Subei-Huainan in the southeastern margin of the North China platform is a key area of convergence of China’s north-south stratigraphic correlation of Neoproterozoic.Due to the lack of fossils,the Neoproterozoic strat...Subei-Huainan in the southeastern margin of the North China platform is a key area of convergence of China’s north-south stratigraphic correlation of Neoproterozoic.Due to the lack of fossils,the Neoproterozoic stratigraphic correlation is still a difficulty in this area.The division of Neoproterozoic strata and the establishment of the correlation framework of the stratigraphic sequences have been done through recognizing the regularity of meter-scale cycles by measuring the outcrop of Neoproterozoic strata and using the Fischer diagram and the sea-level curve of transgressive-regressive by the maximum flooding sedimentary and molar teeth carbonate sedimentary.The maximum flooding sedimentary which becomes cycle sequence comparison of sign is isochronous in the same basin and is a key of cycle sequence comparison although paleogeographic environment and sedimentary sequence may be different in the sedimentary strata of the same geologic time.Molars carbonates,having specific geological distrution time and depositional environment and mainly developing in the ramp environment of the platform edge in the 1500-650 Ma,are the new symbol of the stratigraphic correlation in the Neoproterozoic.Because of the missing of the fossil record,the maximum flooding and the molar-teeth carbonate sedimentary,as the new research ideas,are used in stratigraphic division and correlation.展开更多
合成了4,4'-二甲氧基二苯基氮氧自由基(DMDPN)和相应的烷氧基胺引发剂,用于甲基丙烯酸甲酯(MMA)的氮氧自由基调控聚合,研究了聚合过程中的动力学机理.通过电子自旋共振(ESR)表征,测定了DMDPN型烷氧基胺引发剂在100~120?C范围内的解...合成了4,4'-二甲氧基二苯基氮氧自由基(DMDPN)和相应的烷氧基胺引发剂,用于甲基丙烯酸甲酯(MMA)的氮氧自由基调控聚合,研究了聚合过程中的动力学机理.通过电子自旋共振(ESR)表征,测定了DMDPN型烷氧基胺引发剂在100~120?C范围内的解离速率常数kd0,结果表明kd0符合阿伦尼乌斯公式(k=Ae-Ea/RT),其活化能Ea为135.2 k J·mol-1,指前因子A为3×1014.测定了末端官能团化聚合物PMMA-DMDPN的解离速率常数kd,由于DMDPN中胺氧基团周围的空间位阻较小,受到前末端效应的影响较弱,kd仅为kd0的6倍.采用间接法测定了110?C时增长自由基和DMDPN的结合速率常数kc,并绘制了该温度下MMA/DMDPN聚合体系的Fischer相图,结果表明该聚合体系对应的kd和kc值处于相图的可控/"活性"区域内.展开更多
基金Project(XN2014119) supported by Northeast Petroleum University Cultivation Foundation of ChinaProject(U1262106) supported by the National Natural Science Joint Foundation of China
文摘Subei-Huainan in the southeastern margin of the North China platform is a key area of convergence of China’s north-south stratigraphic correlation of Neoproterozoic.Due to the lack of fossils,the Neoproterozoic stratigraphic correlation is still a difficulty in this area.The division of Neoproterozoic strata and the establishment of the correlation framework of the stratigraphic sequences have been done through recognizing the regularity of meter-scale cycles by measuring the outcrop of Neoproterozoic strata and using the Fischer diagram and the sea-level curve of transgressive-regressive by the maximum flooding sedimentary and molar teeth carbonate sedimentary.The maximum flooding sedimentary which becomes cycle sequence comparison of sign is isochronous in the same basin and is a key of cycle sequence comparison although paleogeographic environment and sedimentary sequence may be different in the sedimentary strata of the same geologic time.Molars carbonates,having specific geological distrution time and depositional environment and mainly developing in the ramp environment of the platform edge in the 1500-650 Ma,are the new symbol of the stratigraphic correlation in the Neoproterozoic.Because of the missing of the fossil record,the maximum flooding and the molar-teeth carbonate sedimentary,as the new research ideas,are used in stratigraphic division and correlation.
文摘合成了4,4'-二甲氧基二苯基氮氧自由基(DMDPN)和相应的烷氧基胺引发剂,用于甲基丙烯酸甲酯(MMA)的氮氧自由基调控聚合,研究了聚合过程中的动力学机理.通过电子自旋共振(ESR)表征,测定了DMDPN型烷氧基胺引发剂在100~120?C范围内的解离速率常数kd0,结果表明kd0符合阿伦尼乌斯公式(k=Ae-Ea/RT),其活化能Ea为135.2 k J·mol-1,指前因子A为3×1014.测定了末端官能团化聚合物PMMA-DMDPN的解离速率常数kd,由于DMDPN中胺氧基团周围的空间位阻较小,受到前末端效应的影响较弱,kd仅为kd0的6倍.采用间接法测定了110?C时增长自由基和DMDPN的结合速率常数kc,并绘制了该温度下MMA/DMDPN聚合体系的Fischer相图,结果表明该聚合体系对应的kd和kc值处于相图的可控/"活性"区域内.
