The electrochemical CO_(2) reduction reaction(CO_(2)RR) to controllable chemicals is considered as a promising pathway to store intermittent renewable energy. Herein, a set of catalysts based on copper-nitrogendoped c...The electrochemical CO_(2) reduction reaction(CO_(2)RR) to controllable chemicals is considered as a promising pathway to store intermittent renewable energy. Herein, a set of catalysts based on copper-nitrogendoped carbon xerogel(Cu-N-C) are successfully developed varying the copper amount and the nature of the copper precursor, for the efficient CO_(2)RR. The electrocatalytic performance of Cu-N-C materials is assessed by a rotating ring-disc electrode(RRDE), technique still rarely explored for CO_(2)RR. For comparison, products are also characterized by online gas chromatography in a H-cell. The as-synthesized Cu-NC catalysts are found to be active and highly CO selective at low overpotentials(from -0.6 to -0.8 V vs.RHE) in 0.1 M KHCO_(3), while H_(2) from the competitive water reduction appears at larger overpotentials(-0.9 V vs. RHE). The optimum copper acetate-derived catalyst containing Cu-N_(4) moieties exhibits a CO_(2)-to-CO turnover frequency of 997 h^(-1) at -0.9 V vs. RHE with a H_(2)/CO ratio of 1.8. These results demonstrate that RRDE configuration can be used as a feasible approach for identifying electrolysis products from CO_(2)RR.展开更多
Due to the fact that conventional heuristic attribute reduction algorithms are poor in running efficiency and difficult in accomplishing the co-evolutionary reduction mechanism in the decision table, an adaptive multi...Due to the fact that conventional heuristic attribute reduction algorithms are poor in running efficiency and difficult in accomplishing the co-evolutionary reduction mechanism in the decision table, an adaptive multicascade attribute reduction algorithm based on quantum-inspired mixed co-evolution is proposed. First, a novel and efficient self- adaptive quantum rotation angle strategy is designed to direct the participating populations to mutual adaptive evolution and to accelerate convergence speed. Then, a multicascade model of cooperative and competitive mixed co-evolution is adopted to decompose the evolutionary attribute species into subpopulations according to their historical performance records, which can increase the diversity of subpopulations and select some elitist individuals so as to strengthen the sharing ability of their searching experience. So the global optimization reduction set can be obtained quickly. The experimental results show that, compared with the existing algorithms, the proposed algorithm can achieve a higher performance for attribute reduction, and it can be considered as a more competitive heuristic algorithm on the efficiency and accuracy of minimum attribute reduction.展开更多
Attribute reduction in the rough set theory is an important feature selection method, but finding a minimum attribute reduction has been proven to be a non-deterministic polynomial (NP)-hard problem. Therefore, it i...Attribute reduction in the rough set theory is an important feature selection method, but finding a minimum attribute reduction has been proven to be a non-deterministic polynomial (NP)-hard problem. Therefore, it is necessary to investigate some fast and effective approximate algorithms. A novel and enhanced quantum-inspired shuffled frog leaping based minimum attribute reduction algorithm (QSFLAR) is proposed. Evolutionary frogs are represented by multi-state quantum bits, and both quantum rotation gate and quantum mutation operators are used to exploit the mechanisms of frog population diversity and convergence to the global optimum. The decomposed attribute subsets are co-evolved by the elitist frogs with a quantum-inspired shuffled frog leaping algorithm. The experimental results validate the better feasibility and effectiveness of QSFLAR, comparing with some representa- tive algorithms. Therefore, QSFLAR can be considered as a more competitive algorithm on the efficiency and accuracy for minimum attribute reduction.展开更多
Ninety-four patients with lumbar intervertebral disc herniation were enrolled in this study. Of these, 48 were treated with Feng's Spinal Manipulation, hot fomentation, and bed rest (treatment group). The remaining...Ninety-four patients with lumbar intervertebral disc herniation were enrolled in this study. Of these, 48 were treated with Feng's Spinal Manipulation, hot fomentation, and bed rest (treatment group). The remaining 46 patients were treated with hot fomentation and bed rest only (control group). After 3 weeks of treatment, clinical parameters including the angle of straight-leg raising, visual analogue scale pain score, and Japanese Orthopaedic Association score for low back pain were improved. The treatment group had significantly better improvement in scores than the control group. Magnetic resonance myelography three-dimensional reconstruction imaging of the vertebral canal demonstrated that filling of the compressed nerve root sleeve with cerebrospinal fluid increased significantly in the treatment group. The diameter of the nerve root sleeve was significantly larger in the treatment group than in the control group. However, the sagittal diameter index of the herniated nucleus pulposus and the angle between the nerve root sleeve and the thecal sac did not change significantly in either the treatment or control groups. The effectiveness of Feng's Spinal Manipulation for the treatment of symptoms associated with lumbar intervertebral disc herniation may be attributable to the relief of nerve root compression, without affecting the herniated nucleus pulposus or changing the morphology or position of the nerve root.展开更多
Electrochemical reduction of dissolved oxygen in seawater on metals is of great importance for corrosion studies. The present paper studied cathodic reduction of dissolved oxygen on Q235 carbon steel in 3.5% sodium ch...Electrochemical reduction of dissolved oxygen in seawater on metals is of great importance for corrosion studies. The present paper studied cathodic reduction of dissolved oxygen on Q235 carbon steel in 3.5% sodium chloride (NaCl) solutions by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), rotating disk electrode (RDE) and rotating ring-disk electrode (RRDE). The cyclic voltammetric results demonstrated the cathodic process on Q235 carbon steel in O2-saturated 3.5% NaCl solution contains three reactions: dissolved oxygen reduction, iron oxides reduction and hydrogen evolution. The peak potential of oxygen reduction reaction (ORR) is - 0.85 V vs Ag/AgCl, 3 molL^-1 KCI. The EIS results indicated that the ORR occurring on Q235 carbon steel is a 4-electron process and that no finite diffusion is caused by the intermediate of H2O2 produced by ORR. The RDE and RRDE voltammograms confirmed the EIS results and it was found that the number of transferred electrons for ORR was nearly 4, i.e., dissolved oxygen reduced to water.展开更多
The Sun has solar rotation;nevertheless, many evidences have suggested that different latitude of the Sun rotates in different speed, which is now known as differential rotation. This work calculates the solar rotatio...The Sun has solar rotation;nevertheless, many evidences have suggested that different latitude of the Sun rotates in different speed, which is now known as differential rotation. This work calculates the solar rotation speeds near the equator and 30? in the northern hemisphere using Fixed-Point Arithmetic method. The calculated results show a greater speed at the equator than the speed at 30?, indicating that the speed decreases as the latitude becomes higher. .展开更多
Narrowband radar has been successfully used for high resolution imaging of fast rotating targets by exploiting their micro-motion features.In some practical situations,however,the target image may suffer from aliasing...Narrowband radar has been successfully used for high resolution imaging of fast rotating targets by exploiting their micro-motion features.In some practical situations,however,the target image may suffer from aliasing due to the fixed pulse repetition interval(PRI)of traditional radar scheme.In this work,the random PRI signal associated with compressed sensing(CS)theory was introduced for aliasing reduction to obtain high resolution images of fast rotating targets.To circumvent the large-scale dictionary and high computational complexity problem arising from direct application of CS theory,the low resolution image was firstly generated by applying a modified generalized Radon transform on the time-frequency domain,and then the dictionary was scaled down by random undersampling as well as the atoms extraction according to those strong scattering areas of the low resolution image.The scale-down-dictionary CS(SDD-CS)processing scheme was detailed and simulation results show that the SDD-CS scheme for narrowband radar can achieve preferable images with no aliasing as well as acceptable computational cost.展开更多
The measurement of an extremely small magneto-optical polarization rotation angle with high sensitivity is integral to many scientific and technological applications. In this Letter, we have presented a technique base...The measurement of an extremely small magneto-optical polarization rotation angle with high sensitivity is integral to many scientific and technological applications. In this Letter, we have presented a technique based on Faraday modulation combined with the optical differential method to measure an extremely small polari- zation rotation angle with high sensitivity. The theoretical and experimental results show that common mode noise is reduced appreciably and signal to noise ratio is enhanced. The effectiveness of this technique has been demonstrated by measuring the Verdet constant of terbium gallium garnet glass and measuring the small polari- zation rotation angle. A sensitivity of enhancement of one order of magnitude has been achieved using differ- ential detection based on Faraday modulation.展开更多
Discrete Tomography(DT)is a technology that uses image projection to reconstruct images.Its reconstruction problem,especially the binary image(0–1matrix)has attracted strong attention.In this study,a fixed point iter...Discrete Tomography(DT)is a technology that uses image projection to reconstruct images.Its reconstruction problem,especially the binary image(0–1matrix)has attracted strong attention.In this study,a fixed point iterative method of integer programming based on intelligent optimization is proposed to optimize the reconstructedmodel.The solution process can be divided into two procedures.First,the DT problem is reformulated into a polyhedron judgment problembased on lattice basis reduction.Second,the fixed-point iterativemethod of Dang and Ye is used to judge whether an integer point exists in the polyhedron of the previous program.All the programs involved in this study are written in MATLAB.The final experimental data show that this method is obviously better than the branch and bound method in terms of computational efficiency,especially in the case of high dimension.The branch and bound method requires more branch operations and takes a long time.It also needs to store a large number of leaf node boundaries and the corresponding consumptionmatrix,which occupies a largememory space.展开更多
基金Grant PID2020-115848RB-C21 "STORELEC" projectTED2021-129694B-C22 "DEFY-CO2" project funded by MCIN/AEI/10.13039/501100011033+3 种基金LMP253_ (2)1 project funded by Gobierno de AragónGrant IJC2019-041874-I funded by the MCIN/AEI/10.13039/501100011033CSIC for her JAE Intro ICU 2021-ICB-04 grantthe Y2020/EMT-6419 "CEOTRES" project funded by the Comunidad Autonoma de Madrid。
文摘The electrochemical CO_(2) reduction reaction(CO_(2)RR) to controllable chemicals is considered as a promising pathway to store intermittent renewable energy. Herein, a set of catalysts based on copper-nitrogendoped carbon xerogel(Cu-N-C) are successfully developed varying the copper amount and the nature of the copper precursor, for the efficient CO_(2)RR. The electrocatalytic performance of Cu-N-C materials is assessed by a rotating ring-disc electrode(RRDE), technique still rarely explored for CO_(2)RR. For comparison, products are also characterized by online gas chromatography in a H-cell. The as-synthesized Cu-NC catalysts are found to be active and highly CO selective at low overpotentials(from -0.6 to -0.8 V vs.RHE) in 0.1 M KHCO_(3), while H_(2) from the competitive water reduction appears at larger overpotentials(-0.9 V vs. RHE). The optimum copper acetate-derived catalyst containing Cu-N_(4) moieties exhibits a CO_(2)-to-CO turnover frequency of 997 h^(-1) at -0.9 V vs. RHE with a H_(2)/CO ratio of 1.8. These results demonstrate that RRDE configuration can be used as a feasible approach for identifying electrolysis products from CO_(2)RR.
基金The National Natural Science Foundation of China(No. 61139002,61171132)the Funding of Jiangsu Innovation Program for Graduate Education (No. CXZZ11_0219 )+2 种基金the Natural Science Foundation of Jiangsu Province (No. BK2010280)the Open Project of Jiangsu Provincial Key Laboratory of Computer Information Processing Technology (No. KJS1023)the Applying Study Foundation of Nantong(No. BK2011062)
文摘Due to the fact that conventional heuristic attribute reduction algorithms are poor in running efficiency and difficult in accomplishing the co-evolutionary reduction mechanism in the decision table, an adaptive multicascade attribute reduction algorithm based on quantum-inspired mixed co-evolution is proposed. First, a novel and efficient self- adaptive quantum rotation angle strategy is designed to direct the participating populations to mutual adaptive evolution and to accelerate convergence speed. Then, a multicascade model of cooperative and competitive mixed co-evolution is adopted to decompose the evolutionary attribute species into subpopulations according to their historical performance records, which can increase the diversity of subpopulations and select some elitist individuals so as to strengthen the sharing ability of their searching experience. So the global optimization reduction set can be obtained quickly. The experimental results show that, compared with the existing algorithms, the proposed algorithm can achieve a higher performance for attribute reduction, and it can be considered as a more competitive heuristic algorithm on the efficiency and accuracy of minimum attribute reduction.
基金supported by the National Natural Science Foundation of China(6113900261171132)+4 种基金the Funding of Jiangsu Innovation Program for Graduate Education(CXZZ11 0219)the Natural Science Foundation of Jiangsu Education Department(12KJB520013)the Applying Study Foundation of Nantong(BK2011062)the Open Project Program of State Key Laboratory for Novel Software Technology,Nanjing University(KFKT2012B28)the Natural Science Pre-Research Foundation of Nantong University(12ZY016)
文摘Attribute reduction in the rough set theory is an important feature selection method, but finding a minimum attribute reduction has been proven to be a non-deterministic polynomial (NP)-hard problem. Therefore, it is necessary to investigate some fast and effective approximate algorithms. A novel and enhanced quantum-inspired shuffled frog leaping based minimum attribute reduction algorithm (QSFLAR) is proposed. Evolutionary frogs are represented by multi-state quantum bits, and both quantum rotation gate and quantum mutation operators are used to exploit the mechanisms of frog population diversity and convergence to the global optimum. The decomposed attribute subsets are co-evolved by the elitist frogs with a quantum-inspired shuffled frog leaping algorithm. The experimental results validate the better feasibility and effectiveness of QSFLAR, comparing with some representa- tive algorithms. Therefore, QSFLAR can be considered as a more competitive algorithm on the efficiency and accuracy for minimum attribute reduction.
基金supported by grants from the Key Topics of China Traditional Chinese Medicine Scientific Research Project,General Logistics Department of Chinese PLA,No.10ZYZ125the Army Medical Science and Technology the125Scientific Research Projects,Chinese PLA,No.AKJ11J004
文摘Ninety-four patients with lumbar intervertebral disc herniation were enrolled in this study. Of these, 48 were treated with Feng's Spinal Manipulation, hot fomentation, and bed rest (treatment group). The remaining 46 patients were treated with hot fomentation and bed rest only (control group). After 3 weeks of treatment, clinical parameters including the angle of straight-leg raising, visual analogue scale pain score, and Japanese Orthopaedic Association score for low back pain were improved. The treatment group had significantly better improvement in scores than the control group. Magnetic resonance myelography three-dimensional reconstruction imaging of the vertebral canal demonstrated that filling of the compressed nerve root sleeve with cerebrospinal fluid increased significantly in the treatment group. The diameter of the nerve root sleeve was significantly larger in the treatment group than in the control group. However, the sagittal diameter index of the herniated nucleus pulposus and the angle between the nerve root sleeve and the thecal sac did not change significantly in either the treatment or control groups. The effectiveness of Feng's Spinal Manipulation for the treatment of symptoms associated with lumbar intervertebral disc herniation may be attributable to the relief of nerve root compression, without affecting the herniated nucleus pulposus or changing the morphology or position of the nerve root.
基金supported by the National Natural Science Foundation of China ( Grant No 40876041)Science and Technology Basic Research Program of Qingdao (Grant No 09-1-3-16-jch)the National Key Technology Research and Development Program of China (Grant No 2007 BAB27B01)
文摘Electrochemical reduction of dissolved oxygen in seawater on metals is of great importance for corrosion studies. The present paper studied cathodic reduction of dissolved oxygen on Q235 carbon steel in 3.5% sodium chloride (NaCl) solutions by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), rotating disk electrode (RDE) and rotating ring-disk electrode (RRDE). The cyclic voltammetric results demonstrated the cathodic process on Q235 carbon steel in O2-saturated 3.5% NaCl solution contains three reactions: dissolved oxygen reduction, iron oxides reduction and hydrogen evolution. The peak potential of oxygen reduction reaction (ORR) is - 0.85 V vs Ag/AgCl, 3 molL^-1 KCI. The EIS results indicated that the ORR occurring on Q235 carbon steel is a 4-electron process and that no finite diffusion is caused by the intermediate of H2O2 produced by ORR. The RDE and RRDE voltammograms confirmed the EIS results and it was found that the number of transferred electrons for ORR was nearly 4, i.e., dissolved oxygen reduced to water.
文摘The Sun has solar rotation;nevertheless, many evidences have suggested that different latitude of the Sun rotates in different speed, which is now known as differential rotation. This work calculates the solar rotation speeds near the equator and 30? in the northern hemisphere using Fixed-Point Arithmetic method. The calculated results show a greater speed at the equator than the speed at 30?, indicating that the speed decreases as the latitude becomes higher. .
基金Projects(61171133,61271442)supported by the National Natural Science Foundation of ChinaProject(61025006)supported by the National Natural Science Foundation for Distinguished Young Scholars of ChinaProject(B110404)supported by the Innovation Program for Excellent Postgraduates of National University of Defense Technology,China
文摘Narrowband radar has been successfully used for high resolution imaging of fast rotating targets by exploiting their micro-motion features.In some practical situations,however,the target image may suffer from aliasing due to the fixed pulse repetition interval(PRI)of traditional radar scheme.In this work,the random PRI signal associated with compressed sensing(CS)theory was introduced for aliasing reduction to obtain high resolution images of fast rotating targets.To circumvent the large-scale dictionary and high computational complexity problem arising from direct application of CS theory,the low resolution image was firstly generated by applying a modified generalized Radon transform on the time-frequency domain,and then the dictionary was scaled down by random undersampling as well as the atoms extraction according to those strong scattering areas of the low resolution image.The scale-down-dictionary CS(SDD-CS)processing scheme was detailed and simulation results show that the SDD-CS scheme for narrowband radar can achieve preferable images with no aliasing as well as acceptable computational cost.
基金supported by the National Key R&D Program of China(No.2017YFB0503100)the National Science Foundation of China(NSFC)(No.61227902)
文摘The measurement of an extremely small magneto-optical polarization rotation angle with high sensitivity is integral to many scientific and technological applications. In this Letter, we have presented a technique based on Faraday modulation combined with the optical differential method to measure an extremely small polari- zation rotation angle with high sensitivity. The theoretical and experimental results show that common mode noise is reduced appreciably and signal to noise ratio is enhanced. The effectiveness of this technique has been demonstrated by measuring the Verdet constant of terbium gallium garnet glass and measuring the small polari- zation rotation angle. A sensitivity of enhancement of one order of magnitude has been achieved using differ- ential detection based on Faraday modulation.
基金funded by the NSFC under Grant Nos.61803279,71471091,62003231 and 51874205in part by the Qing Lan Project of Jiangsu,in part by the China Postdoctoral Science Foundation under Grant Nos.2020M671596 and 2021M692369+2 种基金in part by the Suzhou Science and Technology Development Plan Project(Key Industry Technology Innovation)under Grant No.SYG202114in part by the Natural Science Foundation of Jiangsu Province under Grant No.BK20200989Postdoctoral Research Funding Program of Jiangsu Province.
文摘Discrete Tomography(DT)is a technology that uses image projection to reconstruct images.Its reconstruction problem,especially the binary image(0–1matrix)has attracted strong attention.In this study,a fixed point iterative method of integer programming based on intelligent optimization is proposed to optimize the reconstructedmodel.The solution process can be divided into two procedures.First,the DT problem is reformulated into a polyhedron judgment problembased on lattice basis reduction.Second,the fixed-point iterativemethod of Dang and Ye is used to judge whether an integer point exists in the polyhedron of the previous program.All the programs involved in this study are written in MATLAB.The final experimental data show that this method is obviously better than the branch and bound method in terms of computational efficiency,especially in the case of high dimension.The branch and bound method requires more branch operations and takes a long time.It also needs to store a large number of leaf node boundaries and the corresponding consumptionmatrix,which occupies a largememory space.