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基于Fitts’law的Twiddler点击绩效模型实验 被引量:2
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作者 黄志奇 陈东义 王厚军 《电子测量与仪器学报》 CSCD 2008年第5期33-37,共5页
Fitts'law是一种被广泛用于点击设备绩效模型评估的重要准则,Twiddle是可穿戴计算机最常用的输入设备。为了对Twiddler的点击绩效进行评估,参考Paul Fitts所采用的反复敲击试验,建立了Twiddler点击绩效测试系统。根据D/W取值的不... Fitts'law是一种被广泛用于点击设备绩效模型评估的重要准则,Twiddle是可穿戴计算机最常用的输入设备。为了对Twiddler的点击绩效进行评估,参考Paul Fitts所采用的反复敲击试验,建立了Twiddler点击绩效测试系统。根据D/W取值的不同,设计了11种测试条件,使得Twiddler点击难度系数ID在1~5的范围内。在大量试验数据的分析基础上,根据不同的Fitts'law表达式,建立了3种不同的Twiddler点击绩效模型。结合AIC模型判定准则,得到了最优的Twiddler点击绩效模型,模型反映出Twiddler的点击绩效较低,操控比较困难,这些与Twiddler的实际特性相符。在进行可穿戴计算机GUI设计时,应使Twiddler的点击难度系数ID小于4。 展开更多
关键词 Twiddler fitts'law 绩效模型 AIC判定准则
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基于Fitts定律的指挥信息系统人机交互优化设计
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作者 褚瑞峰 张华 +2 位作者 孙星 王彬 刘华静 《无线互联科技》 2024年第15期72-76,共5页
为优化指挥信息系统在交互操作上的流畅性,降低操作时间成本,提升信息化武器的作战效能,文章选取指挥系统中典型场景为研究对象,基于相关领域性特有的强交互性、时效性、严谨性等特征,并结合Fitts定律完成设计策略制定,解决原有指挥系... 为优化指挥信息系统在交互操作上的流畅性,降低操作时间成本,提升信息化武器的作战效能,文章选取指挥系统中典型场景为研究对象,基于相关领域性特有的强交互性、时效性、严谨性等特征,并结合Fitts定律完成设计策略制定,解决原有指挥系统界面设计中人机交互问题。文章通过分析与实践发现Fitts定理能够在指挥信息系统设计过程中为设计师提供较强的指导性作用,为相关领域设计提供方法论层面指引与参考。 展开更多
关键词 fitts定律 指挥信息系统 人机交互 时间成本
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Fitts’定律实验的设计与实现
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作者 樊丽华 王晓英 +1 位作者 严海芳 王晓青 《微型电脑应用》 2014年第8期8-10,17,共4页
首先,介绍了Fitts’定律,然后,设计了验证Fitts’定律的实验,最后,使用Matlab7.0.1对数据进行了统计和分析。实验结果有效地验证了Fitts’定律,并且Fitts’Law(错误率为4%)得到的预测模型精度高于通过"effective width"Fitts... 首先,介绍了Fitts’定律,然后,设计了验证Fitts’定律的实验,最后,使用Matlab7.0.1对数据进行了统计和分析。实验结果有效地验证了Fitts’定律,并且Fitts’Law(错误率为4%)得到的预测模型精度高于通过"effective width"Fitts’Law得到的预测模型。 展开更多
关键词 fitts'定律 预测模型 距离 大小
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基于Fitts定律的虚拟现实小目标选择模型 被引量:5
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作者 尤乾 吕健 +2 位作者 李阳 金昱潼 赵子健 《工程设计学报》 CSCD 北大核心 2019年第4期416-422,共7页
为了准确地选择虚拟现实人机交互过程中的小目标,避免因手和控制器抖动导致选择精度较低等情况,提出了一种基于Fitts定律的虚拟情境中有效测算小目标交互时间的方法。首先,类比图形用户界面中的移动距离和目标宽度,明确了虚拟情境中Fitt... 为了准确地选择虚拟现实人机交互过程中的小目标,避免因手和控制器抖动导致选择精度较低等情况,提出了一种基于Fitts定律的虚拟情境中有效测算小目标交互时间的方法。首先,类比图形用户界面中的移动距离和目标宽度,明确了虚拟情境中Fitts定律的适用性。其次,设计实验并对虚拟情境下的Fitts公式进行回归分析,得到相关系数R^2=0.8963,说明预测时间与真实时间有偏差。接着,利用MATLABcftool拟合工具箱对不同目标尺寸进行回归分析,结合方差分析发现拟合直线的截距与目标尺寸之间显著相关,结合虚拟情境的Fitts公式建立了虚拟现实小目标选择模型。然后,对新模型进行多元回归分析,确定相关系数R^2=0.976 7,说明新模型能够有效预测捕获小目标的时间;分析了运动方向对交互时间的影响,结果表明新模型在不同运动方向下都具有良好的适用性,能够有效指导虚拟情境交互任务中良好目标尺寸的计算。最后,以某VR(virtual reality,虚拟现实)隧道救援体验系统为例进行实验评估。实验结果表明,利用该模型能够在获取虚拟现实小目标时有效减少用户的交互时间,提供更好的用户体验。研究结果能为相关设计开发人员确定虚拟情境下的界面布局提供有效指导,并一定程度上优化用户的交互体验。 展开更多
关键词 虚拟现实 人机交互 小目标 fitts定律
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A Spectral Convolutional Neural Network Model Based on Adaptive Fick’s Law for Hyperspectral Image Classification
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作者 Tsu-Yang Wu Haonan Li +1 位作者 Saru Kumari Chien-Ming Chen 《Computers, Materials & Continua》 SCIE EI 2024年第4期19-46,共28页
Hyperspectral image classification stands as a pivotal task within the field of remote sensing,yet achieving highprecision classification remains a significant challenge.In response to this challenge,a Spectral Convol... Hyperspectral image classification stands as a pivotal task within the field of remote sensing,yet achieving highprecision classification remains a significant challenge.In response to this challenge,a Spectral Convolutional Neural Network model based on Adaptive Fick’s Law Algorithm(AFLA-SCNN)is proposed.The Adaptive Fick’s Law Algorithm(AFLA)constitutes a novel metaheuristic algorithm introduced herein,encompassing three new strategies:Adaptive weight factor,Gaussian mutation,and probability update policy.With adaptive weight factor,the algorithmcan adjust theweights according to the change in the number of iterations to improve the performance of the algorithm.Gaussianmutation helps the algorithm avoid falling into local optimal solutions and improves the searchability of the algorithm.The probability update strategy helps to improve the exploitability and adaptability of the algorithm.Within the AFLA-SCNN model,AFLA is employed to optimize two hyperparameters in the SCNN model,namely,“numEpochs”and“miniBatchSize”,to attain their optimal values.AFLA’s performance is initially validated across 28 functions in 10D,30D,and 50D for CEC2013 and 29 functions in 10D,30D,and 50D for CEC2017.Experimental results indicate AFLA’s marked performance superiority over nine other prominent optimization algorithms.Subsequently,the AFLA-SCNN model was compared with the Spectral Convolutional Neural Network model based on Fick’s Law Algorithm(FLA-SCNN),Spectral Convolutional Neural Network model based on Harris Hawks Optimization(HHO-SCNN),Spectral Convolutional Neural Network model based onDifferential Evolution(DE-SCNN),SpectralConvolutionalNeuralNetwork(SCNN)model,and SupportVector Machines(SVM)model using the Indian Pines dataset and PaviaUniversity dataset.The experimental results show that the AFLA-SCNN model outperforms other models in terms of Accuracy,Precision,Recall,and F1-score on Indian Pines and Pavia University.Among them,the Accuracy of the AFLA-SCNN model on Indian Pines reached 99.875%,and the Accuracy on PaviaUniversity reached 98.022%.In conclusion,our proposed AFLA-SCNN model is deemed to significantly enhance the precision of hyperspectral image classification. 展开更多
关键词 Adaptive Fick’s law algorithm spectral convolutional neural network metaheuristic algorithm intelligent optimization algorithm hyperspectral image classification
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A Note on the Validity of the Shannon Formulation for Fitts’ Index of Difficulty
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作者 Ian Scott MacKenzie 《Open Journal of Applied Sciences》 2013年第6期360-368,共9页
The three most common variations of Fitts’ index of difficulty are the Fitts formulation, the Welford formulation, and the Shannon formulation. A recent paper by Hoffmann [1] critiqued the three and concluded that th... The three most common variations of Fitts’ index of difficulty are the Fitts formulation, the Welford formulation, and the Shannon formulation. A recent paper by Hoffmann [1] critiqued the three and concluded that the Fitts and Welford formulations are valid and that the Shannon formulation is invalid. In this paper, we challenge Hoffmann’s position regarding the Shannon formulation. It is argued that the issue of validity vs. invalidity is ill-conceived, given that Fitts’ law is a “model by analogy” with no basis in human motor control. The relevant questions are of utility: Does a model work? How well? Is it useful? Where alternative formulations exist, they may be critiqued and compared for strengths and weaknesses, but validity is an irrelevant construct. In a reanalysis of data from Fitts’ law experiments, models built using the Shannon formulation are (re)affirmed to be as good as, and generally better than, those built using the Fitts or Welford formulation. 展开更多
关键词 fitts’ law INDEX of DIFFICULTY shannon FORMULATION Effective Target WIDTH sCIENTIFIC Method
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EXPERIMENTAL STUDY ON DARCY′S LAW IN HELE-SHAW CELLS 被引量:1
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作者 孙建红 许金造 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 2003年第2期134-139,共6页
The basic physics of unsteady Hele-Shaw flow at high Reynolds numbers is mainly studied by an experimental measurement. In order to confirm the Darcy′s law in Hele-Shaw cell, since there is an analogy between flow in... The basic physics of unsteady Hele-Shaw flow at high Reynolds numbers is mainly studied by an experimental measurement. In order to confirm the Darcy′s law in Hele-Shaw cell, since there is an analogy between flow in cells and that in porous media, progressive water waves are utilized to build an unsteady flow in a Hele-Shaw cell, and which complex wave number is measured by a wave height gauge. Meanwhile, theoretical analyses are used to compare with experimental data. Result shows Darcy′s Law is not exactly correct for unsteady Hele-Shaw flows, and it is expected to conduct a modified Darcy′s Law. 展开更多
关键词 Hele-shaw cell surface water wave Darcy′s law
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Benford’s Law在煤矿安全数据真实性判定中的应用和优化研究
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作者 冯英华 《长沙大学学报》 2017年第5期33-37,共5页
首先阐述了对煤矿安全数据进行真实性判定的重要性.然后,提出了基于Benford’s Law的煤矿安全数据真实性的判定方法,并通过对淮南地矿井安全数据的分析,证明了该方法的科学性和有效性.最后,对该方法进行优化,使得优化后的方法在煤矿安... 首先阐述了对煤矿安全数据进行真实性判定的重要性.然后,提出了基于Benford’s Law的煤矿安全数据真实性的判定方法,并通过对淮南地矿井安全数据的分析,证明了该方法的科学性和有效性.最后,对该方法进行优化,使得优化后的方法在煤矿安全数据的真实性判定上,不仅区分度高而且运算量小. 展开更多
关键词 安全数据 Benford’s law 真实性 判定 优化
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THE LAW OF ITERATED LOGARITHM FOR R/S STATISTICS 被引量:5
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作者 林正炎 《Acta Mathematica Scientia》 SCIE CSCD 2005年第2期326-330,共5页
A law of iterated logarithm for R/S statistics with the help of the strong approximations of R/S statistics by functions of a Wiener process is shown.
关键词 R/s statistics law of iterated logarithm strong approximation
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PRECISE RATES IN THE LAW OF THE ITERATED LOGARITHM FOR R/S STATISTICS 被引量:3
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作者 Wu Hongmei Wen Jiwei 《Applied Mathematics(A Journal of Chinese Universities)》 SCIE CSCD 2006年第4期461-466,共6页
Let{Xn;n≥1}be a sequence of i.i.d, random variables with finite variance,Q(n)be the related R/S statistics. It is proved that lim ε↓0 ε^2 ∑n=1 ^8 n log n/1 P{Q(n)≥ε√2n log log n}=2/1 EY^2,where Y=sup0≤t... Let{Xn;n≥1}be a sequence of i.i.d, random variables with finite variance,Q(n)be the related R/S statistics. It is proved that lim ε↓0 ε^2 ∑n=1 ^8 n log n/1 P{Q(n)≥ε√2n log log n}=2/1 EY^2,where Y=sup0≤t≤1B(t)-inf0≤t≤sB(t),and B(t) is a Brownian bridge. 展开更多
关键词 law of the iterated logarithm R/s statistics tail probability.
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结合Cannikin’s Law的离线数据增广方法研究
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作者 邓雪 赵皓 +2 位作者 张静 梅菠萍 张华 《计算机工程与应用》 CSCD 北大核心 2023年第1期207-212,共6页
数据增广是提升深度学习模型性能的有效方法之一。针对多类别目标检测任务中检测性能不平衡问题,提出一种针对“短板类别”(检测性能远低于模型平均检测性能的类别)的离线数据增广方法。受Cannikin’s Law的启发,采用基于复制粘贴(copy-... 数据增广是提升深度学习模型性能的有效方法之一。针对多类别目标检测任务中检测性能不平衡问题,提出一种针对“短板类别”(检测性能远低于模型平均检测性能的类别)的离线数据增广方法。受Cannikin’s Law的启发,采用基于复制粘贴(copy-paste)机制的场景多样性增广方法。随机采集训练集中“短板类别”实例区域,通过相似性度量机制选取训练集中增广目标样本进行随机粘贴。为了降低随机粘贴导致的遮挡问题,采用基于自遮挡(cut-replace)机制的增广方法提升模型遮挡表达能力。通过截取样本自身区域,对特征表达最显著区域进行遮挡。实验表明,FCOS目标检测框架在PASCAL VOC数据上的平均检测精度(mean average precision,mAP)从79.10%提升到83.90%,其中短板类别更为显著,提升了20.8个百分点。在MS-COCO数据上平均检测精度提升了0.9个百分点。 展开更多
关键词 数据增广 Cannikin’s law 相似性度量机制 自遮挡 目标检测
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Strong Law of Large Numbers and Complete Convergence for Sequences of -Mixing Random Variables 被引量:3
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作者 GAN Shixin CHEN Pingyan QIU Dehua 《Wuhan University Journal of Natural Sciences》 CAS 2007年第2期211-217,共7页
We give some theorems of strong law of large numbers and complete convergence for sequences of φ-mixing random variables. In particular, Wittmann's strong law of large numbers and Teicher's strong law of large nnum... We give some theorems of strong law of large numbers and complete convergence for sequences of φ-mixing random variables. In particular, Wittmann's strong law of large numbers and Teicher's strong law of large nnumbers for independent random variables are generalized to the case of φ -minxing random variables. 展开更多
关键词 strong law of large numbers complete convergence φ-mixing random variable sequence Wittmann's strong law oflarge numbers Teicher's strong law of large numbers
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PHOTOREALISTIC COMPUTER GRAPHICS FORENSICS BASED ON LEADING DIGIT LAW 被引量:3
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作者 Xu Bo Wang Junwen Liu Guangjie Dai Yuewei 《Journal of Electronics(China)》 2011年第1期95-100,共6页
As the advent and growing popularity of image rendering software,photorealistic computer graphics are becoming more and more perceptually indistinguishable from photographic images.If the faked images are abused,it ma... As the advent and growing popularity of image rendering software,photorealistic computer graphics are becoming more and more perceptually indistinguishable from photographic images.If the faked images are abused,it may lead to potential social,legal or private consequences.To this end,it is very necessary and also challenging to find effective methods to differentiate between them.In this paper,a novel leading digit law,also called Benford's law,based method to identify computer graphics is proposed.More specifically,statistics of the most significant digits are extracted from image's Discrete Cosine Transform(DCT) coefficients and magnitudes of image's gradient,and then the Support Vector Machine(SVM) based classifiers are built.Results of experiments on the image datasets indicate that the proposed method is comparable to prior works.Besides,it possesses low dimensional features and low computational complexity. 展开更多
关键词 Leading digit law Benford’s law Digital image forensic Computer graphics
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Noether's theorem for non-conservative Hamilton system based on El-Nabulsi dynamical model extended by periodic laws 被引量:5
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作者 龙梓轩 张毅 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第11期359-367,共9页
This paper focuses on the Noether symmetries and the conserved quantities for both holonomic and nonholonomic systems based on a new non-conservative dynamical model introduced by E1-Nabulsi. First, the E1-Nabulsi dyn... This paper focuses on the Noether symmetries and the conserved quantities for both holonomic and nonholonomic systems based on a new non-conservative dynamical model introduced by E1-Nabulsi. First, the E1-Nabulsi dynamical model which is based on a fractional integral extended by periodic laws is introduced, and E1-Nabulsi-Hamilton's canoni- cal equations for non-conservative Hamilton system with holonomic or nonholonomic constraints are established. Second, the definitions and criteria of E1-Nabulsi-Noether symmetrical transformations and quasi-symmetrical transformations are presented in terms of the invariance of E1-Nabulsi-Hamilton action under the infinitesimal transformations of the group. Fi- nally, Noether's theorems for the non-conservative Hamilton system under the E1-Nabulsi dynamical system are established, which reveal the relationship between the Noether symmetry and the conserved quantity of the system. 展开更多
关键词 Noether's theorem non-conservative Hamilton system E1-Nabulsi dynamical model fractionalintegral extended by periodic laws
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Criteria for Beverloo's scaling law 被引量:2
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作者 Sheng Zhang Ping Lin +3 位作者 Guanghui Yang Jiang-Feng Wan Yuan Tian Lei Yang 《Chinese Physics B》 SCIE EI CAS CSCD 2019年第1期628-633,共6页
Beverloo's scaling law can describe the flow rate of grains discharging from hoppers. In this paper, we show that the Beverloo's scaling law is valid for varying material parameters. The flow rates from a hopp... Beverloo's scaling law can describe the flow rate of grains discharging from hoppers. In this paper, we show that the Beverloo's scaling law is valid for varying material parameters. The flow rates from a hopper with different hopper and orifice sizes(D, D_0) are studied by running large-scale simulations. When the hopper size is fixed, the numerical results show that Beverloo's law is valid even if the orifice diameter is very large and then the criteria for this law are discussed.To eliminate the effect of walls, it is found that the criteria can be suggested as D-D_0≥ 40 d or D/D_0≥ 2. Interestingly,it is found that there is still a scaling relation between the flow rate and orifice diameter if D/D_0 is fixed and less than 2.When the orifice diameter is close to the hopper size, the velocity field changes and the vertical velocities of grains above the free fall region are much larger. Then, the free fall arch assumption is invalid and Beverloo's law is inapplicable. 展开更多
关键词 Beverloo’s law ORIFICE DIAMETER HOPPER size discrete element method
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A novel image encryption scheme based on Keplers third law and random Hadamard transform 被引量:3
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作者 罗玉玲 周戎龙 +2 位作者 刘俊秀 丘森辉 曹弋 《Chinese Physics B》 SCIE EI CAS CSCD 2017年第12期146-159,共14页
In this paper, a novel image encryption scheme based on Keplers third law and random Hadamard transform is proposed to ensure the security of a digital image. First, a set of Kepler periodic sequences is generated to ... In this paper, a novel image encryption scheme based on Keplers third law and random Hadamard transform is proposed to ensure the security of a digital image. First, a set of Kepler periodic sequences is generated to permutate image data, which is characteristic of the plain-image and the Keplers third law. Then, a random Hadamard matrix is constructed by combining the standard Hadamard matrix with the hyper-Chen chaotic system, which is used to further scramble the image coefficients when the image is transformed through random Hadamard transform. In the end, the permuted image presents interweaving diffusion based on two special matrices, which are constructed by Kepler periodic sequence and chaos system. The experimental results and performance analysis show that the proposed encrypted scheme is highly sensitive to the plain-image and external keys, and has a high security and speed, which are very suitable for secure real-time communication of image data. 展开更多
关键词 Kepler&#39s third law random Hadamard transform interweaving diffusion security
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Henry's Law constant for phosphine in seawater:determination and assessment of influencing factors 被引量:2
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作者 付梅 俞志明 +1 位作者 卢光远 宋秀贤 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2013年第4期860-866,共7页
The Henry's Law constant (k) for phosphine in seawater was determined by multiple phase equilibration combined with headspace gas chromatography. The effects of pH, temperature, and salinity on k were studied. The ... The Henry's Law constant (k) for phosphine in seawater was determined by multiple phase equilibration combined with headspace gas chromatography. The effects of pH, temperature, and salinity on k were studied. The k value for phosphine in natural seawater was 6.415 at room temperature (approximately 23℃). This value increases with increases in temperature and salinity, but no obvious change was observed at different pH levels. At the same temperature, there was no significant difference between the k for phosphine in natural seawater and that in artificial seawater. This implies that temperature and salinity are major determining factors for k in marine environment. Double linear regression with Henry's Law constants for phosphine as a function of temperature and salinity confirmed our observations. These results provide a basis for the measurement of trace phosphine concentrations in seawater, and will be helpful for future research on the status of phosphine in the oceanic biogeochemical cycle of phosphorus. 展开更多
关键词 PHOsPHINE Henry's law constant seawater influencing factors multiple phase equilibration
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NOETHER’S CONSERVATION LAWS OF HOLONOMIC NONCONSERVATIVE DYNAMICAL SYSTEMS IN GENERALIZED MECHANICS 被引量:2
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作者 乔永芬 岳庆文 董永安 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 1994年第9期877-883,共7页
In the present paper, three kinds of forms for Noether’s conservation laws of hol-onomic nonconservative dynamical systems in generalized mechanics are given.
关键词 generalized mechanics Hamilton canonical equation Raitzincanonical equation Noether’s conservation law
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Atomic level deposition to extend Moore’s law and beyond 被引量:9
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作者 Rong Chen Yi-Cheng Li +2 位作者 Jia-Ming Cai Kun Cao Han-Bo-Ram Lee 《International Journal of Extreme Manufacturing》 2020年第2期29-52,共24页
In the past decades,Moore’s law drives the semiconductor industry to continuously shrink the critical size of transistors down to 7 nm.As transistors further downscaling to smaller sizes,the law reaches its limitatio... In the past decades,Moore’s law drives the semiconductor industry to continuously shrink the critical size of transistors down to 7 nm.As transistors further downscaling to smaller sizes,the law reaches its limitation,and the increase of transistors density on the chip decelerates.Up to now,extreme ultraviolet lithography has been used in some key steps,and it is facing alignment precision and high costs for high-volume manufacturing.Meanwhile,the introduction of new materials and 3D complex structures brings serious challenges for top-down methods.Thus,bottom-up schemes are believed to be necessary methods combined with the top-down processes.In this article,atomic level deposition methods are reviewed and categorized to extend Moore’s law and beyond.Firstly,the deposition brings lateral angstrom resolution to the vertical direction as well as top-down etching,such as double patterning,transfer of nanowires,deposition of nanotubes,and so on.Secondly,various template-assisted selective deposition methods including dielectric templates,inhibitors and correction steps have been utilized for the alignment of 3D complex structures.Higher resolution can be achieved by inherently selective deposition,and the underlying selective mechanism is discussed.Finally,the requirements for higher precision and efficiency manufacturing are also discussed,including the equipment,integration processes,scale-up issues,etc.The article reviews low dimensional manufacturing and integration of 3D complex structures for the extension of Moore’s law in semiconductor fields,and emerging fields including but not limited to energy,catalysis,sensor and biomedicals. 展开更多
关键词 Moore’s law atomic level deposition high resolution selective deposition ALIGNMENT
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Reinvestigation of the Henry's law constant for hydrogen peroxide with temperature and acidity variation 被引量:1
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作者 Daoming Huang,Zhongming Chen The State Key Laboratory of Environmental Simulation and Pollution Control,College of Environmental Sciences and Engineering,Peking University,Beijing 100871,China. 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2010年第4期570-574,共5页
Hydrogen peroxide is not only an important oxidant in itself; it also serves as both sink and temporary reservoir for other important oxidants including HOx (OH and HO2) radicals and O3 in the atmosphere. Its partit... Hydrogen peroxide is not only an important oxidant in itself; it also serves as both sink and temporary reservoir for other important oxidants including HOx (OH and HO2) radicals and O3 in the atmosphere. Its partitioning between gas and aqueous phases in the atmosphere, usually described by its Henry's law constant (KH), significantly influences its role in atmospheric processes. Large discrepancies between the KH values reported in previous work, however, have created uncertainty for atmospheric modelers. Based on our newly developed online instrumentation, we have re-determined the temperature and acidity dependence of KH for hydrogen peroxide at an air pressure of (0.960 ± 0.013) atm (1 atm = 1.01325 × 10^5 Pa). The results indicated that the temperature dependence of KH for hydrogen peroxide fits to the Van't Hoff equation form, expressed as lnKH = a/T - b, and a = -△H/R, where KH is in M/atm (M is mol/L), T is in degrees Kelvin, R is the ideal gas constant, and AH is the standard heat of solution. For acidity dependence, results demonstrated that the KH value of hydrogen peroxide appeared to have no obvious dependence on decreasing pH level (from pH 7 to pH 1). Combining the dependence of both temperature and acidity, the obtained a and b were 7024 ± 138 and 11.97 ± 0.48, respectively, AH was (58.40 ± 1.15) kJ/(K.mol), and the uncertainties represent σ. Our determined KH values for hydrogen peroxide will therefore be of great use in atmospheric models. 展开更多
关键词 hydrogen peroxide Henry's law constant ATMOsPHERE ACIDITY
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