polymers synthesized using this method,and summarizes the development of these polymers,particularly their building blocks including aryl,ketone,and anion exchange groups.We systematically describe the effects of changes in the molecular structure of each polymer component,conducted by various research groups,on the mechanical properties,conductivity,and operational stability of the membrane.This review will provide insights into the development of AEMs with superior performance and operational stability suitable for water electrolysis applications.

Practice and analysis of recycling non-drinking water from air-condition and reverse-osmosis system into rainwater collection system

This paper is based on the rainwater collection project in the retrofit of the Dongyi teaching block in Zhejiang University Xixi Campus.The analysis incorporates the local meteorological data, recycling water utilization, and precipitation adjustment.The rainwater collection system in this program also adds the condensation water from the heating, ventilation and air conditioning （ HVAC） system and the concentration from the reverse-osmosis system used for watering greens and supplying waterscapes.By calculating, the quantity of the HVAC condensation water in summer is 3.48 m3/d, and the quantity of the reverse-osmosis concentrated water is 198 to 396 L/d.This method solves the water shortage caused by high evaporation in summer and low precipitation in winter.Supported by empirical monitoring data, the proposed method significantly increases the economic efficiency of the system during the summer period.

Re-Examination of the Oil and Gas Origins in the Kekeya Gas Condensate Field,Northwest China——A Case Study of Hydrocarbon-Source Correlation Using Sophisticated Geochemical Methods

This work discussed the origins, alteration and accumulation processes of the oil and gas in the Kekeya gas condensate field based on molecular compositions, stable carbon isotopes, light hydrocarbons, diamondoid hydrocarbons and biomarker fingerprints. A comparison study is also made between the geochemical characteristics of the Kekeya hydrocarbons and typical marine and terrigenous hydrocarbons of the Tarim Basin. Natural gas from the Kekeya gas condensate field is derived from Middle–Lower Jurassic coal measures while the condensates are derived from Carboniferous–Permian marine source rocks with a higher maturity. In the study area, both natural gas and condensates have experienced severe water washing. A large amount of methane was dissolved into the water, resulting in a decrease in the dryness coefficient. Water washing also makes the carbon isotopic compositions of the natural gas more negative and partially reverse. Considering that the gas maturities are higher than once expected, gas generation intensity in the study area should be much stronger and the gas related to the Jurassic coal measures could promise a greater prospecting potential. As a result of evaporative fractionation, the Kekeya condensates are enriched in saturates and lack aromatics. Evaporative fractionation disguises the original terrigenous characteristics of the light hydrocarbons associated with the natural gas, making it appear marinesourced. Thus, alteration processes should be fully taken into consideration when gas–source correlations are carried out based on light hydrocarbons. With the condensates discovered in the study area all being ＂migration phase＂, the pre-salt Cretaceous and Jurassic reservoirs may promise great exploration potential for the ＂residual phase＂ hydrocarbons. This research not only is of significance for oil and gas exploration in the southwest Tarim Basin, but also sheds light on the oil/gas-source correlations in general.

Performance Evaluation of Heat Exchangers in OTEC Using Ammonia/Water Mixture as Working Fluid

The ocean thermal energy conversion (OTEC) system is a promising solution to provide stable electricity supply. Although the available temperature difference in OTEC systems is small, an ammonia/water mixture as working fluid is expected to decrease irreversible losses in the heat exchangers and to improve system performance. However, in actual heat exchangers, an adequate temperature crossing does not occur in the condenser but in the evaporator. Therefore, clarification of this characteristic is important. To date, the logarithmic temperature difference (LMTD) method is used in performance evaluations of OTEC heat exchangers. This method is of limited use if physical properties of fluids vary. A generalized mean temperature difference (GMTD) method is introduced to perform this evaluation. As changes in fluid property values can be considered in the GMTD method, method dependencies on heat exchanger characteristics, effectiveness, and system characteristics can be studied. In particular, GMTD and LMTD using a pure substance were found to be almost equal. Mean temperature differences using mixtures as working fluid were higher in the evaporator, but lower in the condenser, from the GMTD method than from the LMTD method. For higher ammonia concentrations in ammonia/water mixtures, the mean temperature differences from both methods are different.

Condensate Polishing System for PWR Nuclear Power Plant

In this paper, operation characteristic of condensate polishing system is studied during startup, based on generator blowdown limit, given limit ion concentration in condensate during condenser leakage. Further give conclusion about condensate polishing system configuration and operation requirement： full flow condensate polishing system （CPS） is necessary to the units cooled by sea water, and it is better that one or two series put in service during normal operation other than all of them in hot standby. While continuous condensate tube leakage is 256 L/h, the units cooled by fresh water will be shutdown immediately, for this level leakage, whichever condensate polishing system capacity is 50% （30%） or 100%, action level 2 will be preformed, so 50% （30%） is enough for fresh water cooled units.

Forests,atmospheric water and an uncertain future: the new biology of the global water cycle

Theory and evidence indicate that trees and other vegetation influence the atmospheric water-cycle in various ways.These influences are more important, more complex, and more poorly characterised than is widely realised.While there is little doubt that changes in tree cover will impact the water-cycle, the wider consequences remain difficult to predict as the underlying relationships and processes remain poorly characterised. Nonetheless, as forests are vulnerable to human activities, these linked aspects of the water-cycle are also at risk and the potential consequences of large scale forest loss are severe. Here, for non-specialist readers, I review our knowledge of the links between vegetation-cover and climate with a focus on forests and rain(precipitation). I highlight advances, uncertainties and research opportunities. There are significant shortcomings in our understanding of the atmospheric hydrological cycle and of its representation in climate models. A better understanding of the role of vegetation and tree-cover wil reduce some of these shortcomings. I outline and il ustrate various research themes where these advances may be found.These themes include the biology of evaporation, aerosols and atmospheric motion, as well as the processes that determine monsoons and diurnal precipitation cycles. A novel theory—the ‘biotic pump’—suggests that evaporation and condensation can exert a major influence over atmospheric dynamics. This theory explains how high rainfall can be maintained within those continental land-masses that are sufficiently forested. Feedbacks within many of these processes can result in non-linear behaviours and the potential for dramatic changes as a result of forest loss(or gain): for example, switching from a wet to a dry local climate(or visa-versa). Much remains unknown and multiple research disciplines are needed to address this: forest scientists and other biologists have a major role to play.New ideas, methods and data offer opportunities to improve understanding. Expect surprises.

Measurement Methodology for Monitoring Fouling Resistance in Condenser of Chiller

This paper established an on-line monitoring model for fouling resistance of cooling water based on heat transfer theory,which was mainly applied to the fouling resistance test for condenser of chiller in operation,and the test requirements were presented.It proves that the load ratio of chiller has big influence on the test result,and the best load ratio for test is the range of 80%～100%.A case has been executed to validate the model's feasibility.

Effects of water and ice clouds on cloud microphysical budget:An equilibrium modeling study

The effects of water and ice clouds on the cloud microphysical budget associated with rainfall are investigated through the analysis of grid-scale data from a series of two-dimensional cloud-resolving model equilibrium sensitivity simulations. The model is imposed without large-scale vertical velocity. In the control experiment, the contribution from rainfall （cM） associated with net evaporation and hydrometeor loss/convergence is about 29% of that from the rainfall （Cm） associated with net condensation and hydrometeor gain/divergence and about 39% of that from the rainfall （CM） associated with net condensation and hydrometeor loss/convergence. The exclusion of ice clouds enhances rainfall contribution of CM, whereas it reduces rainfall contributions of Cm and cM. The removal of radiative effects of water clouds increases rainfall contribution of CM, barely changes rainfall contribution of Cm and reduces the rainfall contribution of cM in the presence of the radiative effects of ice clouds. Elimination of the radiative effects of water clouds reduces the rainfall contributions of CM and Cm, whereas it increases the rainfall contribution of cM in the absence of the radiative effects of ice clouds.

The Degradation and Pollution of Soils on the Territory of the Kovykta Gas Condensate Field

In this paper, research results from the time interval 2002-2012 are used to give an account of the chemical composition of soils on the territory of the Kovykta gas condensate field. The findings presented provide a better understanding of the ecological state of soil cover, its resilience to anthropogenic impacts, and its possible disturbance caused by the drilling pad construction activity, and by the laying of geophysical profiles. An analysis of soil pollution for the study territory generally showed that the soils are polluted with chemical elements which refer to toxicity classes： Pb, Cu, Ni, Cr, Ba and Mn. High levels ofoil products were detected near boreholes. Strong mineralization was recorded in the soil near borehole. It has a chloride-sodium chemical composition. As a result of the construction of foundation pits, recesses, ditches and earth embankments, the soil is totally destroyed, and rock outcrops show up. Disturbances of the sod cover due to road construction or even by all-terrain vehicles in these extreme conditions entail an accelerated development of linear erosion to form scours and gullies. Elimination of the canopy layer leads to an increase in surface heating, and to an acceleration of permafrost thawing. Swamping is accelerated on negative relief forms due to the increased entry of melt waters.

克拉美丽火山岩凝析气藏产水规律及产水模式

克拉美丽火山岩凝析气藏资源丰富,但由于储层岩相多变,裂缝发育,边底水活跃,导致气井在开发过程中产水普遍。准确识别气井水侵规律、产水特征及产水模式,对于气藏新区开发及老区调整具有重要的参考价值。通过对克拉美丽典型气藏地质及开发资料进行综合分析,结果表明,常规的适用于裂缝型产水气藏水侵识别方法存在一定局限性,结合数值模拟技术更有利于认清产水规律;气藏水侵及产水特征曲线显示主要产水来源为边底水,严重影响气井产能;数值模拟研究结果将气井产水模式分为5类,通过统计分析将研究区典型气藏98口气井实际产水曲线定性划分为5类,得到模拟曲线与实际生产曲线分类结果基本吻合。基于数值模拟的产水模式划分结果可靠程度高,该研究结果为火山岩凝析气藏气井的部署开发与实时调控提供借鉴。