Diesel and Jet Fuels from Bitumen-derived Middle Distillates

Narrow fractions of light gas oils obtained from various upgrading processes of Athabasca oilsands bitumen were investigated as diesel and jet fuels. The relationship among the boiling range, cetane number, smoke point, and other properties such as aromatics content, aniline point, and the sulfur and nitrogen content was also studied. The study reveals that when appropriate processes and distillation boiling ranges are selected, oilsands bitumen can produce diesel and jet fuels that meet stringent environmental regulations and future product specifications. New correlations to predict CN and smoke point were developed as a function of density, boiling ranges by simulated distillation, and mono- and total aromatics by supercritical fluid chromatography. The correlations apply to bitumen-derived middle distillates that have a wide range of boiling points.

Desulfurization of Diesel Fuel by Extraction with [BF4]^--based Ionic Liquids

The extractive removal of sulfur compounds （S-compounds） from Dongying and Liaohe diesel fuels with [BF4]^--based ionic liquids were systematically investigated. The results show that the absorption capacity of an ionic liquid for the S-compounds in diesel fuels relies on its structure and its size. In the case of the two examined diesel fuels, both elongating the cation tail length and increasing the mass ratio of ionic liquid/diesel fuel promote the desulfurization ability of the examined ionic liquids. The results also show that imidazolium-based ionic liquids display higher extraction efficiencies than pyridinium-based ionic liquids, presumably owing to the fact that the rings of the S-compounds are similar to the imidazolium head ring. With the 1 ： 1 mass ratio of ionic liquid/diesel fuel, the rates of the first desulfurization of Dongying and Liaohe diesel fuels using [C8mim][BF4] amount to 29.96% and 39.76%, suggesting that [C8mim][BF4] is a promising extractant for desulfurization of these diesel fuels.

Combination of biodiesel-ethanol-diesel fuel blend and SCR catalyst assembly to reduce emissions from a heavy-duty diesel engine

In this study, the efforts to reduce NOx and particulate matter （PM） emissions from a diesel engine using both ethanol-selective catalytic reduction （SCR） of NOx over an Ag/Al2O3 catalyst and a biodiesel-ethanol-diesel fuel blend （BE-diesel） on an engine bench test are discussed. Compared with diesel fuel, use of BE-diesel increased PM emissions by 14% due to the increase in the soluble organic fraction （SOF） of PM, but it greatly reduced the Bosch smoke number by 60%-80% according to the results from 13-mode test of European Stationary Cycle （ESC） test. The SCR catalyst was effective in NOx reduction by ethanol, and the NOx conversion was approximately 73%. Total hydrocarbons （THC） and CO emissions increased significantly during the SCR of NOx process. Two diesel oxidation catalyst （DOC） assemblies were used after Ag/Al2O3 converter to remove CO and HC. Different oxidation catalyst showed opposite effect on PM emission. The PM composition analysis revealed that the net effect of oxidation catalyst on total PM was an integrative effect on SOF reduction and sulfate formation of PM. The engine bench test results indicated that the combination of BE-diesel and a SCR catalyst assembly could provide benefits for NOx and PM emissions control even without using diesel particle filters （DPFs）.

Performance Characteristics of n-Butanol-Diesel Fuel Blend Fired in a Turbo-Charged Compression Ignition Engine

In this study, n-butanol-diesel blends were burned in a turbo-charged, direct injection diesel engine where the brake thermal efficiency, (BTE) or brake specific fuel consumption, (BSFC) was compared with that of ethanol-diesel or methanol-diesel blends in another study by other authors. The test blends used were B5, B10 and B20 (where B5 is 5% n-butanol by volume and 95% diesel fuel-DF). In this study, the BTE was higher and the BSFC improved more than in the other study. Because of improved BTE with increasing brake mean effective pressure, BMEP, the BSFC reduced, however the increased shared volume of n-butanol in DF increased BSFC. Adding n-butanol in DF slightly derated the torque, brake power output with increasing speed, and caused a fall in exhaust gas temperatures, (EGT) which improves the volumetric efficiency and reduces compression work. Therefore, a small-shared volume of n-butanol in DF fired in a turbo-charged diesel engine performs better in terms of BTE and BSFC than that of ethanol or methanol blending in DF.

Medium-Pressure Hydro-upgrading (MHUG) Technology for Producing Clean Diesel Fuel

Abstract： This article introduces the development and application of the medium-pressure hydro-upgrading （MHUG） tech- nology developed by the Research Institute of Petroleum Processing （RIPP）. The MHUG technology based on the chemistry of diesel hydro-upgrading reactions has the advantages of flexible product slate and excellent product quality that can in- crease the cetane rating of diesel fuel up to more than 15 units. The hydrotreating and hydro-upgrading catalysts associated with the MHUG technology have outstanding performance to meet the demand of MHUG technology for hydro-saturation and selective ring-opening of aromatic rings. New MHUG process flow scheme can further increase the yield and selectivity of target products. Commercial application of multiple MHUG units has revealed that the MHUG technology designated for clean diesel production features good feedstock adaptability and operating stability.

Influence of Pre-injection Control Parameters on Main-injection Fuel Quantity for an Electronically Controlled Double-valve Fuel Injection System of Diesel Engine

A simulation model of an electronically controlled two solenoid valve fuel injection system for a diesel engine is established in the AMESim environment.The accuracy of the model is validated through comparison with experimental data.The influence of pre-injection control parameters on main-injection quantity under different control modes is analyzed.In the spill control valve mode,main-injection fuel quantity decreases gradually and then reaches a stable level because of the increase in multi-injection dwell time.In the needle control valve mode,main-injection fuel quantity increases with rising multi-injection dwell time;this effect becomes more obvious at high-speed revolutions and large main-injection pulse widths.Pre-injection pulse width has no obvious influence on main-injection quantity under the two control modes;the variation in main-injection quantity is in the range of 1 mm3.

MECHANISM ON DISTRIBUTION OF PILOT FUEL SPRAY AND COMPRESSING IGNITION IN PREMIXED NATURAL GAS ENGINE IGNITED BY PILOT DIESEL

Numerical simulations of pilot fuel spray and compressing ignition forpre-mixed natural gas ignited by pilot diesel are described. By means of these modeling, the dualfuel and diesel fuel ignition mechanism of some phenomena investigated on an optional engine bytechnology of high-speed CCD is analyzed. It is demonstrated that the longer delay of ignition indual fuel engine is not mainly caused by change of the mixture thermodynamics parameters. Theanalysis results illustrate that the ignition of pre-mixed nataral gas ignited by pilot dieseltaking place in dual fuel engine is a process of homogenous charge compression ignition.

Alternative Diesel Grade Fuel Transformed from Polypropylene (PP) Municipal Waste Plastic Using Thermal Cracking with Fractional Column Distillation

Day by day worldwide use of plastics is increasing because of their light weight and durable characteristics. Waste plastics are major environmental problems all over the world. Waste plastics are not bio-degradable, it remains in the landfill for a long period of time causing vegetation and aquatic ecosystem dilemmas. Abandoned waste plastic thrown into the ocean causes friction of ocean waves and then broken down by sunlight into small pieces and takes the shape of plastic like soup. Aquatic organism mistakes the plastic soup as their food and can’t digest, either they die or through food chain it affects human health. To avoid severe environmental degradation problems of waste plastics some countries and big cities banned or restricted the use of plastic products. The worldwide generation of waste plastics is approximately 280 million tons/year. All most all of these waste plastics are dumped either in land or ocean. City municipalities spend huge amount of money each year just to dispose of these waste plastics into landfill because most waste plastics are not recycled. When the waste plastics are subjected to incineration, they release harmful toxic gas into the environment causing severe pollution. These waste plastics gradually enhance the hazardous environmental problems. Generally plastics are made from crude oil, however crude oil is a very limited natural resource and non-renewable. Every year millions of barrels of crude oil are to produce the waste plastics and when plastics are discarded after use the energy source is lost. A new developed technology plan minimizes the environment pollution problems simultaneously boost up energy sector by renovating the waste plastics into high energy content fuel. The produced fuel is obtained using a unique thermal degradation of waste plastics and converting them into hydrocarbon fuel like materials. Preliminary tests proved that this fuel burns cleaner and the production cost is very low. Unique production setup demonstrated to produce 93% fuel from waste plastic in the pilot scale. The Fuel produced has been tested and proven to work on majority types of internal combustion engines. This technology utilized can avoid waste plastic pollution problem worldwide by the implementation of newly developed technology. Through the utilization of the technology the use of reliable plastics won’t need to be banned and serve as a very reliable alternate source of energy. The technology will also help reduce a significant amount of import oil from foreign countries and help provide a steady economy.

A Fuel Economy Study in Heavy Duty Diesel Engine Lubricants

Internal combustion engines′ fuel economy is an important role for engine designers,engine manufacturers over the past 30 years,especially passenger car motor oils.In heavy duty diesel engine,over the past 20 years,fuel economy has in some cases been sacrificed for exhaust gas emission optimizations.Now,Heavy Duty Automotive and the related industries have strong interest in fuel economy and the lubricants.It is driven by competitive market forces as well as government mandates and new emission regulations.Japan was the first country in the world to establish and implement heavy duty trucks and buses fuel economy standards.Other countries also have followed either by establishing direct fuel economy standards or greenhouse gas(GHG) emissions standards which are directly tied to fuel economy.This paper is discussing that heavy duty diesel engine lubricants can contribute on fuel economy.The contribution of various aspects of engine oil formulations on fuel economy will be discussed such as lubricant viscosity grade,lubricant additives and friction modifiers.In this paper,the evaluation discussions are based on fuel economy measurements in some bench tests,standardized laboratory engine tests and field tests.

Use of Diesel Engine and Surface-Piercing Propeller to Achieve Fuel Savings for Inshore Fishing Boats

Fishing is a major local industry in Malaysia, particularly in rural areas. However, the rapidly increasing price of fuel is seriously affecting the industry＇s viability. At present, outboard petrol engines are the preferred choice for use in small-scale fishing boats because they deliver the advantages of high speed and low weight, they are easy to install, and they use minimal space. Petrol outboard engines are known to consume a greater amount of fuel than inboard diesel engines, but installing diesel engines with conventional submerged propellers in existing small-scale fishing boats is not economically viable because major hullform modifications and extra expenditure are required to achieve this. This study describes a proposal to enable reductions in fuel consumption by introducing the combined use of a diesel engine and Surface-Piercing Propeller （SPP）. An analysis of fuel consumption reduction is presented, together with an economic feasibility study. Resulting data reveal that the use of the proposed modifications would save 23.31 liters of fuel per trip （40.75%） compared to outboard motors, equaling annual savings of RM 3962 per year.

Cooling of a Diesel Reformate Fuelled Solid Oxide Fuel Cell by Internal Reforming of Methane： A Modelling Study

In this paper a system combining a diesel reformer using catalytic partial oxidation （CPOX） with the Solid Oxide Fuel Cell （SOFC） for Auxiliary Power Unit （APU） applications is modeled with respect to the cooling effect provided by internal reforming of methane in anode gas channel. A model mixture consisting of 80% n-hexadecane and 20%..!-methylnaphthalin is used to simulate the commercial diesel. The modelling consists of several steps. First, equilibrium gas composition at the exit of CPOX reformer is modelled in terms oxygen to car- bon （O/C） ratio, fuel utilization ratio and anode gas recirculation. Second, product composition, especially methane content, is determined for the me.th.an, ation process at the operating temperatures ra：ng!ng from 500 ℃to 520 ℃.Finally, the cooling power provided by internal reforming of methane in SOFC fuel channel is calculated for two concepts to increase the methane content of the diesel reformate. The results show that the first concept, operating the diesel reformer at low O/C ratio and/or, recirculation rat!o, is not realizable due to high probability of coke formation, whereas the second concept, combining a methanation process with CPOX, can provide a significant cool- ing effect in addition to the conventional c？oling concept which needs higher levels of excess air.

Study on Separating Naphthenic Acids from Diesel Fuel by Microwave Irradiation

The microwave technology was introduced to separate naphthenic acids from diesel fuel. Thedecrease of zeta-potential of electric double layer on the W/O interface and the reduction of diesel fuelviscosity were responsible for the accelerated separation of naphthenic acids under microwave irradiation.The influences of dosage of alkali compound solvent (Mp/MT), irradiation pressure, irradiation time,irradiation power, the settling time and oil phase-to-solvent phase volume ratio (O/S) had been investigated.The optimum process conditions for the refining process were determined. The removal of naphthenicacids reached 98.4% when the optimum conditions were proposed as follows: Mp/MT=1.5, 0.05MPa, 6 min,375W, 25min and O/S=10, respectively. The diesel recovery could reach 99.3% and the quality of thetreated diesel oil was good enough to meet the specification of GB252-2000.

Endurance Test of Biodiesel Fueled Tractor Engine

A diesel engine for tractor was tested for 250 hours of durability with biodiesel fuel of 100%. An engine test cycle was designed based on the ISO test code of off-road vehicle. Eight test conditions, combination of three engine speeds and eight engine loads, were applied to the engine endurance test, and the engine was operated for eight hours in a day. Power output, fuel consumption rate, exhaust gas quality and particulate matter （PM） were measured and discussed. For the extensive 250 hours of the tractor diesel engine endurance test no significant changes of power output, fuel consumption rate, exhaust gas quality and PM were monitored and authors could not find any difference in the engine patterns of the two fuels of BDF100 and light oil. During all the engine endurance test conditions, no abrupt stopping was encountered but because of temperature down by the cold season the endurance test could not carried out for some periods. PMs were collected and the average F＇M was 0.027 g/kw which was far below than Tier 4 diesel engine PM of 0.3 g/kw h defined by US EPA PM of the diesel engine clas,;. Overall even 100% biodiesel can be an alternative fuel for light oil for diesel engine operation with some considerations for cold sea：son use.

Preparation and emission characteristics of ethanol-diesel fuel blends

The preparation of ethanol-diesel fuel blends and their emission characteristics were investigated. Results showed the absolute ethanol can dissolve in diesel fuel at an arbitrary ratio and a small quantity of water(0.2%) addition can lead to the phase separation of blends. An organic additive was synthesized and it can develop the ability of resistance to water and maintain the stability of ethanol-diesel-trace amounts of water system. The emission characteristics of 10%, 20%, and 30% ethanol-diesel fuel blends, with or without additives, were compared with those of diesel fuel in a direct injection(DI) diesel engine. The experimental results indicated that the blend of ethanol with diesel fuel significantly reduced the concentrations of smoke, hydrocarbon(HC), and carbon monoxide(CO) in exhaust gas. Using 20% ethanol-diesel fuel blend with the additive of 2% of the total volume, the optimum mixing ratio was achieved, at which the bench diesel engine testing showed a significant decrease in exhaust gas. Bosch smoke number was reduced by 55%, HC emission by 70%, and CO emission by 45%, at 13 kW/1540 r/min. However, ethanol-diesel fuel blends produced a few ppm acetaldehydes and more ethanol in exhaust gas.

Miscibility of Ethanol in Diesel Fuels

The primary barrier to the use of ethanol in diesel fuel is the poor miscibility at lower temperatures. The miscibilities of ethanol in 19 diesel fuels having a wide variation in compositions were evaluated by testing their phase separation temperatures. The result shows that aromatic contents and intermediate distillate temperatures have a significant impact on miscibility limits. The FCC diesels, which contain up to 50% of aromatics, exhibit different phase behavior trends in comparison with straight-run diesels and other diesel fuels.

Effects of Far-Infrared Composite Materials Doped with Rare Earth on Physicochemical Properties of Diesel Fuel

The rare earth, far-infrared natural mineral and clay were compounded to prepare the far-infrared composite materials. The effects of the far-infrared composite materials on the physicochemical properties of diesel fuel were studied. It shows that the composite materials can radiate higher intensity of far infrared; and the surface tension, viscosity and flash point decrease when the diesel fuel is dealt with the composite materials containing rare earth elements; and then the available effect mechanisms of the composite materials on the properties of diesel fuel were investigated by testing the activity changes of arene.

Effect of Emulsified Diesel Fuel on Performance and Emissions Characteristics

Diesel fuel has been known as the most effective fuel but it is known as a fuel which produces harmful emissions. Later, emulsified diesel fuel was introduced as a better solution but there is no sufficient research data concerning combustion of emulsified fuel. The present work carried out a simulation of non-surfactant emulsified diesel fuel where composition of water in emulsion varied from 0% to 20% to determine the ratio of water to diesel which is more effective in reducing the exhaust emissions especially NOx. For this simulation,5% of water in diesel without surfactant was able to reduce NOx?up to 35%. It was shown that as the percentage of water increases, the power from that fuel combustion reduces.

Study on Application of Pour Point Depressant for Diesel Fuel

Taking into account the actual crude slate processed at the refinery, it is necessary to make reasonable combination and blending of crude oils. In order to cope with high wax content in diesel fuel it is proposed to appropriately regulate the refining process scheme and add additives to refined products. This measure after being applied in the production practice has brought about good results and has met the needs of commercial production.

Application of Microwave Technology for Desulfurization of Diesel Fuel

The microwave technology was introduced for the desulfurization of diesel fuel. The atmosphericsecond side-cut diesel fraction, which was supplied by Liaohe Petrochemical Company, was desulfurized by anoxidation process under microwave irradiation. Hydrogen peroxide (H2O2), can oxidize the sulfur compounds indiesel fuel selectively and convert them into sulfones. Based on the rule of dissolution by similar substances,these sulfones are removed from diesel fuel because they could be dissolved in solvent phase. So the sulfurcontent of diesel fuel is decreased. The influence of the concentration of oxidizing reagent, solvent phase to oilphase volume ratio (S/O), irradiation pressure, irradiation time, and the irradiation power have been investigated.The optimum conditions for the refining process was determined. The sulfur removal rate was 59.7% under theoptimum conditions of 8%H2O2, S/O=0.25, 0.05MPa, 6 min, and 375W, respectively. When no microwave irradia-tion was applied, the removal rate was 11.5% only.

Measurement of Emissions from a Passenger Truck Fueled with Biodiesel from Different Feedstocks

Biodiesel has generated increased interest recently as an alternative to petroleum-derived diesel. Due to its high oxygen content, biodiesel typically burns more completely than petroleum diesel, and thus has lower emissions of hydrocarbons (HC), carbon monoxide (CO), and particulate matter (PM). However, biodiesel may increase or decrease nitrogen oxide (NOx) and carbon dioxide (CO2) emissions, depending on biodiesel feedstock, engine type, and test cycle. The purpose of this study was to compare emissions from 20% blends of biodiesel made from 4 feedstocks (soybean oil, canola oil, waste cooking oil, and animal fat) with emissions from ultra low sulfur diesel (ULSD). Emissions of NOx and CO2 were made under real-world driving conditions using a Horiba On-Board Measurement System OBS-1300 on a highway route and arterial route;emissions of NOx, CO2, HC, CO, and PM were measured in a controlled setting using a chassis dynamometer with Urban Dynamometer Drive Schedule. Dynamometer test results showed statistically significant lower emissions of HC, CO, and PM from all B20 blends compared to ULSD. For CO2, both on-road testing (arterial, highway, and idling) and dynamometer testing showed no statistically significant difference in emissions among the B20 blends and ULSD. For NOx, dynamometer testing showed only B20 from soybean oil to have statistically significant higher emissions. This is generally consistent with the on-road testing, which showed no statistically significant difference in NOx emissions between ULSD and the B20 blends.